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    • 5. 发明授权
    • Use of fluorinated compounds to confer release properties
    • 使用含氟化合物赋予脱模性能
    • US06514567B2
    • 2003-02-04
    • US09794091
    • 2001-02-28
    • Gabriella CarignanoMattia De Dominicis
    • Gabriella CarignanoMattia De Dominicis
    • B05D102
    • D21H27/001C09J7/401C09J2400/283C09J2401/006C09J2427/005
    • Use of fluorinated compounds to confer release properties to cellulosic substrata, selected from the following structures: (A) [Rf—CFY—L—O]mP(O) (O−Z+)3−m (B) (O−Z+)2P(O)[O—L—YFC—O—Rf—CFY—L—O—P(O) (O−Z+)]m′——[O—L—YFC—O—Rf—CFY—L—O]P(O) (O−Z+)2 (C) Fluorinated (meth)acrylic copolymers (D) [Rt—CF2—SO2N(U1) (U2) —O]g—P(O) (OZ)3−g wherein: m′ is an integer from 0 to 20; L is an organic group selected from —CH2—(OCH2CH2)n—, —CO—NR′—(CH2)q—, with R′═H or C1-C4 alkyl group; n=0-8, q=1-8; Z═H, alkane metal or a NR4 group with R═H or C1-C4 alkyl group; Y═F, CF3; m=1,2,3; Rf is a perfluoropolyether radical; Rt is a linear or branched perfluorocarbon radical having from 1 to 20 carbon atoms; g=1-3; U1, U2 equal to or different from each other, are selected from linear or branched C1-C8 alkyl groups, (CH2CH2O)Q ethylenoxide groups, wherein Q is in the range 1-20.
    • (A)[Rf-CFY-LO] mP(O)(O-Z +)3-m(B)(O-Z +)2P(O-Z +)2P O](O-Z +)2 [O-YFC-O-Rf-CFY-LOP(O)(O-Z +)] m' (C)氟化(甲基)丙烯酸共聚物(D)[Rt-CF2-SO2N(U1)(U2)-O] gP(O)(OZ)3-g其中:m'为0〜20的整数; L是选自-CH 2 - (OCH 2 CH 2)n - , - CO-NR' - (CH 2)q - ,其中R'= H或C 1 -C 4烷基的有机基团; n = 0-8,q = 1-8; Z = H,烷烃金属或具有R = H或C 1 -C 4烷基的NR 4基团; Y = F,CF3; m = 1,2,3; Rf是全氟聚醚基团; R t是具有1至20个碳原子的直链或支链全氟化碳基团; g = 1-3; U1,U2彼此相同或不同,选自直链或支链C 1 -C 8烷基,(CH 2 CH 2 O)Q亚乙基氧基,其中Q在1-20的范围内。
    • 7. 发明授权
    • Treatment of glass substrata with (per) fluoropolyether compounds
    • 用(全)氟聚醚化合物处理玻璃基质
    • US07229503B2
    • 2007-06-12
    • US10062490
    • 2002-02-05
    • Mattia De DominicisGabriella Carignano
    • Mattia De DominicisGabriella Carignano
    • B08B7/00
    • C08G65/007C03C17/30
    • Use in the treatment of glass substrata of mono- and bi-functional (per)fluoropolyether compounds having the following structures: Rf—CFY-L-W  (I) W-L-YFC—O—Rf—CFY-L-W  (II) wherein: L is a linking organic group —CO—NR′—(CH2)q—, with R′=H or C1-C4 alkyl; q=1-8; Y=F, CF3; W is a —Si(R1)α(OR2)3−α group with α=0, 1, 2; R1 and R2 equal to or different from each other are C1-C6 alkyl groups, optionally containing one or more ether O atoms, C6-C10 aryl groups, C7-C12 alkyl-aryl or aryl-alkyl groups; Rf has a number average molecular weight in the range 350-5,000, and comprises repeating units of the type: (CFXO),(CF2CF2O),(CF(CF3)CF2O),(CF2CF(CF3)O), wherein X=F, CF3.
    • 用于处理具有以下结构的单功能和双功能(全)氟代聚醚化合物的玻璃基质:<?in-line-formula description =“In-line formula”end =“lead”?> R& f-CFY-LW(I)<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”→WL-YFC-OR -CFY-LW(II)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中: L是连接的有机基团-CO-NR' - (CH 2 CH 2)q - ,其中R'= H或C 1 -C 烷基; q = 1-8; Y = F,CF 3 3; W是具有α= 0的-Si(R 1)2α(OR 2)3-α ,1,2; R 1和R 2等于或不同的基团是C 1 -C 6烷基,任选地 含有一个或多个醚O原子,C 6 -C 10芳基,C 7 -C 12烷基 芳基或芳基 - 烷基; Rf的数均分子量在350-5,000范围内,并且包含以下类型的重复单元:<?in-line-formula description =“In-line formula”end =“lead”?>(CFXO),(CF (CF(CF 3)CF 2 O),(CF 3 CF 2 CF 2 CF 2) 2 CF(CF 3 O)O),<?在线公式描述=“在线公式”end =“tail”?>其中X = F,CF 3