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1. 发明授权

US5541284A Method for processing crude polyoxymethylene 失效
标题翻译：粗聚甲醛加工方法
公开(公告)号：US5541284A
公开(公告)日：1996-07-30
申请号：US406141
申请日：1995-03-20
申请人： Detlef Arnoldi , Udo Gropp , Edwin Nun
发明人： Detlef Arnoldi , Udo Gropp , Edwin Nun
IPC分类号： C08G2/28 , C08G2/10
CPC分类号： C08G2/28
摘要： The subject invention relates to method for processing crude polyoxymethylene in which the isolation of unstable components from crude polyoxymethylene, such as residual monomers which are at least partly in the form of cyclic formaldehyde derivatives, is effected by treatment of the crude polyoxymethylene with an inert gaseous medium. The method of the invention is characterized in that the gaseous medium contains at least 10 volume % of water vapor, and less than 0.1 volume % of a volatile base, and/or less than 1 volume % of a volatile solvent. In an alternative variant method, the gaseous medium contains at least 10 volume % of water vapor and the treatment occurs at a temperature between 114.degree. C and the softening temperature of the crude polyoxymethylene and at a pressure of less 1.2 .multidot.10.sup.5 Pa.
摘要翻译：本发明涉及用于处理粗聚甲醛的方法，其中从粗聚甲醛分离不稳定组分，例如至少部分为环状甲醛衍生物形式的残留单体，其通过用惰性气体处理粗聚甲醛来实现中。本发明的方法的特征在于，气态介质含有至少10体积％的水蒸气和少于0.1体积％的挥发性碱，和/或少于1体积％的挥发性溶剂。在另一变体方法中，气体介质含有至少10体积％的水蒸气，并且处理在114℃和粗聚甲醛的软化温度之间并且在1.2×10 5 Pa以下的压力下进行。

2. 发明授权

US5218041A Polyoxymethylene molding materials having improved thermal stability and reduced formaldehyde emission 失效
标题翻译：具有改善的热稳定性和降低甲醛释放的聚甲基乙烯模塑材料
公开(公告)号：US5218041A
公开(公告)日：1993-06-08
申请号：US772244
申请日：1991-10-07
申请人： Detlef Arnoldi , Edwin Nun
发明人： Detlef Arnoldi , Edwin Nun
IPC分类号： C08K3/04 , C08K5/13 , C08L25/08 , C08L25/14 , C08L33/06 , C08L33/10 , C08L59/00 , C08L61/28
CPC分类号： C08L59/00 , C08L25/08 , C08L25/14 , C08L33/06 , C08L33/10 , C08L61/28
摘要： Polyoxymethylene molding materials having improved thermal stability and reduced formaldehyde emission consisting essentially of a polyoxymethylene as the main component and containing in addition, relative in each instance to the weight of the polyoxymethylene, 0.1 to 10% by weight of an endocopolymerizate, 0.05 to 3% by weight of a phenolic antioxidant, 0 to 5% by weight carbon black and 0 to 3% by weight of further additives customary in polyoxymethylene molding materials.
摘要翻译：具有改进的热稳定性和甲醛释放降低的聚甲醛成型材料基本上以聚甲醛为主要成分，并且另外相对于聚甲醛的重量相对含量为0.1〜10重量％，内缀合物为0.05〜3重量％的酚类抗氧化剂，0-5重量％的炭黑和0-3重量％的聚氧亚甲基成型材料中通常的其它添加剂。

3. 发明授权

US5693709A Polyoxymethylene with improved acid stability, process for production and use thereof 失效
标题翻译：具有改善的酸稳定性的聚甲醛，其制备方法和用途
公开(公告)号：US5693709A
公开(公告)日：1997-12-02
申请号：US701800
申请日：1996-08-26
申请人： Edwin Nun , Stephanie Schauhoff , Detlef Arnoldi
发明人： Edwin Nun , Stephanie Schauhoff , Detlef Arnoldi
IPC分类号： C08L59/00 , C08L71/00 , C08L75/04 , C08K5/05
CPC分类号： C08L59/00 , C08L71/00 , C08L75/04
摘要： Polyoxymethylene with improved acid stability, process for production and use thereof. By adding 0.01 to 5 parts of an alkali metal salt of a polybasic acid, for example oxalic acid, citric acid and/or 0.01 to 5 parts of a polyalkylene glycol, for example polyethylene glycol and/or 0.1 to 100 parts of a thermoplastic polyurethane, each related to 100 parts of a polyoxymethylene, this polymer is stabilized against attack by acids, wherein in particular the combination of an alkali metal salt, in particular an oxalate, with small proportions of a thermoplastic polyurethane is advantageous. The proportion of thermoplastic polyurethane may be reduced when the thermoplastic polyurethane has a Shore A hardness of 70 to 96. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The products are useful when exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
摘要翻译：具有改善的酸稳定性的聚甲醛，其制备方法和用途。通过加入0.01至5份多元酸的碱金属盐，例如草酸，柠檬酸和/或0.01至5份聚亚烷基二醇，例如聚乙二醇和/或0.1至100份热塑性聚氨酯各自与100份聚甲醛相关，该聚合物被抗酸侵蚀稳定，其中特别是碱金属盐，特别是草酸盐与小比例的热塑性聚氨酯的组合是有利的。当热塑性聚氨酯的肖氏A硬度为70至96时，热塑性聚氨酯的比例可能会降低。在酸作用下稳定的POM的重量损失可能小于不稳定的POM的重量损失的3％。当暴露于酸性剂如灌溉系统，洗碗机，卫生设备时，该产品是有用的。

4. 发明授权

US5393813A Polyoxymethylene having improved acid stability 失效
标题翻译：具有改善的酸稳定性的聚甲醛
公开(公告)号：US5393813A
公开(公告)日：1995-02-28
申请号：US140357
申请日：1993-10-22
申请人： Stephanie Schauhoff , Edwin Nun , Detlef Arnoldi
发明人： Stephanie Schauhoff , Edwin Nun , Detlef Arnoldi
IPC分类号： C08K5/09 , C08K5/3477 , C08K5/3492 , C08L59/00 , C08L61/28 , C08L71/02 , C08L75/04 , C08J5/10 , C08K5/34 , C08L59/02
CPC分类号： C08K5/34924 , C08L59/00 , C08L61/28 , C08L71/02 , C08L75/04
摘要： By adding melamine cyanurate, polyoxymethylene is stabilized against acid attack, wherein in particular as little as under 3 parts of MCA per 100 parts of POM are effective. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The product is useful in products which are exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
摘要翻译：通过加入三聚氰胺氰尿酸酯，聚甲醛稳定，防止酸侵蚀，其中特别是每100份POM少于3份MCA的有效性。在酸作用下稳定的POM的重量损失可能小于不稳定的POM的失重量的3％。该产品适用于暴露于酸性剂（如灌溉系统，洗碗机，卫生设备）的产品中。

5. 发明授权

US08563010B2 Method for preventing mold formation by using hydrophobic materials, and mold-controlling agent for building parts 失效
标题翻译：通过使用疏水性材料防止模具成型的方法，以及用于建筑部件的模具控制剂
公开(公告)号：US08563010B2
公开(公告)日：2013-10-22
申请号：US10551841
申请日：2004-02-09
申请人： Edwin Nun , Andreas Eisenreich
发明人： Edwin Nun , Andreas Eisenreich
IPC分类号： B05D3/00 , B05D5/02
CPC分类号： A01N59/00 , A01N25/04 , A01N25/34 , A01N25/00
摘要： The present invention relates to a method for suppressing mold formation on building parts using hydrophobic substances, wherein a dispersion of hydrophobic particles having a mean particle diameter of from 0.005 to 5 μm in an organic dispersant is applied to the surface to be protected from mold attack and the dispersant is then removed, and to a composition for building parts which inhibits mold growth and comprises from 0.1 to 10% by weight of hydrophobic particles having a mean particle diameter of from 0.005 to 5 μm dispersed in an organic dispersant.
摘要翻译：本发明涉及一种使用疏水性物质抑制建筑部件上的模具成形的方法，其中将有机分散剂中平均粒径为0.005〜5μm的疏水性颗粒的分散体施加到要防止模具侵蚀的表面然后除去分散剂，以及用于构建抑制霉菌生长的部件的组合物，并且包含0.1至10重量％的分散在有机分散剂中的平均粒径为0.005至5微米的疏水性颗粒。

6. 发明授权

US07968202B2 Method for sealing natural stones 有权
标题翻译：天然石材密封方法
公开(公告)号：US07968202B2
公开(公告)日：2011-06-28
申请号：US11572548
申请日：2005-06-01
申请人： Edwin Nun , Volker Hennige , Uwe Paulmann , Hannelore Armoneit , Sigrid Banken , Marie-Theres Wilkes , Norbert Kern , Christian Herkt-Bruns , Thomas Schrief , Eckart Berendes
发明人： Edwin Nun , Volker Hennige , Uwe Paulmann , Hannelore Armoneit , Sigrid Banken , Marie-Theres Wilkes , Norbert Kern , Christian Herkt-Bruns , Thomas Schrief , Eckart Berendes
IPC分类号： B32B9/04
CPC分类号： C04B41/009 , B05D2203/30 , C04B26/32 , C04B41/4922 , C04B41/4933 , C04B2103/0055 , C04B2111/00293 , Y10T428/31663 , Y10T428/4935 , C04B41/5016 , C04B41/5089 , C04B14/064 , C04B14/00 , C04B14/048 , C04B14/06 , C04B14/285
摘要： The present invention relates to a sealed natural cut stone, the pores of which are permeable to water vapor but are impermeable to aqueous liquids, and a method for the production thereof and the use of such natural cut stones.
摘要翻译：本发明涉及一种密封的天然切割石头，其孔隙是透水蒸汽，但不透水性的液体，以及其生产方法和使用这种天然切割的石头。

7. 发明申请

US20100159239A1 METHOD FOR COATING SUBSTRATES AND CARRIER SUBSTRATES 失效
标题翻译：涂覆基板和载体基板的方法
公开(公告)号：US20100159239A1
公开(公告)日：2010-06-24
申请号：US12161031
申请日：2006-12-28
申请人： Edwin Nun , Michael Vetter , Martin Wille
发明人： Edwin Nun , Michael Vetter , Martin Wille
IPC分类号： B32B33/00 , B05D5/10 , B05D3/02 , B32B37/12 , B32B9/04
CPC分类号： B05D7/08 , B05D7/24 , B05D7/52 , B05D2252/10 , B32B7/12 , B32B21/00 , B32B21/02 , B32B21/08 , B32B27/12 , B32B2255/02 , B32B2255/26 , B32B2255/28 , B32B2262/0284 , B32B2264/102 , B32B2264/105 , B32B2307/75 , B32B2419/04 , B32B2607/00 , C23C26/00 , C23C28/00 , Y10T156/10 , Y10T428/2848 , Y10T428/31663
摘要： The present invention relates to a method for coating substrates, comprising the steps: a) provision of a substrate, b) application of a composition to a first side of the substrate, the composition containing an inorganic compound and the inorganic compound containing at least one metal and/or semimetal selected from the group consisting of Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or mixtures thereof and at least one element selected from the group consisting of Te, Se, S, O, Sb, As, P, N, C, Ga or mixtures thereof, c) drying of the composition applied in step b), d) application of at least one coating to the first side of the substrate to which the composition is applied in step b), the coating containing is a silane of the general formula (Z1)Si(OR)3, in which Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having 1 to 18 carbon atoms and all R may be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or mixtures thereof, a polymer and an initiator, and e) drying of the coating applied in step b), f) application of at least one barrier layer to a second side of the substrate, and g) optional application of at least one layer containing at least one adhesive (adhesive layer) to the barrier layer applied in step f), and a coated substrate and coated support substrate obtainable by the abovementioned method.
摘要翻译：本发明涉及一种涂布基材的方法，包括以下步骤：a）提供基材，b）将组合物施用于基材的第一面，所述组合物含有无机化合物和含有至少一种选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，Tl，Si，Ge，Sn，Zn的金属和/或半金属，Pb，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，c）在步骤b）中，d）在步骤b）中向组合物施加至少一层涂料，其中含有通式（Z1）Si（OR）3的硅烷，其中Z 1为R，OR或Gly（Gly = 3-缩水甘油氧基丙基），R为具有1至18个碳原子的烷基，全部R可相同或不同，选自氧化物的Ti，Si，Zr，Al，Y，Sn，Zn，Ce或其混合物，聚合物和引发剂，以及e）在步骤b）中涂覆的涂层的干燥，f）将至少一个阻挡层施加到并且g）可任选地在步骤f）中施加至少一层含有至少一种粘合剂（粘合剂层）的层，以及通过上述方法获得的涂覆的基底和涂覆的支撑基底。

8. 发明授权

US07531598B2 Process for producing detachable dirt- and water-repellent surface coatings 有权
标题翻译：生产可拆卸防污和防水表面涂层的工艺
公开(公告)号：US07531598B2
公开(公告)日：2009-05-12
申请号：US11451868
申请日：2006-06-13
申请人： Felix Müller , Edwin Nun , Patrick Winter
发明人： Felix Müller , Edwin Nun , Patrick Winter
IPC分类号： C08L83/04 , C04B41/49 , C07F7/18
CPC分类号： B08B17/06 , B08B17/065 , C03C17/007 , C03C2217/475 , C03C2217/76 , C04B20/10 , C04B26/32 , C04B2111/00482 , C04B2111/203 , C04B2111/27 , C08K3/013 , C09D183/04 , C09K3/18 , C14C9/00 , Y02W30/94 , C04B14/30 , C04B14/305 , C04B18/146 , C04B20/008 , C08L83/00 , C08L2666/54
摘要： Process for producing detachable dirt- and water-repellent surface coatings on articles, wherein during the coating process, hydrophobic particles are applied to the surface of the articles, thus generating a surface structure with elevations on that surface of the articles that has dirt- and water-repellent properties, which comprises suspending the hydrophobic particles in a solution of a silicone wax in a highly volatile siloxane, and applying this suspension to at least one surface of an article, and then removing the highly volatile siloxane.
摘要翻译：用于在制品上制备可分离的防污和防水表面涂层的方法，其中在涂覆过程中，将疏水性颗粒施加到制品的表面上，从而产生具有在具有污垢和物品的物品表面上的高度的表面结构，防水性能，其包括将疏水性颗粒悬浮在硅氧烷蜡在高挥发性硅氧烷中的溶液中，并将该悬浮液施用到制品的至少一个表面，然后除去高挥发性硅氧烷。

9. 发明申请

US20080280050A1 Ceramic Wall Cladding Composites with Electromagnetic Shielding Properties 有权
标题翻译：陶瓷墙包层复合材料与电磁屏蔽性能
公开(公告)号：US20080280050A1
公开(公告)日：2008-11-13
申请号：US12093025
申请日：2006-12-07
申请人： Edwin Nun , Heike Bergandt , Andreas Gutsch , Gerhard Geipel
发明人： Edwin Nun , Heike Bergandt , Andreas Gutsch , Gerhard Geipel
IPC分类号： B05D3/02 , B32B5/16 , D21H19/72 , E04F13/12
CPC分类号： H01Q17/00 , H05K9/0083 , Y10T156/1153 , Y10T428/24926 , Y10T428/256
摘要： The present invention relates to a method for coating substrates, comprising the steps of: a) preparing a substrate, b) applying a composition onto at least one side of the substrate, the composition containing an inorganic compound, the inorganic compound containing at least one metal and/or semimetal selected from the group Sc, Y, Ti, Zr, Nb, V, Cr, Mo, W, Mn, Fe, Co, B, Al, In, Tl, Si, Ge, Sn, Zn, Pb, Sb, Bi or mixtures thereof and at least one element selected from the group Te, Se, S, O, Sb, As, P, N, C, Ga or mixtures thereof, and an electrically conductive substance selected from metals, particulate metals, metal alloys, particulate metal alloys, conductive compounds containing carbon or mixtures thereof, c) drying the composition applied in step b), d) applying at least one coating onto the at least one side of the substrate onto which the composition was applied in step b), the coating containing a silane of the general formula (Z1)Si(OR)3, where Z1 is R, OR or Gly (Gly=3-glycidyloxypropyl) and R is an alkyl radical having from 1 to 18 carbon atoms and all R may be identical or different, oxide particles selected from the oxides of Ti, Si, Zr, Al, Y, Sn, Zn, Ce or mixtures thereof, and an initiator, the coating preferably containing 3-aminopropyltrimethoxysilane and/or 3-aminopropyltriethoxysilane and/or N-2-aminoethyl-3-aminopropyltrimethoxysilane, and e) drying the coating applied in step d), as well as to the coated substrate.
摘要翻译：本发明涉及一种涂布基材的方法，包括以下步骤：a）制备基材，b）将组合物施加到基材的至少一侧上，所述组合物含有无机化合物，所述无机化合物含有至少一种金属和/或半金属选自Sc，Y，Ti，Zr，Nb，V，Cr，Mo，W，Mn，Fe，Co，B，Al，In，Tl，Si，Ge，Sn，Zn，Pb ，Sb，Bi或其混合物和选自Te，Se，S，O，Sb，As，P，N，C，Ga或其混合物中的至少一种元素，以及选自金属，颗粒金属，金属合金，颗粒状金属合金，含有碳或其混合物的导电化合物，c）干燥步骤b）中施加的组合物，d）将至少一层涂料施加到其上施用组合物的基材的至少一侧上步骤b），所述涂层含有通式（Z 1）Si（OR 3）3的硅烷，其中Z 1 R，OR或Gly（Gly = 3-缩水甘油氧丙基），R为具有1至18个碳原子的烷基，全部R可相同或不同，选自Ti，Si， Zr，Al，Y，Sn，Zn，Ce或其混合物和引发剂，该涂层优选含有3-氨基丙基三甲氧基硅烷和/或3-氨基丙基三乙氧基硅烷和/或N-2-氨基乙基-3-氨基丙基三甲氧基硅烷，以及e）在步骤d）中涂覆的涂层以及涂覆的基材。

10. 发明申请

US20070184981A1 Method for preventing mold formation by using hydrophobic materials, and mold-controlling agent for building parts 失效
标题翻译：通过使用疏水性材料防止模具成型的方法，以及用于建筑部件的模具控制剂
公开(公告)号：US20070184981A1
公开(公告)日：2007-08-09
申请号：US10551841
申请日：2004-02-09
申请人： Edwin Nun , Andreas Eisenreich
发明人： Edwin Nun , Andreas Eisenreich
IPC分类号： A01N55/04 , A01N59/16
CPC分类号： A01N59/00 , A01N25/04 , A01N25/34 , A01N25/00
摘要： The present invention relates to a method for suppressing mold formation on building parts using hydrophobic substances, wherein a dispersion of hydrophobic particles having a mean particle diameter of from 0.005 to 5 μm in an organic dispersant is applied to the surface to be protected from mold attack and the dispersant is then removed, and to a composition for building parts which inhibits mold growth and comprises from 0.1 to 10% by weight of hydrophobic particles having a mean particle diameter of from 0.005 to 5 μm dispersed in an organic dispersant.
摘要翻译：本发明涉及一种使用疏水性物质抑制建筑部件上的模具成形的方法，其中将有机分散剂中平均粒径为0.005〜5μm的疏水性颗粒的分散体施加到要防止模具侵蚀的表面然后除去分散剂，以及用于构建抑制霉菌生长的部件的组合物，并且包含0.1至10重量％的分散在有机分散剂中的平均粒径为0.005至5微米的疏水性颗粒。

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