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1. 发明授权

US5541349A Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom 失效
标题翻译：含有部分离域II结合基团的金属络合物及其加成聚合催化剂
公开(公告)号：US5541349A
公开(公告)日：1996-07-30
申请号：US304301
申请日：1994-09-12
申请人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
发明人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
IPC分类号： C07F7/00 , C07F7/28 , C07F17/00 , C08F4/642 , C08F4/659 , C08F10/00 , C07F5/02 , C07F7/10
CPC分类号： C07F17/00 , C07F7/00 , C07F7/28 , C08F10/00 , C08F4/659 , C08F4/65908 , C08F4/65912
摘要： Novel Group 4 metal complexes wherein the metal is in the +2 or +4 formal oxidation state containing a cyclic or noncyclic, non-aromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes including novel zwitterionic complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型4族金属络合物，其中金属为+2或+4形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，所述络合物的催化衍生物包括新型两性离子复合物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

2. 发明授权

US5495036A Metal (III) complexes containing conjugated, non-aromatic anionic II-bound groups and addition polymerization catalysts therefrom 失效
标题翻译：含有共轭非芳族阴离子II键合基团的金属（III）配合物及其加成聚合催化剂
公开(公告)号：US5495036A
公开(公告)日：1996-02-27
申请号：US304315
申请日：1994-09-12
申请人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
发明人： David R. Wilson , David R. Neithamer , Peter N. Nickias , W. Jack Kruper, Jr.
IPC分类号： C07F5/00 , C07F7/00 , C07F13/00 , C07F17/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/28
CPC分类号： C07F17/00 , C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592
摘要： Novel Group 4, Group 3 or Lanthanide metal complexes wherein the metal is in the +3 formal oxidation state containing a cyclic or non-cyclic, nonaromatic, anionic, dienyl ligand group bound to M and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型第4族，第3族或镧系元素金属络合物，其中金属为+3形式氧化态，其含有与M结合并具有桥连配体结构的环状或非环状，非芳族，阴离子，二烯基配体基团，复合物并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

3. 发明授权

US6034021A Metal complexes containing bridged, non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom 失效
标题翻译：含有桥连的，非芳族的，阴离子的，二烯基的金属络合物和由其加成的聚合催化剂
公开(公告)号：US6034021A
公开(公告)日：2000-03-07
申请号：US113265
申请日：1998-07-10
申请人： David R. Wilson , Peter N. Nickias , David R. Neithamer , Richard D. Ernst
发明人： David R. Wilson , Peter N. Nickias , David R. Neithamer , Richard D. Ernst
IPC分类号： C07F7/08 , C07F7/00 , C07F17/00 , C07F19/00 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F210/16 , C08F4/659 , C08F4/65912 , Y10S526/943
摘要： Catalytic derivatives of novel Group 4 metal complexes wherein the metal is in the +2, +3, or +4 formal oxidation state containing two ligand groups bound by .pi.-electrons, at least one of which is a cyclic or noncyclic, non-aromatic, anionic, dienyl ligand group and having a bridged ligand structure, and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型第4族金属络合物的催化衍生物，其中金属为+2，+3或+4形式氧化态，其含有由π-电子结合的两个配体基团，其中至少一个为环状或非环状，非芳族阴离子，二烯基配体基团并具有桥连配体结构，并且其用作聚合加成聚合单体的催化剂的用途被公开。

4. 发明授权

US5817849A Metal complexes containing bridged non-aromatic, anionic, dienyl groups and addition polymerization catalysts therefrom 失效
标题翻译：含有桥连非芳族，阴离子，二烯基的金属络合物及其加成聚合催化剂
公开(公告)号：US5817849A
公开(公告)日：1998-10-06
申请号：US896898
申请日：1997-07-18
申请人： David R. Wilson , Peter N. Nickias , David R. Neithamer , Richard D. Ernst
发明人： David R. Wilson , Peter N. Nickias , David R. Neithamer , Richard D. Ernst
IPC分类号： C07F7/08 , C07F7/00 , C07F17/00 , C07F19/00 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00 , C07F7/28
CPC分类号： C08F10/00 , C07F17/00 , C08F210/16 , C08F4/659 , C08F4/65912 , Y10S526/943
摘要： Novel Group 4 metal complexes wherein the metal is in the +2, +3, or +4 formal oxidation state containing two ligand groups bound by n-electrons, at least one of which is a cyclic or noncyclic, non-aromatic, anionic, dienyl ligand group and having a bridged ligand structure, catalytic derivatives of such complexes; and the use thereof as catalysts for polymerizing addition polymerizable monomers are disclosed.
摘要翻译：新型4族金属络合物，其中金属为+2，+ 3或+4形式氧化态，其含有由n个电子结合的两个配体基团，其中至少一个是环状或非环状，非芳族的，阴离子的，具有桥连配体结构，这种络合物的催化衍生物; 并且公开了其作为用于聚合加成聚合单体的催化剂的用途。

5. 发明授权

US06268444B1 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process 有权
标题翻译：含3-杂原子取代的环戊二烯基金属络合物和烯烃聚合方法
公开(公告)号：US06268444B1
公开(公告)日：2001-07-31
申请号：US09230185
申请日：1999-01-15
申请人： Jerzy Klosin , William J. Kruper, Jr. , Peter N. Nickias , Jasson T. Patton , David R. Wilson
发明人： Jerzy Klosin , William J. Kruper, Jr. , Peter N. Nickias , Jasson T. Patton , David R. Wilson
IPC分类号： C08F416
CPC分类号： C07F17/00 , C07F7/10 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F2420/02 , Y10S526/943 , C08F210/14 , C08F2500/12
摘要： This invention relates to heteroatom substituted cyclopentadienyl-containing ligands, metal complexes containing these ligands, catalyst systems prepared from catalyst components comprising these metal complexes. The metal complexes contain a “a” heteroatom-Cp bond or a ring heteroatom-Cp bond in the 3-position of the Cp. In preferred metal complexes the ligand is a 3-heteroatom substituted indenyl group. The catalyst systems for olefin polymerization may be used at high temperatures, are highly active and produce high molecular weight polymer.
摘要翻译：本发明涉及含杂原子取代的含环戊二烯基的配位体，含有这些配体的金属络合物，由包含这些金属络合物的催化剂组分制备的催化剂体系金属络合物在Cp的3位上含有“a”个杂原子-Cp键或环杂原子-Cp键。在优选的金属络合物中，配体是3-杂原子取代的茚基。用于烯烃聚合的催化剂体系可以在高温下使用，高活性并且产生高分子量聚合物。

6. 发明授权

US6140521A Ansa group 4 metal bis (.mu.-substituted) aluminum complexes 失效
标题翻译： Ansa组4金属双（μ-取代）铝络合物
公开(公告)号：US6140521A
公开(公告)日：2000-10-31
申请号：US330672
申请日：1999-06-11
申请人： Eugene Y. Chen , William J. Kruper, Jr. , Peter N. Nickias , David R. Wilson
发明人： Eugene Y. Chen , William J. Kruper, Jr. , Peter N. Nickias , David R. Wilson
IPC分类号： C07F5/06 , C07F7/10 , C07F7/28 , C07F17/00 , C07F19/00 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C07F7/00 , C08F4/64
CPC分类号： C08F10/00 , C07F17/00 , C07F5/066 , C08F210/16 , C08F4/65908 , C08F4/6592 , C08F4/65927 , Y10S526/943
摘要： Ansa bis(.mu.-substituted) Group 4 metal and aluminum compounds comprising a single Group 4 metal atom and two aluminum metal atoms corresponding to the formula: ##STR1## wherein: L' is a .pi.-bonded group,M is a Group 4 metal,J is nitrogen or phosphorus;Z is a divalent bridging group causing the complex to have an ansa structure,R' is an inert monovalent ligand;r is one or two;X independently each occurrence is a Lewis basic ligand group able to form a .mu.-bridging ligand group, and optionally the two X groups may be joined together, andA' independently each occurrence is an aluminum containing Lewis acid compound that forms an adduct with the metal complex by means of the .mu.-bridging groups, and optionally two A' groups may be joined together thereby forming a single difunctional Lewis acid containing compound, and a method of preparation comprising contacting a charge-neutral Group IV metal coordination complex having at least two Lewis basic groups with at least two molar equivalents of charge-neutral aluminum coordination complexes having Lewis acidic aluminum atoms such that at least two of the aluminum atoms of the aluminum coordination complexes bond to at least two of the Lewis basic groups of the Group IV coordination complex.
摘要翻译： Ansa双（μ-取代的）第4族金属和铝化合物，其包含对应于下式的单个第4族金属原子和两个铝金属原子：其中：L'是π键合基团，M是第4族金属，J是氮或磷; Z是使络合物具有ansa结构的二价桥连基团，R'是惰性单价配体; r是一两个; 独立地，X独立地是能够形成mu-桥接配体基团的路易斯碱性配体基团，并且任选地两个X基团可以连接在一起，并且A'独立地是含铝的路易斯酸化合物，其与金属络合物，并且任选地两个A'基团可以连接在一起，从而形成单一双官能路易斯酸化合物，以及制备方法，包括使具有至少一个电荷的中性IV族金属配位络合物两个路易斯碱性基团，其具有至少两摩尔当量的具有路易斯酸性铝原子的电荷 - 中性铝配位络合物，使得铝配位络合物的至少两个铝原子与至少两个第IV族的路易斯碱性基团键合协调综合体

7. 发明授权

US06806326B2 Constrained geometry addition polymerization catalysts 失效
标题翻译：约束几何加成聚合催化剂
公开(公告)号：US06806326B2
公开(公告)日：2004-10-19
申请号：US10037335
申请日：2001-11-06
申请人： James C. Stevens , Robert K. Rosen , Peter N. Nickias , David R. Wilson
发明人： James C. Stevens , Robert K. Rosen , Peter N. Nickias , David R. Wilson
IPC分类号： C08F444
CPC分类号： C08F10/02 , C07F7/10 , C07F9/5045 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08L23/08 , C08L23/0838 , C08L25/06 , C08L2203/14 , Y10S526/943 , C08F2/34 , C08L2666/04 , C08F2500/12 , C08F2500/03 , C08F212/08 , C08F214/08 , C08F210/14 , C08F2500/08 , C08F2500/20 , C08F2500/26 , C08F2500/02 , C08F2500/07 , C08F210/08 , C08F210/06 , C08F212/14
摘要： Metal complexes having constrained geometry and a process for preparation thereof, addition polymerization catalysts formed therefrom, processes for preparation of such addition polymerization catalysts, methods of use, and novel polymers formed thereby, including EIPE resins and pseudo-random copolymers, are disclosed and claimed.
摘要翻译：具有约束几何形状的金属络合物及其制备方法，由其形成的加成聚合催化剂，由此形成的加成聚合催化剂，使用方法和由其形成的新型聚合物的方法，包括EIPE树脂和伪随机共聚物，。

8. 发明授权

US08574773B2 Battery electrolyte solutions containing aromatic phosphorus compounds 有权
标题翻译：含有芳香族磷化合物的电池电解液
公开(公告)号：US08574773B2
公开(公告)日：2013-11-05
申请号：US13132374
申请日：2009-11-16
申请人： David R. Wilson , Ravi B. Shankar , Houxiang Tang , Andrew J. Pasztor, Jr. , Peter M. Margl , William J. Kruper, Jr. , Mark D. Newsham , Jing Jin , Matthew M. Yonkey , Deidre A. Strand , Thomas D. Gregory , Jamie L. Cohen , Jeremy R. Stajdl
发明人： David R. Wilson , Ravi B. Shankar , Houxiang Tang , Andrew J. Pasztor, Jr. , Peter M. Margl , William J. Kruper, Jr. , Mark D. Newsham , Jing Jin , Matthew M. Yonkey , Deidre A. Strand , Thomas D. Gregory , Jamie L. Cohen , Jeremy R. Stajdl
IPC分类号： H01M10/0567 , H01M10/052
CPC分类号： H01M10/0567 , H01M6/168 , H01M10/052 , H01M10/4235 , H01M2300/0025 , Y02T10/7011
摘要： A battery electrolyte solution contains from 0.01 to 80% by weight of an aromatic phosphorus compound. The aromatic phosphorus compound provides increased thermal stability for the electrolyte, helping to reduce thermal degradation, thermal runaway reactions and the possibility of burning. The aromatic phosphorus compound has little adverse impact on the electrical properties of the battery, and in some cases actually improves battery performance.
摘要翻译：电池电解液含有0.01〜80重量％的芳香族磷化合物。芳族磷化合物为电解质提供了增加的热稳定性，有助于减少热降解，热失控反应和燃烧的可能性。芳香族磷化合物对电池的电气性能几乎没有不利影响，在某些情况下实际上提高了电池性能。

9. 发明授权

US08324416B2 Multifunctional chain shuttling agents 有权
标题翻译：多功能链式穿梭剂
公开(公告)号：US08324416B2
公开(公告)日：2012-12-04
申请号：US12845023
申请日：2010-07-28
申请人： Thomas P. Clark , Nahrain E. Kamber , Sara B. Klamo , Phillip D. Hustad , David R. Wilson
发明人： Thomas P. Clark , Nahrain E. Kamber , Sara B. Klamo , Phillip D. Hustad , David R. Wilson
IPC分类号： C07F5/06 , C08F4/64 , C08F4/642
CPC分类号： C08F2/38 , C08F10/00 , C08F10/14 , H01M2/1653 , H01M10/0525 , H01M10/4235 , C08F4/64113
摘要： The invention generally relates to chain shuttling agents (CSAs), a process of preparing the CSAs, a composition comprising a CSA and a catalyst, a process of preparing the composition, a processes of preparing polyolefins, end functional polyolefins, and telechelic polyolefins with the composition, and the polyolefins, end functional polyolefins, and telechelic polyolefins prepared by the processes.
摘要翻译：本发明通常涉及链穿梭剂（CSA），制备CSA的方法，包含CSA和催化剂的组合物，制备组合物的方法，制备聚烯烃，末端官能聚烯烃和遥爪聚烯烃的方法，其中组合物，以及通过该方法制备的聚烯烃，末端官能聚烯烃和遥爪聚烯烃。

10. 发明申请

US20080153950A1 Phosphorus-sulfur FR additives and polymer systems containing same 审中-公开
标题翻译：磷硫FR添加剂和含有其的聚合物体系
公开(公告)号：US20080153950A1
公开(公告)日：2008-06-26
申请号：US12004345
申请日：2007-12-20
申请人： Ravi B. Shankar , William J. Kruper , David R. Wilson , Bruce A. King , Michelle L. Hudack , Daniel J. Murray , Chun Wang , William Gerald Stobby , Ted A. Morgan , Mark W. Beach , Inken Beulich , Ing Feng Hu
发明人： Ravi B. Shankar , William J. Kruper , David R. Wilson , Bruce A. King , Michelle L. Hudack , Daniel J. Murray , Chun Wang , William Gerald Stobby , Ted A. Morgan , Mark W. Beach , Inken Beulich , Ing Feng Hu
IPC分类号： C08K5/5398 , C08K5/51 , C07F9/6571
CPC分类号： C07F9/1653 , C07F9/173 , C07F9/657136 , C07F9/657154 , C07F9/657181 , C08K5/5398
摘要： Phosphorus-sulfur compounds have flame retardant activity in organic polymer systems. The phosphorus-sulfur compounds can be represented by the structure: wherein X is oxygen or sulfur, T is a covalent bond, oxygen, sulfur or nitrogen, provided that at least one of X and T is sulfur, each X′ is independently oxygen or sulfur, each m is independently zero or 1 when X′ is oxygen and zero, 1 or 2 when X′ is sulfur, n is at least 1 and preferably at least 2, each R is independently an unsubstituted or inertly substituted hydrocarbyl group or the R groups together form an unsubstituted or inertly substituted divalent organic group and A is an organic linking group.
摘要翻译：磷 - 硫化合物在有机聚合物体系中具有阻燃活性。磷硫化合物可以由以下结构表示：其中X是氧或硫，T是共价键，氧，硫或氮，条件是X和T中的至少一个是硫，每个X'独立地是氧或硫，当X'为氧时，每个m独立为0或1，当X'为硫时为0,1或2，n为至少1，优选为至少2，每个R独立地为未取代或惰性取代的烃基或 R基团一起形成未取代或惰性取代的二价有机基团，A是有机连接基团。

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