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1. 发明授权

US07455762B2 Selective hydrodesulfurization process 有权
标题翻译：选择性加氢脱硫工艺
公开(公告)号：US07455762B2
公开(公告)日：2008-11-25
申请号：US11189666
申请日：2005-07-26
申请人： Chuansheng Bai , Gary B. McVicker , Stuart S. Shih , Michael C. Kerby , Edward A. Lemon, Jr.
发明人： Chuansheng Bai , Gary B. McVicker , Stuart S. Shih , Michael C. Kerby , Edward A. Lemon, Jr.
IPC分类号： C10G45/08
CPC分类号： B01J29/045 , B01J23/85 , B01J23/882 , B01J29/0308 , B01J29/041 , B01J29/044 , B01J35/002 , B01J37/0009 , B01J2229/42 , C10G2400/02
摘要： This invention relates to a process for selectively hydrodesulfurizing naphtha feedstreams using a catalyst comprising at least one hydrodesulfurizing metal supported on a low acidity, ordered mesoporous support material.
摘要翻译：本发明涉及使用包含至少一种负载在低酸性有序介孔载体材料上的加氢脱硫金属的催化剂来选择性加氢脱硫石脑油原料流的方法。

2. 发明授权

US07285512B2 Selective hydrodesulfurization catalyst 有权
标题翻译：选择性加氢脱硫催化剂
公开(公告)号：US07285512B2
公开(公告)日：2007-10-23
申请号：US11189664
申请日：2005-07-26
申请人： Chuansheng Bai , Gary B. McVicker , Stuart S. Shih , Michael C. Kerby , Edward A. Lemon, Jr. , Jean W. Beeckman
发明人： Chuansheng Bai , Gary B. McVicker , Stuart S. Shih , Michael C. Kerby , Edward A. Lemon, Jr. , Jean W. Beeckman
IPC分类号： B01J29/06 , B01J29/068 , B01J29/70 , B01J29/74
CPC分类号： C10G45/08 , B01J29/0333 , B01J29/0341 , B01J29/044 , B01J29/045 , B01J2229/42 , C10G45/12
摘要： This invention relates to a catalyst and process for selectively hydrodesulfurizing naphtha feedstreams using a catalyst comprising at least one hydrodesulfurizing metal supported on a low acidity, ordered mesoporous support material.
摘要翻译：本发明涉及使用包含至少一种负载在低酸性有序介孔载体材料上的加氢脱硫金属的催化剂来选择性加氢脱硫石脑油原料流的催化剂和方法。

3. 发明授权

US09719034B2 Co-production of lubricants and distillate fuels 有权
公开(公告)号：US09719034B2
公开(公告)日：2017-08-01
申请号：US14546565
申请日：2014-11-18
申请人： Stuart S. Shih , Gary P. Schleicher , Michael B. Carroll , Timothy L. Hilbert , Stephen J. McCarthy , William J. Novak
发明人： Stuart S. Shih , Gary P. Schleicher , Michael B. Carroll , Timothy L. Hilbert , Stephen J. McCarthy , William J. Novak
IPC分类号： C10G45/64 , C10G69/02 , C10M103/06 , B01J35/10 , C10G65/04 , C10G65/12 , B01J23/883 , B01J23/888 , B01J29/78
CPC分类号： C10G69/02 , B01J23/883 , B01J23/888 , B01J29/78 , B01J29/7846 , B01J29/7861 , B01J29/7884 , B01J29/7892 , B01J35/1014 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C10G65/043 , C10G65/12 , C10G2300/1048 , C10G2300/203 , C10G2300/301 , C10G2300/302 , C10G2300/307 , C10G2400/04 , C10G2400/10 , C10M103/06
摘要： Methods are provided for processing a gas oil boiling range feedstock, such as a vacuum gas oil, in a single reaction stage and/or without performing intermediate separations. The methods are suitable for forming lubricants and distillate fuels while reducing or minimizing the production of lower boiling products such as naphtha and light ends. The methods can provide desirable yields of distillate fuels and lubricant base oils without requiring separate catalyst beds or stages for dewaxing and hydrocracking. The methods are based in part on use of a dewaxing catalyst that is tolerant of sour processing environments while still providing desirable levels of activity for both feed conversion and feed isomerization.

4. 发明授权

US09487714B2 Hydrocracking process selective for improved distillate and improved lube yield and properties 有权
公开(公告)号：US09487714B2
公开(公告)日：2016-11-08
申请号：US14011061
申请日：2013-08-27
申请人： William J. Novak , Robert Allen Bradway , Stuart S. Shih , Timothy Lee Hilbert , Michel Daage
发明人： William J. Novak , Robert Allen Bradway , Stuart S. Shih , Timothy Lee Hilbert , Michel Daage
IPC分类号： C10G47/18 , C10G49/04 , C10G65/10 , C10G65/12
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

5. 发明申请

US20150275106A1 BASESTOCK PRODUCTION FROM FEEDS CONTAINING SOLVENT EXTRACTS 有权
标题翻译：含有溶剂提取物的饲料的基础油生产
公开(公告)号：US20150275106A1
公开(公告)日：2015-10-01
申请号：US14629997
申请日：2015-02-24
申请人： Nicole D. Vaughn , Teck-Mui Hoo , Michael B. Carroll , Stuart S. Shih , Eric D. Joseck , William J. Novak
发明人： Nicole D. Vaughn , Teck-Mui Hoo , Michael B. Carroll , Stuart S. Shih , Eric D. Joseck , William J. Novak
IPC分类号： C10G67/02 , C10M101/02
CPC分类号： C10G67/02 , C10G65/043 , C10G65/12 , C10G2300/1096 , C10G2300/301 , C10G2400/10 , C10M101/02
摘要： Methods are provided for producing Group II/III lubricant base oil products where at least a portion of the feedstock for forming the lubricant base oil product is a solvent extract fraction from a Group I lubricant production facility. This can increase the overall volume of feedstock available for production of Group II/III lubricant base oils by using a lower value stream (Group I solvent extract) as a portion of the feedstock. The solvent extract fraction can be added to a full range lubricant feedstock or to a portion of a lubricant feedstock, such as adding an extract fraction to a higher viscosity portion (such as a heavy neutral portion) of a feedstock for lubricant production, while a lower viscosity portion (such as a light neutral portion) is processed without addition of an extract fraction.
摘要翻译：提供用于生产组II / III润滑剂基础油产品的方法，其中用于形成润滑剂基础油产品的原料的至少一部分是来自第I组润滑剂生产设备的溶剂提取物部分。这可以通过使用较低价值的流（I类溶剂提取物）作为原料的一部分来增加可用于生产II / III族润滑油基础油的原料的总体积。可以将溶剂萃取馏分加入到全润滑油原料中或一部分润滑剂原料中，例如将提取物馏分加入用于润滑剂生产的原料的较高粘度部分（例如重中性部分），而低粘度部分（如轻中性部分）被加工而不添加萃取部分。

6. 发明授权

US08852425B2 Two stage hydroprocessing with divided wall column fractionator 有权
$Two stage hydroprocessing with divided wall column fractionator$
标题翻译：两级加氢处理与分段壁柱分馏塔
公开(公告)号：US08852425B2
公开(公告)日：2014-10-07
申请号：US12946353
申请日：2010-11-15
申请人： Benjamin S. Umansky , Berne K. Stober , Carlos N. Lopez , Stuart S. Shih , Timothy L. Hilbert , Andre T. Sims , William J. Tracy, III , Akira Murata , Paul W. Kamienski
发明人： Benjamin S. Umansky , Berne K. Stober , Carlos N. Lopez , Stuart S. Shih , Timothy L. Hilbert , Andre T. Sims , William J. Tracy, III , Akira Murata , Paul W. Kamienski
IPC分类号： C10B57/02 , C10G51/02 , B01D3/14 , C10G7/00 , C10G65/04 , C10G45/02 , C10G47/00 , C10G65/12
CPC分类号： C10G45/02 , B01D3/141 , C10G7/00 , C10G47/00 , C10G65/043 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/202 , C10G2300/304 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2400/04 , Y02P30/20
摘要： A divided wall column allows for fractionation of multiple streams while maintaining separate product qualities. Effluents from multiple stages of a reaction system can be processed in a single divided wall column. The divided wall column can produce multiple cuts from each separated area, as well as at least one output from a common area.
摘要翻译：分隔壁柱允许分离多个流，同时保持单独的产品质量。来自反应体系的多个阶段的流出物可以在单个分隔壁塔中进行处理。分隔壁柱可以从每个分离的区域产生多个切割，以及从公共区域产生至少一个输出。

7. 发明授权

US08557106B2 Hydrocracking process selective for improved distillate and improved lube yield and properties 有权
标题翻译：加氢裂化过程选择性改善馏出物和改善润滑油产量和性能
公开(公告)号：US08557106B2
公开(公告)日：2013-10-15
申请号：US13237361
申请日：2011-09-20
申请人： William J. Novak , Robert A. Bradway , Stuart S. Shih , Timothy L. Hilbert , Michel Daage
发明人： William J. Novak , Robert A. Bradway , Stuart S. Shih , Timothy L. Hilbert , Michel Daage
IPC分类号： C10G47/02 , C10G45/62 , C10G45/64 , C10G45/12
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.
摘要翻译：本发明涉及一种包含进料流加氢裂化的方法，其中转化馏分可表现出相对较高的馏出物产物产率和维持或改善的馏出物燃料性质，而未转化的馏分可表现出在润滑剂区域特别有用的改进的性能。在该加氢裂化过程中，相对于转化的馏出物燃料和未转化的润滑剂，可以有利于减少或最小化汽油燃料应用的转化/未转化产物的产率。可以选择催化剂和条件以帮助实现或优化所需的产物产率和/或性能。

8. 发明申请

US20120000817A1 Production of Low Color Middle Distillate Fuels 审中-公开
标题翻译：生产低色中间馏分燃料
公开(公告)号：US20120000817A1
公开(公告)日：2012-01-05
申请号：US13169170
申请日：2011-06-27
申请人： Stuart S. Shih
发明人： Stuart S. Shih
IPC分类号： C10G49/00
CPC分类号： C10G65/04 , C10G45/10 , C10G45/12 , C10G2300/1048 , C10G2300/202 , C10G2300/301 , C10G2300/304 , C10G2300/4006 , C10G2300/4018 , C10G2400/04 , C10G2400/08
摘要： In a process for producing a low color diesel and/or kerosene fuel, a middle distillate feed can be supplied to a reactor having at least one first catalyst bed containing a first desulfurization and/or isomerization catalyst and at least one second catalyst bed containing a decolorization catalyst downstream from the first catalyst bed(s). The feed can be reacted with the hydrogen in the presence of the first catalyst at a temperature from about 290° C. to about 430° C. to produce a first liquid effluent, which can be cooled by about 10° C. to about 40° C. with a quench medium and cascaded to the at least one second catalyst bed. The cooled first liquid effluent can then be reacted with hydrogen in the presence of the decolorization catalyst at a temperature from about 280° C. to about 415° C. to produce a second effluent having an ASTM color less than 2.5.
摘要翻译：在生产低色柴油和/或煤油燃料的方法中，中间馏分料可以供给至具有至少一个含有第一脱硫和/或异构化催化剂的第一催化剂床和至少一个含有脱色催化剂从第一催化剂床下游。在约290℃至约430℃的温度下，进料可以在第一催化剂存在下与氢反应，以产生第一液体流出物，其可被冷却约10℃至约40℃ ℃，并与骤冷介质并级联至至少一个第二催化剂床。然后在约280℃至约415℃的温度下，将冷却的第一液体流出物在脱色催化剂存在下与氢气反应，以产生ASTM颜色小于2.5的第二流出物。

9. 发明授权

US5591326A Catalytic process for crude oil desalting 失效
标题翻译：原油脱盐催化过程
公开(公告)号：US5591326A
公开(公告)日：1997-01-07
申请号：US347934
申请日：1994-12-01
申请人： Stuart S. Shih
发明人： Stuart S. Shih
IPC分类号： C10G45/12 , C10G45/00
CPC分类号： C10G45/12
摘要： A catalytic desalting process for processing whole crude oils. The desalting process uses an M41S catalyst to remove salts from the whole crude. Solids may also be removed from the whole crude using a porous material having a pore size greater than about 10 microns. The catalytic desalting process does not generate waste water.
摘要翻译：一种用于加工全部原油的催化脱盐方法。脱盐方法使用M41S催化剂从整个原油中除去盐。也可以使用孔径大于约10微米的多孔材料，从整个原料中除去固体。催化脱盐过程不会产生废水。

10. 发明授权

US5451312A Catalyst and process for producing low-aromatics distillates 失效
标题翻译：用于生产低芳烃馏出物的催化剂和方法
公开(公告)号：US5451312A
公开(公告)日：1995-09-19
申请号：US143407
申请日：1993-10-26
申请人： Minas R. Apelian , Thomas F. Degnan , Stuart S. Shih
发明人： Minas R. Apelian , Thomas F. Degnan , Stuart S. Shih
IPC分类号： B01J23/58 , B01J29/04 , B01J37/00 , C10G45/54 , C10G65/08 , C10G45/12 , C10G45/52
CPC分类号： C10G45/54 , B01J29/041 , B01J37/0009
摘要： This invention provides a process for producing a distillate boiling-range hydrocarbon product which comprises hydrotreating a hydrodesulfurized aromatic, substantially dealkylated hydrocarbon feed produced by the catalytic cracking of a hydrocarbon fraction, the feed having an initial boiling point of at least 300.degree. F., an aromatic content of at least about 30 weight percent, a hydrogen content not more than about 12 weight percent and a sulfur content of not more than 5000 ppmw, in the presence of a catalyst comprising an inorganic, non-layered, porous, crystalline phase material having pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least one peak with a relative intensity of 100 at a d-spacing greater than about 18 .ANG., said material containing at least one Group VIII metal and less than 5000 ppm Na, said process being carried out at a hydrogen partial pressure of not more than 1000 psig to evolve product containing less than about 10 weight percent aromatics and less than 300 ppmw sulfur at a 390.degree. F.+ feed conversion of less than about 30 weight percent.
摘要翻译：本发明提供了一种生产馏出物沸点烃产物的方法，该方法包括加氢处理通过烃馏分的催化裂化产生的加氢脱硫的芳族，基本上脱烷基化的烃进料，该原料的起始沸点至少为300°F，在包含无机，非层状，多孔的结晶相的催化剂存在下，至少约30重量％的芳族含量，不超过约12重量％的氢含量和不大于5000ppmw的硫含量具有直径至少约为13的孔的材料，并且在煅烧后表现出具有至少一个在d-间距大于约18的相对强度为100的峰的X射线衍射图，所述材料至少包含一个Ⅷ族金属和小于5000ppm的Na，所述方法在不超过1000psig的氢分压下进行，以产生pr 含量小于约10重量％的芳族化合物和小于300ppmw的硫在390°F +进料转化率小于约30重量％。

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