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1. 发明授权

US07161020B2 Phosphite compounds and novel phosphite metal complexes 失效
标题翻译：亚磷酸酯化合物和新型亚磷酸盐金属络合物
公开(公告)号：US07161020B2
公开(公告)日：2007-01-09
申请号：US10485811
申请日：2002-08-13
申请人： Detlef Selent , Armin Boerner , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
发明人： Detlef Selent , Armin Boerner , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/02
CPC分类号： C07F9/65744 , C07C45/50 , C07F15/0073 , C07C47/02
摘要： Phosphites of the formula I and phosphite-metal complexes, their preparation and their use in catalytic reactions, in particular in processes for the hydroformylation of olefins, are described.
摘要翻译：描述了式I的亚磷酸酯和亚磷酸盐 - 金属络合物，它们的制备及其在催化反应中的用途，特别是在烯烃的加氢甲酰化方法中的用途。

2. 发明授权

US07495133B2 Method for hydroformylating olefins in the presence of organophosphoric compounds 失效
标题翻译：在有机磷化合物存在下加氢甲酰化烯烃的方法
公开(公告)号：US07495133B2
公开(公告)日：2009-02-24
申请号：US10593330
申请日：2005-01-27
申请人： Cornelia Borgmann , Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moeller , Dieter Hess
发明人： Cornelia Borgmann , Detlef Selent , Armin Boerner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moeller , Dieter Hess
IPC分类号： C07C45/50
CPC分类号： C07C45/50 , C07F9/6578 , C07F9/65846 , C07F9/65848 , C07C47/02
摘要： (EN) The invention relates to the use of novel organophosphoric compounds and metal complexes thereof in catalytic reactions, and to the hydroformylation of olefins in the presence of these compounds.
摘要翻译：（EN）本发明涉及新型有机磷化合物及其金属络合物在催化反应中的应用，以及在这些化合物存在下烯烃加氢甲酰化的用途。

3. 发明授权

US07217828B2 Phosphinine compounds and metal complexes thereof 失效
标题翻译：膦化合物及其金属络合物
公开(公告)号：US07217828B2
公开(公告)日：2007-05-15
申请号：US10911499
申请日：2004-08-05
申请人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
发明人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
IPC分类号： C07F9/02
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

4. 发明申请

US20050043279A1 Novel phosphinine compounds and metal complexes thereof 失效
标题翻译：新型次膦化合物及其金属配合物
公开(公告)号：US20050043279A1
公开(公告)日：2005-02-24
申请号：US10911499
申请日：2004-08-05
申请人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
发明人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6564 , C07F9/6584 , C07F15/00 , C07F15/06 , C07F9/547 , A61K31/66
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

5. 发明申请

US20070282130A1 Method for Hydroformylating Olefins in the Presence of Organophosphoric Compounds 失效
标题翻译：在有机磷化合物存在下加氢甲酰化烯烃的方法
公开(公告)号：US20070282130A1
公开(公告)日：2007-12-06
申请号：US10593330
申请日：2005-01-27
申请人： Cornelia Borgmann , Detlef Selent , Armin Borner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moller , Dieter Hess
发明人： Cornelia Borgmann , Detlef Selent , Armin Borner , Klaus-Diether Wiese , Dagmara Ortmann , Oliver Moller , Dieter Hess
IPC分类号： C07F9/02 , C07C45/77
CPC分类号： C07C45/50 , C07F9/6578 , C07F9/65846 , C07F9/65848 , C07C47/02
摘要： (EN) The invention relates to the use of novel organophosphoric compounds and metal complexes thereof in catalytic reactions, and to the hydroformylation of olefins in the presence of these compounds.
摘要翻译：（EN）本发明涉及新型有机磷化合物及其金属络合物在催化反应中的应用，以及在这些化合物存在下烯烃的加氢甲酰基化。

6. 发明授权

US06570033B2 Bisphosphite compounds and their metal complexes 有权
标题翻译：二亚磷酸酯化合物及其金属络合物
公开(公告)号：US06570033B2
公开(公告)日：2003-05-27
申请号：US09984263
申请日：2001-10-29
申请人： Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
发明人： Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
IPC分类号： C07F908
CPC分类号： C07F9/65746 , C07C45/50 , C07F9/65744 , C07F15/0073 , C07C47/02
摘要： A bisphosphite of the formula I wherein R1, R2, R3 and R4 are each hydrogen, an aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon or heterocyclic or aliphatic-heterocyclic group having from 1 to 50 carbon atoms, F, Cl, Br, I, —CF3, —OR7, —COR7, —CO2R7, —CO2M, —SR7, —SO2R7, —SOR7, —SO3R7, —SO3M, —CO2NR7R8, NR7R8, N═CR7R8, NH2, where R1 to R4 are identical or different and may be covalently linked to one another; R7 and R8 are each hydrogen, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and may be identical or different; M is an alkali metal, alkaline earth metal, ammonium or phosphonium ion; Q is a substituted or unsubstituted divalent aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms where HO-Q-OH is a diol; W and X are each a substituted or unsubstituted aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms which may be identical or different or covalently linked to one another, provided that when the phosphite oxygens linked to W and X are each linked to an aromatic ring, then they are linked to different aromatic rings, metal complexes thereof, and a method for the hydroformylation of olefins.
摘要翻译：式I的二亚磷酸酯，其中R 1，R 2，R 3和R 4各自为氢，具有1至50个碳原子的脂族，脂环族，脂族 - 脂环族，芳族，芳族 - 芳族，脂族 - 芳族烃或杂环或脂族杂环基，F，Cl，Br，I，-CF 3，-OR 7，-COR 7，-CO 2 R 7，-CO 2 M，-SR 7，-SO 2 R 7，-SOR 7，-SO 3 R 7，-SO 3 M，-CO 2 NR 7 R 8，NR 7 R 8，N = CR 7 R 8，NH 2，其中R 1至R 4相同或不同并且可以彼此共价连接; R 7和R 8各自为氢，具有1至25个碳原子的取代或未取代的脂族或芳族烃基，并且可以相同或不同; M 是碱金属，碱土金属，铵或鏻离子; Q是具有1至50个碳原子的取代或未取代的二价脂族，脂环族，脂族 - 脂环族，芳族，脂族 - 芳族烃，杂环或脂族杂环基团，其中 HO-Q-OH是二醇; W和X各自是取代或未取代的脂族基，脂环族，脂族 - 脂环族，芳族，芳族 - 芳族，脂族 - 芳族烃，具有1至50个碳原子的杂环或脂族 - 杂环基，其可以相同或不同或共价连接，条件是当亚磷酸酯连接到W和X各自连接到芳香环，然后它们连接到不同的芳环，其金属络合物和烯烃的加氢甲酰化方法。

7. 发明授权

US07009068B2 Phosphite compounds and the metal complexes thereof 失效
标题翻译：亚磷酸酯化合物及其金属络合物
公开(公告)号：US07009068B2
公开(公告)日：2006-03-07
申请号：US10485817
申请日：2002-08-07
申请人： Reinhard Schmutzler , Ion Neda , Christine Kunze , Armin Börner , Detlef Selent , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
发明人： Reinhard Schmutzler , Ion Neda , Christine Kunze , Armin Börner , Detlef Selent , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/02
CPC分类号： C07F15/0073 , B01J23/464 , B01J31/185 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65746 , C07C47/02
摘要： Phosphites of the formula I or II and their metal complexes, their preparation and the use of the phosphites as ligands in catalytic reactions, in particular in processes for the hydroformylation of olefins, are described.
摘要翻译：描述了式I或II的亚磷酸酯及其金属络合物，它们的制备和在催化反应中亚磷酸酯作为配体的用途，特别是在烯烃的加氢甲酰化方法中。

8. 发明授权

US06818770B2 Phosphinine compounds and metal complexes thereof 失效
标题翻译：膦化合物及其金属络合物
公开(公告)号：US06818770B2
公开(公告)日：2004-11-16
申请号：US09989077
申请日：2001-11-21
申请人： Detlef Selent , Armin Börner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Röttger
发明人： Detlef Selent , Armin Börner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Röttger
IPC分类号： C07F928
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

9. 发明申请

US20100036143A1 BISPHOSPHITE LIGANDS FOR HYDROFORMYLATION CATALYZED BY TRANSITION METALS 有权
标题翻译：用于过渡金属催化氢化的双相配位体
公开(公告)号：US20100036143A1
公开(公告)日：2010-02-11
申请号：US12515967
申请日：2007-11-13
申请人： Detlef Selent , Armin Boerner , Burkard Kreidler , Dieter Hess , Klaus-Diether Wiese
发明人： Detlef Selent , Armin Boerner , Burkard Kreidler , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/06 , C07C45/00
CPC分类号： C07F9/65746 , C07B41/06
摘要： The invention relates to a bisphosphite of the formula I where X=a divalent substituted or unsubstituted bisalkylene or bisarylene radical, Y=a divalent substituted or unsubstituted bisarylene or bisalkylene radical, Z=oxygen or NR9, and R1, R2, R3, R4 are identical or different, substituted or unsubstituted, linked, unlinked or fused aryl or heteroaryl radicals and R9 is hydrogen or a substituted or unsubstituted alkyl or aryl radical, a process for preparing it and also the use of this phosphite in catalysis in particular in the catalytic hydroformylation of olefins or organic compounds having C—C double bonds.
摘要翻译：本发明涉及式I的双亚磷酸酯，其中X =二价取代或未取代的双亚烷基或双亚芳基，Y =二价取代或未取代的双亚芳基或双亚烷基，Z =氧或NR 9，并且R 1，R 2，R 3，R 4为相同或不同的取代或未取代的连接的，未连接的或稠合的芳基或杂芳基，R 9为氢或取代或未取代的烷基或芳基，其制备方法，以及该亚磷酸酯在催化中的用途，特别是在催化烯烃或具有CC双键的有机化合物的羰基化。

10. 发明授权

US08404902B2 Method for separating 1-butene from C4-containing hydrocarbon streams by hydroformylation 有权
标题翻译：通过加氢甲酰化从含C4烃流中分离1-丁烯的方法
公开(公告)号：US08404902B2
公开(公告)日：2013-03-26
申请号：US12992032
申请日：2009-04-28
申请人： Burkard Kreidler , Klaus-Diether Wiese , Dieter Hess , Detlef Selent , Armin Boerner
发明人： Burkard Kreidler , Klaus-Diether Wiese , Dieter Hess , Detlef Selent , Armin Boerner
IPC分类号： C07C45/50 , C07C29/16
CPC分类号： C07C7/173 , C07C45/50 , C07C11/09 , C07C47/02
摘要： The invention relates to a method for separating 1-butene from C4-containing hydrocarbon mixtures, comprising isobutene and 1-butene, by hydroformylation, wherein the catalytic system used is made of one of the transition metals of the group 8 to 10, preferably rhodium, and a bisphosphite ligand of the formula (I), where X is a divalent substituted or unsubstituted bisalkylene or bisarylene group having one or more heteroatom(s), Y is a divalent substituted or unsubstituted bisarylene or bisalkylene group having one or more heteroatom(s), Z is oxygen or NR9, and R1, R2, R3, R4 are identical or different, substituted or unsubstituted, linked, unlinked or condensed aryl or heteroaryl groups, and R9 is hydrogen or a substituted or unsubstituted alkyl or aryl group having one or more heteroatom(s), wherein the bisphosphite ligand of the formula (I) is used in an excess of a molar ratio of 100:1 to 1:1 to the transition metal, and that with a 1-butene conversion of more than 95% less than 5% of the present isobutene is reacted method for separating 1-butene from c4-containing hydrocarbon streams by hydroformylation.
摘要翻译：本发明涉及通过加氢甲酰化从含有C4的烃混合物中分离出1-丁烯的方法，其中包括异丁烯和1-丁烯，其中使用的催化体系由8-10族的过渡金属之一制成，优选为铑和式（I）的双亚磷酸酯配体，其中X是具有一个或多个杂原子的二价取代或未取代的双亚烷基或双亚芳基，Y是具有一个或多个杂原子的二价取代或未取代的双亚芳基或双亚烷基 s），Z是氧或NR 9，R 1，R 2，R 3，R 4是相同或不同的取代或未取代的连接，未连接或稠合的芳基或杂芳基，并且R 9是氢或被取代或未取代的烷基或芳基，一个或多个杂原子，其中式（I）的二亚磷酸酯配体以过渡金属的过量摩尔比为100:1至1:1使用，而1-丁烯转化率更高比不到95％％的本异丁烯是通过加氢甲酰化从含C4的烃流中分离1-丁烯的反应方法。

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