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    • 2. 发明授权
    • Methods, compositions, and biomimetic catalysts for the synthesis of silica, polysilsequioxanes, polysiloxanes, non-silicon metalloid-oxygen networks, polymetallo-oxanes, and their organic or hydrido conjugates and derivatives
    • 用于合成二氧化硅,聚硅氧烷,聚硅氧烷,非硅准金属氧网络,聚金属氧化物及其有机或氢合偶联物和衍生物的方法,组合物和仿生催化剂
    • US07335717B2
    • 2008-02-26
    • US10807004
    • 2004-03-22
    • Daniel E. MorseDavid KisailusKristian M. Roth
    • Daniel E. MorseDavid KisailusKristian M. Roth
    • C08G77/08
    • C08G77/08B01J21/08B01J31/003B01J31/0235B01J31/0272B01J37/36C01B33/12C01B33/126C08G77/02C08G77/06
    • The in vitro polymerization of silica, silicone, non-silicon metalloid-oxane and metallo-oxane polymer networks, by combining a catalyst and a substrate to polymerize the substrate to form silica, polysiloxanes, polymetalloid-oxanes polymetallo-oxanes (metal oxides), polyorganometalloid oxanes, polyorganometallo oxanes, and the polyhydrido derivatives thereof, at about neutral pH. The nanostructure-directing catalysts have a nucleophilic functionality and a hydrogen-bonding acceptor group, and include: silicateins, enzymes that work by a mechanism functionally related to that of the silicateins; self-assembling peptides related to those synthesized and demonstrated capable of acting as biomimetic substitutes for the silicateins; non-peptide-based synthetic polymers containing a nucleophilic group and a hydrogen bonding amine such that the polymer functions by a mechanism of action related to that of the silicateins; materials having such chemical functionality as a nucleophilic group and or a hydrogen bonding amine which, acting in concert with nanoconfinement and or chemical functionality of the surface or matrix to which the functionality is attached, acts catalytically by a mechanism related to that of the silicateins; and small-molecule non-polymeric biomimetic catalysts that operate by the same mechanism as silicateins.
    • 二氧化硅,硅氧烷,非硅金属 - 氧杂环丁烷和金属氧杂聚合物网络的体外聚合,通过组合催化剂和底物以聚合基材以形成二氧化硅,聚硅氧烷,聚金属氧化物多金属氧杂环丁烷(金属氧化物) 多元有机金属氧杂环己烷,聚有机金属氧化物及其多氢化合物衍生物。 纳米结构导向催化剂具有亲核官能团和氢键受体基团,并且包括:硅酸盐,通过与硅酸盐的功能相关的机理起作用的酶; 自组装肽与合成和证明能够作为硅酸盐的仿生替代物的那些相关; 含有亲核基团和氢键胺的非肽基合成聚合物使得聚合物通过与硅酸盐相关的作用机理起作用; 与功能性所附着的表面或基质的纳米结构和/或化学功能一致起作用的具有如亲核基团和氢键胺的化学官能团的材料通过与硅酸盐相关的机理催化作用; 以及通过与硅酸盐相同的机制操作的小分子非聚合仿生催化剂。
    • 3. 发明授权
    • Polymer shutter compositions and devices for infrared systems
    • 聚合物快门组合物和用于红外系统的装置
    • US08094361B2
    • 2012-01-10
    • US12652584
    • 2010-01-05
    • Andreas HamppAmanda L. HoltJustin Gordon Adams WehnerDaniel E. Morse
    • Andreas HamppAmanda L. HoltJustin Gordon Adams WehnerDaniel E. Morse
    • G02F1/153G02F1/03G02F1/15G09G3/38
    • G02F1/15G02F1/153G02F2001/1515G02F2001/1519G02F2203/11
    • The present disclosure relates, according to some embodiments, to compositions and devices operable for infra-red transmission and blocking comprising a layered structure having a first electrically conducting layer, a conjugated electrochromic polymer layer, an electrolyte layer and a second electrically conducting layer, wherein the first and second electrically conducting layers have an infrared transparency and the conjugated electrochromic polymers may be operable to be electrically switched between a transparent state that transmits infrared light to an opaque state that does not transmit infrared light. In some embodiments, a device of the disclosure may also have one or more outer substrates sandwiching the other layers. Some embodiments relate to single-layered devices. Some embodiments relate to combined layers. Compositions and devices of the disclosure may be integrated into a wide variety of infrared systems for transmission, shuttering and calibration applications.
    • 根据一些实施方案,本公开涉及可操作用于红外透射和阻挡的组合物和装置,其包括具有第一导电层,共轭电致变色聚合物层,电解质层和第二导电层的分层结构,其中 第一导电层和第二导电层具有红外透明度,并且共轭电致变色聚合物可以可操作地在将红外光透射到不透射红外光的不透明状态的透明状态之间电转换。 在一些实施例中,本公开的装置还可以具有夹着其它层的一个或多个外部基底。 一些实施例涉及单层设备。 一些实施例涉及组合层。 本公开的组合物和装置可以集成到用于传输,快门和校准应用的各种红外系统中。
    • 9. 发明申请
    • Polymer Shutter Compositions and Devices for Infrared Systems
    • 用于红外系统的聚合物快门组合物和装置
    • US20110164303A1
    • 2011-07-07
    • US12652584
    • 2010-01-05
    • Andreas HamppAmanda L. HoltJustin Gordon Adams WehnerDaniel E. Morse
    • Andreas HamppAmanda L. HoltJustin Gordon Adams WehnerDaniel E. Morse
    • G02F1/153
    • G02F1/15G02F1/153G02F2001/1515G02F2001/1519G02F2203/11
    • The present disclosure relates, according to some embodiments, to compositions and devices operable for infra-red transmission and blocking comprising a layered structure having a first electrically conducting layer, a conjugated electrochromic polymer layer, an electrolyte layer and a second electrically conducting layer, wherein the first and second electrically conducting layers have an infrared transparency and the conjugated electrochromic polymers may be operable to be electrically switched between a transparent state that transmits infrared light to an opaque state that does not transmit infrared light. In some embodiments, a device of the disclosure may also have one or more outer substrates sandwiching the other layers. Some embodiments relate to single-layered devices. Some embodiments relate to combined layers. Compositions and devices of the disclosure may be integrated into a wide variety of infrared systems for transmission, shuttering and calibration applications.
    • 根据一些实施方案,本公开涉及可操作用于红外透射和阻挡的组合物和装置,其包括具有第一导电层,共轭电致变色聚合物层,电解质层和第二导电层的分层结构,其中 第一导电层和第二导电层具有红外透明度,并且共轭电致变色聚合物可以可操作地在将红外光透射到不透射红外光的不透明状态的透明状态之间电转换。 在一些实施例中,本公开的装置还可以具有夹住其它层的一个或多个外部基板。 一些实施例涉及单层设备。 一些实施例涉及组合层。 本公开的组合物和装置可以集成到用于传输,快门和校准应用的各种红外系统中。