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1. 发明申请

US20070021313A1 Water-soluble amphoteric copolymer, production method thereof, and application thereof 有权
标题翻译：水溶性两性共聚物及其制备方法及其应用
公开(公告)号：US20070021313A1
公开(公告)日：2007-01-25
申请号：US11481965
申请日：2006-07-07
申请人： Daisuke Hattori , Takahiro Tsumori , Yoshikazu Fujii
发明人： Daisuke Hattori , Takahiro Tsumori , Yoshikazu Fujii
IPC分类号： C11D3/02
CPC分类号： C08L33/14 , C08L33/24 , C11D3/3723 , C08L2666/04
摘要： To provide: a water-soluble amphoteric copolymer having excellent hydrophilicity and high adsorption capability, and capable of exhibiting dramatically excellent dispersibility even under high hardness conditions and being preferably used in a detergent composition application, for example; an application thereof; and a production method of such a water-soluble amphoteric copolymer. A water-soluble amphoteric copolymer produced by a copolymerization of a monomer component comprising a cationic monomer (a), an anionic monomer (b), and an unsaturated polyalkylene glycol monomer (c), wherein the monomer (b) is a carboxyl group-containing monomer and/or a sulfonic acid group-containing monomer (d), and the monomer (b) is more than 50% by mole relative to 100% by mole of a total amount of the monomers (a), (b), and (c) if the monomer (b) consists of the carboxyl-group containing monomer, and at least one species of monomer among the monomers (a), (d), and (c) is 30% by mole or less relative to 100% by mole of a total amount of the monomers (a), (d), and (c) if the monomer (b) comprises the sulfonic acid group-containing monomer (d).
摘要翻译：提供：具有优异的亲水性和高吸附能力的水溶性两性共聚物，即使在高硬度条件下也能显示出显着优异的分散性，并且优选用于洗涤剂组合物应用中; 其应用; 以及这种水溶性两性共聚物的制造方法。通过使包含阳离子单体（a），阴离子单体（b）和不饱和聚亚烷基二醇单体（c）的单体组分共聚制备的水溶性两性共聚物，其中单体（b）是羧基 - 含有单体和/或含磺酸基的单体（d），单体（b）相对于单体（a），（b），（b）的总量相对于100摩尔％大于50摩尔％（c）如果单体（b）由含羧基的单体组成，并且单体（a），（d）和（c）中的至少一种单体相对于如果单体（b）包含含磺酸基的单体（d），则单体（a），（d）和（c）的总量为100摩尔％。

2. 发明授权

US07723283B2 Water-soluble amphoteric copolymer, production method thereof, and application thereof 有权
标题翻译：水溶性两性共聚物及其制备方法及其应用
公开(公告)号：US07723283B2
公开(公告)日：2010-05-25
申请号：US11481965
申请日：2006-07-07
申请人： Takahiro Tsumori , Yoshikazu Fujii , Daisuke Hattori
发明人： Takahiro Tsumori , Yoshikazu Fujii , Daisuke Hattori
IPC分类号： C11D3/37 , C11D1/88 , C08G75/24 , C08G73/02
CPC分类号： C08L33/14 , C08L33/24 , C11D3/3723 , C08L2666/04
摘要： To provide: a water-soluble amphoteric copolymer having excellent hydrophilicity and high adsorption capability, and capable of exhibiting dramatically excellent dispersibility even under high hardness conditions and being preferably used in a detergent composition application, for example; an application thereof; and a production method of such a water-soluble amphoteric copolymer. A water-soluble amphoteric copolymer produced by a copolymerization of a monomer component comprising a cationic monomer (a), an anionic monomer (b), and an unsaturated polyalkylene glycol monomer (c), wherein the monomer (b) is a carboxyl group-containing monomer and/or a sulfonic acid group-containing monomer (d), and the monomer (b) is more than 50% by mole relative to 100% by mole of a total amount of the monomers (a), (b), and (c) if the monomer (b) consists of the carboxyl-group containing monomer, and at least one species of monomer among the monomers (a), (d), and (c) is 30% by mole or less relative to 100% by mole of a total amount of the monomers (a), (d), and (c) if the monomer (b) comprises the sulfonic acid group-containing monomer (d).
摘要翻译：提供：具有优异的亲水性和高吸附能力的水溶性两性共聚物，即使在高硬度条件下也能显示出显着优异的分散性，并且优选用于洗涤剂组合物应用中; 其应用; 以及这种水溶性两性共聚物的制造方法。通过使包含阳离子单体（a），阴离子单体（b）和不饱和聚亚烷基二醇单体（c）的单体组分共聚制备的水溶性两性共聚物，其中单体（b）是羧基 - 含有单体和/或含磺酸基的单体（d），单体（b）相对于单体（a），（b），（b）的总量相对于100摩尔％大于50摩尔％（c）如果单体（b）由含羧基的单体组成，并且单体（a），（d）和（c）中的至少一种单体相对于如果单体（b）包含含磺酸基的单体（d），则单体（a），（d）和（c）的总量为100摩尔％。

3. 发明申请

US20050113541A1 Polymer, process for preparing the same, and use of the same 审中-公开
标题翻译：聚合物，其制备方法及其用途
公开(公告)号：US20050113541A1
公开(公告)日：2005-05-26
申请号：US10970005
申请日：2004-10-22
申请人： Takahiro Tsumori , Daisuke Hattori , Akihiko Kanzaki , Yoshikazu Fujii , Shigeru Yamaguchi , Hiroshi Yamazaki , Tsuyoshi Hirata
发明人： Takahiro Tsumori , Daisuke Hattori , Akihiko Kanzaki , Yoshikazu Fujii , Shigeru Yamaguchi , Hiroshi Yamazaki , Tsuyoshi Hirata
IPC分类号： C04B24/00 , C04B24/12 , C04B24/26 , C08F283/06 , C08F290/06 , C08G65/00 , C11D3/37 , C08L51/00
CPC分类号： C11D3/3788 , C04B24/2647 , C04B24/2658 , C04B2103/408 , C08F283/06 , C08F290/062
摘要： An object of the present invention is to provide a polymer which is suitable as a detergent builder in that it exerts an excellent detergency and it has no adverse effect on the environment, and is suitable as a cement admixture in that it is excellent in cement dispersibility, and workability is better. As a means of achieving this object, a polymer of the present invention is: a polymer obtained by a polymerization reaction using a polyaminepolyether compound, an unsaturated carboxylic monomer and polyalkylene glycols as a raw material, characterized in that an amount of a polyaminepolyether compound is 50% by weight or larger relative to a total amount of a polyaminepolyether compound and polyalkylene glycols; or a polymer obtained by a polymerization reaction using a polyaminepolyether compound and an unsaturated carboxylic monomer as a raw material, characterized in that an amount of an unsaturated carboxylic monomer is less than 15% by weight relative to a total amount of a polyaminepolyether compound and an unsaturated carboxylic monomer, or an unsaturated carboxylic monomer contains acrylic acid as an essential component, and an amount of remaining acrylic acid after the reaction is less than 3% by weight.
摘要翻译：本发明的目的是提供一种适合作为洗涤剂助洗剂的聚合物，因为其具有优异的去污力，并且对环境没有不利影响，并且适合作为水泥混合物，因为它具有优异的水泥分散性，可操作性更好。作为实现该目的的手段，本发明的聚合物是：使用聚氨基多醚化合物，不饱和羧酸单体和聚亚烷基二醇作为原料的聚合反应得到的聚合物，其特征在于，聚氨基聚醚化合物的量为相对于聚氨基聚醚化合物和聚亚烷基二醇的总量为50重量％以上; 或通过使用聚氨基聚醚化合物和不饱和羧酸单体作为原料的聚合反应获得的聚合物，其特征在于，不饱和羧酸单体的量相对于聚氨基聚醚化合物的总量小于15重量％不饱和羧酸单体或不饱和羧酸单体含有丙烯酸为必须成分，反应后剩余的丙烯酸含量少于3重量％。

4. 发明申请

US20090198029A1 N-VINYL CYCLIC LACTAM POLYMER, PRODUCTION METHOD THEREOF, AND APPLICATION THEREOF 审中-公开
标题翻译： N-乙烯基环状乳液聚合物，其生产方法及其应用
公开(公告)号：US20090198029A1
公开(公告)日：2009-08-06
申请号：US11915590
申请日：2006-05-26
申请人： Takahiro Tsumori , Daisuke Imai , Yoshikazu Fujii
发明人： Takahiro Tsumori , Daisuke Imai , Yoshikazu Fujii
IPC分类号： C08F4/30 , C08F26/06
CPC分类号： C08F271/02 , C11D3/3776
摘要： To provide: an N-vinyl cyclic lactam polymer, which has excellent dispersibility and adsorptivity, and high calcium-ion capturing capability and can be preferably used in, for example, a detergent additive application; an application thereof; and a production method of the N-vinyl cyclic lactam polymer, the production method being capable of efficiently producing such an N-vinyl cyclic lactam polymer. An N-vinyl cyclic lactam polymer produced by a polymerization of a monomer component containing a carboxyl group-containing unsaturated monomer with a polymer having an N-vinyl cyclic lactam unit, wherein the carboxyl group-containing unsaturated monomer is 200 to 9900 parts by weight, relative to 100 parts by weight of the polymer having an N-vinyl cyclic lactam unit, and the N-vinyl cyclic lactam polymer has a viscosity at 25° C. of 100000 mPa·s or less in an aqueous solution with a solid content of 25% by weight.
摘要翻译：提供：分散性和吸附性优异，钙离子捕获能力高的N-乙烯基环状内酰胺聚合物，优选用于例如洗涤剂添加剂用途中。其应用; 以及N-乙烯基环内酰胺聚合物的制造方法，该制造方法能够有效地制造这种N-乙烯基环状内酰胺类聚合物。通过含有含羧基的不饱和单体的单体组分与具有N-乙烯基环状内酰胺单元的聚合物的聚合制备的N-乙烯基环状内酰胺聚合物，其中含羧基的不饱和单体为200〜9900重量份相对于100重量份的具有N-乙烯基环内酰胺单元的聚合物，N-乙烯基环内酰胺聚合物在固体含量的水溶液中的25℃下的粘度为100000mPa.s以下为25重量％。

5. 发明授权

US07285611B2 (Meth)acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 失效
标题翻译：（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法
公开(公告)号：US07285611B2
公开(公告)日：2007-10-23
申请号：US11518654
申请日：2006-09-11
申请人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
发明人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth)acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译：本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S，不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在分散性，螯合能力和抗胶凝性。

6. 发明申请

US20050032999A1 Water-soluble copolymer 审中-公开
标题翻译：水溶性共聚物
公开(公告)号：US20050032999A1
公开(公告)日：2005-02-10
申请号：US10889012
申请日：2004-07-13
申请人： Takahiro Tsumori , Daisuke Hattori , Shigeru Yamaguchi
发明人： Takahiro Tsumori , Daisuke Hattori , Shigeru Yamaguchi
IPC分类号： B01F17/52 , C08F220/06 , C08F222/00 , C08F222/02 , C11D3/37 , C08F20/06
CPC分类号： C08F220/06 , C08F222/02 , C11D3/3757
摘要： An object of the present invention is to provide a three-monomer-based water-soluble copolymer, obtained from an unsaturated monocarboxylic monomer, an unsaturated dicarboxylic monomer, and an unsaturated alcoholic monomer, wherein the water-soluble copolymer can sufficiently exercise excellent performances particularly when used for detergent builders, detergent compositions, water-treating agents, and dispersants. As a means of achieving this object, the water-soluble copolymer according to the present invention has: an unsaturated alcoholic monomer-derived structural unit content of 0.1 to 40 weight % (but not including 40 weight %); and a product of not less than 200 of the calcium-ion-binding ability and the clay dispersibility (which is measured in an aqueous solution having a calcium ion content of 50 ppm in terms of calcium carbonate) under conditions of solid component content=40 weight % and pH=7.5.
摘要翻译：本发明的目的是提供一种由不饱和单羧酸单体，不饱和二羧酸单体和不饱和醇单体得到的三单体型水溶性共聚物，其中水溶性共聚物可以充分地运用优异的性能当用于洗涤剂助洗剂，洗涤剂组合物，水处理剂和分散剂时。作为实现该目的的手段，本发明的水溶性共聚物具有：不饱和醇单体衍生的结构单元含量为0.1〜40重量％（但不包含40重量％）。并且在固体成分含量= 40的条件下，钙离子结合能力和粘土分散性（以碳酸钙计，钙离子含量为50ppm的水溶液中测定）不小于200的产物重量％，pH = 7.5。

7. 发明授权

US07132487B2 (Meth) acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 有权
标题翻译：（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法
公开(公告)号：US07132487B2
公开(公告)日：2006-11-07
申请号：US11216772
申请日：2005-08-31
申请人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
发明人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth) acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译：本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S，不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在分散性，螯合能力和抗胶凝性。

8. 发明申请

US20060004162A1 (Meth) acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 有权
公开(公告)号：US20060004162A1
公开(公告)日：2006-01-05
申请号：US11216772
申请日：2005-08-31
申请人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
发明人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
IPC分类号： C08F2/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth) acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.

9. 发明授权

US07160849B2 Specific polymer-compounded detergent composition 失效
标题翻译：具体的聚合物复合洗涤剂组合物
公开(公告)号：US07160849B2
公开(公告)日：2007-01-09
申请号：US10414291
申请日：2003-04-16
申请人： Takahiro Tsumori , Takuya Saeki , Yoshikazu Fujii , Shigeru Yamaguchi
发明人： Takahiro Tsumori , Takuya Saeki , Yoshikazu Fujii , Shigeru Yamaguchi
IPC分类号： C11D3/37 , C11D1/02 , C11D1/66
CPC分类号： C11D3/378 , C11D1/143 , C11D1/146 , C11D1/22 , C11D1/29 , C11D1/72 , C11D3/3757 , C11D3/3788
摘要： A detergent composition containing at least 0.1% by weight of at least one polymer selected from the group consisting of 1) a polycarboxylic acid-based polymer containing a polyalkylene glycol chain in the structure thereof, 2) a sulfonic acid group-terminated (meth)acrylic acid-based polymer, and 3) an acrylic acid (salt)-maleic acid (salt)-based copolymer having a clay dispersibility under a condition of 50 ppm of calcium carbonate of 0.3 or more; and at least 0.5% by weight of a longer alkyl chain mid-chain branched surfactant compound. The detergent composition can enhance anti-gelling properties to calcium ions, improve the dispersibility to solid particles at low temperatures or under high-hardness conditions, and improve detergency against stains such as mud and carbon black.
摘要翻译：含有至少0.1重量％的至少一种选自以下的聚合物的洗涤剂组合物：1）在其结构中含有聚亚烷基二醇链的聚羧酸基聚合物，2）磺酸基封端的（甲基）丙烯酸类聚合物，和3）在50ppm碳酸钙为0.3以上的条件下具有粘土分散性的丙烯酸（盐）马来酸（盐）基共聚物; 和至少0.5重量％的较长的烷基链中链支化表面活性剂化合物。洗涤剂组合物可以增强对钙离子的抗胶凝性能，提高在低温或高硬度条件下对固体颗粒的分散性，并且改善对污渍（如泥浆和炭黑）的污渍的去污力。

10. 发明申请

US20070004885A1 (Meth) acrylic acid type polymer and unsaturated polyalkylene glycol type copolymer, and methods for production thereof 失效
标题翻译：（甲基）丙烯酸型聚合物和不饱和聚亚烷基二醇型共聚物及其制备方法
公开(公告)号：US20070004885A1
公开(公告)日：2007-01-04
申请号：US11518654
申请日：2006-09-11
申请人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
发明人： Atsuro Yoneda , Takahiro Tsumori , Yoshikazu Fujii , Shigeru Yamaguchi
IPC分类号： C08F4/00
CPC分类号： C08F20/06 , C08F290/062
摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth)acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.
摘要翻译：本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S，不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在分散性，螯合能力和抗胶凝性。

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