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    • 1. 发明授权
    • Isotactic polypropylene nucleation
    • 全同立构聚丙烯成核
    • US09096747B2
    • 2015-08-04
    • US12013183
    • 2008-01-11
    • Derek ThurmanSudhin DattaWen LiCharles L. Sims
    • Derek ThurmanSudhin DattaWen LiCharles L. Sims
    • C08L23/04C08L23/10C08L23/14C08L23/12
    • C08L23/10C08L23/12C08L23/142C08L2205/02C08L2666/06
    • Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
    • 含有丙烯结晶度的低分子量半结晶丙烯-α烯烃共聚物用作结晶聚丙烯和聚丙烯共聚物中的成核剂。 成核共聚物是结晶度为5-75%,熔点为45℃-105℃,MFR为300-5000g / 10min的丙烯-α-烯烃共聚物。 成核聚丙烯组合物包含在聚丙烯均聚物基质中混合的成核量的共聚物,或熔点大于110℃的0.01至9重量%的α-烯烃共聚物。成核共聚物改善处理时间,几乎没有或没有效果 关于基质的结晶性相关特征。 本发明还提供了使聚丙烯与成核剂结晶并形成具有该组合物的制品的方法,还提供了由该组合物和/或该方法形成的制品。
    • 2. 发明申请
    • Isotactic Polypropylene Nucleation
    • 全同立构聚丙烯成核
    • US20080249248A1
    • 2008-10-09
    • US12013183
    • 2008-01-11
    • Derek ThurmanSudhin DattaWen LiCharles L. Sims
    • Derek ThurmanSudhin DattaWen LiCharles L. Sims
    • C08L23/02
    • C08L23/10C08L23/12C08L23/142C08L2205/02C08L2666/06
    • Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
    • 含有丙烯结晶度的低分子量半结晶丙烯-α烯烃共聚物用作结晶聚丙烯和聚丙烯共聚物中的成核剂。 成核共聚物是结晶度为5-75%,熔点为45℃-105℃,MFR为300-5000g / 10min的丙烯-α-烯烃共聚物。 成核聚丙烯组合物包含在聚丙烯均聚物基质中共混的成核量的共聚物,或0.01至9重量%的熔点大于110℃的α-烯烃共聚物。成核共聚物改善处理时间,几乎没有或没有影响 关于基质的结晶性相关特征。 本发明还提供了使聚丙烯与成核剂结晶并形成具有该组合物的制品的方法,还提供了由该组合物和/或该方法形成的制品。
    • 7. 发明授权
    • Homogeneous polymer blend and articles therefrom
    • 均相聚合物共混物及其制品
    • US07619038B2
    • 2009-11-17
    • US11299022
    • 2005-12-09
    • Aspy K. MehtaChia ChengSudhin DattaWen LiChon Y. LinSrivatsan S. Iyer
    • Aspy K. MehtaChia ChengSudhin DattaWen LiChon Y. LinSrivatsan S. Iyer
    • C08L23/10C08L23/14
    • C08L23/10C08L23/142C08L2205/02C08L2205/025C08L2314/06C08L2666/06
    • This invention relates to homogeneous blends of: 1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170° C. and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having: a) 10 to 50 percent crystallinity or less; b) a melt flow rate of 200 dg/min or less; c) a DSC melting point (second melt Tm) of 130° C. or less; d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt % comonomer content with a difference of no greater than 20 wt % relative to the average wt % comonomer content of the copolymer; e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, for use in films, fibers, non-wovens, molded articles and the like.
    • 本发明涉及以下均质共混物:1)60至99重量%的一种或多种半结晶聚合物(基于半结晶和半无定形聚合物的重量),每种半结晶聚合物包含丙烯和 0至5重量%的α-烯烃共聚单体(基于聚合物的重量),所述半结晶聚合物各自具有100-170℃的熔点和200dg / min以下的熔体流动速率; 和2)1至40重量%的一种或多种半无定形聚合物(基于半结晶和半无定形聚合物的重量),每种包含丙烯的半无定形聚合物和5至12重量%的一种 或更多的C 2和C 4至C 10α-烯烃共聚单体,所述半无定形聚合物各自具有:a)10至50%的结晶度或更低; b)200dg / min或更低的熔体流动速率; c)130℃或更低的DSC熔点(第二熔体Tm); d)通过在己烷中的热分馏测定的分子间组成分布,使得85重量%或更多的聚合物作为一个或两个相邻的可溶性级分分离,在紧邻的前面或后续级分中余量的聚合物分离; 并且其中这些级分中的每一种都具有相对于共聚物的平均重量%共聚单体含量的不大于20重量%的重量%共聚单体含量; e)Mw / Mn为1.5至4,f)通过13 C NMR测量的三个丙烯单元的三单元组立构规整度为75%或更大,用于膜,纤维,无纺布,模制品等。
    • 9. 发明申请
    • Homogeneous polymer blend and articles therefrom
    • 均相聚合物共混物及其制品
    • US20060183860A1
    • 2006-08-17
    • US11299022
    • 2005-12-09
    • Aspy MehtaChia ChengSudhin DattaWen LiChon LinSrivatsan Iyer
    • Aspy MehtaChia ChengSudhin DattaWen LiChon LinSrivatsan Iyer
    • C08F8/00
    • C08L23/10C08L23/142C08L2205/02C08L2205/025C08L2314/06C08L2666/06
    • This invention relates to homogeneous blends of: 1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170° C. and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 5 to 12 weight % of one or more C2 and or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having: a) 10 to 50 percent crystallinity or less; b) a melt flow rate of 200 dg/min or less; c) a DSC melting point (second melt Tm) of 130° C. or less; d) an intermolecular composition distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt % comonomer content with a difference of no greater than 20 wt % relative to the average wt % comonomer content of the copolymer; e) an Mw/Mn of 1.5 to 4, f) a triad tacticity of three propylene units, as measured by 13C NMR, of 75% or greater, for use in films, fibers, non-wovens, molded articles and the like.
    • 本发明涉及以下均质共混物:1)60至99重量%的一种或多种半结晶聚合物(基于半结晶和半无定形聚合物的重量),每种半结晶聚合物包含丙烯和 0至5重量%的α-烯烃共聚单体(基于聚合物的重量),所述半结晶聚合物各自具有100-170℃的熔点和200dg / min以下的熔体流动速率; 和2)1至40重量%的一种或多种半无定形聚合物(基于半结晶和半无定形聚合物的重量),每种包含丙烯的半无定形聚合物和5至12重量%的一种 或更多的C 2和C 4至C 10α-烯烃共聚单体,所述半无定形聚合物各自具有:a)10至50%的结晶度或更低; b)200dg / min或更低的熔体流动速率; c)130℃或更低的DSC熔点(第二熔体Tm); d)通过在己烷中的热分馏测定的分子间组成分布,使得85重量%或更多的聚合物作为一个或两个相邻的可溶性级分分离,在紧邻前面或后续级分中余量的聚合物分离; 并且其中这些级分中的每一种都具有相对于共聚物的平均重量%共聚单体含量的不大于20重量%的重量%共聚单体含量; e)Mw / Mn为1.5至4,f)通过13 C NMR测量的三个丙烯单元的三单元立构规整度为75%或更大,用于膜,纤维, 织物,模制品等。
    • 10. 发明申请
    • Heterogeneous polymer blends and molded articles therefrom
    • US20060173132A1
    • 2006-08-03
    • US11298145
    • 2005-12-09
    • Aspy MehtaSudhin DattaWen LiSrivatsan Iyer
    • Aspy MehtaSudhin DattaWen LiSrivatsan Iyer
    • C08F8/00
    • C08L23/10C08L23/12C08L23/14C08L2023/42C08L2205/02C08L2205/025C08L2205/03C08L2314/06C08L2666/06C08L2666/02
    • This invention relates to a molded article comprising a heterogeneous blend comprising: 1) from 60 to 99 weight percent of one or more semi-crystalline polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-crystalline polymer comprising propylene and from 0 to 5 weight % alpha-olefin comonomer (based upon the weight of the polymer), said semi-crystalline polymers each having a melting point between 100 and 170° C. and a melt flow rate of 200 dg/min or less; and 2) from 1 to 40 weight % of one or more semi-amorphous polymers (based upon the weight of the semi-crystalline and semi-amorphous polymers), each semi-amorphous polymer comprising propylene and from 10 to 25 weight % of one or more C2 and/or C4 to C10 alpha-olefin comonomers, said semi-amorphous polymers each having: a) a heat of fusion of 4 to 70 J/g; and b) a melt flow rate of 0.1 to 200 dg/min; and c) an intermolecular compositional distribution as determined by thermal fractionation in hexane such that 85% by weight or more of the polymer is isolated as one or two adjacent, soluble fractions with the balance of the polymer in immediately preceding or succeeding fractions; and wherein each of these fractions has a wt % comonomer content with a difference of no greater than 20 wt % relative to the average wt % comonomer content of the copolymer; and d) an Mw/Mn of 1.5 to 4, and e) a propylene triad tacticity, as measured by 13C NMR, of 75% or greater; where the blend has: i) a melt flow rate of 0.5 to 200 dg/min; and ii) less than 5 weight % filler, based upon the weight of the polymers and the filler; and iii) a permanent set of greater than 65%; and iv) a haze of 20% or less on a 1 mm injection molded chip; and the molded part has: a) a thickness of 250 μm to 10 mm; and b) a notched Izod impact strength at 23° C. of 80 J/m or more; and c) a notched Izod impact strength at 0° C. of 27 J/m or more; and d) a 1% secant flexural modulus of 1035 MPa or lower; and e) an ultimate elongation where greater than 50% of 5 test specimens suffer no break through extension to 1000%; and f) a resistance to stress whitening of Hunter color ΔL of 15 or lower.