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1. 发明授权

US5554721A Acid catalyzed process for preparing amino acid polymers 失效
标题翻译：用于制备氨基酸聚合物的酸催化方法
公开(公告)号：US5554721A
公开(公告)日：1996-09-10
申请号：US471946
申请日：1995-06-06
申请人： David E. Adler , Michael B. Freeman , James M. Lipovsky , Yi H. Paik , Jan E. Shulman , Graham Swift
发明人： David E. Adler , Michael B. Freeman , James M. Lipovsky , Yi H. Paik , Jan E. Shulman , Graham Swift
IPC分类号： C02F5/10 , A01N61/00 , C08G69/00 , C08G69/10 , C08G69/44 , C08G69/48 , C08G73/10 , C08K3/00 , C08L77/00 , C08L77/04 , C08L101/16 , C09K8/035 , C11D3/37 , C11D7/22 , C11D7/32 , C23F11/173 , C02F5/02 , B01F3/00 , C02F5/08
CPC分类号： C08G69/44 , C08G69/10 , C09K8/035 , C11D3/3719
摘要： The present invention relates to an acid catalyzed thermal polycondensation process for producing amino acid polymers. More specifically, amino acid polymers are produced by thermally condensing a mixture of one or more amino acids and optionally one or more polyfunctional monomers, using an acid catalyst, while maintaining an intimate admixture. Processing techniques useful for maintaining an intimate admixture include adding to the mixture one or more processing aids, using mechanical means, and combinations thereof. The amino acid polymers produced by this process are useful as cleaning and detergent additives; fertilizer and pesticide additives; personal care product additives; dispersants for inorganic particulates, aqueous emulsions, and drilling muds; and water treatment and oil. production operation additives as corrosion and scale inhibitors
摘要翻译：本发明涉及用于生产氨基酸聚合物的酸催化的热缩聚方法。更具体地，氨基酸聚合物通过使用酸催化剂将一种或多种氨基酸和任选的一种或多种多官能单体的混合物进行热缩合同时保持紧密的混合物来制备。用于保持紧密混合物的加工技术包括使用机械方法将混合物加入到一种或多种加工助剂中，及其组合。通过该方法生产的氨基酸聚合物可用作清洁剂和洗涤剂添加剂; 化肥和农药添加剂; 个人护理产品添加剂; 无机颗粒分散剂，水乳液和钻井泥浆; 和水处理和油。生产操作添加剂作为腐蚀和阻垢剂

2. 发明授权

US5552514A Acid catalyzed process for preparing amino acid polymers 失效
公开(公告)号：US5552514A
公开(公告)日：1996-09-03
申请号：US466868
申请日：1995-06-06
申请人： David E. Adler , Michael B. Freeman , James M. Lipovsky , Yi H. Paik , Jan E. Shulman , Graham Swift
发明人： David E. Adler , Michael B. Freeman , James M. Lipovsky , Yi H. Paik , Jan E. Shulman , Graham Swift
IPC分类号： C02F5/10 , A01N61/00 , C08G69/00 , C08G69/10 , C08G69/44 , C08G69/48 , C08G73/10 , C08K3/00 , C08L77/00 , C08L77/04 , C08L101/16 , C09K8/035 , C11D3/37 , C11D7/22 , C11D7/32 , C23F11/173
CPC分类号： C08G69/44 , C08G69/10 , C09K8/035 , C11D3/3719
摘要： The present invention relates to an acid catalyzed thermal polycondensation process for producing amino acid polymers. More specifically, amino acid polymers are produced by thermally condensing a mixture of one or more amino acids and optionally one or more polyfunctional monomers, using an acid catalyst, while maintaining an intimate admixture. Processing techniques useful for maintaining an intimate admixture include adding to the mixture one or more processing aids, using mechanical means, and combinations thereof. The amino acid polymers produced by this process are useful as cleaning and detergent additives; fertilizer and pesticide additives; personal care product additives; dispersants for inorganic particulates, aqueous emulsions, and drilling muds; and water treatment and oil production operation additives as corrosion and scale inhibitors.

3. 发明授权

US5556938A Acid catalyzed process for preparing amino acid polymers 失效
公开(公告)号：US5556938A
公开(公告)日：1996-09-17
申请号：US466867
申请日：1995-06-06
申请人： Michael B. Freeman , James M. Lipovsky , Yi H. Paik , Jan E. Shulman , Graham Swift
发明人： Michael B. Freeman , James M. Lipovsky , Yi H. Paik , Jan E. Shulman , Graham Swift
IPC分类号： C02F5/10 , A01N61/00 , C08G69/00 , C08G69/10 , C08G69/44 , C08G69/48 , C08G73/10 , C08K3/00 , C08L77/00 , C08L77/04 , C08L101/16 , C09K8/035 , C11D3/37 , C11D7/22 , C11D7/32 , C23F11/173
CPC分类号： C08G69/44 , C08G69/10 , C09K8/035 , C11D3/3719
摘要： The present invention relates to an acid catalyzed thermal polycondensation process for producing amino acid polymers. More specifically, amino acid polymers are produced by thermally condensing a mixture of one or more amino acids and optionally one or more polyfunctional monomers, using an acid catalyst, while maintaining an intimate admixture. Processing techniques useful for maintaining an intimate admixture include adding to the mixture one or more processing aids, using mechanical means, and combinations thereof. The amino acid polymers produced by this process are useful as cleaning and detergent additives; fertilizer and pesticide additives; personal care product additives; dispersants for inorganic particulates, aqueous emulsions, and drilling muds; and water treatment and oil production operation additives as corrosion and scale inhibitors.

4. 发明授权

US5457176A Acid catalyzed process for preparing amino acid polymers 失效
标题翻译：用于制备氨基酸聚合物的酸催化方法
公开(公告)号：US5457176A
公开(公告)日：1995-10-10
申请号：US213648
申请日：1994-03-16
申请人： David E. Adler , Michael B. Freeman , James M. Lipovsky , Yi H. Paik
发明人： David E. Adler , Michael B. Freeman , James M. Lipovsky , Yi H. Paik
IPC分类号： C08G69/10 , C08G69/44 , C09K8/035 , C11D3/37
CPC分类号： C11D3/3719 , C08G69/10 , C08G69/44 , C09K8/035
摘要： The present invention relates to an acid catalyzed thermal polycondensation process for producing amino acid polymers. More specifically, amino acid polymers are produced by thermally condensing a mixture of one or more amino acids and optionally one or more polyfunctional monomers, using an acid catalyst, while maintaining an intimate admixture. Processing techniques useful for maintaining an intimate admixture include adding to the mixture one or more processing aids, using mechanical means, and combinations thereof. The amino acid polymers produced by this process are useful as cleaning and detergent additives; fertilizer and pesticide additives; personal care product additives; dispersants for inorganic particulates, aqueous emulsions, and drilling muds; and water treatment and oil production operation additives as corrosion and scale inhibitors.
摘要翻译：本发明涉及用于生产氨基酸聚合物的酸催化的热缩聚方法。更具体地，氨基酸聚合物通过使用酸催化剂将一种或多种氨基酸和任选的一种或多种多官能单体的混合物进行热缩合同时保持紧密的混合物来制备。用于保持紧密混合物的加工技术包括使用机械方法将混合物加入到一种或多种加工助剂中，及其组合。通过该方法生产的氨基酸聚合物可用作清洁剂和洗涤剂添加剂; 化肥和农药添加剂; 个人护理产品添加剂; 无机颗粒分散剂，水乳液和钻井泥浆; 以及水处理和石油生产操作添加剂作为腐蚀和阻垢剂。

5. 发明授权

US5459234A Continuous thermal polycondensation process for preparing polymers 失效
标题翻译：用于制备聚合物的连续热缩聚方法
公开(公告)号：US5459234A
公开(公告)日：1995-10-17
申请号：US731649
申请日：1995-01-12
申请人： Newman M. Bortnick , Robert E. Jerman , James M. Lipovsky , Yi H. Paik , Ethan S. Simon , Graham Swift
发明人： Newman M. Bortnick , Robert E. Jerman , James M. Lipovsky , Yi H. Paik , Ethan S. Simon , Graham Swift
IPC分类号： C08F2/16 , C08F2/18 , C08F2/44 , C08G69/00 , C08G69/10 , C08G73/06 , C08G73/10 , C11D3/37 , C08G63/44
CPC分类号： C11D3/3719 , C08G69/00 , C08G69/10 , C08G73/0611 , C08G73/1092
摘要： A continuous process for preparing polymers is provided: The continuous process produces polymers from monoethylenically unsaturated acids or anhydrides, and a nitrogen-containing compound, optionally in the presence of a fluidizing agent. The polymers are useful as detergent additives, pigment and mineral dispersants, additives for fertilizers, and corrosion and scale inhibitors in boilers and cooling towers.
摘要翻译：提供了制备聚合物的连续方法：连续方法任选地在流化剂存在下，由单烯属不饱和酸或酸酐和含氮化合物产生聚合物。聚合物可用作洗涤剂添加剂，颜料和矿物分散剂，肥料添加剂，以及锅炉和冷却塔中的腐蚀和阻垢抑制剂。

6. 发明授权

US5410017A Continuous thermal polycondensation process for preparing polypeptide polymers 失效
标题翻译：用于制备多肽聚合物的连续热缩聚方法
公开(公告)号：US5410017A
公开(公告)日：1995-04-25
申请号：US65848
申请日：1993-05-21
申请人： Newman M. Bortnick , Robert E. Jerman , James M. Lipovsky , Yi H. Paik , Ethan S. Simon , Graham Swift
发明人： Newman M. Bortnick , Robert E. Jerman , James M. Lipovsky , Yi H. Paik , Ethan S. Simon , Graham Swift
IPC分类号： C08F2/16 , C08F2/18 , C08F2/44 , C08G69/00 , C08G69/10 , C08G73/06 , C08G73/10 , C11D3/37 , C08G63/44
CPC分类号： C11D3/3719 , C08G69/00 , C08G69/10 , C08G73/0611 , C08G73/1092
摘要： A continuous process for preparing polymers is provided: The continuous process produces polymers from monoethylenically unsaturated acids or anhydrides, and a nitrogen-containing compound, optionally in the presence of a fluidizing agent. The polymers are useful as detergent additives, pigment and mineral dispersants, additives for fertilizers, and corrosion and scale inhibitors in boilers and cooling towers.
摘要翻译：提供了制备聚合物的连续方法：连续方法任选地在流化剂存在下，由单烯属不饱和酸或酸酐和含氮化合物产生聚合物。聚合物可用作洗涤剂添加剂，颜料和矿物分散剂，肥料添加剂，以及锅炉和冷却塔中的腐蚀和阻垢抑制剂。

7. 发明授权

US5393868A Production of polysuccinimide by thermal polymerization of maleamic acid 失效
标题翻译：通过马来酰胺酸的热聚合生产聚琥珀酰亚胺
公开(公告)号：US5393868A
公开(公告)日：1995-02-28
申请号：US960070
申请日：1992-10-13
申请人： Michael B. Freeman , Yi H. Paik , Ethan S. Simon , Graham Swift
发明人： Michael B. Freeman , Yi H. Paik , Ethan S. Simon , Graham Swift
IPC分类号： C08F122/40 , C08G69/10 , C08G73/06 , C08G73/10 , C11D1/52 , C11D3/37 , C08F6/00
CPC分类号： C11D3/3719 , C08G69/10 , C08G73/1092
摘要： A method for producing polysuccinimide is provided. Thermal polymerization of maleamic acid at a temperature of from about 160.degree. C. to about 330.degree. C. produces polysuccinimide. The reaction is optionally conducted in the presence of one or more processing aids, solvents or diluents. The polysuccinimide is particularly useful as a detergent additive.
摘要翻译：提供了制备聚琥珀酰亚胺的方法。在约160℃至约330℃的温度下马来酰胺酸的热聚合产生聚琥珀酰亚胺。反应任选在一种或多种加工助剂，溶剂或稀释剂的存在下进行。聚琥珀酰亚胺特别可用作洗涤剂添加剂。

8. 发明授权

US5531934A Method of inhibiting corrosion in aqueous systems using poly(amino acids) 失效
标题翻译：使用聚（氨基酸）在含水体系中抑制腐蚀的方法
公开(公告)号：US5531934A
公开(公告)日：1996-07-02
申请号：US304063
申请日：1994-09-12
申请人： Michael B. Freeman , William M. Hann , Yi H. Paik , Graham Swift
发明人： Michael B. Freeman , William M. Hann , Yi H. Paik , Graham Swift
IPC分类号： C23G5/02 , C09K8/54 , C11D3/37 , C23F11/08 , C23F11/173 , C11D3/06
CPC分类号： C09K8/54 , C11D3/3719 , C23F11/08 , C23F11/173
摘要： The present invention provides a method of inhibiting corrosion of ferrous metals in aqueous systems. The corrosion is inhibited by adding an effective amount of one or more poly(amino acids) to the aqueous system. Aqueous systems include for example water treatment systems and equipment used for detergent applications. The poly(amino acids) comprise a reaction product of at least one compound selected from amino acids, amic acids, ammonium salts of monoethylenically unsaturated dicarboxylic acids, ammonium salts of hydroxypolycarboxylic acids and combinations thereof.In one embodiment the poly(amino acids) are added to detergent solutions to inhibit corrosion in equipment for detergent applications. In another embodiment, corrosion inhibitors comprising one or more homopolymers of amino acids and one or more pyrophosphates are added to aqueous systems to inhibit corrosion.
摘要翻译：本发明提供一种抑制含水体系中黑色金属腐蚀的方法。通过向水性体系中加入有效量的一种或多种聚（氨基酸）来抑制腐蚀。水系统包括例如用于洗涤剂应用的水处理系统和设备。聚（氨基酸）包含至少一种选自氨基酸，酰胺酸，单烯属不饱和二羧酸的铵盐，羟基多羧酸的铵盐及其组合的化合物的反应产物。在一个实施方案中，将聚（氨基酸）加入到洗涤剂溶液中以抑制用于洗涤剂应用的设备中的腐蚀。在另一个实施方案中，包含一种或多种氨基酸均聚物和一种或多种焦磷酸盐的腐蚀抑制剂被加入到含水体系中以抑制腐蚀。

9. 发明授权

US5612447A Production of polysuccinimide by thermal polymerization of maleamic acid 失效
标题翻译：通过马来酰胺酸的热聚合生产聚琥珀酰亚胺
公开(公告)号：US5612447A
公开(公告)日：1997-03-18
申请号：US339605
申请日：1994-11-15
申请人： Michael B. Freeman , Yi H. Paik , Ethan S. Simon , Graham Swift
发明人： Michael B. Freeman , Yi H. Paik , Ethan S. Simon , Graham Swift
IPC分类号： C08F122/40 , C08G69/10 , C08G73/06 , C08G73/10 , C11D1/52 , C11D3/37
CPC分类号： C11D3/3719 , C08G69/10 , C08G73/1092
摘要： A method for producing polysuccinimide is provided. Thermal polymerization of maleamic acid at a temperature of from about 160.degree. C. to about 330.degree. C. produces polysuccinimide. The reaction is optionally conducted in the presence of one or more processing aids, solvents or diluents. The polysuccinimide is particularly useful as a detergent additive.
摘要翻译：提供了制备聚琥珀酰亚胺的方法。在约160℃至约330℃的温度下马来酰胺酸的热聚合产生聚琥珀酰亚胺。反应任选在一种或多种加工助剂，溶剂或稀释剂的存在下进行。聚琥珀酰亚胺特别可用作洗涤剂添加剂。

10. 发明授权

US5266237A Enhancing detergent performance with polysuccinimide 失效
标题翻译：用聚琥珀酰亚胺增强洗涤剂性能
公开(公告)号：US5266237A
公开(公告)日：1993-11-30
申请号：US924697
申请日：1992-07-31
申请人： Michael B. Freeman , Yi H. Paik , Ethan S. Simon , Graham Swift
发明人： Michael B. Freeman , Yi H. Paik , Ethan S. Simon , Graham Swift
IPC分类号： C11D3/00 , C11D3/37 , C11D17/00 , C11D3/28
CPC分类号： C11D3/3719 , C11D3/0036
摘要： Detergent compositions containing from 0.5 to about 50 percent by weight polysuccinimide are provided. These compositions have enhanced anti-encrustation, soil removal and anti-redeposition properties.

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