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    • 5. 发明授权
    • Process for the stabilization of acrylic fibers
    • 丙烯酸纤维稳定方法
    • US4473372A
    • 1984-09-25
    • US494092
    • 1983-05-12
    • James E. KuderGeorge L. CollinsThyagaraja Sarada
    • James E. KuderGeorge L. CollinsThyagaraja Sarada
    • D01F9/22D06M10/00D06M11/34D06M101/00D06M101/16D06M101/18D06M101/28H05B1/00B06B3/00
    • D06M11/34D01F9/225D06M10/008Y10S8/12Y10S8/927
    • The present invention provides an improved process whereby the thermal stabilization of acrylic fibers is accelerated. The process comprises providing a zone of electron radiation and continuously passing a continuous length of acrylic fibrous material through the zone so as to provide an energy absorption of from about 5 to about 30 megarads. The residence time of the acrylic fibrous material in the zone of electron radiation is less than five seconds. The continuous length of acrylic fibrous material is subsequently continuously passed through a thermal stabilization zone wherein the acrylic fibrous material is heated in an oxygen-containing atmosphere provided at a temperature in the range of about 220.degree. C. to 310.degree. C. for about 10 to 30 minutes. The acrylic fibrous material formed thereby is thermally stabilized (i.e., black in appearance, retains its original fibrous configuration substantially intact, and is non-burning when subjected to an ordinary match flame). The electron radiation treatment has surprisingly been found to accelerate the desired thermal stabilization when compared to prior art processes which do not include the treatment of acrylic fibrous material by electron radiation.
    • 本发明提供了改进丙烯酸纤维的热稳定化加工方法。 该方法包括提供电子辐射区域并连续地使连续长度的丙烯酸纤维材料通过该区域,以提供约5至约30兆拉德的能量吸收。 丙烯酸纤维材料在电子辐射区域的停留时间少于5秒。 丙烯酸纤维材料的连续长度随后连续通过热稳定区,其中将丙烯酸纤维材料在约220℃至310℃的温度范围内提供的含氧气氛中加热约10分钟 至30分钟。 由此形成的丙烯酸类纤维材料是热稳定的(即,外观为黑色,保持其原始的纤维状态基本上完整,并且在经受普通火焰时不燃)。 与不包括通过电子辐射处理丙烯酸纤维材料的现有技术方法相比,发现电子辐射处理令人惊奇地加速了所需的热稳定性。