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1. 发明授权

US4339365A Coating compositions containing pigment dispersants 失效
标题翻译：含有颜料分散剂的涂料组合物
公开(公告)号：US4339365A
公开(公告)日：1982-07-13
申请号：US215765
申请日：1980-12-12
申请人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
发明人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
IPC分类号： C09D7/45 , C08K5/01 , C08K5/02 , C08K5/03 , C08L1/00
CPC分类号： C09D7/02
摘要： Coating compositions contain pigment dispersants wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.
摘要翻译：涂料组合物含有颜料分散剂，其中分散剂是（i）烷基中具有3-8个碳原子的甲基丙烯酸烷基酯的聚合产物，（ii）选自苯乙烯，甲基丙烯酸甲酯，乙基甲基丙烯酸酯及其混合物，（iii）选自丙烯酸，甲基丙烯酸，衣康酸，巴豆酸，马来酸，富马酸及其混合物的烯属不饱和羧酸或具有双键α-β至羰基，并且当与水，醇，胺或酸酐反应时提供羧基官能团，（iv）具有双键α-β至羰基和至少一个羟基的单体或当进一步提供此类基团时提供此类基团的单体与酸或环氧化物反应，和（v）提供胺或胺盐官能部分的化合物。分散剂可用于将颜料分散在含有多种成膜树脂的涂料组合物中。

2. 发明授权

US4302560A Pigment dispersants for coating compositions 失效
公开(公告)号：US4302560A
公开(公告)日：1981-11-24
申请号：US178196
申请日：1980-08-14
申请人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
发明人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
IPC分类号： C09B67/46 , C09D7/45 , C08F8/00 , C08F220/34
CPC分类号： C09B67/0091 , C09D7/02
摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.

3. 发明授权

US4302561A Pigment dispersants for coating compositions 失效
标题翻译：用于涂料组合物的颜料分散剂
公开(公告)号：US4302561A
公开(公告)日：1981-11-24
申请号：US178207
申请日：1980-08-14
申请人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
发明人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
IPC分类号： C08F8/00 , C09B67/46 , C09D7/45 , C08F220/34
CPC分类号： C09D7/02 , C08F8/00 , C09B67/0091
摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acids, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.
摘要翻译：用于涂料组合物的颜料分散剂，其中分散剂是（i）烷基中具有3-8个碳原子的甲基丙烯酸烷基酯的聚合产物，（ii）选自苯乙烯，甲基丙烯酸甲酯，甲基丙烯酸乙酯及其混合物，（iii）选自丙烯酸，甲基丙烯酸，衣康酸，巴豆酸，马来酸，富马酸及其混合物的烯属不饱和羧酸或具有双键α-烯烃的单体，当与水，醇，胺或酸酐反应时提供羧基官能团，（iv）具有羰基和至少一个羟基的双键α-β的单体或提供这种基团的单体当与酸或环氧化物进一步反应时，和（v）提供胺或胺盐官能部分的化合物。分散剂可用于将颜料分散在含有多种成膜树脂的涂料组合物中。

4. 发明授权

US4303764A Pigment dispersants for coating compositions 失效
标题翻译：用于涂料组合物的颜料分散剂
公开(公告)号：US4303764A
公开(公告)日：1981-12-01
申请号：US166643
申请日：1980-07-07
申请人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
发明人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
IPC分类号： C08F8/00 , C09B67/46 , C09D7/45 , C08F220/34
CPC分类号： C09D7/02 , C08F8/00 , C09B67/0091
摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.
摘要翻译：用于涂料组合物的颜料分散剂，其中分散剂是（i）烷基中具有3-8个碳原子的甲基丙烯酸烷基酯的聚合产物，（ii）选自苯乙烯，甲基丙烯酸甲酯，甲基丙烯酸乙酯及其混合物，（iii）选自丙烯酸，甲基丙烯酸，衣康酸，巴豆酸，马来酸，富马酸及其混合物的烯属不饱和羧酸或具有双键α-烯烃的单体，当与水，醇，胺或酸酐反应时提供羧基官能团，（iv）具有羰基和至少一个羟基的双键α-β的单体或提供这种基团的单体当与酸或环氧化物进一步反应时，和（v）提供胺或胺盐官能部分的化合物。分散剂可用于将颜料分散在含有多种成膜树脂的涂料组合物中。

5. 发明授权

US4302562A Pigment dispersants for coating compositions 失效
公开(公告)号：US4302562A
公开(公告)日：1981-11-24
申请号：US178247
申请日：1980-08-14
申请人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
发明人： David Z. Becher , Roger M. Christenson , Richard L. Coalson , Percy E. Pierce , Karl F. Schimmel
IPC分类号： C08F8/00 , C09B67/46 , C09D7/45 , C08F220/34
CPC分类号： C09D7/02 , C08F8/00 , C09B67/0091
摘要： Pigment dispersants for use in coating compositions wherein the dispersant is the polymerization product of (i) an alkyl methacrylate having from 3 to 8 carbon atoms in the alkyl group, (ii) a hardening monomer selected from the group consisting of a styrene, methyl methacrylate, ethyl methacrylate and mixtures thereof, (iii) an ethylenically unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid and mixtures thereof or a monomer having a double bond alpha-beta to a carbonyl group and which provides carboxyl functionality when reacted with water, alcohol, amine or anhydride, (iv) a monomer having a double bond alpha-beta to a carbonyl group and at least one hydroxyl group or a monomer which provides such groups when further reacted with an acid or an epoxide, and (v) a compound providing an amine or amine salt functional moiety. The dispersants are useful for dispersing pigments in coating compositions containing a wide variety of film-forming resins.

6. 发明授权

US4007154A Novel pigment paste for cationic electrodeposition 失效
标题翻译：用于阳离子电沉积的新型颜料膏
公开(公告)号：US4007154A
公开(公告)日：1977-02-08
申请号：US601108
申请日：1975-08-01
申请人： Karl F. Schimmel , Percy E. Pierce , James E. Jones
发明人： Karl F. Schimmel , Percy E. Pierce , James E. Jones
IPC分类号： C08G18/08 , C08G18/58 , C08G18/80 , C08G59/40 , C09D5/44 , C08L63/02
CPC分类号： C08G18/8041 , C08G18/0804 , C08G18/0814 , C08G18/58 , C08G18/8061 , C08G18/8064 , C08G18/807 , C08G59/4028 , C09D5/443 , C09D5/4453 , Y10S524/901
摘要： A pigment paste suitable for use in cationic electrodeposition is disclosed. The paste contains pigment dispersed in a resinous vehicle which is the reaction product of an epoxy-containing organic material and an organic tertiary amine acid salt containing blocked isocyanate groups capable of unblocking at elevated temperature.
摘要翻译：公开了适用于阳离子电沉积的颜料浆料。糊状物含有分散在树脂载体中的颜料，其是含环氧基的有机材料和含有能够在高温下解封的封端异氰酸酯基团的有机叔胺酸盐的反应产物。

7. 发明授权

US4299743A Sulfonate-containing polymer 失效
标题翻译：含磺酸盐的聚合物
公开(公告)号：US4299743A
公开(公告)日：1981-11-10
申请号：US153385
申请日：1980-05-27
申请人： Percy E. Pierce , Karl F. Schimmel
发明人： Percy E. Pierce , Karl F. Schimmel
IPC分类号： C08G18/08 , C08G18/67 , C08G63/688 , C08G63/91 , C09D7/45 , C08L93/00
CPC分类号： C08G18/0828 , C08G18/675 , C08G63/688 , C08G63/918 , C09D7/02
摘要： Polymer containing a plurality of organic sulfonate-containing groups is capable of being dissolved or dispersed in a liquid medium. The polymer is useful as a pigment dispersant and as film-forming polymer in coating compositions.
摘要翻译：含有多个含有机磺酸盐基团的聚合物能够溶解或分散在液体介质中。该聚合物可用作颜料分散剂和作为涂料组合物中的成膜聚合物。

8. 发明授权

US4081343A Process for cationic electrodeposition 失效
标题翻译：阳离子电沉积工艺
公开(公告)号：US4081343A
公开(公告)日：1978-03-28
申请号：US738785
申请日：1976-11-03
申请人： Karl F. Schimmel , Percy E. Pierce , James E. Jones
发明人： Karl F. Schimmel , Percy E. Pierce , James E. Jones
IPC分类号： C08G18/08 , C08G18/58 , C08G18/80 , C08G59/40 , C09D5/44 , C25D13/10
CPC分类号： C08G18/8041 , C08G18/0804 , C08G18/0814 , C08G18/58 , C08G18/8061 , C08G18/8064 , C08G18/807 , C08G59/4028 , C09D5/443 , C09D5/4453 , Y10S524/901
摘要： A pigment paste suitable for use in cationic electrodeposition is disclosed. The paste contains pigment dispersed in a resinous vehicle which is the reaction product of an epoxy-contaning organic material and an organic tertiary amine acid salt containing blocked isocyanate groups capable of unblocking at elevated temperature.
摘要翻译：公开了适用于阳离子电沉积的颜料浆料。糊状物含有分散在树脂载体中的颜料，其是含环氧基的有机材料和含有能够在高温下解封的封端异氰酸酯基团的有机叔胺酸盐的反应产物。

9. 发明授权

US5231472A Color matching and characterization of surface coatings 失效
标题翻译：表面涂层的颜色匹配和表征
公开(公告)号：US5231472A
公开(公告)日：1993-07-27
申请号：US760651
申请日：1991-09-16
申请人： Robert T. Marcus , Percy E. Pierce
发明人： Robert T. Marcus , Percy E. Pierce
IPC分类号： G01N21/47
CPC分类号： G01N21/4738 , G01J3/504 , G01J3/463 , G01N2021/4771
摘要： A method of characterization of a coating on a surface such as a paint coating having metallic flakes distributed within such coating. Single and multi-angle models are utilized. The coating is characterized by measurements having components of light reflected by the metal flakes and attenuated on its exit route from the coating, of light scattered in the entering path of the beam as it travels through the coating, of light scattered by the reflected beam on its exit from the coating, of light scattered in the entering path then reflected by the metallic flakes and attenuated in the coating on exiting, and of light scattering in the exit path, both to the metallic flake and reflected by the flake and attenuated on its exit from the coating. Methods of color matching a coating having a metallic flake distribution within the coating are included using reflectance factors and tristimulus values and minimizing the sum of the squares of the deviation between samples.
摘要翻译：表面涂层的表征方法，例如在这种涂层内分布有金属薄片的涂料涂层。使用单角度和多角度模型。涂层的特征在于具有由金属薄片反射的光的成分的测量，并且在其穿过涂层的光束的进入路径中散射的光在其穿过涂层的光的入射路径上散射的光被被反射的光束散射的光在其出射路径上衰减。其从涂层出射，然后在进入路径中散射的光然后被金属薄片反射并且在退出时在涂层中衰减，并且在出射路径中散射光，两者都到金属薄片并由薄片反射并在其上衰减从涂层出来。使用反射系数和三刺激值包括在涂层内具有金属薄片分布的涂层进行颜色匹配的方法，并最小化采样之间的偏差平方和。

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