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1. 发明申请

US20120253000A1 Microcapsule and Methods of Making and Using Microcapsules 有权
标题翻译：微胶囊和制备和使用微胶囊的方法
公开(公告)号：US20120253000A1
公开(公告)日：2012-10-04
申请号：US13393183
申请日：2010-09-02
申请人： David C. Okawa , Stefan J. Pastine , Alexander K. Zettl , Jean M.J. Frechet
发明人： David C. Okawa , Stefan J. Pastine , Alexander K. Zettl , Jean M.J. Frechet
IPC分类号： C08F32/06 , B29D11/00 , C09K3/00 , B82Y30/00
CPC分类号： B01J13/16 , C09B67/0097 , Y10S977/742 , Y10S977/762 , Y10S977/773 , Y10S977/774
摘要： An embodiment of a microcapsule includes a shell surrounding a space, a liquid within the shell, and a light absorbing material within the liquid. An embodiment of a method of making microcapsules includes forming a mixture of a light absorbing material and an organic solution. An emulsion of the mixture and an aqueous solution is then formed. A polymerization agent is added to the emulsion, which causes microcapsules to be formed. Each microcapsule includes a shell surrounding a space, a liquid within the shell, and light absorbing material within the liquid. An embodiment of a method of using microcapsules includes providing phototriggerable microcapsules within a bulk material. Each of the phototriggerable microcapsules includes a shell surrounding a space, a chemically reactive material within the shell, and a light absorbing material within the shell. At least some of the phototriggerable microcapsules are exposed to light, which causes the chemically reactive material to release from the shell and to come into contact with bulk material.
摘要翻译：微胶囊的一个实施方案包括围绕空间的壳体，壳体内的液体和液体内的光吸收材料。制造微胶囊的方法的一个实施方案包括形成光吸收材料和有机溶液的混合物。然后形成混合物的乳液和水溶液。向乳液中加入聚合剂，导致形成微胶囊。每个微胶囊包括围绕空间的壳体，壳体内的液体和液体内的光吸收材料。使用微胶囊的方法的一个实施方案包括在散装材料内提供可光触发的微胶囊。每个可光触发的微胶囊包括围绕空间的外壳，壳内的化学反应性材料，以及壳内的光吸收材料。至少一些可光触发的微胶囊暴露于光，这导致化学反应性材料从壳体释放并与散装材料接触。

2. 发明申请

US20110272598A1 SURFACE TENSION MEDIATED CONVERSION OF LIGHT TO WORK 有权
标题翻译：表面张力介入转换光
公开(公告)号：US20110272598A1
公开(公告)日：2011-11-10
申请号：US13069131
申请日：2011-03-22
申请人： David Okawa , Stefan J. Pastine , Alexander Zettl , Jean M.J. Frechet
发明人： David Okawa , Stefan J. Pastine , Alexander Zettl , Jean M.J. Frechet
IPC分类号： G21K5/00 , B82Y15/00
CPC分类号： B82Y15/00 , B82Y30/00 , Y02E10/46
摘要： Disclosed are a method and apparatus for converting light energy to mechanical energy by modification of surface tension on a supporting fluid. The apparatus comprises an object which may be formed as a composite object comprising a support matrix and a highly light absorptive material. The support matrix may comprise a silicon polymer. The highly light absorptive material may comprise vertically aligned carbon nanotubes (VANTs) embedded in the support matrix. The composite object is supported on a fluid. By exposing the highly light absorptive material to light, heat is generated, which changes the surface tension of the composite object, causing it to move physically within the fluid.
摘要翻译：公开了一种通过修改支撑流体上的表面张力将光能转换成机械能的方法和装置。该装置包括可以形成为包括支撑矩阵和高光吸收材料的复合物体的物体。载体基质可以包含硅聚合物。高光吸收材料可以包括嵌入支撑基质中的垂直排列的碳纳米管（VANT）。复合物体支撑在流体上。通过将高光吸收材料暴露于光，产生热量，这会改变复合物体的表面张力，使其在流体内物理移动。

3. 发明申请

US20120088934A1 OLIGOMER FUNCTIONALIZED NANOTUBES AND COMPOSITES FORMED THEREWITH 有权
标题翻译：低分子官能化纳米管和复合材料
公开(公告)号：US20120088934A1
公开(公告)日：2012-04-12
申请号：US13162422
申请日：2011-06-16
申请人： Alexander K. Zettl , Toby Sainsbury , Jean M.J. Frechet
发明人： Alexander K. Zettl , Toby Sainsbury , Jean M.J. Frechet
IPC分类号： C07C233/65 , C07C211/51 , C07C233/80 , B82Y40/00 , B82Y30/00
CPC分类号： C07C233/65 , B82Y30/00 , B82Y40/00 , C07C211/44 , C07C233/80 , C08J5/005 , C08J2377/06
摘要： Disclosed herein is a sequential functionalization methodology for the covalent modification of nanotubes with between one and four repeat units of a polymer. Covalent attachment of oligomer units to the surface of nanotubes results in oligomer units forming an organic sheath around the nanotubes, polymer-functionalized-nanotubes (P-NTs). P-NTs possess chemical functionality identical to that of the functionalizing polymer, and thus provide nanoscale scaffolds which may be readily dispersed within a monomer solution and participate in the polymerization reaction to form a polymer-nanotube/polymer composite. Formation of polymer in the presence of P-NTs leads to a uniform dispersion of nanotubes within the polymer matrix, in contrast to aggregated masses of nanotubes in the case of pristine-NTs. The covalent attachment of oligomeric units to the surface of nanotubes represents the formation of a functional nanoscale building block which can be readily dispersed and integrated within the polymer to form a novel composite material.
摘要翻译：本文公开了用聚合物的一至四个重复单元共价修饰纳米管的顺序官能化方法。寡聚体单元与纳米管表面的共价连接导致形成纳米管周围的有机鞘的低聚物单元，聚合物官能化的纳米管（P-NT）。 P-NT具有与官能化聚合物相同的化学功能，因此提供纳米级支架，其可以容易地分散在单体溶液中并参与聚合反应以形成聚合物 - 纳米管/聚合物复合材料。在存在P-NT的情况下，聚合物的形成导致纳米管在聚合物基质内的均匀分散，与原始NT的情况下的纳米管的聚集体相反。低聚单元与纳米管表面的共价连接代表形成功能性纳米级结构单元，其可以容易地分散并整合在聚合物内以形成新的复合材料。

4. 发明授权

US5929214A Thermally responsive polymer monoliths 失效
标题翻译：热响应聚合物整料
公开(公告)号：US5929214A
公开(公告)日：1999-07-27
申请号：US30754
申请日：1998-02-25
申请人： Eric C. Peters , Frantisek Svec , Jean M.J. Frechet
发明人： Eric C. Peters , Frantisek Svec , Jean M.J. Frechet
IPC分类号： B01D15/16 , B01D15/20 , B01D15/32 , B01J20/26 , B01J20/28 , C07K1/16 , C08F290/00 , A23J1/00 , C07K1/00 , C07K14/00
CPC分类号： B01J20/28092 , B01D15/327 , B01D15/424 , B01J20/26 , B01J20/28004 , B01J20/28042 , B01J20/28097 , C07K1/16 , C08F290/00 , B01D15/161 , B01D15/20 , B01J2220/82
摘要： Porous polymer monoliths are made thermally responsive by functionalizing/grafting the pores with thermally responsive polymers and copolymers. Depending on the reaction conditions employed, the grafted polymer can either completely block flow through micrometer-sized pores in the monoliths or control the flow rate through the monoliths. The grafted monoliths are useful as thermal gates, thermal valves, and for isocratic hydrophobic interaction chromatography of proteins.
摘要翻译：多孔聚合物整料通过用热响应的聚合物和共聚物官能化/接枝孔而制成热响应。根据所采用的反应条件，接枝的聚合物可以完全阻止流过单块中微米尺寸的孔，或控制通过整料的流速。接枝的整料可用作热门，热阀，以及用于蛋白质的等度疏水相互作用层析。

5. 发明申请

US20090220615A1 Main Chain Acid-Degradable Polymers for the Delivery of Bioactive Materials 有权
标题翻译：主链酸降解聚合物用于生物活性材料的输送
公开(公告)号：US20090220615A1
公开(公告)日：2009-09-03
申请号：US12299506
申请日：2007-05-04
申请人： Jean M.J. Frechet , Stephen M. Standley , Rachna Jain , Cameron C. Lee
发明人： Jean M.J. Frechet , Stephen M. Standley , Rachna Jain , Cameron C. Lee
IPC分类号： A61K9/14 , C08G73/02 , C08G73/06
CPC分类号： A61K31/787 , A61K9/1641 , A61K47/34
摘要： Novel main chain acid degradable polymer backbones and drug delivery systems comprised of materials capable of delivering bioactive materials to cells for use as vaccines or other therapeutic agents are described. The polymers are synthesized using monomers that contain acid-degradable linkages cleavable under mild acidic conditions. The main chain of the resulting polymers readily degrade into many small molecules at low pH, but remain relatively stable and intact at physiological pH. The new materials have the common characteristic of being able to degrade by acid hydrolysis under conditions commonly found within the endosomal or lysosomal compartments of cells thereby releasing their payload within the cell. The materials can also be used for the delivery of therapeutics to the acidic regions of tumors and other sites of inflammation.
摘要翻译：描述了由能够将生物活性物质递送至用作疫苗或其它治疗剂的细胞的材料组成的新型主链酸可降解聚合物主链和药物递送系统。使用含有酸可降解键的单体在温和的酸性条件下可裂解来合成聚合物。所得聚合物的主链在低pH下容易降解成许多小分子，但在生理pH下保持相对稳定和完整。新材料具有在细胞的内体或溶酶体区室内通常发现的条件下能够通过酸水解降解的共同特征，从而释放其在细胞内的有效载荷。这些材料也可以用于将治疗剂递送到肿瘤和其它炎症部位的酸性区域。

6. 发明授权

US5814707A Process for oxidative functionalization of polymers containing alkylstyrene 失效
标题翻译：含烷基苯乙烯的聚合物的氧化官能化方法
公开(公告)号：US5814707A
公开(公告)日：1998-09-29
申请号：US868544
申请日：1997-06-04
申请人： Jean M.J. Frechet , Shah A. Haque , Hsien-Chang Wang
发明人： Jean M.J. Frechet , Shah A. Haque , Hsien-Chang Wang
IPC分类号： C08F8/00 , C08F8/06 , C08F212/08
CPC分类号： C08F8/06 , C08F2800/10 , C08F2810/50
摘要： This invention provides a method by which an alkylstyrene containing polymer may be exclusively functionalized at the primary benzylic carbon site of the styrenic monomer. The process of this invention comprises the treatment of an alkylstyrene containing polymer dissolved in a non-polar liquid medium with an organic hydroperoxide oxidizing reagent in the presence of a catalytically sufficient amount of a chromium compound, to oxidize a portion of the aromatic alkyl groups of the polymer to an oxygen containing functional group.
摘要翻译：本发明提供了一种含烷基苯乙烯的聚合物可以在苯乙烯类单体的伯苄基碳原子官能化官能化的方法。本发明的方法包括在催化足够量的铬化合物存在下，用有机氢过氧化物氧化试剂处理溶解在非极性液体介质中的含烷基苯乙烯的聚合物，以将一部分芳族烷基氧化成该聚合物与含氧官能团。

7. 发明授权

US5663260A Hyperbranched copolymers from AB monomers and C monomers 失效
标题翻译： AB单体和C单体的超支化共聚物
公开(公告)号：US5663260A
公开(公告)日：1997-09-02
申请号：US335935
申请日：1994-11-08
申请人： Jean M.J. Frechet , Sadahito Aoshima
发明人： Jean M.J. Frechet , Sadahito Aoshima
IPC分类号： C08F116/14 , C08G83/00 , C09J201/00 , C08G61/12
CPC分类号： C08G83/003 , C08F116/14 , C09J201/005 , Y10S424/16
摘要： A process for preparing hyperbranched polymers from AB monomers and C monomers Using a self-constructing approach is disclosed along with the hyperbranched polymers of a living-like character produced by such process.
摘要翻译：从AB单体和C单体制备超支化聚合物的方法使用自建方法以及通过这种方法产生的类似活体的特征的超支化聚合物被公开。

8. 发明申请

US20120085992A1 Furan Conjugated Polymers Useful for Photovoltaic Applications 审中-公开
标题翻译：用于光伏应用的呋喃共轭聚合物
公开(公告)号：US20120085992A1
公开(公告)日：2012-04-12
申请号：US13251044
申请日：2011-09-30
申请人： Pierre M. Beaujuge , Claire H. Woo , Jean M.J. Frechet
发明人： Pierre M. Beaujuge , Claire H. Woo , Jean M.J. Frechet
IPC分类号： H01L51/50 , H01B1/12 , C08G75/06 , C08G73/06
CPC分类号： C08G73/0672 , C08G61/124 , C08G61/126 , C08G2261/124 , C08G2261/3222 , C08G2261/3223 , C08G2261/334 , C08G2261/344 , C08G2261/414 , C08G2261/91 , C08G2261/92 , C08G2261/94 , C08G2261/95 , H01B1/12 , H01L51/0036 , H01L51/0043 , H01L51/0053 , H01L51/4253 , Y02E10/549
摘要： The present invention provides for a polymer comprising a π-conjugated backbone comprising a furan. The polymer has a narrow or low band gap and/or is solution processable. In some embodiments, the polymer is PDPP2FT or PDPP3F. The present invention also provides for a device comprising the polymer, such as a light-emitting diode, thin-film transistor, chemical biosensor, non-emissive electrochromic, memory device, photovoltaic cells, or the like.
摘要翻译：本发明提供了包含含有呋喃的共轭骨架的聚合物。聚合物具有窄带或低带隙和/或溶液可加工。在一些实施方案中，聚合物是PDPP2FT或PDPP3F。本发明还提供了一种包括聚合物的装置，例如发光二极管，薄膜晶体管，化学生物传感器，非发射电致变色，存储器件，光伏电池等。

9. 发明申请

US20110229550A1 Acid-Degradable and Bioerodible Modified Polyhydroxylated Materials 有权
标题翻译：酸可降解和生物腐蚀改性的多羟基化材料
公开(公告)号：US20110229550A1
公开(公告)日：2011-09-22
申请号：US12987679
申请日：2011-01-10
申请人： Jean M.J. Frechet , Eric M. Bachelder , Tristan T. Beaudette , Kyle E. Broaders
发明人： Jean M.J. Frechet , Eric M. Bachelder , Tristan T. Beaudette , Kyle E. Broaders
IPC分类号： A61K9/00 , C08B37/02 , C08B37/14 , C08B30/18 , A61K31/7088 , A61K38/02 , A61K38/16 , A61K39/395 , A61K39/00 , A61P37/04 , A61P25/00 , A61P35/00 , A61P31/12 , C08F16/06 , C08F8/00 , B82Y5/00
CPC分类号： C08B37/0006 , A61K9/00 , A61K9/1652 , A61K38/02 , A61K38/16 , A61K39/00 , A61K39/0011 , A61K39/385 , A61K39/395 , A61K45/06 , A61K47/48 , A61K47/6939 , A61K2039/55555 , A61K2039/55561 , A61L17/10 , A61L17/145 , A61L27/14 , A61L27/34 , A61L27/58 , A61L31/10 , A61L31/148 , B82Y5/00 , C08B30/18 , C08B37/0021 , C08B37/14 , C08F8/00 , C08F8/28 , C08F16/06 , C08L1/02 , C08L1/08 , C08L3/02 , C08L5/00 , C08L5/02 , C08L5/06 , C08L101/02 , C09D129/14
摘要： Compositions and methods of making a modified polyhydroxylated polymer comprising a polyhydroxylated polymer having reversibly modified hydroxyl groups, whereby the hydroxyl groups are modified by an acid-catalyzed reaction between a polydroxylated polymer and a reagent such as acetals, aldehydes, vinyl ethers and ketones such that the modified polyhydroxylated polymers become insoluble in water but freely soluble in common organic solvents allowing for the facile preparation of acid-sensitive materials. Materials made from these polymers can be made to degrade in a pH-dependent manner. Both hydrophobic and hydrophilic cargoes were successfully loaded into particles made from the present polymers using single and double emulsion techniques, respectively. Due to its ease of preparation, processability, pH-sensitivity, and biocompatibility, of the present modified polyhydroxylated polymers should find use in numerous drug delivery applications.
摘要翻译：制备改性多羟基化聚合物的组合物和方法，其包含具有可逆地改性羟基的多羟基化聚合物，由此羟基通过聚羟基化聚合物和试剂如缩醛，醛，乙烯基醚和酮之间的酸催化反应而被改性，使得改性的多羟基化聚合物变得不溶于水，但可溶于普通的有机溶剂，容易制备酸敏感的材料。可以使由这些聚合物制成的材料以pH依赖的方式降解。疏水和亲水性货物都分别使用单和双乳液技术装载到由本发明聚合物制成的颗粒中。由于其易于制备，加工性，pH敏感性和生物相容性，本发明的改性多羟基化聚合物应用于许多药物递送应用中。

10. 发明申请

US20110033663A1 SUPERHYDROPHOBIC AND SUPERHYDROPHILIC MATERIALS, SURFACES AND METHODS 审中-公开
标题翻译：超级和超级材料，表面和方法
公开(公告)号：US20110033663A1
公开(公告)日：2011-02-10
申请号：US12988497
申请日：2009-04-21
申请人： Frantisek Svec , Pavel A. Levkin , Jean M.J. Frechet
发明人： Frantisek Svec , Pavel A. Levkin , Jean M.J. Frechet
IPC分类号： B32B3/10 , C08J9/00 , B29C65/00
CPC分类号： C08J9/286 , C08F220/18 , C08F222/1006 , C08J5/00 , C08J2333/16 , C08L33/16 , Y10T428/24355
摘要： A broadly applicable method requiring no more than a single step facilitates the preparation of large area super hydrophobic or super hydrophilic surfaces on a variety of substrates such as such as glass, metal, plastic, paper, wood, concrete and masonry. The technique involves the free radical polymerization of common acrylic or styrenic monomers in the presence of porogenic solvents in a mold or on a free surface. The material can be semi- or fully-transparent and either super hydrophobic or super hydrophilic depending on the choice of the monomers. Because porosity and dual scale roughness are intrinsic bulk properties of the monolithic materials and not only a surface characteristic, the polymers can be powdered to produce a super hydrophobic powder or otherwise fragmented and attached to the surface of any object to render it super hydrophobic or super hydrophilic. The surface properties of the porous material may also be altered locally by photografting with selected monomers.
摘要翻译：广泛应用的方法不需要单一步骤便于在各种基材如玻璃，金属，塑料，纸，木材，混凝土和砖石上制备大面积超疏水或超亲水表面。该技术涉及常规丙烯酸或苯乙烯类单体在造孔溶剂存在下在模具中或自由表面上的自由基聚合。根据单体的选择，该材料可以是半透明的或完全透明的，并且是超疏水的或超亲水的。由于孔隙率和双重尺度粗糙度是整体材料的固有本体特性，不仅表面特性，聚合物可以被粉末化以产生超疏水性粉末，或以其他方式分散和附着到任何物体的表面，使其超疏水或超级亲水的。多孔材料的表面性质也可以通过用选择的单体进行光刻而局部改变。

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