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    • 2. 发明授权
    • Method of selectively etching silicon dioxide dielectric layers on
semiconductor wafers
    • 在半导体晶片上选择性地蚀刻二氧化硅电介质层的方法
    • US5300463A
    • 1994-04-05
    • US847368
    • 1992-03-06
    • David A. CatheyJ. Brett Rolfson
    • David A. CatheyJ. Brett Rolfson
    • H01L21/311H01L21/00H01L21/02H01L21/465
    • H01L21/31111
    • A method of utilizing and etching SiO.sub.2 in the processing of semiconductor wafers comprises: a) providing a layer of undoped SiO.sub.2 atop a wafer; b) providing a layer of doped SiO.sub.2 atop the layer of undoped SiO.sub.2 ; and c) wet etching the layer of doped SiO.sub.2 selectively relative to the undoped layer of SiO.sub.2 utilizing an acid solution, the acid solution comprising a mixture of at least two different mineral acids provided in a selected ratio relative to one another, one of the mineral acids being HF. The preferred volumetric ratio of other mineral acids in the acid solution to HF in the acid solution is from 20:1 to 110:1, with a ratio of from 45:1 to 65:1 being most preferred. Example acids to be combined with the HF include H.sub.2 SO.sub.4, HCl, HNO.sub.3, H.sub.3 PO.sub.4, HBr, HI, HClO.sub.4, and HIO.sub.4, or mixtures thereof.
    • 在半导体晶片的处理中利用和蚀刻SiO 2的方法包括:a)在晶片顶上提供未掺杂的SiO 2层; b)在未掺杂的SiO 2层的顶部提供掺杂SiO 2层; 和c)使用酸溶液相对于未掺杂的SiO 2层选择性地浸蚀掺杂SiO 2层,所述酸溶液包含以相对于彼此的选定比率提供的至少两种不同的无机酸的混合物,所述矿物质之一 酸是HF。 在酸溶液中酸溶液中的其它无机酸与HF的优选体积比为20:1至110:1,最优选的比例为45:1至65:1。 与HF组合的实例酸包括H 2 SO 4,HCl,HNO 3,H 3 PO 4,HBr,HI,HClO 4和HIO 4,或其混合物。
    • 5. 发明授权
    • Removable bandpass filter for microlithographic aligners
    • 用于微光刻对准器的可移动带通滤光片
    • US5372901A
    • 1994-12-13
    • US927210
    • 1992-08-05
    • J. Brett RolfsonDavid A. Cathey
    • J. Brett RolfsonDavid A. Cathey
    • G03F1/00G03F1/26G03F7/20G03F9/00
    • G03F1/26G03F7/70575
    • A removable bandpass filter layer (22), which is preferably part of a pattern transfer tool (10), improves the resolution of a semiconductor wafer aligner that uses a relatively broad bandwidth radiation source. A narrower bandwidth filter layer provides more complete destructive interference of undesirable diffraction patterns when it is used with a phase-shift pattern transfer tool and removes radiation of longer wavelengths to improve resolution when it is used with a nonphase-shift pattern transfer tool. Using a removable bandpass filter layer, rather than permanently installing a narrow bandpass filter in the aligner, does not affect the speed of patterning layers that do not require the enhanced resolution. The same aligner can thus be used for either high resolution or high throughput without substantial modification to the aligner.
    • 优选为图案转印工具(10)的一部分的可拆卸带通滤光层(22)提高了使用相对宽的带宽辐射源的半导体晶片对准器的分辨率。 较窄的带宽滤波器层当与相移图案转移工具一起使用时,提供更为完整的不希望的衍射图形的相消干涉,并且当与非相移图案转印工具一起使用时,可以去除较长波长的辐射以提高分辨率。 使用可拆卸的带通滤光层,而不是在对准器中永久性安装窄带通滤光片,不会影响不需要增强分辨率的图案层的速度。 因此,相同的对准器可以用于高分辨率或高通量而不对对准器进行实质修改。
    • 8. 发明授权
    • Method of preventing null formation in phase shifted photomasks
    • 防止相移光掩模中无效形成的方法
    • US5281500A
    • 1994-01-25
    • US754893
    • 1991-09-04
    • David A. CatheyBrett Rolfson
    • David A. CatheyBrett Rolfson
    • G03F1/30H01L21/027G03F9/00
    • G03F1/30
    • A method of preventing null formation is performed on a phase shifted photomask including a clear quartz substrate, dark chrome feature features, and alternating clear phase shifters raised from the substrate. The phase shifter features are terminated in a transmissive, optically clear edge. To prevent null formation and consequent formation of stringers on the surface of the integrated circuit, the substantially vertical edge of the optically clear end of the phase shifter is tapered. The slope at any point along the tapered edge between the photomask substrate and the phase shifter is set to an angle, typically less than forty-five degrees, shallow enough that the point spread function does not produce an image. The point spread function of the imaging system spreads out the null, which is therefore not printed into the photoresist layer on the integrated circuit. The tapered edge of the phase shifter is created by either discrete or continuous etching methods. Both methods create the phase shifter and tapered edges simultaneously and are compatible with photomasks having either additive or subtractive type phase shifters.
    • 对包括透明石英基板,黑铬特征特征的相移光掩模以及从基板凸起的交替的透明移相器执行防止空白形成的方法。 移相器的特征端接在透射光学透明的边缘。 为了防止在集成电路的表面上的空隙形成和随之形成桁条,移相器的光学透明端的基本上垂直的边缘是锥形的。 沿着光掩模基板和移相器之间的锥形边缘的任何点处的斜率被设定为通常小于四十五度的角度,足以使点扩散函数不产生图像。 成像系统的点扩散功能扩展为零,因此不会印刷到集成电路上的光致抗蚀剂层中。 移相器的锥形边缘通过离散或连续蚀刻方法产生。 两种方法同时产生移相器和锥形边缘,并且与具有加法或减法型移相器的光掩模兼容。
    • 10. 发明授权
    • Method to form self-aligned gate structures and focus rings
    • 形成自对准栅极结构和聚焦环的方法
    • US5259799A
    • 1993-11-09
    • US977477
    • 1992-11-17
    • Trung T. DoanTyler A. LowreyDavid A. CatheyJ. Brett Rolfson
    • Trung T. DoanTyler A. LowreyDavid A. CatheyJ. Brett Rolfson
    • H01J9/02H01J9/04
    • H01J9/025H01J2209/0226H01J2329/00
    • A selective etching and chemical mechanical planarization process for the formation of self-aligned gate and focus ring structures surrounding an electron emission tip for use in field emission displays in which the emission tip is i) optionally sharpened through oxidation, ii) deposited with a first conformal layer, iii) deposited with a conductive material layer, iv) deposited with a second conformal insulating layer, v) deposited with a focus electrode ring material layer, vi) optionally deposited with a buffering material, vii) planarized with a chemical mechanical planarization (CMP) step, to expose a portion of the second conformal layer, viii) etched to form a self-aligned gate and focus ring, and thereby expose the emitter tip, afterwhich xi) the emitter tip may be coated with a low work function material.
    • 用于形成围绕用于场发射显示器中的电子发射尖端的自对准栅极和聚焦环结构的选择性蚀刻和化学机械平面化工艺,其中发射尖端i)可选地通过氧化锐化,ii)沉积有第一 保留层,iii)沉积有导电材料层,iv)沉积有第二共形绝缘层,v)沉积有焦点电极环材料层,vi)任选地沉积有缓冲材料,vii)用化学机械平面化 (CMP)步骤,以暴露第二共形层的一部分,viii)蚀刻以形成自对准栅极和聚焦环,从而暴露发射极尖端,之后xi)发射极尖端可以被涂覆有低功函数 材料。