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1. 发明授权

US06723349B1 Polyoxometalate materials, metal-containing materials, and methods of use thereof 失效
标题翻译：多金属氧酸盐材料，含金属材料及其使用方法
公开(公告)号：US06723349B1
公开(公告)日：2004-04-20
申请号：US09689231
申请日：2000-10-11
申请人： Craig L. Hill , Ling Xu , Jeffrey T. Rhule , Eric A. Boring
发明人： Craig L. Hill , Ling Xu , Jeffrey T. Rhule , Eric A. Boring
IPC分类号： A61K906
CPC分类号： A62D3/30 , A61K31/01 , A61K31/14 , A61K33/24 , A61K33/26 , A61K33/32 , A61K33/34 , A61K33/36 , A61K33/42 , A62D3/38 , A62D5/00 , A62D2101/02 , A62D2101/22 , A62D2101/24 , A62D2101/26 , A62D2101/28 , A62D2101/47 , C07F9/005 , Y02A50/395 , Y10S424/13 , Y10S514/823 , Y10S514/844 , Y10S514/845 , Y10S514/848 , Y10S514/862 , Y10S514/887 , Y10S514/937 , Y10S514/944 , Y10S514/969 , Y10S514/974
摘要： The invention relates to a polyoxometalate topical composition for removing a contaminant from an environment, comprising a topical carrier and at least one polyoxometalate, with the proviso that the polyoxometalate is not H5PV2Mo10O40; K5Si(H2O)MnIIIW11O39; K4Si(H2O)MnIVW11O39; or K5CoIIIW12O40. The invention further relates to a method for removing a contaminant from an environment, comprising contacting the polyoxometalate topical composition of the present invention with the environment containing the contaminant for a sufficient time to remove the contaminant from the environment. The invention further relates to a modified polyoxometalate, wherein the modified polyoxometalate comprises the admixture of (1) a polyoxometalate and (2) a cerium compound, a silver compound, a gold compound, a platinum compound, or a combination thereof. The invention further relates to a method for removing a contaminant from an environment, comprising contacting a modified material with the environment containing the contaminant for a sufficient time to remove the contaminant from the environment, wherein the modified material comprises (1) a material and (2) a metal compound comprising a transition metal compound, an actinide compound, a lanthanide compound, or a combination thereof, wherein the metal compound is not a polyoxometalate. The invention further relates to an article comprising the modified material of the present invention.
摘要翻译：本发明涉及用于从环境中除去污染物的多金属氧酸盐局部组合物，其包含局部载体和至少一种多金属氧酸盐，条件是多金属氧酸盐不是H5PV2Mo10O40; K5Si（H2O）Mn W11O39; K4Si（H2O）MnⅣW11O39; 或K5Co W12O40。本发明还涉及一种从环境中去除污染物的方法，包括将本发明的多金属氧酸盐局部组合物与含有污染物的环境接触足够的时间以从环境中除去污染物。本发明还涉及改性多金属氧酸盐，其中改性多金属氧酸盐包括（1）多金属氧酸盐和（2）铈化合物，银化合物，金化合物，铂化合物或其组合的混合物。本发明还涉及从环境中去除污染物的方法，包括使改性材料与含有污染物的环境接触足够的时间以从环境中除去污染物，其中改性材料包括（1）材料和（ 2）包含过渡金属化合物，锕系化合物，镧系元素化合物或其组合的金属化合物，其中所述金属化合物不是多金属氧酸盐。本发明还涉及包含本发明的改性材料的制品。

2. 发明申请

US20080187601A1 Polyoxometalate materials, metal-containing materials, and methods of use thereof 审中-公开
公开(公告)号：US20080187601A1
公开(公告)日：2008-08-07
申请号：US11636280
申请日：2006-12-07
申请人： Craig L. Hill , Ling Xu , Jeffrey T. Rhule , Eric A. Boring
发明人： Craig L. Hill , Ling Xu , Jeffrey T. Rhule , Eric A. Boring
IPC分类号： A61K33/32 , A61K33/26 , A61K33/24 , A61K33/38 , A61K33/42
CPC分类号： A62D3/30 , A61K31/01 , A61K31/14 , A61K33/24 , A61K33/26 , A61K33/32 , A61K33/34 , A61K33/36 , A61K33/42 , A62D3/38 , A62D5/00 , A62D2101/02 , A62D2101/22 , A62D2101/24 , A62D2101/26 , A62D2101/28 , A62D2101/47 , C07F9/005 , Y02A50/395 , Y10S424/13 , Y10S514/823 , Y10S514/844 , Y10S514/845 , Y10S514/848 , Y10S514/862 , Y10S514/887 , Y10S514/937 , Y10S514/944 , Y10S514/969 , Y10S514/974
摘要： The invention relates to a polyoxometalate topical composition for removing a contaminant from an environment, comprising a topical carrier and at least one polyoxometalate, with the proviso that the polyoxometalate is not H5PV2Mo10O40; K5Si(H2O)MnIIIW11O39; K4Si(H2O)MnIVW11O39; or K5CoIIIW12O40. The invention further relates to a method for removing a contaminant from an environment, comprising contacting the polyoxometalate topical composition of the present invention with the environment containing the contaminant for a sufficient time to remove the contaminant from the environment. The invention further relates to a method for removing a contaminant from an environment, comprising contacting a polyoxometalate powder or a polyoxometalate coating with the environment containing the contaminant for a sufficient time to remove the contaminant from the environment. The invention further relates to a modified polyoxometalate, wherein the modified polyoxometalate comprises the admixture of (1) a polyoxometalate and (2) a cerium compound, a silver compound, a gold compound, a platinum compound, or a combination thereof. The invention further relates to a method for removing a contaminant from an environment, comprising contacting a modified material with the environment containing the contaminant for a sufficient time to remove the contaminant from the environment, wherein the modified material comprises (1) a material and (2) a metal compound comprising a transition metal compound, an actinide compound, a lanthanide compound, or a combination thereof, wherein the metal compound is not a polyoxometalate. The invention further relates to a modified material for removing a contaminant from an environment, wherein the modified material comprises (1) a material comprising a topical carrier, a powder, a coating, or a fabric, and (2) a metal compound comprising a transition metal compound, an actinide compound, a lanthanide compound, or a combination thereof, wherein the metal compound is not a polyoxometalate. The invention further relates to an article comprising the modified material of the present invention.

3. 发明授权

US07097858B2 Polyoxometalate materials, metal-containing materials, and methods of use thereof 有权
标题翻译：多金属氧酸盐材料，含金属材料及其使用方法
公开(公告)号：US07097858B2
公开(公告)日：2006-08-29
申请号：US10134774
申请日：2002-04-29
申请人： Craig L. Hill , Ling Xu , Jeffrey T. Rhule , Eric A. Boring
发明人： Craig L. Hill , Ling Xu , Jeffrey T. Rhule , Eric A. Boring
IPC分类号： A61K33/00 , A61K33/24 , A61K33/32 , A61K33/34 , A61K33/42 , A01N59/16 , A01N59/26 , A61L9/00 , A61L9/01 , A62D3/00
CPC分类号： A62D3/30 , A61K31/01 , A61K31/14 , A61K33/24 , A61K33/26 , A61K33/32 , A61K33/34 , A61K33/36 , A61K33/42 , A62D3/38 , A62D5/00 , A62D2101/02 , A62D2101/22 , A62D2101/24 , A62D2101/26 , A62D2101/28 , A62D2101/47 , C07F9/005 , Y02A50/395 , Y10S424/13 , Y10S514/823 , Y10S514/844 , Y10S514/845 , Y10S514/848 , Y10S514/862 , Y10S514/887 , Y10S514/937 , Y10S514/944 , Y10S514/969 , Y10S514/974
摘要： Polyoxometalate topical compositions for removing contaminants from an environment and methods of use thereof are disclosed. An embodiment of the polyoxometalate topical composition includes a topical carrier and at least one polyoxometalate, with the proviso that the polyoxometalate is not H5PV2Mo10O40; K5Si(H2O)MnIIIW11O39; K4Si(H2O)MnIVW11O39; or K5CoIIIW12O40. Another embodiment relates to a method for removing a contaminant from an environment, including contacting the polyoxometalate topical composition with the environment containing the contaminant for a sufficient time to remove the contaminant from the environment. An additional embodiment relates to a modified material for removing a contaminant from an environment, wherein the modified material includes (1) a material comprising a topical carrier, a powder, a coating, or a fabric, and (2) a metal compound including a transition metal compound, an actinide compound, a lanthanide compound, or a combination thereof, wherein the metal compound is not a polyoxometalate.
摘要翻译：公开了用于从环境中除去污染物的多金属氧酸盐局部组合物及其使用方法。多金属氧酸盐局部组合物的一个实施方案包括局部载体和至少一种多金属氧酸盐，条件是多金属氧酸盐不是H 5 PV 2 O 10， 40 K 5 S（H 2 O 2）Mn III III 11 N 30 O 3 K 4 Si（H 2 O 2）Mn IV W 11 11 O 39; 或者是第5位，第30位，第30位。另一个实施方案涉及从环境中除去污染物的方法，包括使多金属氧酸盐局部组合物与含有污染物的环境接触足够的时间以从环境中除去污染物。另外的实施方案涉及用于从环境中除去污染物的改性材料，其中所述改性材料包括（1）包含局部载体，粉末，涂层或织物的材料，和（2）包括过渡金属化合物，锕系化合物，镧系元素化合物或其组合，其中所述金属化合物不是多金属氧酸盐。

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