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1. 发明授权

US06208553B1 High density non-volatile memory device incorporating thiol-derivatized porphyrins 有权
标题翻译：含有硫醇衍生的卟啉的高密度非挥发性记忆装置
公开(公告)号：US06208553B1
公开(公告)日：2001-03-27
申请号：US09346221
申请日：1999-07-01
申请人： Daniel Tomasz Gryko , Peter Christian Clausen , Kristian M. Roth , David F. Bocian , Werner G. Kuhr , Jonathan S. Lindsey
发明人： Daniel Tomasz Gryko , Peter Christian Clausen , Kristian M. Roth , David F. Bocian , Werner G. Kuhr , Jonathan S. Lindsey
IPC分类号： G11C1100
CPC分类号： G11C11/5664 , B82Y10/00 , C07D487/22 , C07D519/00 , C07F17/02 , G11B9/14 , G11B9/149 , G11C13/0014 , G11C13/0016 , G11C13/025 , G11C2213/77 , H01L27/285 , H01L51/0077 , H01L51/0078 , H01L51/0084 , H01L51/0595
摘要： This invention provides novel high density memory devices that are electrically addressable permitting effective reading and writing, that provide a high memory density (e.g., 1015 bits/cm3), that provide a high degree of fault tolerance, and that are amenable to efficient chemical synthesis and chip fabrication. The devices are intrinsically latchable, defect tolerant, and support destructive or non-destructive read cycles. In a preferred embodiment, the device comprises a fixed electrode electrically coupled to a storage medium comprising one or more thiol-derivatized porphyrins. The storage medium has a multiplicity of different and distinguishable oxidation states and data is stored in said oxidation states by the addition or withdrawal of one or more electrons from the storage medium via the electrically coupled electrode(s).
摘要翻译：本发明提供了新颖的高密度存储器件，其可电寻址以允许有效读取和写入，其提供高存储密度（例如，1015比特/ cm 3），其提供高度的容错性，并且适于有效的化学合成和芯片制造。器件本质上可锁定，缺陷容忍，并支持破坏性或非破坏性的读取周期。在优选的实施方案中，该装置包括电耦合到包含一种或多种硫醇衍生的卟啉的存储介质的固定电极。存储介质具有多种不同且可区分的氧化态，并且通过经由电耦合的电极从存储介质中添加或取出一个或多个电子，将数据存储在所述氧化态中。

2. 发明授权

US08568686B2 Synthesis of thin films and materials utilizing a gaseous catalyst 有权
标题翻译：使用气态催化剂合成薄膜和材料
公开(公告)号：US08568686B2
公开(公告)日：2013-10-29
申请号：US11737087
申请日：2007-04-18
申请人： Daniel E. Morse , Birgit Schwenzer , John R. Gomm , Kristian M. Roth , Brandon Heiken , Richard Brutchey
发明人： Daniel E. Morse , Birgit Schwenzer , John R. Gomm , Kristian M. Roth , Brandon Heiken , Richard Brutchey
IPC分类号： C01G51/00 , B32B18/00
CPC分类号： C01G1/02 , B82Y30/00 , C01G9/02 , C01G19/00 , C01G19/02 , C01G23/003 , C01G23/04 , C01G23/047 , C01G51/00 , C01G51/04 , C01P2002/34 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2002/84 , C01P2002/85 , C01P2004/03 , C01P2004/04 , C01P2004/41 , C01P2004/64 , H01M4/52 , H01M10/24 , Y02E60/124
摘要： A method for the fabrication of nanostructured semiconducting, photoconductive, photovoltaic, optoelectronic and electrical battery thin films and materials at low temperature, with no molecular template and no organic contaminants. High-quality metal oxide semiconductor, photovoltaic and optoelectronic materials can be fabricated with nanometer-scale dimensions and high dopant densities through the use of low-temperature biologically inspired synthesis routes, without the use of any biological or biochemical templates.
摘要翻译：一种在低温下制造纳米结构半导体，光电导，光伏，光电和电池薄膜和材料的方法，没有分子模板，没有有机污染物。高品质的金属氧化物半导体，光电和光电子材料可以通过使用低温生物启发的合成路线，以纳米级尺寸和高掺杂剂密度制造，而不使用任何生物或生物化学模板。

3. 发明授权

US07335717B2 Methods, compositions, and biomimetic catalysts for the synthesis of silica, polysilsequioxanes, polysiloxanes, non-silicon metalloid-oxygen networks, polymetallo-oxanes, and their organic or hydrido conjugates and derivatives 失效
标题翻译：用于合成二氧化硅，聚硅氧烷，聚硅氧烷，非硅准金属氧网络，聚金属氧化物及其有机或氢合偶联物和衍生物的方法，组合物和仿生催化剂
公开(公告)号：US07335717B2
公开(公告)日：2008-02-26
申请号：US10807004
申请日：2004-03-22
申请人： Daniel E. Morse , David Kisailus , Kristian M. Roth
发明人： Daniel E. Morse , David Kisailus , Kristian M. Roth
IPC分类号： C08G77/08
CPC分类号： C08G77/08 , B01J21/08 , B01J31/003 , B01J31/0235 , B01J31/0272 , B01J37/36 , C01B33/12 , C01B33/126 , C08G77/02 , C08G77/06
摘要： The in vitro polymerization of silica, silicone, non-silicon metalloid-oxane and metallo-oxane polymer networks, by combining a catalyst and a substrate to polymerize the substrate to form silica, polysiloxanes, polymetalloid-oxanes polymetallo-oxanes (metal oxides), polyorganometalloid oxanes, polyorganometallo oxanes, and the polyhydrido derivatives thereof, at about neutral pH. The nanostructure-directing catalysts have a nucleophilic functionality and a hydrogen-bonding acceptor group, and include: silicateins, enzymes that work by a mechanism functionally related to that of the silicateins; self-assembling peptides related to those synthesized and demonstrated capable of acting as biomimetic substitutes for the silicateins; non-peptide-based synthetic polymers containing a nucleophilic group and a hydrogen bonding amine such that the polymer functions by a mechanism of action related to that of the silicateins; materials having such chemical functionality as a nucleophilic group and or a hydrogen bonding amine which, acting in concert with nanoconfinement and or chemical functionality of the surface or matrix to which the functionality is attached, acts catalytically by a mechanism related to that of the silicateins; and small-molecule non-polymeric biomimetic catalysts that operate by the same mechanism as silicateins.
摘要翻译：二氧化硅，硅氧烷，非硅金属 - 氧杂环丁烷和金属氧杂聚合物网络的体外聚合，通过组合催化剂和底物以聚合基材以形成二氧化硅，聚硅氧烷，聚金属氧化物多金属氧杂环丁烷（金属氧化物）多元有机金属氧杂环己烷，聚有机金属氧化物及其多氢化合物衍生物。纳米结构导向催化剂具有亲核官能团和氢键受体基团，并且包括：硅酸盐，通过与硅酸盐的功能相关的机理起作用的酶; 自组装肽与合成和证明能够作为硅酸盐的仿生替代物的那些相关; 含有亲核基团和氢键胺的非肽基合成聚合物使得聚合物通过与硅酸盐相关的作用机理起作用; 与功能性所附着的表面或基质的纳米结构和/或化学功能一致起作用的具有如亲核基团和氢键胺的化学官能团的材料通过与硅酸盐相关的机理催化作用; 以及通过与硅酸盐相同的机制操作的小分子非聚合仿生催化剂。

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