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    • 5. 发明授权
    • Methods of making composite aluminum nitride ceramic articles having
embedded filler
    • 制备具有嵌入填料的复合氮化铝陶瓷制品的方法
    • US5420085A
    • 1995-05-30
    • US7387
    • 1993-01-21
    • Marc S. NewkirkHarry R. ZwickerAndrew W. UrquhartHarold D. LesherTerry D. ClaarMichael K. AghajanianJohn P. Biel, Jr.
    • Marc S. NewkirkHarry R. ZwickerAndrew W. UrquhartHarold D. LesherTerry D. ClaarMichael K. AghajanianJohn P. Biel, Jr.
    • C04B35/65C04B35/76C04B35/80C04B41/50C04B41/87C04B35/58
    • C04B41/5025C04B35/652C04B35/76C04B35/80C04B41/87
    • A method of making self-supporting ceramic composite structures having filler embedded therein includes infiltrating a permeable mass of filler with polycrystalline material comprising an oxidation reaction product obtained by oxidation of a parent metal such as aluminum and optionally, containing therein non-oxidized constituents of the parent metal. The structure is formed by placing a parent metal adjacent to a permeable filler and heating the assembly to melt the parent metal and provide a molten body of parent metal which is contacted with a suitable vapor-phase oxidant. Within a certain temperature region and optionally, aided by one or more dopants in or on the parent metal, molten parent metal will migrate through previously formed oxidation reaction product into contact with the oxidant, causing the oxidation reaction product to grow so as to embed the adjacent filler and provide the composite structure. In a preferred embodiment, a parent metal comprising aluminum is oxidized by a vapor-phase oxidant comprising nitrogen to form a ceramic matrix comprising an aluminum nitride oxidation reaction product. In a particularly preferred embodiment, one or more protective coatings are applied to the filler prior to formation of the aluminum nitride oxidation reaction product matrix.
    • 制造具有嵌入其中的填料的自支撑陶瓷复合结构的方法包括用多晶材料渗透可渗透的填料,所述多晶材料包含通过氧化母体金属如铝而获得的氧化反应产物,并且任选地含有其中的非氧化成分 母金属。 通过将母体金属放置在可渗透填料附近并加热该组件以熔化母体金属并提供与合适的气相氧化剂接触的母体金属的熔融体来形成结构。 在一定温度范围内,任选地,由母体金属中或母体金属上的一种或多种掺杂剂辅助,熔融母体金属将迁移通过预先形成的氧化反应产物与氧化剂接触,使氧化反应产物生长,从而嵌入 相邻填料并提供复合结构。 在优选的实施方案中,包含铝的母体金属被包含氮的气相氧化剂氧化以形成包含氮化铝氧化反应产物的陶瓷基体。 在特别优选的实施方案中,在形成氮化铝氧化反应产物基质之前,将一种或多种保护性涂料施加到填料上。
    • 9. 发明授权
    • Method of making ceramic articles having channels therein and articles
made thereby
    • 制造具有通道的陶瓷制品的方法和由此制成的制品
    • US4847025A
    • 1989-07-11
    • US907924
    • 1986-09-16
    • Danny R. WhiteMichael K. Aghajanian
    • Danny R. WhiteMichael K. Aghajanian
    • C04B35/622B28B1/00B28B3/02B28B7/34C04B35/10C04B35/65C04B38/00C04B38/06
    • B28B3/025B28B1/00B28B7/342C04B35/652C04B38/061
    • A method is provided for producing a self-supporting ceramic body comprising a polycrystalline material comprised of the oxidation reaction product of a parent metal and having therein one or more channels which inversely replicate the geometry of a configured fugitive metal. The method includes providing an assembly of the configured fugitive metal and the parent metal, optionally including a bed of permeable filler, and heating the assembly to form a body of molten parent metal. The molten parent metal is oxidized under selected conditions to grow the polycrystalline material to engulf the configured fugitive metal (and to infiltrate the filler, if the filler is present) and to cause the fugitive metal to disperse into the engulfing polycrystalline material thereby leaving behind as the one or more channels the space formerly occupied by the configured fugitive metal. The method provides self-supporting ceramic bodies having therein one or more channels inversely replicating the shape of the configured fugitive metal.
    • 提供了一种用于生产自支撑陶瓷体的方法,其包括由母体金属的氧化反应产物组成的多晶材料,并且在其中具有一个或多个通道,其反复地构成配置的逃逸金属的几何形状。 该方法包括提供配置的短暂金属和母体金属的组件,任选地包括可渗透填料床,以及加热组件以形成熔融母体金属体。 熔融母体金属在选择的条件下被氧化以生长多晶材料以吞没配置的短暂金属(并且如果存在填料,则渗透填料)并且使短暂金属分散到吞没的多晶材料中,从而留下如 一个或多个通道,空间以前由配置的逃逸金属占据。 该方法提供了在其中具有一个或多个通道的自支撑陶瓷体,反向复制了配置的短效金属的形状。