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    • 4. 发明申请
    • POLYCARBONATE-POLYSILOXANE COPOLYMER COMPOSITIONS AND ARTICLES FORMED THEREFROM
    • 聚碳酸酯 - 聚硅氧烷共聚物组合物及其形成的制品
    • US20080081884A1
    • 2008-04-03
    • US11537056
    • 2006-09-29
    • Katherine GlasgowJan-Pleun LensBrian MullenVandita Pai-Paranjape
    • Katherine GlasgowJan-Pleun LensBrian MullenVandita Pai-Paranjape
    • C08F283/02
    • C08G77/448C08L83/10
    • A thermoplastic composition comprises a copolycarbonate comprising 25 to 100 mole percent of a first carbonate unit derived from a dihydroxy aromatic compound having the formula wherein Ra′ and Rb′ are C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4, and r and s are 1 to 4; and 0 to 75 mole percent of a second carbonate unit, wherein the first carbonate unit and second carbonate unit are not identical; a polysiloxane-polycarbonate copolymer comprising 0.15 to 30 weight percent of a polysiloxane block comprising siloxane units of the formula wherein E is on average of 4 to 60 units, and 70 to 99.85 weight percent of a third carbonate unit, wherein an article having a thickness of 3.2 mm and molded from the thermoplastic composition has a Dynatup total energy of greater than 50 Joules, as measured at a constant speed of 3.3 to 3.6 m/sec at 23° C. according to ASTM D3763-02. A method of making and articles prepared therefrom are also disclosed.
    • 热塑性组合物包含共聚碳酸酯,其包含25至100摩尔%的衍生自具有下式的二羟基芳族化合物的第一碳酸酯单元,其中R a a'和R b'均为C C 1-12烷基,T是C 5-16亚烷基,C 5-16亚烷基,C 1-5 亚烷基,C 1-5亚烷基,C 6-13亚芳基,C 7-12芳基亚烷基,C 1 -C 6亚烷基, C 7-12芳基亚烷基,C 7-12烷基亚芳基或C 7-12亚芳基烷基,r和s各自独立地为1至4个 ,r和s为1〜4; 和0至75摩尔%的第二碳酸酯单元,其中所述第一碳酸酯单元和第二碳酸酯单元不相同; 聚硅氧烷 - 聚碳酸酯共聚物,其包含0.15至30重量%的包含下式的硅氧烷单元的聚硅氧烷嵌段,其中E平均为4至60个单元,和70至99.85重量%的第三个碳酸酯单元,其中具有厚度 根据ASTM D3763-02,由热塑性组合物模塑的Dynatup总能量大于50焦耳,其在23℃下以3.3至3.6m /秒的恒定速度测量。 还公开了一种制备方法和由其制备的制品。
    • 5. 发明授权
    • Polycarbonate-polysiloxane copolymer compositions and articles formed therefrom
    • 聚碳酸酯 - 聚硅氧烷共聚物组合物和由其形成的制品
    • US07709581B2
    • 2010-05-04
    • US11537056
    • 2006-09-29
    • Katherine GlasgowJan-Pleun LensBrian MullenVandita Pai-Paranjape
    • Katherine GlasgowJan-Pleun LensBrian MullenVandita Pai-Paranjape
    • C08L69/00C08G81/00
    • C08G77/448C08L83/10
    • A thermoplastic composition comprises a copolycarbonate comprising 25 to 100 mole percent of a first carbonate unit derived from a dihydroxy aromatic compound having the formula wherein Ra′ and Rb′ are C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4, and r and s are 1 to 4; and 0 to 75 mole percent of a second carbonate unit, wherein the first carbonate unit and second carbonate unit are not identical; a polysiloxane-polycarbonate copolymer comprising 0.15 to 30 weight percent of a polysiloxane block comprising siloxane units of the formula wherein E is on average of 4 to 60 units, and 70 to 99.85 weight percent of a third carbonate unit, wherein an article having a thickness of 3.2 mm and molded from the thermoplastic composition has a Dynatup total energy of greater than 50 Joules, as measured at a constant speed of 3.3 to 3.6 m/sec at 23° C. according to ASTM D3763-02. A method of making and articles prepared therefrom are also disclosed.
    • 热塑性组合物包括共聚碳酸酯,其包含25至100摩尔%的衍生自具有下式的二羟基芳族化合物的第一碳酸酯单元:其中R a'和R b'为C 1-12烷基,T为C 5-6亚环烷基,C 5-16 C 1 -C 5亚烷基,C 1-5亚烷基,C 6-13亚芳基,C 7-12芳基亚烷基,C 7-12芳烷基亚烷基,C 7-12烷基亚芳基或C 7-12亚芳基烷基,r和s分别为 独立地1至4,r和s为1至4; 和0至75摩尔%的第二碳酸酯单元,其中所述第一碳酸酯单元和第二碳酸酯单元不相同; 聚硅氧烷 - 聚碳酸酯共聚物,其包含0.15至30重量%的包含下式的硅氧烷单元的聚硅氧烷嵌段,其中E平均为4至60个单元,和70至99.85重量%的第三个碳酸酯单元,其中具有厚度 根据ASTM D3763-02,由热塑性组合物模塑的Dynatup总能量大于50焦耳,其在23℃下以3.3至3.6m /秒的恒定速度测量。 还公开了一种制备方法和由其制备的制品。