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1. 发明授权

US06743369B2 Method for manufacturing electrode for secondary battery 失效
标题翻译：二次电池用电极的制造方法
公开(公告)号：US06743369B2
公开(公告)日：2004-06-01
申请号：US10015774
申请日：2001-12-17
申请人： Daizo Jito , Hisaki Tarui
发明人： Daizo Jito , Hisaki Tarui
IPC分类号： H01M404
CPC分类号： H01M4/623 , H01M4/04 , H01M4/0404 , H01M4/0492 , H01M4/1391 , H01M4/625 , H01M4/661 , H01M4/667 , H01M10/052 , H01M2300/0025 , H01M2300/0037
摘要： A method of manufacturing an electrode for a secondary battery by depositing a thin film composed of active material on a current collector in which a surface-treated layer such as an antirust-treated layer is formed, including the steps of: removing at least part of the surface-treated layer by etching the surface of the current collector with an ion beam or plasma in order to improve the diffusion of the current collector material into the active material thin film; and depositing the thin film on the surface of the current collector subjected to the etching step.
摘要翻译：一种制造二次电池用电极的方法，其特征在于，在形成有防锈处理层的表面处理层的集电体上沉积由活性物质构成的薄膜，包括以下步骤：除去至少一部分通过用离子束或等离子体蚀刻集电体的表面以改善集电体材料扩散到活性材料薄膜中的表面处理层; 以及在经过蚀刻步骤的集电体的表面上沉积薄膜。

2. 发明授权

US07294359B2 Method of manufacturing electrode for secondary cell 失效
标题翻译：二次电池用电极的制造方法
公开(公告)号：US07294359B2
公开(公告)日：2007-11-13
申请号：US10122367
申请日：2002-04-16
申请人： Daizo Jito , Hisaki Tarui
发明人： Daizo Jito , Hisaki Tarui
IPC分类号： B05D5/12
CPC分类号： H01M4/0421 , H01M2/26 , H01M4/04 , H01M4/0402 , H01M4/0404 , H01M6/10 , H01M10/05
摘要： A method of manufacturing an electrode for a secondary cell capable of readily forming an active material layer only on a necessary portion of a collector by a method supplying raw material from a gas phase is obtained. This method of manufacturing an electrode for a secondary cell comprises steps of forming a mask layer containing a material reduced in adhesion to a collector due to a high temperature for forming an active material layer on a prescribed region of the collector, forming the active material layer on the collector and on the mask layer by a method supplying raw material from a gas phase and removing the mask layer and part of the active material layer formed on the mask layer. Thus, the mask layer is readily separated from the collector after the active material layer is formed by the method supplying raw material from a gas phase. Consequently, the mask layer and part of the active material layer formed on the mask layer are so readily removed that the active material layer is readily located only on a necessary portion of the collector.
摘要翻译：获得了通过从气相提供原料的方法仅在集电体的必要部分上容易地形成活性物质层的二次电池用电极的制造方法。这种制造二次电池用电极的方法包括以下步骤：由于在集电体的规定区域上形成活性物质层的高温而形成含有与集电体粘合性降低的材料的掩模层，形成活性物质层在集电体和掩模层上通过从气相提供原料的方法，并且去除掩模层和形成在掩模层上的部分活性材料层。因此，在通过从气相供给原料的方法形成活性物质层之后，掩模层容易与集电体分离。因此，形成在掩模层上的掩模层和活性物质层的一部分被容易地去除，使得活性物质层容易地位于集电体的必要部分上。

3. 发明授权

US07105253B2 Method of and apparatus for manufacturing lithium secondary cell 失效
公开(公告)号：US07105253B2
公开(公告)日：2006-09-12
申请号：US10177215
申请日：2002-06-24
申请人： Daizo Jito , Hisaki Tarui
发明人： Daizo Jito , Hisaki Tarui
IPC分类号： H01M6/00 , H01M10/14 , H01M4/58 , H01M2/16
CPC分类号： H01M4/0421 , C23C14/564 , H01M4/04 , H01M4/0404 , H01M4/0426 , H01M4/139 , H01M10/0436 , H01M10/052 , H01M10/058 , H01M2006/106 , H01M2010/0495 , Y10T29/49108 , Y10T29/4911 , Y10T29/49112 , Y10T29/49114 , Y10T29/49115 , Y10T29/53135
摘要： A method of manufacturing a lithium secondary cell capable of preventing an active material layer from oxidation and moisture absorption is obtained. This method of manufacturing a lithium secondary cell comprises steps of forming an active material layer on a collector by a method supplying raw material through discharge into a vapor phase and holding the collector formed with the active material layer at least under an inert atmosphere or under a vacuum atmosphere up to preparation of the cell. Thus, the collector formed with the active material layer is prevented from exposure to the atmosphere, whereby the active material layer is prevented from oxidation and moisture absorption. Consequently, a lithium secondary cell having excellent characteristics can be prepared.

4. 发明授权

US06979516B2 Lithium secondary battery and positive electrode for lithium secondary battery 失效
标题翻译：锂二次电池和锂二次电池正极
公开(公告)号：US06979516B2
公开(公告)日：2005-12-27
申请号：US10056209
申请日：2002-01-28
申请人： Yasuyuki Kusumoto , Masahisa Fujimoto , Shin Fujitani , Yoichi Domoto , Daizo Jito , Hisaki Tarui
发明人： Yasuyuki Kusumoto , Masahisa Fujimoto , Shin Fujitani , Yoichi Domoto , Daizo Jito , Hisaki Tarui
IPC分类号： H01M4/66 , H01M4/13 , H01M4/131 , H01M4/139 , H01M4/1391 , H01M4/52 , H01M10/05 , H01M10/052 , H01M10/0566 , H01M4/36 , H01M4/58 , C23C14/00 , C23C14/32
CPC分类号： H01M4/525 , H01M4/04 , H01M4/485 , H01M4/661 , H01M10/052 , H01M10/0525 , H01M2004/028
摘要： A lithium secondary battery comprises a negative electrode containing lithium metal or a material previously storing lithium as an active material, a positive electrode containing a positive active material, and an electrolyte containing a non-aqueous electrolyte solution. The positive active material is a thin film formed by depositing on a substrate from vapor phase or liquid phase and including an oxide containing at least iron as a main constituent by a sputtering method, a reactive deposition method, a vacuum deposition method, a chemical vapor deposition method, a spraying method, a plating method, or a method in combination of these methods.
摘要翻译：锂二次电池包括含有锂金属的负极或预先存储锂作为活性材料的材料，含有正极活性物质的正极和含有非水电解质溶液的电解质。正极活性物质是通过溅射法，反应性沉积法，真空沉积法，化学蒸气法，从气相或液相沉积在基底上而形成的薄膜，包括至少含有铁作为主要成分的氧化物沉积法，喷涂法，电镀法或这些方法的组合方法。

5. 发明申请

US20130330628A1 POSITIVE ELECTRODE ACTIVE MATERIAL FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY, POSITIVE ELECTRODE FOR NONAQUEOUS ELECTROLYTE SECONDARY BATTERY USING THE POSITIVE ELECTRODE ACTIVE MATERIAL, AND NONAQUEOUS ELECTROLYTE SECONDARY BATTERY USING THE POSITIVE ELECTRODE 审中-公开
标题翻译：用于非电解电解质二次电池的正极电极活性材料，使用正极电极活性材料的非水电解质二次电池的正极和使用正极的非电解电解质二次电池
公开(公告)号：US20130330628A1
公开(公告)日：2013-12-12
申请号：US13981053
申请日：2012-01-23
申请人： Kazuhiro Hasegawa , Takeshi Ogasawara , Daizo Jito , Shun Nomura , Hiroyuki Fujimoto
发明人： Kazuhiro Hasegawa , Takeshi Ogasawara , Daizo Jito , Shun Nomura , Hiroyuki Fujimoto
IPC分类号： H01M4/525
CPC分类号： H01M4/525 , C01G53/44 , C01P2004/80 , C01P2004/84 , C01P2006/40 , H01M4/362 , H01M4/38 , H01M4/386 , H01M4/505 , H01M10/052
摘要： The present invention provides a positive electrode active material for a nonaqueous electrolyte secondary battery which is capable of improving an initial discharge capacity and suppressing a decrease in discharge voltage and a decrease in battery capacity even in repeated charge-discharge cycles, a positive electrode using the active material, and a nonaqueous electrolyte secondary battery using the positive electrode. The positive electrode active material includes a particle 21 of a lithium transition metal composite oxide containing lithium, nickel, and manganese and having a layered structure; and a particle 22 of a compound of at least one element adhered to a portion of the surface of the particle 21 and selected from the rare earth elements with atomic numbers 59 to 71.
摘要翻译：本发明提供一种非水电解质二次电池用正极活性物质，即使在重复的充放电循环中也能够提高初期放电容量，抑制放电电压的降低和电池容量的降低，使用活性物质和使用该正极的非水电解质二次电池。正极活性物质包含含有锂，镍和锰的锂过渡金属复合氧化物的粒子21，具有层状结构; 以及至少一种元素的化合物的颗粒22，其粘附到颗粒21的表面的一部分并且选自原子序数59至71的稀土元素。

6. 发明申请

US20110206981A1 LITHIUM SECONDARY BATTERY 审中-公开
标题翻译：锂二次电池
公开(公告)号：US20110206981A1
公开(公告)日：2011-08-25
申请号：US13006931
申请日：2011-01-14
申请人： Daizo Jito , Maruo Kamino
发明人： Daizo Jito , Maruo Kamino
IPC分类号： H01M4/525 , H01M4/58
CPC分类号： H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/366 , H01M4/386 , H01M4/525 , H01M10/052 , H01M10/056 , H01M10/0564 , H01M10/4235 , Y02T10/7011
摘要： A lithium secondary battery includes a positive electrode in which a positive electrode mixture layer including a positive electrode binder and a positive electrode active material containing particles of a lithium transition metal composite oxide represented by a chemical formula LiaNi1-b-cCobAlcO2 (wherein 0
摘要翻译：锂二次电池包括正电极，其中包括正电极粘合剂的正电极混合物层和含有由化学式LiaNi1-b-cCobAlcO2表示的锂过渡金属复合氧化物的颗粒的正电极活性材料（其中0

7. 发明授权

US07258950B2 Electrode for rechargeable lithium battery and rechargeable lithium battery 失效
标题翻译：可充电锂电池和可充电锂电池电极
公开(公告)号：US07258950B2
公开(公告)日：2007-08-21
申请号：US10380801
申请日：2001-09-19
申请人： Noriyuki Tamura , Shiori Nakamizo , Daizo Jito , Ryuji Ohshita , Masahisa Fujimoto , Shin Fujitani , Maruo Kamino
发明人： Noriyuki Tamura , Shiori Nakamizo , Daizo Jito , Ryuji Ohshita , Masahisa Fujimoto , Shin Fujitani , Maruo Kamino
IPC分类号： H01M4/72 , H01M4/58
CPC分类号： H01M4/134 , H01M4/661 , H01M4/667 , H01M10/052
摘要： An electrode having a current collector and, formed thereon, a thin film comprising an active material, characterized in that a thin alloy film (such as Sn—Co) comprising a metal which can form an alloy with lithium (such as Sn) and a metal which can not form an alloy with lithium (such as Co) is formed on a current collector such as a copper foil. It is preferred that the above metal which can form an alloy with lithium and the above metal which can not form an alloy with lithium can not form an intermetallic compound with each other.
摘要翻译：一种具有集电体并且在其上形成包含活性材料的薄膜的电极，其特征在于，包含可以与锂（例如Sn）形成合金的金属的薄合金膜（例如Sn-Co）和在诸如铜箔的集电体上形成不能与锂（例如Co）形成合金的金属。优选与锂形成合金的上述金属和不能与锂形成合金的上述金属彼此不能形成金属间化合物。

8. 发明申请

US20070077494A1 Lithium secondary battery 失效
标题翻译：锂二次电池
公开(公告)号：US20070077494A1
公开(公告)日：2007-04-05
申请号：US11527716
申请日：2006-09-27
申请人： Kei Kobayashi , Hiromasa Yagi , Masaki Hirase , Daizo Jito , Katsunobu Sayama
发明人： Kei Kobayashi , Hiromasa Yagi , Masaki Hirase , Daizo Jito , Katsunobu Sayama
IPC分类号： H01M4/40 , H01M4/58 , H01M4/66
CPC分类号： H01M10/0587 , H01M4/134 , H01M4/366 , H01M4/62 , H01M4/661 , H01M4/70 , H01M2004/021 , H01M2004/027
摘要： A lithium secondary battery is provided with a positive electrode, a negative electrode (1), a separator interposed between the positive and negative electrodes, and an electrode assembly having the negative electrode (1), the positive electrode, and the separator. The negative electrode (1) has a negative electrode current collector (11) and negative electrode active material layers (12), (13) formed on respective surfaces of the negative electrode current collector (11). The negative electrode active material layers are composed of an alloy containing silicon, which intercalates and deintercalates lithium, and iron, which does not intercalate or deintercalate lithium. At least a portion of the electrode assembly has a curved portion in which the negative electrode active material layer (13) disposed inward relative to the negative electrode current collector contains a higher concentration of the iron than the negative electrode active material layer (12) disposed outward relative to the negative electrode current collector.
摘要翻译：锂二次电池设置有正极，负极（1），介于正极和负极之间的隔板以及具有负极（1），正极和隔板的电极组件。负极（1）具有形成在负极集电体（11）的各表面上的负极集电体（11）和负极活性物质层（12），（13）。负极活性物质层由含有硅的合金，其插入和脱嵌锂，以及不插入或脱嵌锂的铁。电极组件的至少一部分具有弯曲部分，其中相对于负极集电体向内设置的负极活性材料层（13）含有比设置的负极活性材料层（12）更高的铁浓度向外相对于负极集电体。

9. 发明申请

US20060024588A1 Lithium secondary battery and method for producing same 失效
公开(公告)号：US20060024588A1
公开(公告)日：2006-02-02
申请号：US10531045
申请日：2004-06-03
申请人： Daizo Jito , Noriyuki Tamura , Nobuhiro Sakitani , Hiroshi Minami , Hiromasa Yagi , Maruo Kamino , Katsunobu Sayama , Yoshio Kato , Shigeki Matsuta
发明人： Daizo Jito , Noriyuki Tamura , Nobuhiro Sakitani , Hiroshi Minami , Hiromasa Yagi , Maruo Kamino , Katsunobu Sayama , Yoshio Kato , Shigeki Matsuta
IPC分类号： H01M4/58 , H01M4/66 , H01M10/40
CPC分类号： H01M10/052 , H01M4/134 , H01M4/386 , H01M4/405 , H01M10/0565 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0585 , H01M10/4235 , H01M2300/0017 , Y10T29/49115
摘要： A rechargeable lithium battery including a negative electrode made by depositing a noncrystalline thin film composed entirely or mainly of silicon on a current collector, a positive electrode and a nonaqueous electrolyte, characterized in that said nonaqueous electrolyte contains carbon dioxide dissolved therein.

10. 发明授权

US09437869B2 Positive electrode for nonaqueous electrolyte secondary battery and nonaqueous electrolyte secondary battery using the positive electrode 有权
标题翻译：非水电解质二次电池用正极和使用该正极的非水电解质二次电池
公开(公告)号：US09437869B2
公开(公告)日：2016-09-06
申请号：US13992944
申请日：2011-09-21
申请人： Daizo Jito , Takeshi Ogasawara
发明人： Daizo Jito , Takeshi Ogasawara
IPC分类号： H01M4/36 , H01M4/131 , H01M4/505 , H01M4/525 , H01M2/16 , H01M4/62 , H01M10/052
CPC分类号： H01M4/366 , H01M2/1673 , H01M4/131 , H01M4/364 , H01M4/505 , H01M4/525 , H01M4/62 , H01M10/052 , Y02E60/122 , Y02T10/7011
摘要： It is an object of the present invention to provide a positive electrode for nonaqueous electrolyte secondary batteries that can suppress decreases in the discharge capacity and discharge voltage even when continuous charging is performed at high temperature and that can also suppress decreases in the discharge voltage and energy density even in the charge and discharge after the continuous charging, and to provide a nonaqueous electrolyte secondary battery that uses the positive electrode. The positive electrode includes a positive electrode active material composed of a mixture containing lithium cobalt oxide 21 having a surface to which an erbium compound 22 is partly adhered and lithium nickel cobalt manganese oxide and a binder. The content of the lithium nickel cobalt manganese oxide is 1% by mass or more and 50% by mass or less relative to the total amount of the positive electrode active material.
摘要翻译：本发明的目的是提供一种非水电解质二次电池用正极，其即使在高温下进行连续充电也能够抑制放电容量和放电电压的降低，并且还可以抑制放电电压和能量的降低即使在连续充电之后的充放电中，也提供使用正极的非水电解质二次电池。正极包括由含有铒化合物22部分地附着的表面的锂钴氧化物21和锂镍钴锰氧化物和粘合剂的混合物构成的正极活性物质。锂镍钴锰氧化物的含量相对于正极活性物质的总量为1质量％以上且50质量％以下。

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