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    • 3. 发明授权
    • Herbicidal 9-arylimino-8-thia-1,6-diazabicyclo [4.3.0]nonane-7-ones (and
thiones)
    • 除草9-芳基亚氨基-8-硫杂-1,6-二氮杂双环[4.3.0]壬烷-7-酮(和硫杂)
    • US4906281A
    • 1990-03-06
    • US214278
    • 1988-07-01
    • Jun H. Chang
    • Jun H. Chang
    • A01N43/90C07D513/04
    • C07D513/04A01N43/90
    • Disclosed are herbicidal compounds of the formula ##STR1## wherein W is sulfur or oxygen;X is Br, Cl, F, alkyl, or haloalkyl; Y is Br, Cl, F, methyl, haloalkyl, haloalkoxy, nitro, or a radical of the formula --CH.sub.2 QR.sup.8 in which Q is O, S, S(O), or S(O).sub.2 and R.sup.8 is alkyl, alkenyl, alkynyl, optionally substituted phenyl; R is alkyl, haloalkyl, dialkylamino, carboxymethyl, hydroxy, or optionally substituted phenyl; R.sup.1 is hydrogen, alkyl, benzyl, haloalkyl, alkoxy, alkynyl, alkenyl, alkoxymethyl, cyanomethyl, hydroxycarbonylmethyl, alkoxycarbonylmethyl, or a group of the formula --SO.sub.2 R or --alkylene--SO.sub.2 R in which R is as defined above; or R and R.sup.1 together are a divalent alkylene radical; or a base addition salt of a compound as defined above in which R or R.sup.1 is or contains an acidic proton.
    • 公开了式IMA的除草化合物,其中W是硫或氧; X是Br,Cl,F,烷基或卤代烷基; Y是Br,Cl,F,甲基,卤代烷基,卤代烷氧基,硝基或其中Q是O,S,S(O)或S(O)2的式-CH 2 QR 8基团,R 8是烷基,烯基, 炔基,任选取代的苯基; R是烷基,卤代烷基,二烷基氨基,羧甲基,羟基或任选取代的苯基; R1是氢,烷基,苄基,卤代烷基,烷氧基,炔基,烯基,烷氧基甲基,氰基甲基,羟基羰基甲基,烷氧基羰基甲基或式-SO2R或 - 亚烷基-SO2R的基团,其中R定义如上; 或R和R 1一起为二价亚烷基; 或其中R或R 1为或含有酸性质子的上述化合物的碱加成盐。
    • 4. 发明授权
    • 9-Arylimino-8 thia-1,6-Duzafucyclo[4.3.0] nomane-7-one (and thione)
herbicides
    • 9-芳基亚氨基-8-硫杂-1,6-二氮杂环[4.3.0]正庚烷-7-酮(和硫酮)除草剂
    • US4913723A
    • 1990-04-03
    • US229585
    • 1988-08-08
    • Jun H. Chang
    • Jun H. Chang
    • A01N43/90C07D513/04
    • C07D513/04A01N43/90
    • Disclosed are herbicidal compounds, compositions containing them, and a method of use for the compositions in controlling undesired plant growth. The herbicidal compounds are compounds of the formula ##STR1## in which W is S or O and Z-Ph is a substituted phenyl group in which Z is -C(R).dbd.Q; R is H, lower alkyl, or aryl; Q is NR' or oxygen; R' is alkoxy, hydroxy, alkenyloxy, alkynyloxy, alkylcarbonyloxy, arylcarbonloxy, trialkylsilyloxy, arylalkoxy, aryl, alkyl, cycloalkyl, or a group of the formula --SO.sub.2 R", --OCO.sub.2 R", OC(O)NHR", or --CH.sub.2 CO.sub.2 R"; and R" is lower alkyl or aryl. The phenyl moiety Ph is advantageously multisubstituted.
    • 公开了除草化合物,含有它们的组合物,以及用于控制不期望的植物生长的组合物的方法。 除草化合物是其中W是S或O并且Z-Ph是其中Z是-C(R)= Q的取代的苯基的式“IMAGE”的化合物; R是H,低级烷基或芳基; Q是NR'或氧; R'是烷氧基,羟基,烯氧基,炔氧基,烷基羰基氧基,芳基羰氧基,三烷基甲硅烷氧基,芳基烷氧基,芳基,烷基,环烷基或式-SO2R“,-OCO2R”,OC(O)NHR“ -CH 2 CO 2 R“ 并且R“为低级烷基或芳基。 苯基部分Ph有利地是多取代的。
    • 7. 发明授权
    • Tetrahydrophthalimide carbamate herbicidal compositions
    • 四氢邻苯二甲酰亚胺氨基甲酸酯除草组合物
    • US4994104A
    • 1991-02-19
    • US286434
    • 1988-12-19
    • Jun H. Chang
    • Jun H. Chang
    • A01N47/22
    • A01N47/22
    • Disposed are herbicidal compounds of the formula ##STR1## wherein Q is a heterocyclic ring having 5 to 7 ring atoms and having the formula ##STR2## wherein Z is an oxygen or sulfur atom or a vinylene group, R.sup.4 and R.sup.5 are independently alkylene groups having 1 to 4 carbon atoms, and m and n are each independently an integer of 0 or 1; and in which R.sup.1 is H, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, alkoxyalkyl, alkoxyalkoxyalkyl, cycloalkyl, aralkyl, alkylthioalkyl, hydroxy, alkoxy, cyanoalkyl or alkylcarbonylalkyl; R.sup.2 and R.sup.3 are independently H or alkyl; and X is H, Cl or F. Also disclosed are herbicidal compositions and an herbicidal method of use for the herbicidal compounds.
    • 其中Q为具有5至7个环原子并具有式“IMAGE”的杂环,其中Z为氧或硫原子或亚乙烯基,R4和R5独立地为具有式 1至4个碳原子,m和n各自独立地为0或1的整数; 其中R 1为H,烷基,烯基,炔基,卤代烷基,卤代烯基,卤代炔基,烷氧基烷基,烷氧基烷氧基烷基,环烷基,芳烷基,烷硫基烷基,羟基,烷氧基,氰基烷基或烷基羰基烷基。 R2和R3独立地是H或烷基; X是H,Cl或F.还公开了用于除草化合物的除草组合物和除草方法。
    • 10. 发明授权
    • Herbicidal isoxazolidinone derivatives
    • 除草异恶唑烷酮衍生物
    • US4692182A
    • 1987-09-08
    • US864686
    • 1986-05-19
    • Jun H. Chang
    • Jun H. Chang
    • A01N43/80C07D261/04
    • C07D261/04A01N43/80
    • Isoxazolidinones of the following formula are herbicides: ##STR1## or an agriculturally acceptable salt thereof in which R.sub.1 and R.sub.2 are independently selected from -hydrogen and-halogen; and R.sub.3 is of the formula ##STR2## wherein n is 0 or 1, andwhen n is 0,W is selected from -hydrogen, -lower alkyl, -lower haloalkanoyl, and -benzoyl;X is selected from -hydrogen and -lower alkyl; andY is selected from -hydrogen, -lower alkyl, -cycloalkyl, -lower alkanoyl, -lower haloalkanoyl, -benzoyl, -2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)benzoyl, -2,4-dichlorophenoxyacetyl, -lower alkyloxycarbonyl, -lower alkyloxycarbonyl, -lower alkylaminocarbonyl, -phenylaminocarbonyl, and -lower alkylthiocarbonyl; orW and X together constitute a chemical bond; and Y is selected from -nitrogen and -lower alkyloxycarbonyl; andwhen n is 1,X and Z together constitute a chemical bond;W is -hydrogen;V is selected from -hydrogen and -lower alkyl; andY is selected from -lower alkyl, -phenyl, -carboxyl, and -lower alkyloxycarbonyl, orV and Y together are an alkyl chain of 4-6 carbon atoms.
    • 下式的异恶唑烷酮是除草剂:其中R 1和R 2独立地选自氢和卤素;或其农业上可接受的盐, 其中n为0或1,当n为0时,W选自氢,低级烷基, - 低级卤代烷酰基和 - 苯甲酰基; X选自氢和低级烷基; 并且Y选自氢,较低的烷基, - 环烷基, - 低级链烷酰基, - 低级卤代烷酰基, - 苯甲酰基,-2-硝基-5-(2-氯-4-三氟甲基苯氧基)苯甲酰基,-2,4-二氯苯氧基乙酰基 低级烷氧基羰基,低级烷基氨基羰基,苯基氨基羰基和低级烷硫基羰基; 或W和X一起构成化学键; Y选自 - 和 - 低级烷氧基羰基; 当n为1时,X和Z一起构成化学键; W是氢; V选自氢和低级烷基; 并且Y选自低级烷基, - 苯基, - 羧基和 - 低级烷氧基羰基,或V和Y一起是4-6个碳原子的烷基链。