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    • 2. 发明申请
    • Ion Exchange Regeneration and Nuclide Specific Selective Processes
    • 离子交换再生和核素特异性选择过程
    • US20120088949A1
    • 2012-04-12
    • US13267603
    • 2011-10-06
    • Dennis Frank HusseyDavid BradburyGeorge Richard ElderLisa Maxine Edwards
    • Dennis Frank HusseyDavid BradburyGeorge Richard ElderLisa Maxine Edwards
    • G21F9/12G21F9/06
    • G21F9/12G21F9/28G21F9/30
    • A method of processing ion exchange resin radioactive waste, wherein the radioactive waste contains a plurality of fractions of radioactive waste based on density, which may include cation resin waste and anion resin waste, wherein at least one of the plurality of fractions comprises a total concentration of at least one radionuclide, including performing at least one of the following operations (i), (ii) or (iii): (i) separating the at least one of the plurality of fractions from the radioactive waste utilizing a moving freeboard; (ii) separating the radioactive waste into cation resin waste and anion resin waste; or (iii) removing at least a portion of the total concentration of the at least one radionuclide from: the radioactive waste; the at least one of the plurality of fractions separated by the moving freeboard; or at least one of the radioactive waste, the cation resin waste or the anion resin waste.
    • 一种处理离子交换树脂放射性废物的方法,其中所述放射性废物基于密度包含多个放射性废物部分,其可包括阳离子树脂废物和阴离子树脂废物,其中所述多个馏分中的至少一个包含总浓度 包括执行以下操作(i),(ii)或(iii)中的至少一个:(i)利用移动的干舷将多个馏分中的至少一个与放射性废物分离; (ii)将放射性废物分解为阳离子树脂废物和阴离子树脂废物; 或(iii)从放射性废物中去除至少一种放射性核素的总浓度的至少一部分; 由移动的干舷分开的多个分数中的至少一个; 或放射性废物,阳离子树脂废物或阴离子树脂废物中的至少一种。
    • 4. 发明授权
    • Regenerative LOMI decontamination process
    • 再生LOMI去污工艺
    • US5805654A
    • 1998-09-08
    • US826835
    • 1997-04-08
    • Christopher J. WoodDavid BradburyGeorge Richard Elder
    • Christopher J. WoodDavid BradburyGeorge Richard Elder
    • G21F9/28B01J49/00G21F9/00G21F9/12
    • G21F9/004G21F9/12
    • A method for operating the LOMI decontamination process in a regenerative manner. The method incorporates an initial injection of a dilute LOMI solution (vanadous formate, picolinic acid and sodium hydroxide) into a decontamination circuit followed by operation of a small cluster of cation exchange columns during the decontamination process. The cation exchange resin is used to remove metals in the same manner as in prior decontamination processes but operation of the cation exchange resin is continued to allow picolinic acid initially bound to the cation exchange resin to be released and recycled to the LOMI solution. Operation of the cation exchange columns ceases after the picolinic acid has been released but before the metals (e.g. sodium, iron and vanadium) are released back to the LOMI solution. The cluster of cation exchange columns are operated according to a sequence wherein one column is releasing picolinic acid while another is binding picolinic acid. The method further includes continuous additions of vanadous formate and sodium hydroxide. Clean-up at the end of the method proceeds in the normal manner wherein larger cation and anion exchange columns are utilized. Because the concentration of the components is much lower than conventional LOMI processes, however, the amount of cation exchange resin required at this stage is greatly reduced.
    • 一种以再生方式操作LOMI去污工艺的方法。 该方法将稀释的LOMI溶液(甲酸钒酸盐,吡啶甲酸和氢氧化钠)初始注入去污电路,然后在净化过程中操作一小群阳离子交换柱。 使用阳离子交换树脂以与先前的去污处理相同的方式除去金属,但继续使阳离子交换树脂的操作使得最初与阳离子交换树脂结合的吡啶甲酸被释放并再循环到LOMI溶液中。 在吡啶甲酸释放后,但金属(例如钠,铁和钒)释放回LOMI溶液之前,阳离子交换柱的操作停止。 阳离子交换柱的簇根据其中一个塔释放吡啶甲酸而另一个是结合吡啶甲酸的顺序操作。 该方法还包括连续加入甲酸铵和氢氧化钠。 在方法结束时的清理以正常方式进行,其中使用较大的阳离子和阴离子交换柱。 然而,由于组分的浓度远远低于常规的LOMI方法,所以在此阶段所需的阳离子交换树脂的量大大降低。
    • 5. 发明授权
    • Electrochemical process for decontamination of radioactive materials
    • 放射性物质去污电化学工艺
    • US06682646B2
    • 2004-01-27
    • US10106481
    • 2002-03-25
    • Christopher John WoodDavid BradburyGeorge Richard Elder
    • Christopher John WoodDavid BradburyGeorge Richard Elder
    • C02F1461
    • G21F9/04B01J47/08C02F1/001C02F1/4693C02F1/4695C02F2001/425C02F2001/46119C02F2101/006C02F2101/20G21F9/06G21F9/12G21F9/16
    • A system for decontamination of radioactive components includes an acidic decontamination solution which is exposed to radioactive components to remove a layer of contaminated material and an ion exchange cell which removes the radioactive contamination from the decontamination solution. The ion exchange cell has cathode, anode and central compartments. The decontamination solution flows into the central compartment and the radioactive cations in the solution are drawn towards the cathode. The acidity in the cathode chamber is controlled so that small radioactive metal particles are deposited on the cathode. A cathode solution flows over the cathode which removes the deposited radioactive particles. The cathode solution and small particles flow into a waste collection container where the metal particles settle to the bottom of the container where they are easily separated from the solution. The only waste product produced by the system are the small radioactive metal particles which are easily disposed of. All liquids used in the decontamination process may be recycled.
    • 用于放射性成分去污的系统包括暴露于放射性组分以除去一层被污染物质的酸性去污溶液和从去污溶液中去除放射性污染物的离子交换池。 离子交换池具有阴极,阳极和中央隔室。 去污溶液流入中央隔室,溶液中的放射性阳离子被吸向阴极。 控制阴极室中的酸度使得小的放射性金属颗粒沉积在阴极上。 阴极溶液流过阴极,去除沉积的放射性粒子。 阴极溶液和小颗粒流入废物收集容器中,其中金属颗粒沉降到容器的底部,在容器的底部容易与溶液分离。 该系统产生的唯一废物是容易处理的小型放射性金属颗粒。 在去污过程中使用的所有液体都可以回收利用。