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1. 发明授权

US6025450A Amine containing polymers and products therefrom 失效
标题翻译：含胺的聚合物及其产品
公开(公告)号：US6025450A
公开(公告)日：2000-02-15
申请号：US112913
申请日：1998-07-09
申请人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
发明人： David F. Lawson , Mark L. Stayer, Jr. , David Saffles , Koichi Morita , Yoichi Ozawa , Ryota Fujio , Thomas A. Antkowiak
IPC分类号： B60C1/00 , B60C15/06 , C08C19/44 , C08F36/04
CPC分类号： C08C19/44 , B60C1/00 , B60C1/0016 , B60C1/0025 , B60C15/06 , C08F36/04 , Y10S152/905
摘要： A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.
摘要翻译：官能化聚合物包括携带至少一种选自具有通式的烷基，二烷基和环烷基胺基的官能团的聚合物链和具有以下通式的环胺基：其中R1是具有1至约12个碳原子的烷基，环烷基或芳烷基原子，并且R 2是具有约3至约16个亚甲基的亚烷基，取代的亚烷基，氧基或N-烷基氨基 - 亚烷基。本发明还提供了基于这样的聚合物的产品。

2. 发明授权

US5329005A Soluble anionic polymerization initiators and preparation thereof 失效
标题翻译：可溶性阴离子聚合引发剂及其制备方法
公开(公告)号：US5329005A
公开(公告)日：1994-07-12
申请号：US955582
申请日：1992-10-02
申请人： David F. Lawson , Koichi Morita , Yoichi Ozawa , Mark L. Stayer, Jr. , Ryota Fujio
发明人： David F. Lawson , Koichi Morita , Yoichi Ozawa , Mark L. Stayer, Jr. , Ryota Fujio
IPC分类号： B60C1/00 , C07F1/02 , C08F4/00 , C08F4/08 , C08F4/42 , C08F4/48 , C08F36/00 , C08F36/04 , C08K3/04 , C08L9/00 , C08L21/00 , C07D487/08 , C07D295/00
CPC分类号： C08F36/04
摘要： The present invention is directed toward anionic polymerization initiators which are soluble in hydrocarbon solvents. The initiators include a lithio amine having the general formula ALi. The component A is a dialkyl or dicycloalkyl amine radical or a cyclic amine. The invention is also directed toward polymers and other products made using the initiator, and methods therefor. Further, the invention contemplates a polymer, a polymer composition and products therefrom, which include a functional group from the reaction product of an amine and an organolithium compound. The resulting polymers may be terminated with a terminating, coupling or linking agent, which may provide the polymer with a multifunctionality.
摘要翻译：本发明涉及可溶于烃溶剂的阴离子聚合引发剂。引发剂包括具有通式ALi的锂胺。组分A是二烷基或二环烷基胺基或环胺。本发明还涉及使用引发剂制备的聚合物和其它产品及其方法。此外，本发明涉及聚合物，聚合物组合物及其产物，其包括来自胺和有机锂化合物的反应产物的官能团。所得聚合物可以用终止的，偶联或连接剂终止，其可以为聚合物提供多功能性。

3. 发明授权

US5625017A Process for preparing a polymer using lithium initiator prepared by in situ preparation 失效
标题翻译：通过原位制备制备使用锂引发剂的聚合物的方法
公开(公告)号：US5625017A
公开(公告)日：1997-04-29
申请号：US531975
申请日：1995-09-21
申请人： Koichi Morita , Atsushi Nakayama , Yoichi Ozawa , Ryota Fujio
发明人： Koichi Morita , Atsushi Nakayama , Yoichi Ozawa , Ryota Fujio
IPC分类号： C08F2/06 , C08F4/48 , C08F36/04 , C08F4/08
CPC分类号： C08F36/04
摘要： A process for preparing a polymer comprises polymerizing a conjugated diene monomer and/or a vinylaromatic hydrocarbon monomer in a hydrocarbon solvent in the presence of or in the absence of a randomizer by using a lithium polymerization initiator which is formed by bringing an organolithium compound and at least one secondary amine compound into contact with each other in the polymerization system in the presence of at least said monomer, wherein the polymerization conversion at the time of contact is less than 5%. The secondary amine is an amine compound having two hydrocarbon groups bonded to N or an imine compound in which an NH group and a saturated or unsaturated cyclic structure group form a cyclic structure. The cyclic structure group comprises a hydrocarbon group as the ring member and may also comprise N or O. The method of production uses the initiator which does not require separate preparation of the initiator, shows excellent reproducibility, allows for the evaluation of accuracy of concentration and realizes high effective initiator concentration. The high molecular weight polymer produced by the method has a narrow molecular weight distribution; is controllable; has a highly reproducible molecular weight and microstructure; exhibits excellent coupling properties based on the living polymerization and provides low hysteresis loss properties.
摘要翻译：制备聚合物的方法包括在烃溶剂中，在无规脱硫剂的存在下或在不存在无规化剂的情况下，通过使用通过使有机锂化合物形成的锂聚合引发剂和在有机锂化合物中形成的聚合引发剂来聚合共轭二烯单体和/ 至少一种仲胺化合物在至少所述单体的存在下在聚合体系中彼此接触，其中接触时的聚合转化率小于5％。仲胺是具有与N键合的两个烃基或其中NH基和饱和或不饱和的环状结构基团形成环状结构的亚胺化合物的胺化合物。环状结构基包括作为环成员的烃基，也可以包含N或O.生产方法使用不需要分离制备引发剂的引发剂，显示出优异的再现性，允许评价浓度的精确度和实现高效引发剂浓度。通过该方法制备的高分子量聚合物具有窄的分子量分布; 是可控的具有高度可重复的分子量和微观结构; 基于活性聚合表现出优异的偶联性能，并提供低滞后损失性能。

4. 发明授权

US5514753A Process for preparing a block copolymer 失效
标题翻译：制备嵌段共聚物的方法
公开(公告)号：US5514753A
公开(公告)日：1996-05-07
申请号：US268323
申请日：1994-06-30
申请人： Yoichi Ozawa , Ryota Fujio
发明人： Yoichi Ozawa , Ryota Fujio
IPC分类号： C08F297/02 , C08F271/02 , C08F265/06
CPC分类号： C08F297/02
摘要： A block copolymer containing a non-polar polymer block and a polar polymer block was prepared by using an anionic polymerization initiator, by reacting an organic compound which can form an ate complex at the active end of the non-polar polymer block, the compound which contains a main group element of II or III group, before the addition of the polar monomer.
摘要翻译：含有非极性聚合物嵌段和极性聚合物嵌段的嵌段共聚物是通过使用阴离子聚合引发剂，通过使在非极性聚合物嵌段的活性端上形成复合物的有机化合物，在加入极性单体之前，含有II或III族的主要元素。

5. 发明授权

US5576376A Rubber composition containing a conjugated diene polymer 失效
标题翻译：含有共轭二烯聚合物的橡胶组合物
公开(公告)号：US5576376A
公开(公告)日：1996-11-19
申请号：US219284
申请日：1994-03-28
申请人： Tadashi Shibata , Ryota Fujio
发明人： Tadashi Shibata , Ryota Fujio
IPC分类号： C08C19/44 , C08F4/42 , C08F4/48 , C08F8/30 , C08F8/32 , C08F36/04 , C08K3/04 , C08L9/00 , C08L9/06 , C08L19/00 , C08F36/00 , C08F8/34
CPC分类号： C08L19/006 , C08C19/44 , C08F36/04 , C08F8/30 , C08L9/00 , C08K3/04 , C08K5/01 , C08L9/06
摘要： A rubber composition having good physical properties such as breaking properties, wear strength and grip properties, and good processability at the same time is suitable for a high performance tire. A nitrogen containing polymer with a weight average molecular weight of 70.times.10.sup.4 to 250.times.10.sup.4 is compounded with 60 to 200 phr of carbon black, a softener comprising 30 to 250 phr of a process oil and/or 5 to 100 phr of liquid polymer, and not more than 60 parts of another polymer.
摘要翻译：具有良好的物理性能如断裂性，磨损强度和抓地性能以及同时具有良好加工性能的橡胶组合物适用于高性能轮胎。将重均分子量为70×10 4至250×10 4的含氮聚合物与60至200phr的炭黑混合，软化剂包含30至250phr的工艺油和/或5至100phr的液体聚合物，而不是更多超过60份的另一种聚合物。

6. 发明授权

US5183543A Polyanilines, process for the preparation thereof and cells using them 失效
标题翻译：聚氨酯，其制备方法和使用它们的细胞
公开(公告)号：US5183543A
公开(公告)日：1993-02-02
申请号：US863527
申请日：1986-05-15
申请人： Shinichi Toyosawa , Tadashi Nakajima , Kinya Suzuki , Takahiro Kawagoe , Tadaaki Miyazaki , Takashi Kitamura , Tadashi Fuse , Masao Ogawa , Yoshitomo Masuda , Hideharu Daifuku , Ryota Fujio
发明人： Shinichi Toyosawa , Tadashi Nakajima , Kinya Suzuki , Takahiro Kawagoe , Tadaaki Miyazaki , Takashi Kitamura , Tadashi Fuse , Masao Ogawa , Yoshitomo Masuda , Hideharu Daifuku , Ryota Fujio
IPC分类号： C08F2/58 , C08G73/02 , H01M4/02 , H01M4/40 , H01M4/60 , H01M4/66 , H01M10/36
CPC分类号： H01M4/137 , C08G73/0266 , H01M10/05 , H01M10/36 , H01M4/40 , H01M4/60 , H01M4/66 , H01M4/663 , H01M4/669
摘要： There is provided a polyaniline having a thickness of 0.3 to 5 mm which is suitable for an electronic material, particularly for an electrode material in a cell. Also provided is a cell comprising a positive electrode, a negative electrode and an electrolyte in which the polyaniline having a thickness of 0.3 to 5 mm is employed in at least one of the positive and negative electrodes, the cell having a high energy density and good cell performance stable for a long period of time.
摘要翻译：提供了厚度为0.3-5mm的聚苯胺，其适用于电子材料，特别是电池中的电极材料。还提供了一种电池，其包括正极，负极和电解质，其中在正极和负极中的至少一个中使用厚度为0.3至5mm的聚苯胺，电池具有高的能量密度和良好的电池性能长期稳定。

7. 发明授权

US5916962A Rubber composition including a diene copolymer 失效
标题翻译：包含二烯共聚物的橡胶组合物
公开(公告)号：US5916962A
公开(公告)日：1999-06-29
申请号：US653746
申请日：1996-05-23
申请人： Tadashi Shibata , Ryota Fujio
发明人： Tadashi Shibata , Ryota Fujio
IPC分类号： C08F2/44 , C08F2/38 , C08F4/00 , C08F4/42 , C08F4/46 , C08F4/48 , C08F236/10 , C08K3/04 , C08K5/01 , C08L9/00 , C08L9/06 , C08L21/00
CPC分类号： C08F236/10 , C08L9/06 , C08K3/04
摘要： A rubber composition having good breaking properties, high tan.delta., good wear resistance and a method for preparing a copolymer used in the rubber composition. The copolymer is a butadiene-styrene copolymer prepared in the presence of an organopotassium compound, an oxolanyl alkane and an organolithium initiator compound. The copolymer may be modified. A vulcanite of the rubber composition including 20 parts or more of the copolymer of the present invention has good properties.
摘要翻译：具有良好的断裂性，高的tanδ，良好的耐磨性的橡胶组合物和用于橡胶组合物中使用的共聚物的制备方法。共聚物是在有机钾化合物，氧杂环丁烷基烷烃和有机锂引发剂化合物存在下制备的丁二烯 - 苯乙烯共聚物。可以改性共聚物。包含20份或更多份本发明共聚物的橡胶组合物的硫化胶具有良好的性能。

8. 发明授权

US5292790A Conjugated diene series rubber compositions 失效
标题翻译：共轭二烯系橡胶组合物
公开(公告)号：US5292790A
公开(公告)日：1994-03-08
申请号：US921257
申请日：1992-07-29
申请人： Takashi Shimizu , Takashi Kitamura , Ryota Fujio
发明人： Takashi Shimizu , Takashi Kitamura , Ryota Fujio
IPC分类号： C08F2/06 , C08F4/48 , C08F236/10 , C08K3/04
CPC分类号： C08F236/10 , C08K3/04
摘要： A conjugated diene series rubber composition comprises 100 parts by weight of a diene series rubber containing at least 30 parts by weight of a particular modified styrene-butadiene copolymer rubber, and 30-80 parts by weight of a specified carbon black, and is excellent in strength at breakage, abrasion resistance and low fuel consumption after vulcanization.
摘要翻译：共轭二烯系橡胶组合物包含100重量份含有至少30重量份特定改性苯乙烯 - 丁二烯共聚物橡胶和30-80重量份特定炭黑的二烯系橡胶，并且具有优异的硫化后的断裂强度，耐磨性和低燃料消耗。

9. 发明授权

US5250630A Pneumatic tire 失效
标题翻译：气动轮胎
公开(公告)号：US5250630A
公开(公告)日：1993-10-05
申请号：US691879
申请日：1991-04-26
申请人： Nobumitsu Oshima , Takashi Kitamura , Ryota Fujio , Kenji Matsuo
发明人： Nobumitsu Oshima , Takashi Kitamura , Ryota Fujio , Kenji Matsuo
IPC分类号： B60C1/00 , B60C11/00 , C08C19/28 , C08F8/00 , C08F279/00 , C08F279/02 , C08L13/00 , C08F265/02 , C08F267/02
CPC分类号： C08L13/00 , C08C19/28
摘要： A heat resistant pneumatic tire whose tread is composed of a rubber composition comprising, as a main rubber component, a modified, conjugated diene based polymer prepared by adding an .alpha., .beta.-unsaturated carboxylic acid represented by the following general formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 independently represent hydrogen atom, halogen atom, or an alkyl, alkenyl or allyl group having at most 5 carbon atoms, or a substituted alkyl, alkenyl or allyl group,to a conjugated diene based polymer in an amount within the range between 0.1% and 5.0% based on the weight of the conjugated diene based polymer. This tire is suitable for continuous running at high temperatures and maintains a good road-surface-grip performance even during such running.
摘要翻译：一种耐热充气轮胎，其胎面由橡胶组合物构成，所述橡胶组合物包含通过加入由以下通式表示的α，β-不饱和羧酸作为主要橡胶组分的改性共轭二烯系聚合物：（ I）其中R 1，R 2和R 3独立地表示氢原子，卤素原子或具有至多5个碳原子的烷基，烯基或烯丙基或取代的烷基，烯基或烯丙基，以共轭二烯基聚合物的量在基于共轭二烯基聚合物的重量的0.1％至5.0％的范围内。该轮胎适用于高温连续运行，即使在运行过程中也能保持良好的路面抓地力性能。

10. 发明授权

US5137981A Halogenated polybutadiene series elastomers, method of producing the same and rubber compositions for tire containing this elastomer 失效
标题翻译：卤化聚丁二烯系列弹性体，其制造方法和含有该弹性体的轮胎用橡胶组合物
公开(公告)号：US5137981A
公开(公告)日：1992-08-11
申请号：US347082
申请日：1989-05-26
申请人： Tomoharu Yamada , Ryota Fujio
发明人： Tomoharu Yamada , Ryota Fujio
IPC分类号： C08C19/12
CPC分类号： C08C19/12
摘要： A novel halogenated polybutadiene series elastomer is produced by reacting a polybutadiene series elastomer with a particular active halogen group-containing compound in the presence of a particular organic halogenating agent. The resulting halogenated polybutadiene series elastomer can be subjected to heat-resistant crosslinking with a particular polyvalent amine, and is suitable for the preparation of rubber compositions for tire requiring the heat resistance.
摘要翻译：通过使聚丁二烯系列弹性体与特定的含有活性卤素基团的化合物在特定的有机卤化剂的存在下反应来制备新的卤代聚丁二烯系列弹性体。得到的卤化聚丁二烯系列弹性体可以用特定的多元胺进行耐热交联，适用于制备需要耐热性的轮胎用橡胶组合物。

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