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    • 2. 发明授权
    • Dyes of the coumarin series
    • 香豆素系列染料
    • US4055568A
    • 1977-10-25
    • US693187
    • 1976-06-07
    • Manfred PatschChristos Vamvakaris
    • Manfred PatschChristos Vamvakaris
    • C09B57/02D06P1/16D06P5/28C07D419/00
    • C09B57/02D06P5/006
    • Dyes of the formula: ##STR1## in which Z is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, aryl or heteroaryl or a radical of the formula ##STR2## Z.sup.1, Z.sup.2, Z.sup.3 and Z.sup.4 are hydrogen or unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl;Z.sup.1 and Z.sup.2 or Z.sup.3 and Z.sup.4 may together with the nitrogen form a heterocyclic ring;Z.sup.1 and Z.sup.2 together with the nitrogen may be a saturated unsubstituted or substituted 5-membered or 6-membered ring condensed on in the ortho-position to the nitrogen;B is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl, aryl or heteroaryl; andX is imino or oxygen.The dyes give brilliant yellow dyeings having good fastness properties on textile materials, particularly polyester materials, and in plastics.
    • 式(I)其中Z是未取代或取代的烷基,烯基,环烷基,芳烷基,芳基或杂芳基或下式的基团的化合物:其中Z 1,Z 2,Z 3和Z 4的基团是氢或未取代的或未取代的 取代的烷基,环烷基,芳烷基或芳基; Z 1和Z 2或Z 3和Z 4可以与氮一起形成杂环; Z1和Z2与氮一起可以是在与氮原子相邻的位置上稠合的饱和的未取代或取代的5元或6元环; B是未取代或取代的烷基,烯基,环烷基,芳烷基,芳基或杂芳基; X是亚氨基或氧。
    • 3. 发明授权
    • Thiazole containing coumarin compounds
    • 噻唑含香豆素化合物
    • US4404389A
    • 1983-09-13
    • US403118
    • 1982-07-29
    • Christos VamvakarisManfred PatschWolfgang Mach
    • Christos VamvakarisManfred PatschWolfgang Mach
    • C09B57/02D06P1/90D06P3/60D06P5/28C07D417/04
    • D06P1/908C09B57/02D06P3/6041D06P5/006
    • Compounds of the general formula I ##STR1## where B.sup.2 and B.sup.2 independently of one another are hydrogen, C.sub.1 -C.sub.6 -alkyl which may or may not be interrupted by oxygen or sulfur and is unsubstituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylmercapto, cyano, phenylmercapto (which is unsubstituted by chorine or methyl), unsubstituted or substituted carbamoyl or a carboxylic acid ester group, benzyl or phenylethyl which are unsubstituted or substituted in the ring by chlorine, bromine, methyl, ethyl, methoxy or ethoxy, phenyl which is unsubstituted or substituted by chlorine, bromine, hydroxyl, methoxy, ethoxy, methyl, C.sub.1 -C.sub.4 -alkylmercapto, C.sub.1 -C.sub.4 -alkanoylamino or amino, unsubstituted or substituted carbamoyl or a carboxylic acid ester group,B.sup.2 may in addition be cyano, C.sub.2 -C.sub.4 -alkanoyl, benzoyl which is unsubstituted or substituted by chlorine, methyl, methoxy or ethoxy, C.sub.1 -C.sub.6 -alkylsulfonyl, or phenylsulfonyl, which is unsubstituted or substituted by chlorine, bromine, methyl, methoxy, ethoxy, amino, C.sub.1 -C.sub.4 -alkanoylamino, C.sub.1 -C.sub.4 -alkylsulfonyl or benzoylamino,B.sup.1 and B.sup.2 together may also be a saturated 5-membered or 6-membered ring which may or may not contain oxygen or sulfur,X is oxygen or imino andthe ring A may be substituted.Such compounds are outstandingly suitable for dyeing synthetic fibers and plastics.
    • 其中B2和B2彼此独立的通式I的化合物是氢,可被或不被氧或硫中断的未被羟基取代的C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C4 - 烷基巯基,氰基,苯基巯基(未被氯或甲基取代),未取代或取代的氨基甲酰基或羧酸酯基,未被取代或被环取代的氯,溴,甲基,乙基,甲氧基 或乙氧基,未被取代或被氯,溴,羟基,甲氧基,乙氧基,甲基,C1-C4烷基巯基,C1-C4-烷酰基氨基或氨基,未取代或取代的氨基甲酰基或羧酸酯基取代的苯基,B2可以 氰基,C 2 -C 4烷酰基,未被取代或被氯,甲基,甲氧基或乙氧基取代的苯甲酰基,未被取代或被氯,溴,甲基,甲氧基,乙氧基, 氨基, C1-C4-烷酰基氨基,C1-C4-烷基磺酰基或苯甲酰基氨基,B1和B2一起也可以是饱和的5元或6元环,其可以含有或不含氧或硫,X是氧或亚氨基,环A 可以被替代。 这种化合物非常适合于染色合成纤维和塑料。