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    • 1. 发明授权
    • Low temperature plasma oxidation process
    • 低温等离子体氧化工艺
    • US5412246A
    • 1995-05-02
    • US186568
    • 1994-01-26
    • David M. DobuzinskyDavid L. HarmonSrinandan R. KasiDonald M. KenneySon V. NguyenTue NguyenPai-Hung Pan
    • David M. DobuzinskyDavid L. HarmonSrinandan R. KasiDonald M. KenneySon V. NguyenTue NguyenPai-Hung Pan
    • C23C8/36H01L21/31H01L21/316H01L21/321H01L21/8242H01L27/108H01L29/12
    • H01L21/32105H01L21/02238H01L21/02252H01L21/31662Y10S148/118Y10S257/90
    • A process for forming a thin film on a surface of a semiconductor device. The process involves formation of a silicon dioxide film by plasma enhanced thermal oxidation, employing a mixture of ozone and oxygen which are generated separately from the reactor chamber in a volume ratio of about 1-10/1, preferably about 5-7/1, at a temperature generally below 440.degree. C., preferably about 350.degree.-400.degree. C. The process is used to form sidewall oxide spacers on polysilicon gates for field effect transistors. A relatively fast oxidation rate is achieved at a temperature significantly below that employed in conventional oxidation processes, and this serves to reduce dopant diffusion from the polysilicon. In addition, the resulting film demonstrates low stress with good conformal step coverage of the polysilicon gates. Another use of the process is to grow thin gate oxides and oxide-nitride-oxide with a thickness of less than 100 .ANG.. An oxide film of uniform thickness is formed by controlling the temperature, RF power, exposure time and oxygen/ozone ratio for thin gate oxide (
    • 一种在半导体器件的表面上形成薄膜的工艺。 该方法包括通过等离子体增强的热氧化形成二氧化硅膜,采用臭氧和氧的混合物,其以反应器室分开产生,体积比约为1-10 / 1,优选约5-7 / 1, 在一般低于440℃,优选约350-400℃的温度下进行。该方法用于在场效应晶体管的多晶硅栅上形成侧壁氧化物间隔物。 在显着低于常规氧化工艺中使用的温度下实现相对较快的氧化速率,这用于减少掺杂剂从多晶硅的扩散。 此外,所得膜表现出低应力,并具有多晶硅栅极的良好的共形台阶覆盖。 该方法的另一个用途是生长厚度小于100安培的薄栅氧化物和氧化物 - 氮化物 - 氧化物。 通过控制ULSI FET制造中薄栅氧化物(<100 ANGSTROM)应用的温度,RF功率,曝光时间和氧/臭氧比,形成均匀厚度的氧化膜。
    • 4. 发明授权
    • Low temperature plasma oxidation process
    • 低温等离子体氧化工艺
    • US5330935A
    • 1994-07-19
    • US915752
    • 1992-07-21
    • David M. DobuzinskyDavid L. HarmonSrinandan R KasiDonald M. KenneySon Van NguyenTue NguyenPai-Hung Pan
    • David M. DobuzinskyDavid L. HarmonSrinandan R KasiDonald M. KenneySon Van NguyenTue NguyenPai-Hung Pan
    • C23C8/36H01L21/31H01L21/316H01L21/321H01L21/8242H01L27/108H01L21/02
    • H01L21/32105H01L21/02238H01L21/02252H01L21/31662Y10S148/118Y10S257/90
    • A process for forming a thin film on a surface of a semiconductor device. The process involves formation of a silicon dioxide film by plasma enhanced thermal oxidation, employing a mixture of ozone and oxygen which are generated separately from the reactor chamber in a volume ratio of about 1-10/1, preferably about 5-7/1, at a temperature generally below 440.degree. C., preferably about 350.degree.-400.degree. C. The process is used to form sidewall oxide spacers on polysilicon gates for field effect transistors. A relatively fast oxidation rate is achieved at a temperature significantly below that employed in conventional oxidation processes, and this serves to reduce dopant diffusion from the polysilicon. In addition, the resulting film demonstrates low stress with good conformal step coverage of the polysilicon gates. Another use of the process is to grow thin gate oxides and oxide-nitride-oxide with a thickness of less than 100.ANG.. An oxide film of uniform thickness is formed by controlling the temperature, RF power, exposure time and oxygen/ozone ratio for thin gate oxide (
    • 一种在半导体器件的表面上形成薄膜的工艺。 该方法包括通过等离子体增强的热氧化形成二氧化硅膜,采用臭氧和氧的混合物,其以反应器室分开产生,体积比约为1-10 / 1,优选约5-7 / 1, 在一般低于440℃,优选约350-400℃的温度下进行。该方法用于在场效应晶体管的多晶硅栅上形成侧壁氧化物间隔物。 在显着低于常规氧化工艺中使用的温度下实现相对较快的氧化速率,这用于减少掺杂剂从多晶硅的扩散。 此外,所得膜表现出低应力,并具有多晶硅栅极的良好的共形台阶覆盖。 该方法的另一个用途是生长厚度小于100安培的薄栅氧化物和氧化物 - 氮化物 - 氧化物。 通过控制ULSI FET制造中薄栅氧化物(<100 ANGSTROM)应用的温度,RF功率,曝光时间和氧/臭氧比,形成均匀厚度的氧化膜。