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1. 发明授权

US06648998B2 Reduced sensitivity melt-cast explosives 有权
公开(公告)号：US06648998B2
公开(公告)日：2003-11-18
申请号：US09747303
申请日：2000-12-21
申请人： Daniel W. Doll , Jami M. Hanks , Thomas K. Highsmith , Gary K. Lund , John B. Niles
发明人： Daniel W. Doll , Jami M. Hanks , Thomas K. Highsmith , Gary K. Lund , John B. Niles
IPC分类号： C06B4506
CPC分类号： C06B21/005 , C06B25/06
摘要： This melt-cast explosive shares comparable explosive properties to those of COMP B explosives and is melt-pourable and castable under conditions comparable to those of COMP B explosives, but experiences less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with COMP B. A fundamental and well-accepted component of COMP B, i.e., trinitrotoluene (TNT), is replaced with one or more mononitro-substituted or dinitro-substituted melt-cast binders, such as dinitroanisole, which can be melt cast without presenting the toxicity drawbacks experienced with the use of TNT. The melt-cast binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. Preferably, the composition also includes coarse oxidizer particles and energetic filler in fine particulate form.

2. 发明申请

US20080099112A1 Reduced sensitivity melt-pourable Tritonal replacements 审中-公开
标题翻译：灵敏度降低灵敏度可替代Tritonal替代品
公开(公告)号：US20080099112A1
公开(公告)日：2008-05-01
申请号：US11271359
申请日：2005-11-09
申请人： Daniel W. Doll , Jami M. Hanks , Alan G. Allred , John B. Niles
发明人： Daniel W. Doll , Jami M. Hanks , Alan G. Allred , John B. Niles
IPC分类号： C06B45/10
CPC分类号： C06B21/005 , C06B33/08
摘要： This melt-pourable explosive composition shares explosive properties comparable to those of Tritonal and is melt-pourable and castable under conditions comparable to those of Tritonal, but experiences equal or less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with trinitrotoluene. The trinitrotoluene component of Tritonal is replaced with one or more mononitro aromatic and/or dinitro aromatic melt-pourable binders, such as dinitroanisole, which may be melt poured without presenting the toxicity drawbacks experienced with the use of TNT. The melt-pourable binder may also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. The composition also includes oxidizer particles, which are preferably inorganic oxidizer particles, and a reactive metallic fuel, such as aluminum.
摘要翻译：这种可熔融倾倒的爆炸物组合物具有与Tritonal相当的爆炸特性，并且在与Tritonal相当的条件下可熔融浇注和浇注，但具有等同或更小的影响，冲击和热敏感性，并避免与三硝基甲苯相关的毒性问题。 Triton的三硝基甲苯组分被一种或多种单硝基芳族和/或二硝基芳香族可熔融流失的粘合剂（例如二硝基苯甲醚）代替，二硝基苯甲醚可以熔融浇注而不呈现使用TNT所经历的毒性缺点。可熔融倾倒的粘合剂也可以与选自烷基硝基苯胺和芳基硝基苯胺的加工助剂组合。组合物还包括氧化剂颗粒，其优选为无机氧化剂颗粒，以及反应性金属燃料，例如铝。

3. 发明授权

US06964714B2 Reduced sensitivity, melt-pourable tritonal replacements 有权
标题翻译：灵敏度降低，可熔融倾倒的三联替代品
公开(公告)号：US06964714B2
公开(公告)日：2005-11-15
申请号：US09893336
申请日：2001-06-27
申请人： Daniel W. Doll , Jami M. Hanks , Alan G. Allred , John B. Niles
发明人： Daniel W. Doll , Jami M. Hanks , Alan G. Allred , John B. Niles
IPC分类号： C06B21/00 , C06B33/08 , C06B45/06
CPC分类号： C06B21/005 , C06B33/08
摘要： This melt-pourable explosive composition shares explosive properties comparable to those of Tritonal and is melt-pourable and castable under conditions comparable to those of Tritonal, but experiences equal or less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with trinitrotoluene. The trinitrotoluene component of Tritonal is replaced with one or more mononitro aromatic and/or dinitro aromatic melt-pourable binders, such as dinitroanisole, which can be melt poured without presenting the toxicity drawbacks experienced with the use of TNT. The melt-pourable binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. The composition also includes oxidizer particles, which are preferably inorganic oxidizer particles, and a reactive metallic fuel, such as aluminum.
摘要翻译：这种可熔融倾倒的爆炸物组合物具有与Tritonal相当的爆炸特性，并且在与Tritonal相当的条件下可熔融浇注和浇注，但具有等同或更小的影响，冲击和热敏感性，并避免与三硝基甲苯相关的毒性问题。 Triton的三硝基甲苯组分被一种或多种单硝基芳香族和/或二硝基芳香族可熔融流失的粘合剂（例如二硝基苯甲醚）代替，二硝基苯甲醚可以熔融浇注而不呈现使用TNT所经历的毒性缺点。可熔融注射的粘合剂也可以与选自烷基硝基苯胺和芳基硝基苯胺的加工助剂组合。组合物还包括氧化剂颗粒，其优选为无机氧化剂颗粒，以及反应性金属燃料，例如铝。

4. 发明授权

US07067024B2 Reduced sensitivity, melt-pourable TNT replacements 有权
标题翻译：降低敏感性，可熔融倾倒的TNT替代品
公开(公告)号：US07067024B2
公开(公告)日：2006-06-27
申请号：US09893337
申请日：2001-06-27
申请人： Daniel W. Doll , Jami M. Hanks , Alan G. Allred , John B. Niles
发明人： Daniel W. Doll , Jami M. Hanks , Alan G. Allred , John B. Niles
IPC分类号： C06B45/06 , C06B25/04
CPC分类号： C06B21/005
摘要： This melt-pourable explosive composition shares explosive properties comparable to those of trinitrotoluene and is melt-pourable and castable under conditions comparable to those of trinitrotoluene, but experiences equal or less impact, shock, and thermal sensitivity and avoids the issues of toxicity associated with trinitrotoluene. Trinitrotoluene is replaced with one or more mononitro aromatic and/or dinitro aromatic melt-pourable binders, such as dinitroanisole, which can be melt poured without presenting the toxicity drawbacks experienced with the use of TNT. The melt-pourable binder can also be combined with a processing aid selected from the group consisting of alkylnitroanilines and arylnitroanilines. The composition also includes oxidizer particles, which are preferably inorganic oxidizer particles.
摘要翻译：这种可熔融倾倒的爆炸物组合物具有与三硝基甲苯相当的爆炸特性，并且在与三硝基甲苯相当的条件下是可熔融倾倒和浇注的，但具有相同或更小的影响，冲击和热敏感性，并避免与三硝基甲苯的毒性相关的问题。三硝基甲苯被一种或多种单硝基芳族和/或二硝基芳香族可熔融流失的粘合剂如二硝基苯甲醚代替，二硝基苯甲醚可以熔融浇注而不呈现使用TNT所经历的毒性缺点。可熔融注射的粘合剂也可以与选自烷基硝基苯胺和芳基硝基苯胺的加工助剂组合。组合物还包括氧化剂颗粒，其优选为无机氧化剂颗粒。

5. 发明授权

US5516377A Gas generating compositions based on salts of 5-nitraminotetrazole 失效
标题翻译：基于5-硝基四氮唑盐的气体发生组合物
公开(公告)号：US5516377A
公开(公告)日：1996-05-14
申请号：US179736
申请日：1994-01-10
申请人： Thomas K. Highsmith , Gary K. Lund , Reed J. Blau , Jerald C. Hinshaw , Daniel W. Doll
发明人： Thomas K. Highsmith , Gary K. Lund , Reed J. Blau , Jerald C. Hinshaw , Daniel W. Doll
IPC分类号： C06D5/06 , C06B45/06 , C06B25/34 , C06B31/12
CPC分类号： C06D5/06
摘要： A composition is provided which has at least one salt of 5-nitraminotetrazole and an at least one oxidizer selected from among inorganic nitrates, inorganic nitrites, metal oxides, metal peroxides, organic peroxides, inorganic perchlorates, inorganic chlorates, metal hydroxides, and mixtures thereof. The compositions are useful in the gas generant field.
摘要翻译：提供一种组合物，其具有5-硝基四氮唑和至少一种选自无机硝酸盐，无机亚硝酸盐，金属氧化物，金属过氧化物，有机过氧化物，无机高氯酸盐，无机氯酸盐，金属氢氧化物及其混合物中的至少一种盐。该组合物可用于气体发生剂领域。

6. 发明授权

US06425966B1 Energetic plasticizer, and explosive and propellant composition containing same 失效
标题翻译：能量增塑剂，含有其的爆炸性和推进剂组合物
公开(公告)号：US06425966B1
公开(公告)日：2002-07-30
申请号：US09661557
申请日：2000-09-14
申请人： Thomas K. Highsmith , Daniel W. Doll , Louis F. Cannizzo
发明人： Thomas K. Highsmith , Daniel W. Doll , Louis F. Cannizzo
IPC分类号： C06B4510
CPC分类号： C06B45/105
摘要： 2,2-dinitro-1,3-propanediol-diformate is a novel low sensitivity, energetic plasticizer that is useful in explosive and propellant compositions. 2,2-dinitro-1,3-propanediol-diformate can be made by reacting 2,2-dinitro-1,3-propane diol with acetic formic anhydride in the presence of pyridine and at least one solvent.
摘要翻译： 2,2-二硝基-1,3-丙二醇二甲酸酯是一种新颖的低灵敏度，高能增塑剂，可用于爆炸和推进剂组合物。 2,2-二硝基-1,3-丙二醇二甲酸酯可以通过使2,2-二硝基-1,3-丙二醇与乙酸甲酸酐在吡啶和至少一种溶剂的存在下反应来制备。

7. 发明授权

US5592812A Metal complexes for use as gas generants 失效
标题翻译：用作气体发生剂的金属络合物
公开(公告)号：US5592812A
公开(公告)日：1997-01-14
申请号：US599634
申请日：1996-02-09
申请人： Jerald C. Hinshaw , Daniel W. Doll , Reed J. Blau , Gary K. Lund
发明人： Jerald C. Hinshaw , Daniel W. Doll , Reed J. Blau , Gary K. Lund
IPC分类号： B60R21/26 , C06B29/00 , C06B31/00 , C06B41/00 , C06B43/00 , C06D5/00 , C06D5/06
CPC分类号： C06B43/00 , C06B29/00 , C06B31/00 , C06B41/00 , C06D5/06
摘要： Gas generating compositions and methods for their use are provided. Metal complexes are used as gas generating compositions. These complexes are comprised of a cationic metal template, sufficient oxidizing anion to balance the charge of the complex, and a neutral ligand containing hydrogen and nitrogen. The complexes are formulated such that when the complex combusts nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite ammine, metal nitrate ammine, and metal perchlorate ammine complexes, as well as hydrazine complexes. Such complexes are adaptable for use in gas generating devices such as automobile air bags.
摘要翻译：提供了气体生成组合物及其使用方法。金属络合物用作气体发生组合物。这些络合物由阳离子金属模板，足够的氧化阴离子组成，以平衡络合物的电荷，以及含有氢和氮的中性配体。络合物配制成使得当复合物燃烧氮气并产生水蒸气时。这种络合物的具体实例包括亚硝酸金属亚胺，金属硝酸铵和金属高氯酸铵氨络合物，以及肼络合物。这种配合物适用于气体发生装置，例如汽车气囊。

8. 发明授权

US09199886B2 Metal complexes for use as gas generants 有权
标题翻译：用作气体发生剂的金属络合物
公开(公告)号：US09199886B2
公开(公告)日：2015-12-01
申请号：US12631030
申请日：2009-12-04
申请人： Jerald C. Hinshaw , Daniel W. Doll , Reed J. Blau , Gary K. Lund
发明人： Jerald C. Hinshaw , Daniel W. Doll , Reed J. Blau , Gary K. Lund
IPC分类号： C06B31/00 , C06B43/00 , C06B29/00 , C06B41/00 , C06D5/06
CPC分类号： C06B43/00 , C06B29/00 , C06B31/00 , C06B41/00 , C06D5/06
摘要： Gas-generating compositions and methods for their use are provided. Metal complexes are used as gas-generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite amine, metal nitrate amine, and metal perchlorate amine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas-generating compositions and to permit efficient combustion of the binder. Such gas-generating compositions are adaptable for use in gas-generating devices, such as automobile air bags.
摘要翻译：提供气体组合物及其使用方法。金属络合物用作气体发生组合物。这些络合物由金属阳离子模板，含有氢和氮的中性配体以及足够的氧化阴离子组成，以平衡络合物的电荷。络合物配制成使得当复合物燃烧时，产生氮气和水蒸气。这种络合物的具体实例包括金属亚硝酸盐胺，金属硝酸盐和金属高氯酸盐络合物，以及肼配合物。粘合剂和辅助氧化剂可以与金属络合物组合以改善气体发生组合物的压碎强度并允许粘合剂的有效燃烧。这种气体发生组合物适用于气体发生装置，例如汽车安全气囊。

9. 发明申请

US20100084060A1 METAL COMPLEXES FOR USE AS GAS GENERANTS 有权
标题翻译：金属复合材料作为天然气生产者使用
公开(公告)号：US20100084060A1
公开(公告)日：2010-04-08
申请号：US12631030
申请日：2009-12-04
申请人： Jerald C. Hinshaw , Daniel W. Doll , Reed J. Blau , Gary K. Lund
发明人： Jerald C. Hinshaw , Daniel W. Doll , Reed J. Blau , Gary K. Lund
IPC分类号： C06B31/02 , C06B31/00
CPC分类号： C06B43/00 , C06B29/00 , C06B31/00 , C06B41/00 , C06D5/06
摘要： Gas-generating compositions and methods for their use are provided. Metal complexes are used as gas-generating compositions. These complexes are comprised of a metal cation template, a neutral ligand containing hydrogen and nitrogen, and sufficient oxidizing anion to balance the charge of the complex. The complexes are formulated such that when the complex combusts, nitrogen gas and water vapor is produced. Specific examples of such complexes include metal nitrite amine, metal nitrate amine, and metal perchlorate amine complexes, as well as hydrazine complexes. A binder and co-oxidizer can be combined with the metal complexes to improve crush strength of the gas-generating compositions and to permit efficient combustion of the binder. Such gas-generating compositions are adaptable for use in gas-generating devices, such as automobile air bags.
摘要翻译：提供气体组合物及其使用方法。金属络合物用作气体发生组合物。这些络合物由金属阳离子模板，含有氢和氮的中性配体以及足够的氧化阴离子组成，以平衡络合物的电荷。络合物配制成使得当复合物燃烧时，产生氮气和水蒸气。这种络合物的具体实例包括金属亚硝酸盐胺，金属硝酸盐和金属高氯酸盐络合物，以及肼配合物。粘合剂和辅助氧化剂可以与金属络合物组合以改善气体发生组合物的压碎强度并允许粘合剂的有效燃烧。这种气体发生组合物适用于气体发生装置，例如汽车安全气囊。

10. 发明授权

US06340175B1 Air bag assemblies with foamed energetic igniters 失效
标题翻译：具有发泡能量点火器的气囊组件
公开(公告)号：US06340175B1
公开(公告)日：2002-01-22
申请号：US09417713
申请日：1999-10-13
申请人： Craig D. Hughes , Daniel W. Doll , Gary K. Lund , Dean M. Lester
发明人： Craig D. Hughes , Daniel W. Doll , Gary K. Lund , Dean M. Lester
IPC分类号： B60R2128
CPC分类号： C06B45/00 , C06C9/00
摘要： An air bag igniter including a foamed material, and an air bag assembly containing the same are disclosed. The foamed material is formed from a composition including, as ingredients, a polyfunctional isocyanate, a polymeric binder having a plurality of hydroxyl groups which are reactive with the polyfunctional isocyanate, a fuel source, an oxidizer, and a foaming agent which may or may not be retained in the foamed material.
摘要翻译：公开了一种包括发泡材料的气囊点火器和包含其的气囊组件。泡沫材料由组合物形成，所述组合物包含作为成分的多官能异氰酸酯，具有多个与多官能异氰酸酯反应的羟基的聚合物粘合剂，燃料源，氧化剂和发泡剂，其可以或不可以保留在泡沫材料中。

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