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1. 发明授权

US06642383B2 Oxopiperazinyl derivatives and light stabilized compositions 失效
标题翻译：氧哌嗪衍生物和光稳定组合物
公开(公告)号：US06642383B2
公开(公告)日：2003-11-04
申请号：US09855905
申请日：2001-05-15
申请人： Dario Lazzari , Graziano Zagnoni , Mirko Rossi , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
发明人： Dario Lazzari , Graziano Zagnoni , Mirko Rossi , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
IPC分类号： C07D24106
CPC分类号： G03C1/8155 , C07D241/08 , C07D403/14 , C07D405/12 , C07D409/14 , C08G63/6856 , C08G73/0633 , C08K5/3462
摘要： Compounds of the formula (I) wherein p is zero or 1; q and r, independently of each other, are an integer from 1 to 6; and s is a number ranging from 1 to 8; X is —O— or, when p is 1, X is also a group Rw, Rx, Ry and Rz are, independently of each other, C1-C18alkyl, C5-C12cycloalkyl or C1-C5hydroxyalkyl, especially methyl; R1 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R1 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)—G, in which G is hydrogen, methyl or phenyl; R2 is hydrogen, C1-C8alkyl, C5-C12cycloalkyl or C1-C4hydroxyalkyl; R3, R4, R5 independently of each other are hydrogen, C1-C8alkyl or C5-C12cycloalkyl; and W and other residues are as described in claim 1, are effective stabilizers for organic materials, for example thermoplastic organic polymers, coating compositions or photographic materials.
摘要翻译：式（I）的化合物，其中p为0或1; q和r彼此独立地是1至6的整数; 且为1至8的数; X为-O-或当p为1时，X为基团R w，R x，R y和R z彼此独立地为C 1 -C 18烷基，C 5 -C 12环烷基或C 1 -C 18烷基， C5羟烷基，特别是甲基; R1是氢; C1-C18烷基; 氧基哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 1为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基或基团-CH 2 CH（OH）-G，其中G是氢，甲基或苯基; R 2是氢，C 1 -C 8烷基，C 5 -C 12环烷基或C 1 -C 4羟烷基; R 3，R 4，R 5彼此独立地是氢，C 1 -C 1-8烷基或C 5 -C 12环烷基; 和W和其它残余物如权利要求1所述，是有机材料的有效稳定剂，例如热塑性有机聚合物，涂料组合物或照相材料。

2. 发明授权

US6114420A Triazine derivatives containing 2,2,6,6-tetramethyl-4-piperidyl groups 失效
标题翻译：含有2,2,6,6-四甲基-4-哌啶基的三嗪衍生物
公开(公告)号：US6114420A
公开(公告)日：2000-09-05
申请号：US84681
申请日：1998-05-26
申请人： Alessandro Zedda , Gianluca Ferri
发明人： Alessandro Zedda , Gianluca Ferri
IPC分类号： C07D401/14 , C08K5/3492 , C08K5/3435
CPC分类号： C07D401/14
摘要： A compound of the formula (I) ##STR1## wherein n is an integer from 1 to 4; the radicals R.sub.1 are for example a group of the formula ##STR2## R.sub.3 is for example hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.5 -C.sub.12 cycloalkoxy; Z and R.sub.2 are for example a group ##STR3## the radicals A and E are, for example, independently of one another --N(R.sub.11)(R.sub.12) or a group of the formula ##STR4## R.sub.11 and R.sub.12 are for example C.sub.1 -C.sub.12 alkyl; R.sub.13 has for example one of the meanings given for R.sub.3 ; E* has for example one of the meanings given for A or is a group of the formula ##STR5## The compounds of the formula (I) are useful as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers such as polyolefins.
摘要翻译：式（I）的化合物，其中n为1至4的整数; 基团R 1是例如式R 3的基团是例如氢，C 1 -C 8烷基或C 5 -C 12环烷氧基; Z和R 2是例如基团A和E例如彼此独立的基团-N（R 11）（R 12）或式R 11和R 12的基团是例如C 1 -C 12烷基; R13具有例如R3给出的含义之一; E *具有例如A给出的含义之一或者是一组式。式（I）的化合物可用作有机材料的光稳定剂，热稳定剂和氧化稳定剂，特别是合成聚合物如聚烯烃。

3. 发明申请

US20050239927A1 Dyeable polyolefin fibers and fabrics 审中-公开
标题翻译：可染聚烯烃纤维和织物
公开(公告)号：US20050239927A1
公开(公告)日：2005-10-27
申请号：US11107613
申请日：2005-04-15
申请人： Andrew Leggio , John McNamara , Jean-Roch Pauquet , Paul Shields , Alessandro Zedda
发明人： Andrew Leggio , John McNamara , Jean-Roch Pauquet , Paul Shields , Alessandro Zedda
IPC分类号： C08K5/34 , C08L23/02 , D01F1/06 , D01F6/46
CPC分类号： D01F6/46 , C08K5/34 , C08L23/02 , D06P3/794 , C08L2666/02
摘要： Polyolefin fibers and filaments, and fabrics made therefrom, are rendered dyeable via a combination of dyeability additives. The dyeability additive combination comprises at least one compound selected from the group consisting of the polyamides, copolyamides and polyetherpolyamides and at least one ethylene vinyl acetate. The dyed polyolefin fibers and fabrics are rendered light stable via the use of a combination of stabilizers, which comprises at least one compound selected from the group consisting of the ultraviolet light stabilizers and at least one compound selected from the group consisting of the hindered amine light stabilizers. The ultraviolet light stabilizers are for example hydroxyphenylbenzotriazoles or tris-aryl-s-triazines. The hindered amine light stabilizers are for example of high molecular weight, for instance greater than 1000 g/mol. The dyes are for example anthraquinone blue dyes, anthraquinone red dyes, diazo red dyes or nitro yellow dyes.
摘要翻译：聚烯烃纤维和长丝以及由其制成的织物通过可染性添加剂的组合变得可染色。可染性添加剂组合包含至少一种选自聚酰胺，共聚酰胺和聚醚多胺和至少一种乙烯 - 乙酸乙烯酯的化合物。染色的聚烯烃纤维和织物通过使用稳定剂的组合使其变得光稳定，稳定剂包括至少一种选自紫外光稳定剂和至少一种选自受阻胺光稳定剂紫外光稳定剂是例如羟基苯基苯并三唑或三 - 芳基-s-三嗪。受阻胺光稳定剂例如具有高分子量，例如大于1000g / mol。染料是例如蒽醌蓝染料，蒽醌红染料，重氮红染料或硝基黄染料。

4. 发明授权

US06596461B1 Piperazinone derivatives 失效
标题翻译：哌嗪酮衍生物
公开(公告)号：US06596461B1
公开(公告)日：2003-07-22
申请号：US09856574
申请日：2001-05-22
申请人： Dario Lazzari , Mirko Rossi , Graziano Zagnoni , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
发明人： Dario Lazzari , Mirko Rossi , Graziano Zagnoni , Alessandro Zedda , Valerio Borzatta , Stephen Mark Andrews
IPC分类号： G03C173
CPC分类号： C07D403/14 , C08G73/0273 , C08G73/0644 , C08K5/34926 , Y10S430/106 , Y10S430/107 , Y10S430/108
摘要： A compound of formula (I) wherein n is e.g. a number from 2 to 50; R5′ and R5″ are e.g. a group of formula (II); G1, G2, G3 and G4 are e.g. C1-C4akyl; R1 is e.g. hydrogen or C1-C4alkyl; R2 is e.g. methylene; R3′ is e.g. hydrogen and R3″ is e.g. hydrogen or C1-C4alkyl; R4 is e.g. C2-C8alkylene; and X is e.g. —N(R7)R8) with R7 and R8 being independently of one another hydrogen or C1-C8alkyl, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.
摘要翻译：其中n为例如式（I）的化合物。从2到50的数字; R5'和R5“是例如。一组式（II）; G1，G2，G3和G4是例如。 C1-C4烷基; R1是例如氢或C 1 -C 4烷基; R2是例如亚甲基 R3'是例如。氢和R3“是例如。氢或C 1 -C 4烷基; R4是例如 C2-C8亚烷基; 而X是例如。 -N（R 7）R 8），其中R 7和R 8彼此独立地为氢或C 1 -C 8烷基，可用于稳定有机材料以防止由光，热或氧化引起的降解。

5. 发明授权

US5589557A Fluorinated polymers and copolymers containing cyclic structures 失效
标题翻译：含有环状结构的氟化聚合物和共聚物
公开(公告)号：US5589557A
公开(公告)日：1996-12-31
申请号：US441197
申请日：1995-05-15
申请人： Walter Navarrini , Vito Tortelli , Alessandro Zedda
发明人： Walter Navarrini , Vito Tortelli , Alessandro Zedda
IPC分类号： C08F214/18 , C07C41/00 , C07C43/16 , C07C43/313 , C08F14/18 , C08F16/14 , C08F16/24 , C08F16/32 , C08F24/00 , C08F34/00 , C08F216/12 , C08F216/14 , C08F224/00 , C08F234/02 , C09D137/00
CPC分类号： C08F16/32 , C07C43/313
摘要： Polymers and copolymers of one or more fluorinated dienes of structure CFX.sup.1 .dbd.CX.sup.2 --O--CX.sup.3 X.sup.4 --O--CX.sup.2 .dbd.CX.sup.1 F, wherein X.sup.1 and X.sup.2 are F, Cl or H, and X.sup.3 and X.sup.4 are F or CF.sub.3, wherein said dienes essentially form cyclic repetitive units, the comonomers used for preparing copolymers being ethylene unsaturated fluorinated compounds.Processes for preparing the fluorinated dienes having said structure which comprise the reaction in solution between one halogenated olefin and one hypofluorite CX.sup.3 X.sup.4 (OF).sub.2, wherein X.sup.3 and X.sup.4 are F or CF.sub.3, and the dehalogenation or dehydrohalogenation of the linear adduct between one hypofluorite molecule and two olefin molecules. The polymers and copolymers of the invention are particularly suitable for preparing coatings for applications at high temperatures.
摘要翻译：结构CFX1 = CX2-O-CX3X4-O-CX2 = CX1F的一种或多种氟化二烯的聚合物和共聚物，其中X 1和X 2是F，Cl或H，且X 3和X 4是F或CF 3，其中所述二烯基本上形成用于制备共聚物的共聚单体是乙烯不饱和氟化化合物。用于制备具有所述结构的氟化二烯的方法，其包含在一种卤代烯烃和一种次氟酸盐CX3X4（OF）2之间的溶液中的反应，其中X 3和X 4是F或CF 3，并且一个次氟酸盐分子之间的线性加合物的脱卤或脱卤化氢和两个烯烃分子。本发明的聚合物和共聚物特别适用于制备高温应用的涂料。

6. 发明授权

US07122663B2 Stable free nitroxyl radicals as oxidation catalysts and process for oxidation 失效
标题翻译：稳定的游离硝酰自由基作为氧化催化剂和氧化过程
公开(公告)号：US07122663B2
公开(公告)日：2006-10-17
申请号：US10466726
申请日：2002-01-15
申请人： Alessandro Zedda , Massimiliano Sala , Armin Schneider
发明人： Alessandro Zedda , Massimiliano Sala , Armin Schneider
IPC分类号： C07D245/00 , C07D487/00
CPC分类号： B01J31/40 , B01J31/006 , B01J31/0237 , B01J31/0244 , B01J2231/70 , C07C45/29 , C07C45/294 , C07C45/30 , C07C45/38 , C07C45/39 , C07C51/29 , C07D471/18 , C07D487/18 , C08K5/34926 , Y02P20/584 , C07C49/04 , C07C47/19 , C07C59/305
摘要： The instant invention relates to stable free nitroxyl radicals of formula (I) wherein at least one of the substituents R is —O. and the others are hydrogen or OH; X is —NR1R2, wherein R1 and R2 are independently hydrogen, C1–C18alkyl or together with the nitrogen atom to which they are bound form a 5 or 6 membered ring which may be further interrupted by an O atom. Further subjects of the invention are an oxidation process for alcohols to aldehydes or ketones or to carboxylic acids in the presence of a compound of formula (I) and the use of stable free nitroxyl radicals of formula (I) as oxidation catalysts.
摘要翻译：本发明涉及式（I）的稳定的游离硝酰基，其中至少一个取代基R为-O。其余为氢或OH; X是-NR 1 R 2 R 2，其中R 1和R 2分别独立地是氢，C 1 -C 4烷基，或者与它们所连接的氮原子一起形成可被O原子进一步中断的5或6元环。本发明的其它主题是在式（I）化合物和式（I）的稳定的游离硝酰基作为氧化催化剂的存在下，将醇与醛或酮或羧酸的氧化方法。

7. 发明申请

US20060167153A1 Film compositions with permanent anti-fog, anti-mist and anti-cloud properties 审中-公开
标题翻译：具有永久防雾，防雾和防云性能的电影作品
公开(公告)号：US20060167153A1
公开(公告)日：2006-07-27
申请号：US10524456
申请日：2003-08-28
申请人： Armin Schneider , Alessandro Zedda , Ernst Minder
发明人： Armin Schneider , Alessandro Zedda , Ernst Minder
IPC分类号： C08K5/06 , C09K3/18
CPC分类号： C08K5/06 , C08L23/02 , C08L29/04 , C08L31/04
摘要： The instant invention discloses a film a composition with anti-fog, anti-mist and anti-cloud properties comprising (a) a polyolefin, a polyvinylalcohol, a polyvinylester or mixtures thereof, (b) an effective amount of at least one linear ethoxylated alcohol; and (c) an effective amount of at least one fluorine-containing surfactant. The films are useful as a greenhouse film for agricultural applications.
摘要翻译：本发明公开了一种具有防雾，防雾和抗云特性的组合物，其包含（a）聚烯烃，聚乙烯醇，聚酯或其混合物，（b）有效量的至少一种直链乙氧基化醇 ; 和（c）有效量的至少一种含氟表面活性剂。这些电影可用作农业应用的温室膜。

8. 发明授权

US07037964B2 Polyolefin film compositions with permanent antifog properties 失效
标题翻译：具有永久防雾性能的聚烯烃膜组合物
公开(公告)号：US07037964B2
公开(公告)日：2006-05-02
申请号：US10880680
申请日：2004-06-30
申请人： Anunay Gupta , David Devore , John James McNamara , Alessandro Zedda
发明人： Anunay Gupta , David Devore , John James McNamara , Alessandro Zedda
IPC分类号： C08K5/06
CPC分类号： C08J5/18 , C08J2323/04 , C08K5/04 , C08K5/06 , Y10T428/31855 , Y10T428/31909 , C08L23/02
摘要： Polyolefin films having incorporated therein a compound of the formula CH3CH2(CH2CH2)aCH2CH2(OCH2CH2)bOH, where a is 9 to 25 and b is 1 to 10, exhibit superior long lasting fog resistance. The polyolefin films are useful as packaging film for moist products and as a greenhouse film for agricultural applications.
摘要翻译：其中并入其中的通式为CH 3 CH 2（CH 2 CH 2）的化合物的聚烯烃膜（CH 2）2 CH 2（OCH 2 CH 2 CH 2）b 其中a为9〜25，b为1〜10，表现出优异的持久耐雾性。聚烯烃膜可用作潮湿产品的包装膜和用于农业应用的温室膜。

9. 发明授权

US06762226B2 Compositions stabilized by dioxopiperazinyl derivatives 失效
标题翻译：由二氧代哌嗪衍生物稳定的组合物
公开(公告)号：US06762226B2
公开(公告)日：2004-07-13
申请号：US10272193
申请日：2002-10-15
申请人： Alessandro Zedda , Graziano Zagnoni , Massimiliano Sala , Dario Lazzari , Stephen Mark Andrews
发明人： Alessandro Zedda , Graziano Zagnoni , Massimiliano Sala , Dario Lazzari , Stephen Mark Andrews
IPC分类号： C07D40304
CPC分类号： C08L55/02 , C08K5/34926 , C08L59/00 , C08L59/02 , C08L69/00 , C08L2666/14 , C08L2666/02
摘要： Polyoxymethylene, blends of polycarbonate with acrylonitrile-butadiene-styrene terpolymer, and coatings based on a functional acrylate resin and a crosslinking agent, which are stabilized by addition of a compound of the formula I wherein s is from the range 1 to 8; R1, R2, R3 and R4, independently of each other, are C1-C4alkyl, or R1 and R2 or R3 and R4, together with the carbon atom to which they are bound, form a cyclopentyl or cyclohexyl ring; R5 is hydrogen; C1-C18alkyl; oxyl; OH; CH2CN; C1-C18alkoxy; C5-C12cycloalkoxy; C3-C8alkenyl; C3-C8alkynyl; C7-C12phenylalkyl; C7-C15phenylalkyl, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; C7-C15phenylalkoxy; C7-C15phenylalkoxy, which is substituted on the phenyl ring by 1, 2 or 3 radicals selected from C1-C4alkyl and C1-C4alkoxy; or R5 is C1-C8alkanoyl; C3-C5alkenoyl; C1-C18alkanoyloxy; glycidyl; or a group —CH2CH(OH)-G, in which G is hydrogen, methyl or phenyl; and A is as described in claim 1, show a good resistance against harmful effects of light, oxygen and heat.
摘要翻译：聚甲醛，聚碳酸酯与丙烯腈 - 丁二烯 - 苯乙烯三元共聚物的共混物，以及基于官能丙烯酸酯树脂和交联剂的涂料，其通过加入式I化合物而得到稳定，其中s为1至8; R1，R2 R 3和R 4彼此独立地是C 1 -C 4烷基，或者R 1和R 2或R 3和R 4与它们所连接的碳原子一起形成环戊基或环己基环; R 5是氢; C1-C18烷基; 氧基哦; CH2CN; C1-C18烷氧基; C5-C12环烷氧基; C3-C8链烯基; C3-C8炔基; C7-C12苯基烷基; C7-C15苯基烷基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; C7-C15苯基烷氧基; C7-C15苯基烷氧基，其在苯环上被1,2或3个选自C 1 -C 4烷基和C 1 -C 4烷氧基的基团取代; 或R 5为C 1 -C 8烷酰基; C3-C5链烯酰基; C1-C18烷酰氧基; 缩水甘油基或基团-CH 2 CH（OH）-G，其中G是氢，甲基或苯基; 和A如权利要求1所述，显示出对光，氧和热的有害影响的良好抵抗性。

10. 发明授权

US07790807B2 Fluorocarbon terminated oligo- and poly-carbonates as surface modifiers 失效
标题翻译：氟碳封端的低聚和碳酸酯作为表面改性剂
公开(公告)号：US07790807B2
公开(公告)日：2010-09-07
申请号：US10582749
申请日：2004-12-08
申请人： Martin Brunner , Archana Kishore Desai , Shrirang Bhikaji Hindalekar , Suhas Dattatraya Sahasrabudhe , Armin Schneider , Paragkumar Nathalal Thanki , Michael Tinkl , Alessandro Zedda , Michèle Gerster , Fabien Jean Brand
发明人： Martin Brunner , Archana Kishore Desai , Shrirang Bhikaji Hindalekar , Suhas Dattatraya Sahasrabudhe , Armin Schneider , Paragkumar Nathalal Thanki , Michael Tinkl , Alessandro Zedda , Michèle Gerster , Fabien Jean Brand
IPC分类号： C08L69/00 , C08G64/10 , C08G64/14
CPC分类号： C08L23/12 , C08G64/10 , C08G64/14 , C08K5/005 , C08L67/00 , C08L69/00 , C08L2666/18
摘要： The instant invention relates to new compounds of the formula I R1 and R2 are each independently of the other a fluorine containing group, R3 and R4 are each independently of the other hydrogen, a fluorine containing group, C1-C12alkyl, phenyl or R4, together with the carbon atom to which they are bonded, form a C5-C8-cycloalkylidene ring that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl groups; R5, R6, R7 and R8 are each independently of the other hydrogen, C1-C12alkyl or C3-C12alkenyl, X1 and X2 are each independently of the other a direct bond or C1-C12alkylene, m is 1 to 10,000, and n is 0 to 10,000. These new compounds of the formula I are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an “easy to clean”, “self-cleaning” “antisoiling”, “soil-release” “antigraffiti”, “oil resistance”, “solvent resistance”, “chemical resistance”, “self lubricating”, “scratch resistance”, “low moisture absorption” and “hydrophobic” surface.
摘要翻译：本发明涉及新的式Ⅰ化合物R1和R2各自独立地为含氟基团，R3和R4分别独立地为氢，含氟基团，C1-C12烷基，苯基或R4，一起形成未被取代或被1至3个C 1 -C 4烷基取代的C 5 -C 8亚环烷基环; R 5，R 6，R 7和R 8各自独立地为氢，C 1 -C 12烷基或C 3 -C 12链烯基，X 1和X 2各自独立地为直接键或C 1 -C 12亚烷基，m为1至10,000，n为0 到10,000。这些式I化合物可用作有机材料如聚碳酸酯，聚酯或聚酮或其混合物，共混物或合金的表面能的还原剂。具有这种表面能降低的聚合物具有“易清洁”，“自清洁”，“防污”，“释放”“防泼溅”，“耐油性”，“耐溶剂性”，“耐化学性” 润滑性“，”耐刮擦性“，”低吸湿性“和”疏水性“表面。

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