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    • 10. 发明授权
    • Method for inhibiting hydrate formation
    • 抑制水合物形成的方法
    • US5600044A
    • 1997-02-04
    • US449151
    • 1995-05-24
    • Karla S. ColleChristine A. CostelloRussell H. OelfkeLarry D. TalleyJohn M. LongoEnoch Berluche
    • Karla S. ColleChristine A. CostelloRussell H. OelfkeLarry D. TalleyJohn M. LongoEnoch Berluche
    • F17D1/05C09K8/52C10L3/06C07C7/20F15D1/00
    • C09K8/52C10L3/06C09K2208/22Y10S585/95Y10T137/0329Y10T137/0391
    • A method for inhibiting the formation of clathrate hydrates in a fluid having hydrate forming constituents is disclosed. More specifically, the method can be used in treating a petroleum fluid stream such as natural gas conveyed in a pipe to inhibit the formation of a hydrate restriction in the pipe. The hydrate inhibitors used for practicing the method are substantially water soluble polymers formed from a N-substituted acrylamide having two nitrogen substituent groups, R.sub.1 and R.sub.2, where R.sub.1 is a hydrocarbon group having from one to ten carbon atoms and zero to four heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and combinations thereof, and R.sub.2 is a hydrogen atom or a hydrocarbon group having from one to ten carbon atoms selected from the group consisting of carbon, nitrogen, oxygen, and sulfur; alternatively, R.sub.1 and R.sub.2 may be linked to produce a cyclic ring having ten atoms comprising a combination of between three and ten carbon atoms and zero to four heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, and combinations thereof. Some examples of such inhibitors include, but are not limited to, poly(N-ethylacrylamide), poly(N,N-diethylacrylamide), poly(N-methyl, N-acrylamide), poly(iso-propylacrylamide), poly(n-propylacrylamide), poly(N-cyclopentylacrylamide), poly(N-cyclohexylacrylamide), poly(acryloylpiperdine), poly(acryloylpiperdine), poly(acryloylmorpholine) and various N-substituted acrylamide copolymers.
    • 公开了一种抑制在具有水合物形成成分的流体中形成笼形水合物的方法。 更具体地说,该方法可用于处理在管道中输送的天然气等石油流体流,以抑制管道中的水合物限制。 用于实施该方法的水合物抑制剂基本上是由具有两个氮取代基的N-取代丙烯酰胺R 1和R 2形成的水溶性聚合物,其中R 1是具有1至10个碳原子的烃基和0至4个选自 由氮,氧,硫及其组合构成的组,R2为氢原子或碳原子数为1〜10的选自碳,氮,氧,硫的烃基; 或者,R1和R2可以连接以产生具有10个原子的环,所述原子包含3至10个碳原子和0至4个选自氮,氧,硫及其组合的杂原子的组合。 这些抑制剂的一些实例包括但不限于聚(N-乙基丙烯酰胺),聚(N,N-二乙基丙烯酰胺),聚(N-甲基,N-丙烯酰胺),聚(异丙基丙烯酰胺),聚(n - 丙基丙烯酰胺),聚(N-环戊基丙烯酰胺),聚(N-环己基丙烯酰胺),聚(丙烯酰基哌啶),聚(丙烯酰基哌啶),聚(丙烯酰基吗啉)和各种N-取代的丙烯酰胺共聚物。