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1. 发明授权

US06648998B2 Reduced sensitivity melt-cast explosives 有权
公开(公告)号：US06648998B2
公开(公告)日：2003-11-18
申请号：US09747303
申请日：2000-12-21
申请人： Daniel W. Doll , Jami M. Hanks , Thomas K. Highsmith , Gary K. Lund , John B. Niles
发明人： Daniel W. Doll , Jami M. Hanks , Thomas K. Highsmith , Gary K. Lund , John B. Niles
IPC分类号： C06B4506
CPC分类号： C06B21/005 , C06B25/06
摘要： This melt-cast explosive shares comparable explosive properties to those of COMP B explosives and is melt-pourable and castable under conditions comparable to those of COMP B explosives, but experiences less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with COMP B. A fundamental and well-accepted component of COMP B, i.e., trinitrotoluene (TNT), is replaced with one or more mononitro-substituted or dinitro-substituted melt-cast binders, such as dinitroanisole, which can be melt cast without presenting the toxicity drawbacks experienced with the use of TNT. The melt-cast binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. Preferably, the composition also includes coarse oxidizer particles and energetic filler in fine particulate form.

2. 发明授权

US5516377A Gas generating compositions based on salts of 5-nitraminotetrazole 失效
标题翻译：基于5-硝基四氮唑盐的气体发生组合物
公开(公告)号：US5516377A
公开(公告)日：1996-05-14
申请号：US179736
申请日：1994-01-10
申请人： Thomas K. Highsmith , Gary K. Lund , Reed J. Blau , Jerald C. Hinshaw , Daniel W. Doll
发明人： Thomas K. Highsmith , Gary K. Lund , Reed J. Blau , Jerald C. Hinshaw , Daniel W. Doll
IPC分类号： C06D5/06 , C06B45/06 , C06B25/34 , C06B31/12
CPC分类号： C06D5/06
摘要： A composition is provided which has at least one salt of 5-nitraminotetrazole and an at least one oxidizer selected from among inorganic nitrates, inorganic nitrites, metal oxides, metal peroxides, organic peroxides, inorganic perchlorates, inorganic chlorates, metal hydroxides, and mixtures thereof. The compositions are useful in the gas generant field.
摘要翻译：提供一种组合物，其具有5-硝基四氮唑和至少一种选自无机硝酸盐，无机亚硝酸盐，金属氧化物，金属过氧化物，有机过氧化物，无机高氯酸盐，无机氯酸盐，金属氢氧化物及其混合物中的至少一种盐。该组合物可用于气体发生剂领域。

3. 发明授权

US06603018B2 Process for the synthesis and recovery of nitramines 失效
标题翻译：合成和回收硝胺的方法
公开(公告)号：US06603018B2
公开(公告)日：2003-08-05
申请号：US10060051
申请日：2002-01-29
申请人： Thomas K. Highsmith , Jami M. Hanks , Stephen P. Velarde , Jeffrey Bottaro
发明人： Thomas K. Highsmith , Jami M. Hanks , Stephen P. Velarde , Jeffrey Bottaro
IPC分类号： C07D24908
CPC分类号： C07D249/10
摘要： A method is provided for the synthesis of nitramines and the recovery of the nitramines from a clathrate.
摘要翻译：提供了一种用于合成硝胺和从包合物中回收硝胺的方法。

4. 发明授权

US06881847B2 Process for the synthesis and recovery of nitramines 失效
标题翻译：合成和回收硝胺的方法
公开(公告)号：US06881847B2
公开(公告)日：2005-04-19
申请号：US10455092
申请日：2003-06-05
申请人： Thomas K. Highsmith , Jami M. Hanks , Stephen P. Velarde , Jeffrey Bottaro
发明人： Thomas K. Highsmith , Jami M. Hanks , Stephen P. Velarde , Jeffrey Bottaro
IPC分类号： C07D233/92 , C07D249/08 , C07D249/10 , C07D249/14
CPC分类号： C07D249/10
摘要： A method is provided for the synthesis of nitramines and the recovery of the nitramines from a clathrate.
摘要翻译：提供了一种用于合成硝胺和从包合物中回收硝胺的方法。

5. 发明授权

US5451682A Method for synthesizing 5-aminotetrazole 失效
标题翻译：合成5-氨基四唑的方法
公开(公告)号：US5451682A
公开(公告)日：1995-09-19
申请号：US179559
申请日：1994-01-10
申请人： Thomas K. Highsmith , Gary K. Lund
发明人： Thomas K. Highsmith , Gary K. Lund
IPC分类号： C07D257/06
CPC分类号： C07D257/06
摘要： A process of preparing 5-aminotetrazole ("5-AT") which proceeds at substantially neutral pH is disclosed. In the process, cyanamide or dicyandiamide and an azide salt are reacted at elevated temperature in the presence of an acid reagent. The acid reagent has a pK.sub.a in the range from about 3 to about 7. Large quantities of hydrazoic acid are not produced during the reaction. Upon completion of the reaction, the reaction mixture is acidified to a pH less than 3 to protonate the 5-AT. Several variations of the acidification step permit control of particle size and morphology. The precipitated particles are isolated to yield 5-AT.
摘要翻译：公开了以基本中性pH进行的制备5-氨基四唑（“5-AT”）的方法。在此过程中，将氰胺或双氰胺和叠氮化物盐在升高的温度下在酸性试剂的存在下反应。酸试剂的pKa在约3至约7的范围内。在反应期间不会产生大量的氢偶氮。反应完成后，将反应混合物酸化至小于3的pH以质子化5-AT。酸化步骤的几个变化允许控制粒度和形态。分离出沉淀的颗粒，得到5-AT。

6. 发明授权

US5468866A Methods for synthesizing and processing bis-(1(2)H-tetrazol-5-yl)-amine 失效
标题翻译：合成和加工双 - （1（2）H-四唑-5-基） - 胺的方法
公开(公告)号：US5468866A
公开(公告)日：1995-11-21
申请号：US177737
申请日：1994-01-04
申请人： Thomas K. Highsmith , Robert M. Hajik , Robert B. Wardle , Gary K. Lund , Reed J. Blau
发明人： Thomas K. Highsmith , Robert M. Hajik , Robert B. Wardle , Gary K. Lund , Reed J. Blau
IPC分类号： C07D257/06 , C07D403/12
CPC分类号： C07D257/06
摘要： Methods of preparing bis-(1(2)H-tetrazol-5-yl)-amine (BTA) having improved physical and chemical characteristics are disclosed. In the process, a dicyanamide salt and an azide salt are reacted at high temperature in the presence of an acid reagent. Best yields are obtained when the reaction is allowed to proceed for approximately 48 hours. The dicyanamide salt is preferably present in a stoichiometric excess. The acid reagent has a pK.sub.a in the range from about 3 to about 9. The reaction mixture is acidified to a pH less than 3. Several variations of the acidification step permit control of particle size and morphology. Small, rounded particles are prepared by rapidly cooling the hot crude reaction product coincidentally with acidification. This is preferably accomplished by adding the hot crude reaction product directly to cold concentrated acid. The precipitated particles are isolated to yield BTA.
摘要翻译：公开了具有改善的物理和化学特性的双 - （1（2）H-四唑-5-基） - 胺（BTA）的制备方法。在此过程中，二氰胺盐和叠氮盐在酸性试剂的存在下在高温下反应。当允许反应进行约48小时时，获得最佳收率。二氰胺盐优选以化学计量过量存在。酸试剂的pKa在约3至约9的范围内。将反应混合物酸化至小于3的pH。酸化步骤的几个变化允许控制粒度和形态。通过与酸化偶然地快速冷却热粗反应产物来制备小的圆形颗粒。这优选通过将热粗反应产物直接加入到冷的浓酸中来完成。分离沉淀的颗粒以产生BTA。

7. 发明授权

US5682014A Bitetrazoleamine gas generant compositions 失效
标题翻译：哌嗪胺气体发生剂组合物
公开(公告)号：US5682014A
公开(公告)日：1997-10-28
申请号：US101396
申请日：1993-08-02
申请人： Thomas K. Highsmith , Reed J. Blau , Gary K. Lund
发明人： Thomas K. Highsmith , Reed J. Blau , Gary K. Lund
IPC分类号： B60R21/26 , C06B21/00 , C06B43/00 , C06D5/00 , C06D5/06 , C06B47/08
CPC分类号： C06D5/06 , C06B21/0066 , C06B43/00
摘要： A solid composition for generating a nitrogen containing gas is provided. The composition includes an oxidizer and a non-azide fuel selected from a bitetrazoleamine or a derivative or a salt or complex thereof and mixtures thereof. The preferred bitetrazole-amine is bis-(1(2)H-tetrazol-5-yl)-amine, a metal salt, a salt with a nonmetallic cation of a high nitrogen content base or a complex thereof. The salts and complexes are generally metal salts and complexes. The metal can be a transition metal. Metals that have been found to be particularly useful include copper, boron, cobalt, zinc, potassium, sodium, and strontium. The oxidizer is generally a metal oxide or a metal hydroxide. The composition can include certain other components such as secondary oxidizers, burn rate modifiers, slag formers, and binders.
摘要翻译：提供了一种用于产生含氮气体的固体组合物。组合物包括选自四唑胺或其衍生物或其盐或络合物的氧化剂和非叠氮化物燃料及其混合物。优选的四唑 - 胺是双 - （1（2）H-四唑-5-基） - 胺，金属盐，与高氮含量碱的非金属阳离子或其络合物的盐。盐和络合物通常是金属盐和络合物。金属可以是过渡金属。已发现特别有用的金属包括铜，硼，钴，锌，钾，钠和锶。氧化剂通常是金属氧化物或金属氢氧化物。组合物可以包括某些其它组分，例如二次氧化剂，燃烧速率改性剂，成矿剂和粘合剂。

8. 发明授权

US06425966B1 Energetic plasticizer, and explosive and propellant composition containing same 失效
标题翻译：能量增塑剂，含有其的爆炸性和推进剂组合物
公开(公告)号：US06425966B1
公开(公告)日：2002-07-30
申请号：US09661557
申请日：2000-09-14
申请人： Thomas K. Highsmith , Daniel W. Doll , Louis F. Cannizzo
发明人： Thomas K. Highsmith , Daniel W. Doll , Louis F. Cannizzo
IPC分类号： C06B4510
CPC分类号： C06B45/105
摘要： 2,2-dinitro-1,3-propanediol-diformate is a novel low sensitivity, energetic plasticizer that is useful in explosive and propellant compositions. 2,2-dinitro-1,3-propanediol-diformate can be made by reacting 2,2-dinitro-1,3-propane diol with acetic formic anhydride in the presence of pyridine and at least one solvent.
摘要翻译： 2,2-二硝基-1,3-丙二醇二甲酸酯是一种新颖的低灵敏度，高能增塑剂，可用于爆炸和推进剂组合物。 2,2-二硝基-1,3-丙二醇二甲酸酯可以通过使2,2-二硝基-1,3-丙二醇与乙酸甲酸酐在吡啶和至少一种溶剂的存在下反应来制备。

9. 发明授权

US6107483A Process for the large-scale synthesis of 4,10-dinitro-2,6,8-12-tetraoxa-4,10-diazatetracyclo-[5.5.0.05,903,11]-do decane 有权
标题翻译：大规模合成4,10-二硝基-2,6,8-12-四氧杂-4,10-二氮杂四环[5.5.0.05,903,11] - 十二烷的方法
公开(公告)号：US6107483A
公开(公告)日：2000-08-22
申请号：US362083
申请日：1999-07-28
申请人： Robert B. Wardle , Robert M. Hajik , Jerald C. Hinshaw , Thomas K. Highsmith
发明人： Robert B. Wardle , Robert M. Hajik , Jerald C. Hinshaw , Thomas K. Highsmith
IPC分类号： C07D267/02 , C07D498/22
CPC分类号： C07D498/22
摘要： A process for synthesizing 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo-[5.5.0.0.sup.5,9 0.sup.3,11 ]-dodecane ("TEX") involves combining at least one hexa-substituted piperazine derivative with a medium containing at least one nitronium anion source and at least one acid sufficiently strong to generate nitronium anions from the nitronium anion source. According to this invention, TEX yield is significantly improved by pre-heating the medium to 55.degree. C. to about 70.degree. C. and maintaining the medium from 55.degree. C. to about 70.degree. C. to permit the hexa-substituted piperazine derivative and nitronium anions to react and form the TEX. At least one NO.sub.x scavenger is added to the medium, preferably before the addition of the hexa-substituted piperazine derivative, to increase TEX yield.
摘要翻译：合成4,10-二硝基-2,6,8,12-四氧杂-4,10-二氮杂四环[5.5.0.05,903,11] - 十二烷（“TEX”）的方法涉及将至少一种六取代哌嗪衍生物与含有至少一个硝鎓阴离子源的介质和至少一种足够强的酸从硝鎓阴离子源产生硝鎓阴离子。根据本发明，通过将培养基预加热至55℃至约70℃，并将培养基保持在55℃至约70℃，可显着改善TEX产率，以允许六取代的哌嗪衍生物和硝酸根阴离子反应并形成TEX。向培养基中加入至少一种NO x清除剂，优选在加入六取代的哌嗪衍生物之前，以提高TEX产率。

10. 发明授权

US06705075B1 Digital solid rocket motor and gas generator 失效
标题翻译：数字固体火箭发动机和气体发生器
公开(公告)号：US06705075B1
公开(公告)日：2004-03-16
申请号：US09698472
申请日：2000-10-30
申请人： Thomas K. Highsmith , Michael D. Blair , Steven R. Wassom , William D. Starrett , Joel Dever
发明人： Thomas K. Highsmith , Michael D. Blair , Steven R. Wassom , William D. Starrett , Joel Dever
IPC分类号： F02K928
CPC分类号： F02K9/10 , F02K9/24 , F02K9/28
摘要： A method and device for producing a controlled combustion by placing a combustion chamber in communication with a feed chamber that contains a solid propellant/body, introducing at least a portion of the body into the combustion chamber, isolating the combustion chamber from the feed chamber, and igniting the solid propellant in the combustion chamber while the combustion chamber is isolated from the feed chamber.
摘要翻译：一种用于通过将燃烧室与包含固体推进剂/体的进料室连通来产生受控燃烧的方法和装置，将主体的至少一部分引入燃烧室，将燃烧室与进料室隔离，并且在燃烧室与进料室隔离的同时点燃燃烧室中的固体推进剂。

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