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    • 1. 发明授权
    • Dirt pickup resistant coating binder and coatings
    • 防污涂层粘合剂和涂料
    • US06258887B1
    • 2001-07-10
    • US09450580
    • 1999-11-30
    • James Keith BardmanRalph Craig EvenMark Stephen FrazzaYili GuoRobert KrasnanskyRosemarie Palmer Lauer
    • James Keith BardmanRalph Craig EvenMark Stephen FrazzaYili GuoRobert KrasnanskyRosemarie Palmer Lauer
    • C08J300
    • C08F265/06C08F263/04C08F265/02C09D151/003C08L2666/02
    • A multi-stage aqueous emulsion-polymer suitable for use in dirt pickup resistant coatings and coatings containing the polymer are provided. The multi-stage aqueous emulsion polymer includes (i) a first polymer including at least one nonionic copolymerized monoethylenically unsaturated monomer, from 0.5% to 7% of a copolymerized monoethylenically unsaturated ionic monomer, based on the weight of the first polymer, and from 0% to 1.0%, based on the weight of the first polymer, of a copolymerized multi-ethylenically unsaturated monomer, the first polymer having a Tg of 15° C. to 105° C.; and (ii) a second polymer comprising at least one nonionic copolymerized monoethylenically unsaturated monomer, from 0% to 2% of a copolymerized monoethylenically unsaturated ionic monomer, and from 0.25% to 6%, based on the weight of the second polymer, copolymerized multi-ethylenically unsaturated monomer, the second polymer having a Tg of −55° C. to 30° C., the second polymer having a different composition than the first copolymer, and the second polymer being from 25% to 75% of the total weight of the first polymer and the second polymer, based on dry polymer weights.
    • 提供了适用于防尘涂层和含有聚合物的涂层的多级水性乳液聚合物。 多级水性乳液聚合物包括(i)包含至少一种非离子共聚单烯属不饱和单体的第一聚合物,基于第一聚合物重量的0.5%至7%的共聚单烯属不饱和离子单体,和0 基于第一聚合物的重量计,共聚多烯属不饱和单体的百分比至1.0%,第一聚合物的Tg为15℃至105℃; 和(ii)包含至少一种非离子共聚单烯属不饱和单体,0%至2%共聚单烯属不饱和离子单体和基于第二聚合物重量的0.25%至6%的第二聚合物,共聚多 烯属不饱和单体,第二聚合物的Tg为-55℃至30℃,第二聚合物的组成不同于第一共聚物,第二聚合物的总重量为25%至75% 的第一聚合物和第二聚合物,基于干聚合物重量。