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1. 发明申请

US20110108762A1 PROCESS FOR THE PRODUCTION OF ALKYLENE CARBONATE 有权
标题翻译：生产亚烷基碳酸酯的方法
公开(公告)号：US20110108762A1
公开(公告)日：2011-05-12
申请号：US12993136
申请日：2009-05-19
申请人： Cyrille Paul Allais , Evert Van Der Heide , Gerardus Martinus Maria Van Kessel
发明人： Cyrille Paul Allais , Evert Van Der Heide , Gerardus Martinus Maria Van Kessel
IPC分类号： C07D317/36 , C09K3/00
CPC分类号： C07D317/36 , C07D317/38
摘要： The invention relates to a process for the production of an alkylene carbonate by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium catalyst in which process (a) the alkylene oxide, carbon dioxide and phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and phosphonium catalyst is withdrawn; (b) alkylene carbonate and a stream containing phosphoniura catalyst are separated from the product stream; (c) the alkylene carbonate, separated in step (b), is recovered as product; and (d) the stream containing phosphoniura catalyst, separated in step (b), is recycled to the reaction zone, in which process a treatment of alkylene carbonate and/or catalyst with a sorption agent comprising carbon is carried out.
摘要翻译：本发明涉及在鏻催化剂存在下，通过烯化氧与二氧化碳的反应制备碳酸亚烷基酯的方法，其中方法（a）将环氧烷，二氧化碳和鏻催化剂连续引入取出含有碳酸亚烷基酯和鏻催化剂的产物流的反应区; （b）将碳酸亚烃酯和含有膦酰氧基催化剂的物流与产物流分离; （c）在步骤（b）中分离的碳酸亚烃酯作为产物回收; 和（d）将在步骤（b）中分离的含有膦酰氧基催化剂的料流再循环到反应区，在该方法中，用含碳吸附剂处理碳酸亚烷基酯和/或催化剂。

2. 发明授权

US08735607B2 Process for the production of alkylene carbonate 有权
标题翻译：碳酸亚烷基酯的制备方法
公开(公告)号：US08735607B2
公开(公告)日：2014-05-27
申请号：US12993136
申请日：2009-05-19
申请人： Cyrille Paul Allais , Evert Van Der Heide , Gerardus Martinus Maria Van Kessel
发明人： Cyrille Paul Allais , Evert Van Der Heide , Gerardus Martinus Maria Van Kessel
IPC分类号： C07D317/36 , C07D317/38
CPC分类号： C07D317/36 , C07D317/38
摘要： The invention relates to a process for the production of an alkylene carbonate by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium catalyst in which process (a) the alkylene oxide, carbon dioxide and phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and phosphonium catalyst is withdrawn; (b) alkylene carbonate and a stream containing phosphoniura catalyst are separated from the product stream; (c) the alkylene carbonate, separated in step (b), is recovered as product; and (d) the stream containing phosphoniura catalyst, separated in step (b), is recycled to the reaction zone, in which process a treatment of alkylene carbonate and/or catalyst with a sorption agent comprising carbon is carried out.
摘要翻译：本发明涉及在鏻催化剂存在下，通过烯化氧与二氧化碳的反应制备碳酸亚烷基酯的方法，其中方法（a）将环氧烷，二氧化碳和鏻催化剂连续引入取出含有碳酸亚烷基酯和鏻催化剂的产物流的反应区; （b）将碳酸亚烃酯和含有膦酰氧基催化剂的物流与产物流分离; （c）在步骤（b）中分离的碳酸亚烃酯作为产物回收; 和（d）将在步骤（b）中分离的含有膦酰氧基催化剂的料流再循环到反应区，在该方法中，用含碳吸附剂处理碳酸亚烷基酯和/或催化剂。

3. 发明授权

US07456299B2 Process for the production of alkylene carbonate and use of alkylene carbonate thus produced in the manufacture of an alkane diol and a dialkyl carbonate 有权
标题翻译：用于制备碳酸亚烷基酯的方法和在制备烷烃二醇和碳酸二烷基酯中如此制备的亚烷基碳酸酯的用途
公开(公告)号：US07456299B2
公开(公告)日：2008-11-25
申请号：US11677997
申请日：2007-02-22
申请人： Evert Van Der Heide , Gerardus Martinus Maria Van Kessel , Timothy Michael Nisbet , Garo Garbis Vaporciyan
发明人： Evert Van Der Heide , Gerardus Martinus Maria Van Kessel , Timothy Michael Nisbet , Garo Garbis Vaporciyan
IPC分类号： C07D317/08
CPC分类号： C07C29/128 , C07D317/36 , Y02P20/584 , C07C31/202
摘要： An alkylene carbonate is produced by the reaction of an alkylene oxide with carbon dioxide in the presence of a phosphonium compound as catalyst in a process in which (a) the alkylene oxide, carbon dioxide and the phosphonium catalyst are continuously introduced into a reaction zone from which a product stream containing alkylene carbonate and catalyst is withdrawn, (b) alkylene carbonate and a mixture of alkylene carbonate and phosphonium catalyst are separated from the product stream, (c) the alkylene carbonate, separated in step (b), is recovered as product, and (d) the mixture of alkylene carbonate and phosphonium catalyst is continuously recycled to the reaction zone. The alkylene carbonate thus produced is suitably reacted with an alkanol to produce an alkane diol and a dialkyl carbonate.
摘要翻译：在鏻化合物作为催化剂的存在下，通过烯化氧与二氧化碳的反应制备碳酸亚烃酯，其中（a）将环氧烷，二氧化碳和鏻催化剂从取出含有碳酸亚烃酯和催化剂的产物流，（b）碳酸亚烷基酯和碳酸亚烃酯和鏻催化剂的混合物与产物流分离，（c）将步骤（b）中分离的碳酸亚烃酯回收为产物，和（d）碳酸亚烷基酯和鏻催化剂的混合物连续循环到反应区。这样制得的碳酸亚烃酯适当地与烷醇反应生成烷烃二醇和碳酸二烷基酯。

4. 发明申请

US20100121078A1 PROCESS FOR PREPARING ALKANEDIOL AND DIALKYL CARBONATE 审中-公开
标题翻译：制备阿尔卡尼和碳酸二乙酯的方法
公开(公告)号：US20100121078A1
公开(公告)日：2010-05-13
申请号：US12435173
申请日：2009-05-04
申请人： Cyrille Paul Allais , Minne Boelens , Evert Van Der Heide
发明人： Cyrille Paul Allais , Minne Boelens , Evert Van Der Heide
IPC分类号： C07D317/10
CPC分类号： C07C68/065 , C07C69/96
摘要： The invention relates to a process for the preparation of an alkanediol and a dialkyl carbonate comprising: (a) reacting an alkylene carbonate and an alkanol at a temperature of from 10 to 200° C., at a pressure of from 5×104 to 5×106 N/m2 and in the absence of a transesterification catalyst, to obtain a mixture comprising hydroxyalkyl alkyl carbonate, alkanol and alkylene carbonate; (b) contacting the mixture comprising hydroxyalkyl alkyl carbonate, alkanol and alkylene carbonate with a transesterification catalyst at a temperature of from 10 to 200° C. and at a pressure of from 5×104 to 5×106 N/m2, to obtain a mixture comprising the alkanediol and the dialkyl carbonate; and (c) recovering the alkanediol and the dialkyl carbonate from the mixture comprising the alkanediol and the dialkyl carbonate.
摘要翻译：本发明涉及一种制备链烷二醇和碳酸二烷基酯的方法，包括：（a）在10至200℃的温度下，在5×10 4至5的压力下使碳酸亚烷基酯和链烷醇反应 ×106N / m 2，并且在不存在酯交换催化剂的情况下，得到包含碳酸烷基酯，链烷醇和碳酸亚烷基酯的混合物; （b）使含碳酸烷基酯，链烷醇和碳酸亚烷基酯的混合物与酯交换催化剂在10〜200℃，压力为5×10 4〜5×10 6 N / m 2下接触，得到包含链烷二醇和碳酸二烷基酯的混合物; 和（c）从包含链烷二醇和碳酸二烷基酯的混合物中回收链烷二醇和碳酸二烷基酯。

5. 发明授权

US07732629B2 Process for the preparation of diaryl carbonate 有权
标题翻译：制备碳酸二芳基酯的方法
公开(公告)号：US07732629B2
公开(公告)日：2010-06-08
申请号：US12017303
申请日：2008-01-21
申请人： Evert Van Der Heide , Timothy Michael Nisbet , Garo Garbis Vaporciyan , Cornelis Leonardus Maria Vrouwenvelder
发明人： Evert Van Der Heide , Timothy Michael Nisbet , Garo Garbis Vaporciyan , Cornelis Leonardus Maria Vrouwenvelder
IPC分类号： C07C69/96
CPC分类号： C07C68/06 , Y02P20/127 , C07C69/96
摘要： The invention relates to a process for the preparation of a diaryl carbonate by transesterification of an aromatic alcohol with a dialkyl carbonate in the presence of a transesterification catalyst during a period of time [ta], in which the aryl moiety is selected from unsubstituted phenyl and mono-, di- and trisubstituted phenyl groups, in which the alkyl moiety is selected from C2 to C4 linear and branched alkyl groups, in which the catalyst concentration is designated [ca], expressed as gram catalyst per gram of aromatic alcohol and dialkyl carbonate, in which the period of time [tm] and catalyst concentration [cm] are determined to arrive at a pre-set approach to the equilibrium for the transesterification of the aromatic alcohol with dimethyl carbonate to methyl aryl carbonate and methanol, in which the product [ca]*ta is at least 1.5*[cm]*tm under otherwise the same reaction conditions.
摘要翻译：本发明涉及一种在酯交换催化剂存在下，在一段时间[ta]期间通过芳族醇与碳酸二烷基酯的酯交换制备碳酸二芳基酯的方法，其中芳基部分选自未取代的苯基和单取代，二取代和三取代的苯基，其中烷基部分选自C2至C4直链和支链烷基，其中催化剂浓度指定为[ca]，表示为克催化剂/克芳族醇和碳酸二烷基酯，其中确定时间段[tm]和催化剂浓度[cm]达到用于将芳族醇与碳酸二甲酯转化为碳酸甲基芳基酯和甲醇的酯交换的平衡的预设方法，其中产物 [ca] * ta在相同的反应条件下为至少1.5 * [cm] * tm。

6. 发明申请

US20070203373A1 PROCESS FOR THE PREPARATION OF ALKANEDIOL 失效
标题翻译：制备阿尔卡尼醇的方法
公开(公告)号：US20070203373A1
公开(公告)日：2007-08-30
申请号：US11678009
申请日：2007-02-22
申请人： Evert Van Der Heide , Cornelis Vrouwenvelder
发明人： Evert Van Der Heide , Cornelis Vrouwenvelder
IPC分类号： C07C29/10
CPC分类号： C07C29/12 , C07C68/065 , C07C31/202 , C07C31/205 , C07C69/96
摘要： The invention provides a process for the preparation of alkanediol comprising the steps: (i) contacting alkylene oxide with carbon dioxide in the presence of a carbonation catalyst to obtain a reaction mixture containing alkylene carbonate at a reaction temperature of from 100 to 200° C.; (ii) contacting the reaction mixture obtained in step (i) with R—OH, in which R is hydrogen or an alkyl group in the presence of a catalyst to obtain a second reaction mixture containing alkanediol and R2CO3; (iii) subjecting the second reaction mixture containing alkanediol and R2CO3 to a separation step to yield a crude alkanediol stream, which is subjected to distillation to yield a purified stream of alkanediol as the bottom stream; (iv) subjecting the purified stream of alkanediol obtained in step (iii) to further distillation to obtain a second bottom stream containing a mixture of alkanediol, heavy components, and optionally carbonation catalyst, and a top stream containing high purity alkanediol; wherein at least part of the reaction mixture obtained in step (i) is used for heat exchange with at least part of the crude alkanediol stream and/or with at least part of the purified alkanediol stream.
摘要翻译：本发明提供一种制备链烷二醇的方法，包括以下步骤：（i）在碳酸化催化剂存在下使环氧烷与二氧化碳接触，得到反应温度为100-200℃的含有碳酸亚烷基酯的反应混合物 ; （ii）在催化剂存在下使步骤（i）中获得的反应混合物与R-OH（其中R是氢或烷基）接触，得到含有链烷二醇和R 2的第二反应混合物 > CO 3 3; （iii）将含有链烷二醇和R 2 CO 3的第二反应混合物进行分离步骤以产生粗链烷二醇流，将其进行蒸馏以产生纯化的流的链烷二醇作为底部流; （iv）使步骤（iii）中获得的纯化的烷烃二醇进一步蒸馏，得到含有链烷二醇，重组分和任选碳酸化催化剂的混合物的第二塔底料流和含有高纯度链烷二醇的顶流; 其中步骤（i）中获得的至少部分反应混合物用于与至少部分粗链烷二醇流和/或至少部分纯化的链烷二醇流进行热交换。

7. 发明授权

US08901325B2 Method for producing furfural from lignocellulosic biomass material 有权
标题翻译：从木质纤维素生物质材料生产糠醛的方法
公开(公告)号：US08901325B2
公开(公告)日：2014-12-02
申请号：US12970131
申请日：2010-12-16
申请人： Evert Van Der Heide , Ting Zhang
发明人： Evert Van Der Heide , Ting Zhang
IPC分类号： C07D307/50 , C07D307/48
CPC分类号： C07D307/48 , C07D307/50
摘要： A method for producing furfural from lignocellulosic biomass material is provided, comprising (a) contacting the lignocellulosic biomass material with a mixture comprising water and an organic acid at a temperature of at least 100° C. and a pressure of at most 10 bar (absolute) to obtain a first liquid stream comprising hydrolyzed hemicellulose and a second stream comprising lignin and cellulose; (b) maintaining the first liquid stream comprising hydrolyzed hemicellulose at a temperature of at least 130° C. to obtain a second liquid stream comprising furfural; and (c) separating the furfural obtained in step b) from the second liquid stream.
摘要翻译：提供了一种从木质纤维素生物质材料生产糠醛的方法，包括（a）在至少100℃的温度和至多10巴的压力（绝对值）下使木质纤维素生物质材料与包含水和有机酸的混合物接触）以获得包含水解的半纤维素的第一液体流和包含木质素和纤维素的第二流; （b）在至少130℃的温度下保持包含水解半纤维素的第一液体流，以获得包含糠醛的第二液体流; 和（c）将步骤b）中获得的糠醛与第二液体流分离。

8. 发明申请

US20090270657A1 PROCESS FOR THE PREPARATION OF A 1,2-ALKYLENE DIOL AND A DIALKYLCARBONATE 审中-公开
标题翻译：制备1,2-亚苄基二醇和对二氯甲烷的方法
公开(公告)号：US20090270657A1
公开(公告)日：2009-10-29
申请号：US12108299
申请日：2008-04-23
申请人： Evert Van Der Heide , Cornelis Leonardus Maria Vrouwenvelder
发明人： Evert Van Der Heide , Cornelis Leonardus Maria Vrouwenvelder
IPC分类号： C07C31/18
CPC分类号： C07C68/065 , C07C69/96
摘要： The present invention relates to a process for the preparation of a 1,2-alkylene diol and a dialkylcarbonate, comprising the steps of (i) contacting a 1,2-alkylene oxide with carbon dioxide in the presence of a carbonation catalyst in a downflow jet reactor to obtain a reaction mixture containing a 1,2-alkylene carbonate, wherein the downflow jet reactor further comprises a deflection means situated in between the ejector means and the outlet means in the direction of the flow path of the gas/liquid mixture generated by the ejector means; (ii) contacting at least part of the reaction mixture obtained in step (i) with an alkanol to obtain a reaction mixture containing a 1,2-alkylene diol and a dialkylcarbonate; and (iii) recovering the 1,2-alkylene diol and the dialkylcarbonate from the reaction mixture obtained in step (ii).
摘要翻译：本发明涉及一种1,2-亚烷基二醇和碳酸二烷基酯的制备方法，包括以下步骤：（i）在碳酸化催化剂存在下使1,2-环氧烷与二氧化碳在下流以获得含有1,2-亚烷基碳酸酯的反应混合物，其中所述下流喷射反应器还包括位于所述喷射装置和所述出口装置之间的偏转装置，所述偏转装置沿所述气/液混合物的流动路径的方向产生通过喷射器装置; （ii）使步骤（i）中获得的反应混合物的至少一部分与链烷醇接触，得到含有1,2-亚烷基二醇和碳酸二烷基酯的反应混合物; 和（iii）从步骤（ii）中获得的反应混合物中回收1,2-亚烷基二醇和碳酸二烷基酯。

9. 发明授权

US07563919B2 Process for the preparation of an alkanediol and a dialkyl carbonate 失效
标题翻译：制备链烷二醇和碳酸二烷基酯的方法
公开(公告)号：US07563919B2
公开(公告)日：2009-07-21
申请号：US11677999
申请日：2007-02-22
申请人： Evert Van Der Heide , Timothy Michael Nisbet , Garo Garbis Vaporciyan
发明人： Evert Van Der Heide , Timothy Michael Nisbet , Garo Garbis Vaporciyan
IPC分类号： C07C69/96 , C07C27/00
CPC分类号： C07C68/065 , Y02P20/127 , C07C69/96
摘要： An alkanediol and a dialkyl carbonate are prepared in a process comprising: (a) contacting an alkylene carbonate with an alkanol feedstock under transesterification conditions in a reactive distillation zone to obtain a top stream comprising dialkyl carbonate and the alkanol and a bottom stream comprising an alkanediol; (b) separating the top stream comprising dialkyl carbonate and the alkanol into an alkanol-rich stream and a dialkyl carbonate-rich stream; (c) recovering the dialkyl carbonate from the dialkyl carbonate-rich stream; and (d) recycling at least part of the alkanol-rich stream to the reactive distillation zone as part of the alkanol feedstock, wherein the alkanol-rich stream is split in at least two portions, and at least one portion is condensed and freed from compounds with a lower boiling point than the alkanol. The process is especially suitable for the production of propylene glycol and dimethyl carbonate from propylene carbonate and methanol.
摘要翻译：制备烷基二醇和碳酸二烷基酯的方法包括：（a）在反应蒸馏区中在酯交换反应条件下使烯烃碳酸酯与链烷醇原料接触以获得包含碳酸二烷基酯和链烷醇的底部料流和包含链烷二醇 ; （b）将包含碳酸二烷基酯和链烷醇的顶部料流分离成富链烷醇流和富含碳酸二烷基酯的料流; （c）从富含碳酸二烷基酯的料流中回收碳酸二烷基酯; 和（d）作为链烷醇原料的一部分将至少部分富含链烷醇的料流再循环至反应性蒸馏区，其中富链烷醇流分成至少两部分，并且至少一部分被冷凝并从沸点低于链烷醇的化合物。该方法特别适用于从碳酸丙烯酯和甲醇生产丙二醇和碳酸二甲酯。

10. 发明申请

US20090118551A1 Integrated Separation and Preparation Process 审中-公开
标题翻译：综合分离和制备过程
公开(公告)号：US20090118551A1
公开(公告)日：2009-05-07
申请号：US11794448
申请日：2005-12-27
申请人： Andre Buijs , Leslie Andrew Chewter , Gerrit Jan Harmsen , Evert Van Der Heide , Jean-Francois Menard , Dominicus Fredericus Mulder , Wouter Spiering
发明人： Andre Buijs , Leslie Andrew Chewter , Gerrit Jan Harmsen , Evert Van Der Heide , Jean-Francois Menard , Dominicus Fredericus Mulder , Wouter Spiering
IPC分类号： B01D53/22 , C07C29/04 , C07C27/06 , C07C5/02 , C07C5/03
CPC分类号： B01D53/229 , B01D53/22 , B01D63/06 , B01D2313/42 , B01D2319/04 , C07C29/04 , C07C29/12 , C07C29/145 , C07C29/76 , C07C41/09 , C07C45/002 , Y02C10/10 , C07C49/08 , C07C49/10 , C07C31/10 , C07C31/12 , C07C31/202 , C07C31/205 , C07C43/13
摘要： Integrated separation and preparation process comprising a gas separation process wherein a first component is separated from a mixture of components by diffusion of the first component through a porous partition into a stream of sweeping component; and a preparation process wherein the sweeping component is used as feed. Separation unit and device for use in such a process and industrial set-up for use in such a process.
摘要翻译：一种综合分离和制备方法，包括气体分离方法，其中第一组分通过第一组分通过多孔隔板扩散成清扫组分流而与组分混合物分离; 以及其中清扫组分用作饲料的制备方法。用于这种过程的分离单元和设备以及用于这种过程的工业设置。

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