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1. 发明授权

US07078457B2 Polymer composition and process for the preparation thereof 有权
标题翻译：聚合物组合物及其制备方法
公开(公告)号：US07078457B2
公开(公告)日：2006-07-18
申请号：US10617330
申请日：2003-07-10
申请人： David Richard Amick , Ralph Craig Even , Ann Robertson Hermes , Rosemarie Palmer Lauer
发明人： David Richard Amick , Ralph Craig Even , Ann Robertson Hermes , Rosemarie Palmer Lauer
IPC分类号： C08L33/02
CPC分类号： C08F4/34
摘要： An aqueous composition including a polymer having polymerized ethylenically unsaturated acid monomer is disclosed. The aqueous composition is prepared in the presence of select organic compounds. As provided is a process to prepare the aqueous composition. The aqueous composition is useful as a dispersant for inorganic particles, a thickener or rheology modifiers for various aqueous formulations, and as a dispersing resin.
摘要翻译：公开了一种包含具有聚合的烯属不饱和酸单体的聚合物的水性组合物。在选择的有机化合物的存在下制备含水组合物。提供制备含水组合物的方法。水性组合物可用作无机颗粒的分散剂，用于各种水性配方的增稠剂或流变改性剂以及作为分散树脂。

2. 发明授权

US07138438B2 Polymeric nanoparticle formulations and their use for improving the dirt pick up resistance of a coating 有权
标题翻译：聚合物纳米颗粒制剂及其用于改善涂层的污垢吸附阻力的用途
公开(公告)号：US07138438B2
公开(公告)日：2006-11-21
申请号：US10461963
申请日：2003-06-13
申请人： Rosemarie Palmer Lauer , Ralph Craig Even , Donna Staley Grecian , Robert David Solomon
发明人： Rosemarie Palmer Lauer , Ralph Craig Even , Donna Staley Grecian , Robert David Solomon
IPC分类号： C08L27/12 , C08L43/04 , C08F220/22 , C08F220/10 , G03C1/73
CPC分类号： B82Y30/00 , C08F220/14 , C08F220/18 , C08F222/1006 , C08F230/08 , C09D5/1668 , C09D5/1687 , C09D143/04
摘要： A formulation for repelling particulate matter on the surface of a coating comprising polymeric nanoparticles having a mean particle diameter of from 1 to 50 nm. The polymeric nanoparticles may further be functionalized to impart additional characteristics to modify the surface of the dried coating to minimize the chances for particles to become embedded or attached to the coating.
摘要翻译：用于排斥包含平均粒径为1至50nm的聚合物纳米颗粒的涂层表面上的颗粒物质的制剂。聚合物纳米颗粒可以进一步官能化以赋予干燥涂层的表面的附加特性，以最小化颗粒嵌入或附着到涂层的机会。

3. 发明授权

US06258887B1 Dirt pickup resistant coating binder and coatings 失效
标题翻译：防污涂层粘合剂和涂料
公开(公告)号：US06258887B1
公开(公告)日：2001-07-10
申请号：US09450580
申请日：1999-11-30
申请人： James Keith Bardman , Ralph Craig Even , Mark Stephen Frazza , Yili Guo , Robert Krasnansky , Rosemarie Palmer Lauer
发明人： James Keith Bardman , Ralph Craig Even , Mark Stephen Frazza , Yili Guo , Robert Krasnansky , Rosemarie Palmer Lauer
IPC分类号： C08J300
CPC分类号： C08F265/06 , C08F263/04 , C08F265/02 , C09D151/003 , C08L2666/02
摘要： A multi-stage aqueous emulsion-polymer suitable for use in dirt pickup resistant coatings and coatings containing the polymer are provided. The multi-stage aqueous emulsion polymer includes (i) a first polymer including at least one nonionic copolymerized monoethylenically unsaturated monomer, from 0.5% to 7% of a copolymerized monoethylenically unsaturated ionic monomer, based on the weight of the first polymer, and from 0% to 1.0%, based on the weight of the first polymer, of a copolymerized multi-ethylenically unsaturated monomer, the first polymer having a Tg of 15° C. to 105° C.; and (ii) a second polymer comprising at least one nonionic copolymerized monoethylenically unsaturated monomer, from 0% to 2% of a copolymerized monoethylenically unsaturated ionic monomer, and from 0.25% to 6%, based on the weight of the second polymer, copolymerized multi-ethylenically unsaturated monomer, the second polymer having a Tg of −55° C. to 30° C., the second polymer having a different composition than the first copolymer, and the second polymer being from 25% to 75% of the total weight of the first polymer and the second polymer, based on dry polymer weights.
摘要翻译：提供了适用于防尘涂层和含有聚合物的涂层的多级水性乳液聚合物。多级水性乳液聚合物包括（i）包含至少一种非离子共聚单烯属不饱和单体的第一聚合物，基于第一聚合物重量的0.5％至7％的共聚单烯属不饱和离子单体，和0 基于第一聚合物的重量计，共聚多烯属不饱和单体的百分比至1.0％，第一聚合物的Tg为15℃至105℃; 和（ii）包含至少一种非离子共聚单烯属不饱和单体，0％至2％共聚单烯属不饱和离子单体和基于第二聚合物重量的0.25％至6％的第二聚合物，共聚多烯属不饱和单体，第二聚合物的Tg为-55℃至30℃，第二聚合物的组成不同于第一共聚物，第二聚合物的总重量为25％至75％的第一聚合物和第二聚合物，基于干聚合物重量。

4. 发明授权

US06756075B2 In-press coating method and composition 有权
标题翻译：压制涂布方法及组成
公开(公告)号：US06756075B2
公开(公告)日：2004-06-29
申请号：US10081681
申请日：2002-02-25
申请人： Anne Seton DeMasi , Rosemarie Palmer Lauer
发明人： Anne Seton DeMasi , Rosemarie Palmer Lauer
IPC分类号： B05D312
CPC分类号： B29C37/0028
摘要： A method and composition are provided for applying a single aqueous coating composition to a composite substrate during an in-press molding operation to achieve (i) improved initial whiteness in a white pigmented composition, (ii) excellent color retention/stability and (iii) excellent press release properties. The aqueous coating composition incorporates an ion exchange resin and serves as a combined sealer and topcoat finish for press molded composite substrates.
摘要翻译：提供了一种方法和组合物，用于在压制成型操作期间将单一水性涂料组合物施加到复合基材上，以实现（i）改善白色着色组合物中的初始白度，（ii）优异的保色性/稳定性和（iii）出色的新闻发布性能。水性涂料组合物包含离子交换树脂，并用作压模复合基材的组合密封剂和顶涂层。

5. 发明申请

US20050027079A1 Aqueous multistage emulsion polymer composition 审中-公开
标题翻译：水性多级乳液聚合物组合物
公开(公告)号：US20050027079A1
公开(公告)日：2005-02-03
申请号：US10887261
申请日：2004-07-08
申请人： Rosemarie Palmer Lauer , Jennifer Petoff
发明人： Rosemarie Palmer Lauer , Jennifer Petoff
IPC分类号： C08F2/22 , C08F4/32 , C08F20/12 , C08F265/06 , C09D133/06 , C08F4/00
CPC分类号： C08F20/12 , C08F2/22 , C08F265/06 , C09D133/06
摘要： An aqueous multistage emulsion polymer formed by the free radical polymerization in at least two stages of, in each stage, at least one ethylenically unsaturated nonionic acrylic monomer, the polymer in two of the stages having glass transition temperatures (Tg) differing by at least 10 ° C.; the polymerization, in at least one stage, being effected in the presence of 0.01-1.0%%, by weight based on the dry weight of the stage polymer, t-alkyl hydroperoxide, t-alkyl peroxide, or t-alkyl perester wherein the t-alkyl group includes at least 5 Carbon atoms, preferably t-amyl hydroperoxide, is provided. Also provided is a method for preparing the aqueous multistage emulsion polymer, an aqueous coating composition including the aqueous multistage emulsion polymer and a method for treating a substrate with the aqueous coating composition.
摘要翻译：通过自由基聚合形成的水性多级乳液聚合物，其在至少两个阶段中，在每个阶段中至少一种烯属不饱和非离子丙烯酸单体，所述两个阶段中的聚合物的玻璃化转变温度（Tg）至少为10 C。; 在至少一个阶段中的聚合在基于载体聚合物，叔烷基氢过氧化物，叔烷基过氧化物或叔烷基过酸酯的干重的0.01-1.0 %%的存在下进行，其中 t-烷基包括至少5个碳原子，优选叔戊基过氧化氢。还提供了一种制备含水多阶段乳液聚合物的方法，包括含水多层乳液聚合物的水性涂料组合物和用水性涂料组合物处理基材的方法。

6. 发明授权

US5922410A Wood coating composition 失效
标题翻译：木材涂料组成
公开(公告)号：US5922410A
公开(公告)日：1999-07-13
申请号：US374459
申请日：1995-01-18
申请人： Andrew Joseph Swartz , Maria Elizabeth Curry-Nkansah , Rosemarie Palmer Lauer , Matthew Stewart Gebhard
发明人： Andrew Joseph Swartz , Maria Elizabeth Curry-Nkansah , Rosemarie Palmer Lauer , Matthew Stewart Gebhard
IPC分类号： C09D133/14 , C08G18/08 , C09D133/04 , C09D133/06 , C09D133/26 , C09D201/02 , B05D5/06 , B05D5/00 , B32B21/04
CPC分类号： C08F220/18 , C08G18/0828 , C09D133/062 , C08F220/06 , C08F2220/585 , C08F230/02 , Y10T428/31989
摘要： The invention relates to wood coating composition selected to accentuate the color and the natural grain structure of the underlying surface of a wood article, such as, a furniture or carving. The surface of the article is coated with a waterborne system that includes a copolymer copolymerized from at least one first copolymerizable monomer and at least one second copolymerizable monomer containing a conjugate base of a strong acid. The coating enhances the reddish-yellow hues and suppress the bluish hues and grays. Such a coating is aesthetically pleasing and it enhances the natural beauty of high quality wood, such as, rose, cherry, teak, mahogany. The present method can be utilized by furniture manufacturers who plan to replace solvent borne coating compositions, such as nitrocellulose-based lacquers, with waterborne coating compositions.
摘要翻译：本发明涉及木质涂料组合物，所述木质涂料组合物被选择用于强调木制品如家具或雕刻物的下表面的颜色和天然颗粒结构。该制品的表面涂覆有一种水性体系，其包括由至少一种第一可共聚单体和至少一种含有强酸共轭碱的第二可共聚单体共聚合的共聚物。涂层增强了红黄色的色调，并抑制了蓝色的色调和灰度。这种涂层在美学上令人愉快，并且增强了高品质木材的自然美，如玫瑰，樱桃，柚木，桃花心木。本方法可以由计划用水性涂料组合物代替溶剂型涂料组合物如硝酸纤维素类漆的家具制造商利用。

7. 发明申请

US20090004394A1 Aqueous polymeric composition 审中-公开
标题翻译：水性聚合物组合物
公开(公告)号：US20090004394A1
公开(公告)日：2009-01-01
申请号：US12157046
申请日：2008-06-06
申请人： Anne Denise Koller , Rosemarie Palmer Lauer , Robert Mitchell Blankenship , Wayne Devonport
发明人： Anne Denise Koller , Rosemarie Palmer Lauer , Robert Mitchell Blankenship , Wayne Devonport
IPC分类号： B05D3/00 , C08K5/09
CPC分类号： C09D201/06 , C09D133/14 , C09D135/06
摘要： An aqueous polymeric composition including an emulsion polymer including, as copolymerized units, from 0.5% to 25%, by weight based on the weight of the polymer, carbonyl-functional ethylenically-unsaturated monomer, and an autoxidizable material having less than 10%, by weight based on the weight of fatty acid residues therein, tri-unsaturated fatty acid residues; wherein the autoxidizable material is from 8% to 35% of the total weight of the polymer and the autoxidizable material; and wherein the polymeric composition is free from copolymerized-carbonyl-functional-monomer-reactive amine and hydrazine functional groups is provided. An aqueous coating composition including the aqueous polymeric composition, a method for improving the repaintability of an aqueous coating during drying, and a method for providing a coating are also provided.
摘要翻译：一种包含乳液聚合物的水性聚合物组合物，其包含基于所述聚合物的重量计为0.5重量％至25重量％的共聚单元，羰基官能的烯属不饱和单体和具有小于10％的可自动氧化材料基于其中脂肪酸残基重量的三重不饱和脂肪酸残基; 其中所述可自动氧化材料为聚合物和可自动氧化材料总重量的8％至35％; 并且其中所述聚合物组合物不含共聚羰基官能单体反应性胺，并且提供肼官能团。还提供了一种包含该水性聚合物组合物的水性涂料组合物，一种用于改善干燥期间的水性涂料的再污染性的方法和一种提供涂料的方法。

8. 发明授权

US5932350A Coating substrates 失效
标题翻译：涂层基材
公开(公告)号：US5932350A
公开(公告)日：1999-08-03
申请号：US985665
申请日：1997-12-05
申请人： Rosemarie Palmer Lauer , Matthew Stewart Gebhard , Anne Seton Demasi
发明人： Rosemarie Palmer Lauer , Matthew Stewart Gebhard , Anne Seton Demasi
IPC分类号： B05D1/34 , B05C1/02 , B05D3/06 , B05D7/00 , B05D7/06 , B05D7/08 , B05D7/24 , C09D4/00 , C09D4/02 , C09D5/00 , C09D129/12 , C09D133/14 , C09D133/18 , C09D133/26 , C09D139/00 , C09D201/06 , B32B9/04
CPC分类号： B05D7/546 , B05D7/06 , B05D7/08 , B05D7/586 , B05D3/067 , Y10T428/31504
摘要： In a method for coating a substrate, preferably a cellulosic substrate, an aqueous coating comprising a polymer having carbonyl functional moities may be tandem coated directly onto or beneath an UV cured coating. The method provides a low VOC system which offers good adhesion between the two coatings.
摘要翻译：在用于涂覆基材，优选纤维素基材的方法中，包含具有羰基官能团的聚合物的水性涂料可以直接串联涂布在UV固化涂层上或其下。该方法提供了低VOC系统，其在两个涂层之间提供良好的粘附性。

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