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1. 发明授权

US06268529B1 Method for the manufacture of acrylic acid 失效
标题翻译：使用碱金属，钙，铁，铋和钼的混合氧化物催化剂制造丙烯酸的方法
公开(公告)号：US06268529B1
公开(公告)日：2001-07-31
申请号：US09207837
申请日：1998-12-08
申请人： Dev Dhanaraj Suresh , Christos Paparizos , Patrick Eugene Mosier , Ying Wu , Maria Strada Friedrich , Michael J. Seely
发明人： Dev Dhanaraj Suresh , Christos Paparizos , Patrick Eugene Mosier , Ying Wu , Maria Strada Friedrich , Michael J. Seely
IPC分类号： C07C5116
CPC分类号： C07C51/252 , B01J2523/00 , C07C57/04 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/845
摘要： A process for the manufacture of acrylic acid comprising reacting propylene and oxygen (preferably in the form of air) in a reaction zone having a catalyst characterized by the following formula: AaBbCcCadFeeBifMo12Ox where A=one or more of Li, Na, K, Rb and Cs B=one or more of Mg, Sr, Mn, Ni, Co and Zn C=one or more of Ce, Cr, Al, Sb, P, Ge, Sn, Cu, V and W and a=0.01 to 1.0; b and e =1.0-10 c=0 to 5.0, preferably 0.05 to 5.0, especially preferred being 0.05 to 4.0 d and f=0.05 to 5.0, and x is a number determined by the valence requirements of the other elements present; at an elevated temperature to produce acrylic acid and acrolein.
摘要翻译：一种制备丙烯酸的方法，其包括在具有催化剂的反应区中使丙烯和氧（优选空气形式）反应，其特征在于下式：其中A = Li，Na，K，Rb和CsB中的一种或多种= Ce，Cr，Al，Sb，P，Ge，Sn，Cu，V和Wanda中的一种或多种中的一种或多种Mg，Sr，Mn，Ni，Co和ZnC = 0.01至1.0; b和e = 1.0-10c = 0〜5.0，优选为0.05〜5.0，特别优选为0.05〜4.0d，f = 0.05〜5.0，x为通过存在的其他元素的化合价要求决定的数; 产生丙烯酸和丙烯醛的温度。

2. 发明授权

US5688739A Ammoxidation catalysts containing germanium to produce high yields of acrylonitrile 失效
标题翻译：含有锗的氨氧化催化剂产生高产率的丙烯腈
公开(公告)号：US5688739A
公开(公告)日：1997-11-18
申请号：US642707
申请日：1996-05-03
申请人： Tama Lee Drenski , Maria Strada Friedrich , Christos Paparizos , Michael J. Seely , Dev Dhanaraj Suresh
发明人： Tama Lee Drenski , Maria Strada Friedrich , Christos Paparizos , Michael J. Seely , Dev Dhanaraj Suresh
IPC分类号： B01J23/31 , B01J23/887 , B01J23/14 , B01J23/16 , B01J23/28
CPC分类号： B01J23/31 , B01J23/8876
摘要： A catalyst having the atomic ratios set forth in the empirical formula below: A.sub.a B.sub.b C.sub.c Ge.sub.d Bi.sub.e Mo.sub.12 O.sub.x where A=two or more of alkali metals, In and Tl B=one or more of Mg, Mn, Ni, Co, Ca, Fe, Ce, Sm, Cr, Sb, and W; preferably B equals the combination of Fe and at least one element selected from the group consisting of Ni and Co and at least one element selected from the group consisting of Mg, Mn, Ca, Ce, Sn, Cr, Sb, and W C=one or more of Pb, Eu, B, Sn, Te and Cu a=0.05 to 5.0 b=5 to 12 c=0 to 5.0 d=0.1 to 2.0 e=0.1 to 2.0 x=the number of oxygen atoms required to satisfy the valency requirements of the other elements and b>a+c.
摘要翻译：具有以下经验式所示的原子比的催化剂：AaBbCcGedBieMo12Ox其中A =两种或更多种碱金属，In和Tl B = Mg，Mn，Ni，Co，Ca，Fe，Ce，Sm，Cr中的一种或多种，Sb和W; 优选B等于Fe和选自Ni和Co中的至少一种元素和从由Mg，Mn，Ca，Ce，Sn，Cr，Sb和WC = 1组成的组中的至少一种元素的组合。以上的Pb，Eu，B，Sn，Te和Cu a = 0.05〜5.0 b = 5〜12 c = 0〜5.0 d = 0.1〜2.0 e = 0.1〜2.0 x =满足其他元素的价格要求和b> a + c。

3. 发明授权

US5770757A Ammoxidation catalysts containing germanium to produce high yields of acrylonitrile 失效
标题翻译：含有锗的氨氧化催化剂产生高产率的丙烯腈
公开(公告)号：US5770757A
公开(公告)日：1998-06-23
申请号：US646742
申请日：1996-05-03
申请人： Tama Lee Drenski , Maria Strada Friedrich , Christos Paparizos , Michael J. Seely , Dev Dhanaraj Suresh
发明人： Tama Lee Drenski , Maria Strada Friedrich , Christos Paparizos , Michael J. Seely , Dev Dhanaraj Suresh
IPC分类号： C07C253/26 , C07C255/08 , C07C253/12
CPC分类号： C07C253/26 , Y02P20/52
摘要： A catalyst having the atomic ratios set forth in the empirical formula below: A.sub.a B.sub.b C.sub.c Ge.sub.d Bi.sub.e Mo.sub..sub.12 O.sub.x where A=two or more of alkali metals, In and Tl B=one or more of Mg, Mn, Ni, Co, Ca, Fe, Ce, Sm, Cr, Sb, and W; preferably B equals the combination of Fe and at least one element selected from the group consisting of Ni and Co and at least one element selected from the group consisting of Mg, Mn, Ca, Ce, Sn, Cr, Sb, and W C=one or more of Pb, Eu, B, Sn, Te and Cu a=0.05 to 5.0 b=5 to 12 c=0 to 5.0 d=0.1 to 2.0 e=0.1 to 2.0 x=the number of oxygen atoms required to satisfy the valency requirements of the other elements and b>a+c.
摘要翻译：具有以下经验式所示的原子比的催化剂：AaBbCcGedBieMo12Ox其中A =两种或更多种碱金属，In和Tl B = Mg，Mn，Ni，Co，Ca，Fe，Ce，Sm，Cr中的一种或多种，Sb和W; 优选B等于Fe和选自Ni和Co中的至少一种元素和从由Mg，Mn，Ca，Ce，Sn，Cr，Sb和WC = 1组成的组中的至少一种元素的组合。以上的Pb，Eu，B，Sn，Te和Cu a = 0.05〜5.0 b = 5〜12 c = 0〜5.0 d = 0.1〜2.0 e = 0.1〜2.0 x =满足其他元素的价格要求和b> a + c。

4. 发明授权

US5840648A Catalyst for the manufacture of acrylonitrile and hydrogen cyanide 失效
标题翻译：用于制造丙烯腈和氰化氢的催化剂
公开(公告)号：US5840648A
公开(公告)日：1998-11-24
申请号：US923878
申请日：1997-09-02
申请人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Maria Strada Friedrich , Tama Lee Drenski
发明人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Maria Strada Friedrich , Tama Lee Drenski
IPC分类号： B01J23/00 , B01J23/31 , B01J23/76 , B01J23/84 , B01J23/843 , B01J23/88 , B01J23/887 , B01J23/89 , B01J27/192 , B01J27/199 , B01J37/00 , B01J37/08 , C01C3/02 , C01G53/00 , C07B61/00 , C07C253/18 , C07C253/24 , C07C253/26 , C07C255/08 , B01J23/04 , B01J23/18
CPC分类号： C07C253/18 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J37/08 , C01C3/0216 , C01G53/006 , B01J2523/00 , B01J37/0045 , Y02P20/52
摘要： A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum and calcium and characterized by the following empirical formula: A.sub.a B.sub.b C.sub.c D.sub.d Fe.sub.e Bi.sub.f MO.sub.12 O.sub.x where A=one or more of Li, Na, K, Rb and Cs or mixtures thereof B=one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures thereof C=one or more of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or mixtures thereofD=one or more of Ca, Sr, Ba or mixtures thereof and a=0.01 to 1.0; b and e=1.0-10; c, d, and f=0.1 to 5.0 and x is a number determined by the valence requirements of the other elements present.
摘要翻译：一种催化剂组合物，其包含铁，铋，钼和钙的催化氧化物的络合物，其特征在于以下经验式：AaBbCcDdFeeBifMO12Ox其中A = Li，Na，K，Rb和Cs中的一种或多种或其混合物B =一种或多种 Mg，Mn，Ni，Co，Ag，Pb，Re，Cd和Zn或其混合物C = Ce，Cr，Al，Sb，P，Ge，La，Sn，V和W中的一种或多种或其混合物D = Ca，Sr，Ba或其混合物中的一种或多种，a = 0.01至1.0; b和e = 1.0-10; c，d和f = 0.1〜5.0，x是由存在的其他元素的化合价要求决定的数。

5. 发明授权

US5877108A Performance of used molybdenum based catalysts by the addition of ammonium dimolybdate 失效
标题翻译：通过加入二钼酸铵的二氧化钼基催化剂的性能
公开(公告)号：US5877108A
公开(公告)日：1999-03-02
申请号：US988589
申请日：1997-12-11
申请人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Tama Lee Drenski , Maria Strada Friedrich
发明人： Dev Dhanaraj Suresh , Christos Paparizos , Michael J. Seely , Tama Lee Drenski , Maria Strada Friedrich
IPC分类号： B01J23/28 , B01J23/30 , B01J23/34 , B01J23/64 , B01J23/88 , B01J23/92 , B01J27/057 , B01J27/192 , B01J38/00 , B01J38/68 , B01J20/34 , B01J23/90
CPC分类号： B01J23/92 , B01J38/68
摘要： A process for regenerating molybdenum containing ammoxidation catalyst comprising replacing the molybdenum loss from the catalyst during the ammoxidation reaction wherein ammonium dimolybdenum is utilized as the source for replacement of the molybdenum loss from the original catalyst.
摘要翻译：一种用于再生含钼氨氧化催化剂的方法，其包括在氨氧化反应期间代替钼催化剂的损失，其中使用铵二钼作为替代原始催化剂的钼损失的来源。

6. 发明授权

US06451730B1 Two-stage preparation of promoted V/Sb-oxide ammoxidation catalysts 失效
标题翻译：促进的V / Sb氧化物氨氧化催化剂的两阶段制备
公开(公告)号：US06451730B1
公开(公告)日：2002-09-17
申请号：US08883716
申请日：1997-06-27
申请人： Maria Strada Friedrich , Michael J. Seely , Dev Dhanaraj Suresh
发明人： Maria Strada Friedrich , Michael J. Seely , Dev Dhanaraj Suresh
IPC分类号： B01J2370
CPC分类号： C07C253/26 , B01J23/002 , B01J23/8472 , B01J2523/00 , Y02P20/52 , B01J2523/43 , B01J2523/47 , B01J2523/53 , B01J2523/55 , B01J2523/842 , C07C255/08
摘要： A process for the preparation of a promoted VSbOx catalyst comprising mixing a vanadium compound, at least a first portion of an antimony compound, and at least a portion of the support material to form a slurry, heating the slurry to remove the water, calcining the dried slurry to form a catalyst precursor, combining the catalyst precursor with a second aqueous sol containing the remaining portion of the support material and the remaining portion of the antimony compound to form a second slurry, drying the second slurry to remove the water and calcining the dried mixture to form the finished catalyst.
摘要翻译：一种用于制备促进的VSbOx催化剂的方法，包括将钒化合物，至少第一部分锑化合物和至少一部分载体材料混合以形成浆料，加热浆料以除去水，煅烧干燥的浆料以形成催化剂前体，将催化剂前体与含有载体材料的剩余部分和剩余部分的锑化合物的第二水性溶胶组合以形成第二浆料，干燥第二浆料以除去水并煅烧干燥的混合物形成成品催化剂。

7. 发明授权

US5821192A Method of improving the attrition resistance of V/SB oxide based catalyst 失效
标题翻译：提高V / SB氧化物基催化剂耐磨性的方法
公开(公告)号：US5821192A
公开(公告)日：1998-10-13
申请号：US717074
申请日：1996-09-23
申请人： Michael J. Seely , Maria Strada Friedrich , Dev Dhanaraj Suresh , Frank John Kocjancic
发明人： Michael J. Seely , Maria Strada Friedrich , Dev Dhanaraj Suresh , Frank John Kocjancic
IPC分类号： B01J23/18 , B01J23/22 , B01J37/00
CPC分类号： B01J37/0045 , B01J23/18 , B01J23/22
摘要： A process for preparing a catalyst having the following formula: V.sub.a Sb.sub.b M.sub.c O.sub.x wherein M=tin, titanium, lithium, sodium, potassium, molybdenum, tungsten, iron, chromium, cobalt, copper, gallium, niobium, tantalum, tellurium, bismuth, or mixtures thereof, a=0.1 to 5, preferably 0.1 to 3, most preferably 0.1 to 2 b=0.1 to 5, preferably 0.1 to 3, most preferably 0.1 to 2 c=0.0 to 5, preferably greater than 0 to 5, most preferably 0.01 to 3, and x is a number sufficient to satisfy the valency requirements of the elements, comprising forming an aqueous slurry comprising vanadium and antimony, adding a peptizing agent free of any lithium compounds capable of providing hydroxide ions to said slurry and spray drying said slurry to form an attrition resistant catalyst.
摘要翻译：一种制备具有下式的催化剂的方法：其中M =锡，钛，锂，钠，钾，钼，钨，铁，铬，钴，铜，镓，铌，钽，碲，铋或其混合物中的VaSbbMcOx， a = 0.1〜5，优选为0.1〜3，最优选为0.1〜2，b = 0.1〜5，优选为0.1〜3，最优选为0.1〜2，c = 0.0〜5，优选为0〜5，最优选为0.01〜，x是足以满足元素的化合价要求的数字，包括形成含有钒和锑的含水浆料，将不含能够提供氢氧根离子的任何锂化合物的胶溶剂加入到所述浆料中并喷雾干燥所述浆料以形成耐磨耗催化剂。

8. 发明授权

US06413485B2 Ammoxidation of a mixture of ketones to acetonitrile and HCN 失效
标题翻译：酮与乙腈和HCN的混合物的氨氧化
公开(公告)号：US06413485B2
公开(公告)日：2002-07-02
申请号：US09320937
申请日：1999-05-27
申请人： Michael J. Seely , Sanjay Purushottam Godbole , Dev Dhanaraj Suresh
发明人： Michael J. Seely , Sanjay Purushottam Godbole , Dev Dhanaraj Suresh
IPC分类号： C01C302
CPC分类号： C07C253/26 , C01C3/0212 , C01C3/0225 , C07C253/24 , Y02P20/52 , C07C255/08
摘要： A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.
摘要翻译：包括将选自丙烯和丙烷，粗酮和/或至少两种酮，氨和空气的混合物的烃引入到丙烯和丙烯的制备过程中产生的HCN和乙腈的产率的方法，含有氨氧化催化剂的反应区，在升高的温度下使所述催化剂上的烃，酮，氨和氧反应生成丙烯腈，氰化氢和乙腈，并从反应器回收丙烯腈，氰化氢和乙腈。

9. 发明授权

US06667020B2 Ammoxidation of a mixture of ketones to acetonitrile and HCN 失效
标题翻译：酮与乙腈和HCN的混合物的氨氧化
公开(公告)号：US06667020B2
公开(公告)日：2003-12-23
申请号：US10016703
申请日：2001-12-10
申请人： Michael J. Seely , Sanjay Purushottam Godbole , Dev Dhanaraj Suresh
发明人： Michael J. Seely , Sanjay Purushottam Godbole , Dev Dhanaraj Suresh
IPC分类号： C01C302
CPC分类号： C07C253/26 , C01C3/0212 , C01C3/0225 , C07C253/24 , Y02P20/52 , C07C255/08
摘要： A process increasing the yield of both HCN and acetonitrile produced during the manufacture of acrylonitrile comprising introducing a hydrocarbon selected from the group consisting of propylene and propane, a crude ketone and/or a mixture of at least two ketones, ammonia and air, into a reaction zone containing an ammoxidation catalyst, reacting the. hydrocarbon, the ketone, ammonia and oxygen over said catalyst at an elevated temperature to produce acrylonitrile, hydrogen cyanide and acetonitrile, and recovering the acrylonitrile, hydrogen cyanide and acetonitrile from the reactor.
摘要翻译：包括将选自丙烯和丙烷，粗酮和/或至少两种酮，氨和空气的混合物的烃引入到丙烯和丙烯的制备过程中产生的HCN和乙腈的产率的方法，反应区含有氨氧化催化剂，碳氢化合物，酮，氨和氧在所述催化剂上升高以产生丙烯腈，氰化氢和乙腈，并从反应器回收丙烯腈，氰化氢和乙腈。

10. 发明授权

US06458742B1 Catalyst for the manufacture of acrylonitrile 有权
标题翻译：用于制造丙烯腈的催化剂
公开(公告)号：US06458742B1
公开(公告)日：2002-10-01
申请号：US09641380
申请日：2000-08-17
申请人： Christos Paparizos , Michael J. Seely , Maria S. Friedrich , Dev D. Suresh
发明人： Christos Paparizos , Michael J. Seely , Maria S. Friedrich , Dev D. Suresh
IPC分类号： B01J2310
CPC分类号： C07C253/26 , B01J23/8876 , Y02P20/52 , C07C255/08
摘要： A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum, cobalt, cerium, antimony, at least one of nickel or magnesium, and at least one of lithium, sodium, potassium, rubidium, or thallium, and characterized by the following empirical formula: AaBbCcFedBieCofCegSbhMomOx wherein A is at least one of Cr, P, Sn, Te, B, Ge, Zn, In, Mn, Ca, W, or mixtures thereof B is at least one of Li, Na, K, Rb, Cs, Tl, or mixtures thereof C is least one of Ni, Mg or mixtures thereof a is 0 to 4.0 b is 0.01 to 1.5 c is 1.0 to 10.0 d is 0.1 to 5.0 e is 0.1 to 2.0 f is 0.1 to 10.0 g is 0.1 to 2.0 h is 0.1 to 2.0 m is 12.0 to 18.0 and x is a number determined by the valence requirements of the other elements present. The catalyst is useful in processes for the ammoxidation of an olefin selected from the group consisting of propylene, isobutylene or mixtures thereof, to acrylonitrile, methacrylonitrile and mixtures thereof, respectively.
摘要翻译：一种催化剂组合物，其包含铁，铋，钼，钴，铈，锑，镍或镁中的至少一种和锂，钠，钾，铷或铊中的至少一种的催化氧化物的络合物，其特征在于以下经验式：其中A为Cr，P，Sn，Te，B，Ge，Zn，In，Mn，Ca，W或其混合物中的至少一种B为Li，Na，K，Rb，Cs， T1或其混合物C是Ni，Mg或其混合物中的至少一种，a为0〜4.0b为0.01〜1.5c为1.0〜10.0d，0.1〜5.0e为0.1〜2.0f，0.1〜10.0g为0.1〜2.0h 0.1至2.0μm为12.0至18.0，x为由其它元素的化合价要求确定的数。催化剂可用于将选自丙烯，异丁烯或其混合物的烯烃的氨氧化反应，丙烯腈，甲基丙烯腈及其混合物。

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