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    • 1. 发明授权
    • Polymer particles with additives encapsulated in microvoids
    • 具有包封在微孔中的添加剂的聚合物颗粒
    • US08252414B2
    • 2012-08-28
    • US12505757
    • 2009-07-20
    • David D. PutnamMridula NairMary C. BrickTamara K. Jones
    • David D. PutnamMridula NairMary C. BrickTamara K. Jones
    • B32B5/16
    • C08J9/28C08J2201/0502G03G9/0804G03G9/0825G03G9/0827Y10T428/2982Y10T428/2989
    • Porous particles comprising a polymer binder and at least one additive distinct from any pore stabilizing compound present in the particle, wherein: the polymer binder comprises a solid compositionally continuous phase having an external particle surface; discrete pores are dispersed within the solid compositionally continuous phase, forming internal pore surfaces; and the at least one additive is present primarily in the discrete pores. The additive may further preferably not be present in the solid compositionally continuous phase, and be substantially absent from the external particle surface. A toner set for forming a color electrophotographic image comprising a plurality of different colored toners, where at least one of the different colored toners comprise such porous particles comprising additives, and in a particular embodiment wherein at least two different colored toners each comprise different pigments present primarily in the internal pores. A process of making such porous particles.
    • 包含聚合物粘合剂和至少一种不同于颗粒中存在的任何孔稳定化合物的添加剂的多孔颗粒,其中:聚合物粘合剂包括具有外部颗粒表面的固体组成连续相; 离散的孔分散在固体组成连续相中,形成内孔表面; 并且所述至少一种添加剂主要存在于离散孔中。 添加剂可以进一步优选不存在于固体组成连续相中,并且基本上不存在于外部颗粒表面。 一种用于形成彩色电子照相图像的调色剂,其包含多种不同颜色的调色剂,其中至少一种不同颜色的调色剂包含这种包含添加剂的多孔颗粒,并且在特定实施方案中,至少两种不同颜色的调色剂各自包含不同颜料 主要在内部毛孔。 制造这种多孔颗粒的方法。
    • 2. 发明申请
    • POLYMER PARTICLES WITH ADDITIVES ENCAPSULATED IN MICROVOIDS
    • 具有添加剂的聚合物颗粒在微生物中包封
    • US20100021838A1
    • 2010-01-28
    • US12505757
    • 2009-07-20
    • David D. PutnamMridula NairMary C. BrickTamara K. Jones
    • David D. PutnamMridula NairMary C. BrickTamara K. Jones
    • G03G9/08G03G9/087G03G9/093
    • C08J9/28C08J2201/0502G03G9/0804G03G9/0825G03G9/0827Y10T428/2982Y10T428/2989
    • Porous particles comprising a polymer binder and at least one additive distinct from any pore stabilizing compound present in the particle, wherein: the polymer binder comprises a solid compositionally continuous phase having an external particle surface; discrete pores are dispersed within the solid compositionally continuous phase, forming internal pore surfaces; and the at least one additive is present primarily in the discrete pores. The additive may further preferably not be present in the solid compositionally continuous phase, and be substantially absent from the external particle surface. A toner set for forming a color electrophotographic image comprising a plurality of different colored toners, where at least one of the different colored toners comprise such porous particles comprising additives, and in a particular embodiment wherein at least two different colored toners each comprise different pigments present primarily in the internal pores. A process of making such porous particles.
    • 包含聚合物粘合剂和至少一种不同于存在于颗粒中的孔稳定化合物的添加剂的多孔颗粒,其中:聚合物粘合剂包括具有外部颗粒表面的固体组成连续相; 离散的孔分散在固体组成连续相中,形成内孔表面; 并且所述至少一种添加剂主要存在于离散孔中。 添加剂可以进一步优选不存在于固体组成连续相中,并且基本上不存在于外部颗粒表面。 一种用于形成彩色电子照相图像的调色剂,其包含多种不同颜色的调色剂,其中至少一种不同颜色的调色剂包含这种包含添加剂的多孔颗粒,并且在特定实施方案中,至少两种不同颜色的调色剂各自包含不同颜料 主要在内部毛孔。 制造这种多孔颗粒的方法。
    • 6. 发明授权
    • Solid particle dispersions for imaging systems
    • 用于成像系统的固体颗粒分散体
    • US5468598A
    • 1995-11-21
    • US228839
    • 1994-04-18
    • David D. MillerMary C. BrickMridula Nair
    • David D. MillerMary C. BrickMridula Nair
    • C08J3/02C08J3/03C09B67/46G03C1/005G03C7/388G03C11/00
    • G03C7/3882C09B67/0085G03C1/005
    • A process for preparing a stable, solid particle dispersion of a substantially water-insoluble compound useful in imaging, comprises the steps of:(a) forming a coarse aqueous slurry of solid particles of said compound and a hydrophobic, water-soluble or water-dispersible polymer in an amount of 0.1 to 100% by weight based on the weight of said compound; and(b) milling said slurry for time sufficient to provide particles of the desired average particle size;wherein the polymer is an uncharged or weakly anionically charged water-soluble or water-dispersible homopolymer or copolymer in which at least 10 mole % of the repeat units contain an uncharged pendant group that terminates in (a) a CH.sub.3 unit, (b) a ring containing at least two contiguous CH.sub.2 units, or (c) an aromatic group.The resulting dispersion has dispersed solid particles of said compound having the desired small particle size and is stable toward particle agglomeration, particle growth and needle growth.
    • 制备用于成像的基本上不溶于水的化合物的稳定的固体颗粒分散体的方法包括以下步骤:(a)形成所述化合物的固体颗粒和疏水性,水溶性或水溶性的粗浆状物, 相对于所述化合物的重量,可分散的聚合物的量为0.1〜100重量% 和(b)将所述浆料研磨足够的时间以提供所需平均粒径的颗粒; 其中所述聚合物是不带电荷或弱阴离子电荷的水溶性或水分散性均聚物或共聚物,其中至少10摩尔%的重复单元含有终止于(a)CH3单元的不带电荷的侧基,(b) 环包含至少两个相邻的CH2单元,或(c)芳族基团。 所得到的分散体具有所需化合物的固体颗粒,其粒径小,对颗粒聚集,颗粒生长和针生长稳定。