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1. 发明授权

US06596461B1 Piperazinone derivatives 失效
标题翻译：哌嗪酮衍生物
公开(公告)号：US06596461B1
公开(公告)日：2003-07-22
申请号：US09856574
申请日：2001-05-22
申请人： Dario Lazzari , Mirko Rossi , Graziano Zagnoni , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
发明人： Dario Lazzari , Mirko Rossi , Graziano Zagnoni , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
IPC分类号： G03C173
CPC分类号： C07D403/14 , C08G73/0273 , C08G73/0644 , C08K5/34926 , Y10S430/106 , Y10S430/107 , Y10S430/108
摘要： A compound of formula (I) wherein n is e.g. a number from 2 to 50; R5′ and R5″ are e.g. a group of formula (II); G1, G2, G3 and G4 are e.g. C1-C4akyl; R1 is e.g. hydrogen or C1-C4alkyl; R2 is e.g. methylene; R3′ is e.g. hydrogen and R3″ is e.g. hydrogen or C1-C4alkyl; R4 is e.g. C2-C8alkylene; and X is e.g. —N(R7)R8) with R7 and R8 being independently of one another hydrogen or C1-C8alkyl, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
摘要翻译：其中n为例如式（I）的化合物。从2到50的数字; R5'和R5“是例如。一组式（II）; G1，G2，G3和G4是例如。 C1-C4烷基; R1是例如氢或C 1 -C 4烷基; R2是例如亚甲基 R3'是例如。氢和R3“是例如。氢或C 1 -C 4烷基; R4是例如 C2-C8亚烷基; 而X是例如。 -N（R 7）R 8），其中R 7和R 8彼此独立地为氢或C 1 -C 8烷基，可用于稳定有机材料以防止由光，热或氧化引起的降解。

2. 发明授权

US06642383B2 Oxopiperazinyl derivatives and light stabilized compositions 失效
标题翻译：氧哌嗪衍生物和光稳定组合物
公开(公告)号：US06642383B2
公开(公告)日：2003-11-04
申请号：US09855905
申请日：2001-05-15
申请人： Dario Lazzari , Graziano Zagnoni , Mirko Rossi , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
发明人： Dario Lazzari , Graziano Zagnoni , Mirko Rossi , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
IPC分类号： C07D24106
CPC分类号： G03C1/8155 , C07D241/08 , C07D403/14 , C07D405/12 , C07D409/14 , C08G63/6856 , C08G73/0633 , C08K5/3462
摘要： Compounds of the formula (I) wherein p is zero or 1; q and r, independently of each other, are an integer from 1 to 6; and s is a number ranging from 1 to 8; X is —O— or, when p is 1, X is also a group Rw, Rx, Ry and Rz are, independently of each other, C1-C18alkyl, C5-C12cycloalkyl or C1-C5hydroxyalkyl, especially methyl; R1 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)—G, in which G is hydrogen, methyl or phenyl; R2 is hydrogen, C1-C8alkyl, C5-C12cycloalkyl or C1-C4hydroxyalkyl; R3, R4, R5 independently of each other are hydrogen, C1-C8alkyl or C5-C12cycloalkyl; and W and other residues are as described in claim 1, are effective stabilizers for organic materials, for example thermoplastic organic polymers, coating compositions or photographic materials.
摘要翻译：式（I）的化合物，其中p为0或1; q和r彼此独立地是1至6的整数; 且为1至8的数; X为-O-或当p为1时，X为基团R w，R x，R y和R z彼此独立地为C 1 -C 18烷基，C 5 -C 12环烷基或C 1 -C 18烷基， C5羟烷基，特别是甲基; R1是氢; C1-C18烷基; 氧基哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 1为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基或基团-CH 2 CH（OH）-G，其中G是氢，甲基或苯基; R 2是氢，C 1 -C 8烷基，C 5 -C 12环烷基或C 1 -C 4羟烷基; R 3，R 4，R 5彼此独立地是氢，C 1 -C 1-8烷基或C 5 -C 12环烷基; 和W和其它残余物如权利要求1所述，是有机材料的有效稳定剂，例如热塑性有机聚合物，涂料组合物或照相材料。

3. 发明授权

US07109259B2 Piperazinone derivatives 失效
标题翻译：哌嗪酮衍生物
公开(公告)号：US07109259B2
公开(公告)日：2006-09-19
申请号：US10138986
申请日：2002-05-03
申请人： Dario Lazzari , Mirko Rossi , Graziano Zagnoni , Alessandro Zedda , Stephen Mark Andrews
发明人： Dario Lazzari , Mirko Rossi , Graziano Zagnoni , Alessandro Zedda , Stephen Mark Andrews
IPC分类号： C08K5/3452 , C08K5/3492 , C07D403/14
CPC分类号： C07D241/06 , C07D403/12 , C07D403/14 , C08K5/34926 , G03C1/815 , G03C1/8155 , G03C7/39244 , C08L59/00
摘要： A compound of the formula (I) wherein n is preferably 3; G1, G2, G3 and G4 are independently of one another e.g. C1–C4alkyl; A1 is e.g. hydrogen or methyl; A2 is e.g. methylene; A3′ and A3″ are e.g. C1–C4alkyl; A4 is e.g. C1–C8alkyl; Y is e.g. a group of the formula (IV) wherein R1 is e.g. hydrogen or methyl, R2 is e.g. methylene, R3′ and R3″ are e.g. C1–C4alkyl and R4 is e.g. hydrogen or C1–C8alkyl; and Z is e.g. a group of the formula (VI) with A10′ and A10″ being independently of one another e.g. hydrogen or C1–C4alkyl and A11′ and A11″ being independently of one another e.g. C2–C6alkylene, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
摘要翻译：式（I）的化合物，其中n优选为3; G 1，G 2，G 3和G 4各自彼此独立地是例如不同的。 C 1 -C 4烷基; 例如，A 1＆lt; 1＆gt; 氢或甲基; A 是例如。亚甲基 A 3＆lt; 3＆gt;和＆lt; 3＆gt; C 1 -C 4烷基; A 4是例如。 C 1 -C 8烷基; Y是例如其中R 1为例如式（Ⅳ）的基团。氢或甲基，R 2是例如。亚甲基，R 3'和R 3“是例如。 C 1 -C 4烷基和R 4是例如C 1 -C 4烷基。氢或C 1 -C 8烷基; Z是例如具有A 10'和A 10“的式（VI）的基团彼此独立地是例如。氢或C 1 -C 4烷基，A 11和A 11'彼此独立地为氢或C 1 -C 4烷基。例如 C 2 -C 6亚烷基可用于稳定有机材料以防止由光，热或氧化引起的降解。

4. 发明授权

US06762226B2 Compositions stabilized by dioxopiperazinyl derivatives 失效
标题翻译：由二氧代哌嗪衍生物稳定的组合物
公开(公告)号：US06762226B2
公开(公告)日：2004-07-13
申请号：US10272193
申请日：2002-10-15
申请人： Alessandro Zedda , Graziano Zagnoni , Massimiliano Sala , Dario Lazzari , Stephen Mark Andrews
发明人： Alessandro Zedda , Graziano Zagnoni , Massimiliano Sala , Dario Lazzari , Stephen Mark Andrews
IPC分类号： C07D40304
CPC分类号： C08L55/02 , C08K5/34926 , C08L59/00 , C08L59/02 , C08L69/00 , C08L2666/14 , C08L2666/02
摘要： Polyoxymethylene, blends of polycarbonate with acrylonitrile-butadiene-styrene terpolymer, and coatings based on a functional acrylate resin and a crosslinking agent, which are stabilized by addition of a compound of the formula I wherein s is from the range 1 to 8; R1, R2, R3 and R4, independently of each other, are C1-C4alkyl, or R1 and R2 or R3 and R4, together with the carbon atom to which they are bound, form a cyclopentyl or cyclohexyl ring; R5 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R5 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)-G, in which G is hydrogen, methyl or phenyl; and A is as described in claim 1, show a good resistance against harmful effects of light, oxygen and heat.
摘要翻译：聚甲醛，聚碳酸酯与丙烯腈 - 丁二烯 - 苯乙烯三元共聚物的共混物，以及基于官能丙烯酸酯树脂和交联剂的涂料，其通过加入式I化合物而得到稳定，其中s为1至8; R1，R2 R 3和R 4彼此独立地是C 1 -C 4烷基，或者R 1和R 2或R 3和R 4与它们所连接的碳原子一起形成环戊基或环己基环; R 5是氢; C1-C18烷基; 氧基哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 5为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基或基团-CH 2 CH（OH）-G，其中G是氢，甲基或苯基; 和A如权利要求1所述，显示出对光，氧和热的有害影响的良好抵抗性。

5. 发明授权

US08273822B2 Reversible thermochromic compositions 失效
标题翻译：可逆热变色组合物
公开(公告)号：US08273822B2
公开(公告)日：2012-09-25
申请号：US12223235
申请日：2007-01-25
申请人： Mirko Rossi , Graziano Zagnoni , Manuele Vitali , Dario Lazzari , Walter Fischer
发明人： Mirko Rossi , Graziano Zagnoni , Manuele Vitali , Dario Lazzari , Walter Fischer
IPC分类号： C08L49/00 , G11B7/24 , G02B5/23
CPC分类号： C09K11/02 , C09K9/02 , C09K2211/1007
摘要： The present invention pertains to a reversible thermochromic system comprising a β-phenylvinylketone or a ω-phenyl polyacetylenyl ketone with at least one acidic hydrogen and a base and to a reversible thermochromic composition comprising the reversible thermochromic system and a carrier material and to novel substituted β-phenylvinylketones or ω-phenyl polyacetylenyl ketones with at least one acidic hydrogen.
摘要翻译：本发明涉及一种可逆热变色系统，其包括具有至少一个酸性氢和碱的“ - 苯基乙烯基酮或ω-苯基聚乙炔基酮”，以及包含可逆热变色系和载体材料的可逆热变色组合物，苯基乙烯基酮或ω-苯基聚乙炔基酮与至少一种酸性氢。

6. 发明授权

US06441166B1 Sterically hindered amine compounds 有权
标题翻译：受阻胺化合物
公开(公告)号：US06441166B1
公开(公告)日：2002-08-27
申请号：US09459697
申请日：1999-12-13
申请人： Dario Lazzari , Graziano Zagnoni , Stephen Mark Andrews
发明人： Dario Lazzari , Graziano Zagnoni , Stephen Mark Andrews
IPC分类号： C07D25142
CPC分类号： C07D401/14 , C08K5/34 , C08K5/3435 , C08K5/34926 , C08K5/5419 , C08K5/5442 , C09K15/30
摘要： A product containing 5 to 85% of a group (A-1-a) and/or (A-1-b) and 15 to 95% of a group (A-2), the total sum of the groups (A-1-a), (A-1-b) and (A-2) being 100%, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
摘要翻译：含有5-85％（A-1-a）和/或（A-1-b）和15-95％（A-2）的产物，基团（A- 1-a），（A-1-b）和（A-2）为100％可用于稳定有机材料，防止由光，热或氧化引起的降解。

7. 发明申请

US20100234522A1 Reversible Thermochromic Compositions 失效
标题翻译：可逆热变色组合物
公开(公告)号：US20100234522A1
公开(公告)日：2010-09-16
申请号：US12223235
申请日：2007-01-25
申请人： Mirko Rossi , Graziano Zagnoni , Manuele Vitali , Dario Lazzari , Walter Fischer
发明人： Mirko Rossi , Graziano Zagnoni , Manuele Vitali , Dario Lazzari , Walter Fischer
IPC分类号： C08L49/00
CPC分类号： C09K11/02 , C09K9/02 , C09K2211/1007
摘要： The present invention pertains to a reversible thermochromic system comprising a β-phenylvinylketone or a ω-phenyl polyacetylenyl ketone with at least one acidic hydrogen and a base and to a reversible thermochromic composition comprising the reversible thermochromic system and a carrier material and to novel substituted β-phenylvinylketones or ω-phenyl polyacetylenyl ketones with at least one acidic hydrogen.
摘要翻译：本发明涉及一种可逆热变色系统，其包括具有至少一个酸性氢和碱的“ - 苯基乙烯基酮或ω-苯基聚乙炔基酮”，以及包含可逆热变色系和载体材料的可逆热变色组合物，苯基乙烯基酮或ω-苯基聚乙炔基酮与至少一种酸性氢。

8. 发明申请

US20080032078A1 Highly compatible hydroxyphenyltriazine UV-absorbers 失效
标题翻译：高度相容的羟基苯基三嗪紫外线吸收剂
公开(公告)号：US20080032078A1
公开(公告)日：2008-02-07
申请号：US11904511
申请日：2007-09-27
申请人： Dario Lazzari , David Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
发明人： Dario Lazzari , David Leppard , Massimiliano Sala , Manuele Vitali , Graziano Zagnoni , Gianluca Ferri
IPC分类号： B32B1/02 , C07D251/14 , F21V9/06
CPC分类号： C08K5/3492 , C07D251/24 , C08F8/30 , Y10T428/1352
摘要： The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in protecting plants in green houses and the protection of foodstuffs, beverages, pharmaceuticals, cosmetics, personal care products, shampoos and the like from the deleterious effects of ultraviolet radiation. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
摘要翻译：本发明涉及高度相容的羟基苯基三嗪紫外线吸收剂及其在保护温室中植物和保护食品，饮料，药物，化妆品，个人护理产品，洗发剂等方面的用途，从紫外线辐射的有害作用。已经发现，某些高度相容的三 - 芳基-s-三嗪在结合到其中存储这些材料的容器或薄膜中时特别有效。

9. 发明授权

US5196465A Polymeric thermoplastic materials, comprising 1,2,4-triazolidine-3,5-dione derivatives as stabilizers 失效
标题翻译：聚合物热塑性材料，包括1,2,4-三唑烷-3,5-二酮衍生物作为稳定剂
公开(公告)号：US5196465A
公开(公告)日：1993-03-23
申请号：US830013
申请日：1992-02-03
申请人： Roberto Scrima , Graziano Zagnoni , Valerio Borzatta
发明人： Roberto Scrima , Graziano Zagnoni , Valerio Borzatta
IPC分类号： C07D249/12 , C07D403/14 , C08K5/3472 , C08K5/3477 , C08K5/3492
CPC分类号： C08K5/3472
摘要： The present invention relates to polymeric thermoplastic materials stabilized against thermal degradation by means of using one or more compounds of the formula (I) ##STR1## in which R.sub.1 is e.g. C.sub.1 -C.sub.4 alkyl or phenyl and n is e.g. 1 or 2 and, when n is 1, R.sub.2 is e.g. C.sub.1 -C.sub.4 alkyl, phenyl or cyclohexyl, and, when n is 2, R.sub.2 is e.g. C.sub.2 -C.sub.6 alkylene, methylenedicyclohexylene, a group ##STR2## methylphenylene or methylenediphenylene.

10. 发明申请

US20060235116A1 Highly compatible and non-migratory polymeric uv-absorber 审中-公开
标题翻译：高度兼容和非迁移的聚合物紫外线吸收剂
公开(公告)号：US20060235116A1
公开(公告)日：2006-10-19
申请号：US10558316
申请日：2004-05-14
申请人： Dario Lazzari , Manuele Vitali , Michela Bonora , Graziano Zagnoni , Marie-Raphael Morvillier
发明人： Dario Lazzari , Manuele Vitali , Michela Bonora , Graziano Zagnoni , Marie-Raphael Morvillier
IPC分类号： C08K5/34
CPC分类号： C08G63/6854 , C08K3/08 , C08K5/132 , C08K5/3492 , C08K2201/012 , C08L67/02 , C08L67/04 , C08L69/00 , C08L2666/18
摘要： The present invention relates to highly compatible hydroxyphenyltriazine UV-absorbers and to their use in organic polymers, especially for protecting the contents of transparent plastic packages such as pharmaceuticals, cosmetics, personal care products, shampoos and the like, and especially foodstuffs such as beverages, fresh vegetables or meat, from the deleterious effects of ultraviolet radiation. Especially advantageous is the combined use of a UV absorber and an oxygen scavenger. It has been found that certain highly compatible tris-aryl-s-triazines are especially effective towards this end when incorporated in the containers or films in which such materials are stored.
摘要翻译：本发明涉及高度相容的羟基苯基三嗪UV吸收剂及其在有机聚合物中的用途，特别是用于保护诸如药物，化妆品，个人护理产品，洗发剂等的透明塑料包装的内容物，特别是食品如饮料，新鲜蔬菜或肉类，从紫外线辐射的有害影响。特别有利的是UV吸收剂和除氧剂的组合使用。已经发现，某些高度相容的三 - 芳基-s-三嗪在结合到其中存储这些材料的容器或薄膜中时特别有效。

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