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    • 4. 发明授权
    • Colorants and intermediates therefor having branched
poly(oxyalkylene)moieties, and their manufacture
    • 具有支链聚(氧化烯)部分的着色剂和中间体及其制备
    • US5591833A
    • 1997-01-07
    • US104276
    • 1993-08-10
    • John B. HinesDavid J. MoodyEdward W. Kluger
    • John B. HinesDavid J. MoodyEdward W. Kluger
    • C09B69/00C09B69/10D06P5/13
    • C09B69/00
    • Colorants and compositions useful as a fugitive or permanent colorant for a variety of substrates, or as intermediates for their manufacture, and having one or more improved properties of enhanced aqueous washability, compatibility with and non-extractibility from thermoplastic resins, or reactivity with resins having reactive functionality, said composition having the formula C(Z).sub.1-8 wherein:C is the residue of a reactant having from 1-8 nucleophilic site residues to which the Z moieties are attached; said Z moieties containing at least about 60 weight percent of poly(oxyalkylene) which is comprised of(a) at least one glycidol residue segment of 2-6 glycidol residues attached to a nucleophilic site of C, wherein said poly(oxyalkylene) contains a total of from 2-20 glycidol residues,(b) and wherein said poly(oxyalkylene) further contains the residues of one or more other epoxide reactants of ethylene oxide (EO), propylene oxide (PO), or butylene oxide (BO), or mixtures thereof, wherein said poly(oxyalkylene) contains a total of from about 10 to about 600 of said EO, PO or BO residues, or mixtures thereof, at least about 75 mole percent of which are EO residues,(c) and with the provisions that the ratio of the total of --0--PO-- and --O--BO-- linkages of all glycidol residues to the total of all functional oxy linkages of said glycidol residues is less than one, and the molar ratio of EO residues to glycidol residues is from 4 to 75.
    • 可用作各种底物的挥发性或永久性着色剂的着色剂和组合物,或作为其制造的中间体,并且具有一种或多种改进的水性洗涤性,与热塑性树脂的相容性和不可萃取性的改进性能,或与具有 所述组合物具有式C(Z)1-8,其中:C是具有与Z部分连接的1-8个亲核位点残基的反应物的残基; 所述Z部分包含至少约60重量%的聚(氧化烯),其由(a)至少一个连接到C的亲核位点的2-6个缩水甘油残基的缩水甘油残基部分组成,其中所述聚(氧化烯)含有 总共2-20个缩水甘油残基,(b),其中所述聚(氧化烯)还含有环氧乙烷(EO),环氧丙烷(PO)或环氧丁烷(BO))的一种或多种其它环氧化物反应物的残基, 或其混合物,其中所述聚(氧化烯)含有总共约10至约600的所述EO,PO或BO残基或其混合物,其至少约75摩尔%为EO残基,(c)和 所有缩水甘油残基的-O-PO-和-O-BO-键的总和与所述缩水甘油残基的所有功能氧键的总和的比例小于1,EO残基与 缩水甘油残基为4-75。