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1. 发明申请

US20080081884A1 POLYCARBONATE-POLYSILOXANE COPOLYMER COMPOSITIONS AND ARTICLES FORMED THEREFROM 有权
标题翻译：聚碳酸酯 - 聚硅氧烷共聚物组合物及其形成的制品
公开(公告)号：US20080081884A1
公开(公告)日：2008-04-03
申请号：US11537056
申请日：2006-09-29
申请人： Katherine Glasgow , Jan-Pleun Lens , Brian Mullen , Vandita Pai-Paranjape
发明人： Katherine Glasgow , Jan-Pleun Lens , Brian Mullen , Vandita Pai-Paranjape
IPC分类号： C08F283/02
CPC分类号： C08G77/448 , C08L83/10
摘要： A thermoplastic composition comprises a copolycarbonate comprising 25 to 100 mole percent of a first carbonate unit derived from a dihydroxy aromatic compound having the formula wherein Ra′ and Rb′ are C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4, and r and s are 1 to 4; and 0 to 75 mole percent of a second carbonate unit, wherein the first carbonate unit and second carbonate unit are not identical; a polysiloxane-polycarbonate copolymer comprising 0.15 to 30 weight percent of a polysiloxane block comprising siloxane units of the formula wherein E is on average of 4 to 60 units, and 70 to 99.85 weight percent of a third carbonate unit, wherein an article having a thickness of 3.2 mm and molded from the thermoplastic composition has a Dynatup total energy of greater than 50 Joules, as measured at a constant speed of 3.3 to 3.6 m/sec at 23° C. according to ASTM D3763-02. A method of making and articles prepared therefrom are also disclosed.
摘要翻译：热塑性组合物包含共聚碳酸酯，其包含25至100摩尔％的衍生自具有下式的二羟基芳族化合物的第一碳酸酯单元，其中R a a'和R b'均为C C 1-12烷基，T是C 5-16亚烷基，C 5-16亚烷基，C 1-5 亚烷基，C 1-5亚烷基，C 6-13亚芳基，C 7-12芳基亚烷基，C 1 -C 6亚烷基， C 7-12芳基亚烷基，C 7-12烷基亚芳基或C 7-12亚芳基烷基，r和s各自独立地为1至4个，r和s为1〜4; 和0至75摩尔％的第二碳酸酯单元，其中所述第一碳酸酯单元和第二碳酸酯单元不相同; 聚硅氧烷 - 聚碳酸酯共聚物，其包含0.15至30重量％的包含下式的硅氧烷单元的聚硅氧烷嵌段，其中E平均为4至60个单元，和70至99.85重量％的第三个碳酸酯单元，其中具有厚度根据ASTM D3763-02，由热塑性组合物模塑的Dynatup总能量大于50焦耳，其在23℃下以3.3至3.6m /秒的恒定速度测量。还公开了一种制备方法和由其制备的制品。

2. 发明授权

US07709581B2 Polycarbonate-polysiloxane copolymer compositions and articles formed therefrom 有权
标题翻译：聚碳酸酯 - 聚硅氧烷共聚物组合物和由其形成的制品
公开(公告)号：US07709581B2
公开(公告)日：2010-05-04
申请号：US11537056
申请日：2006-09-29
申请人： Katherine Glasgow , Jan-Pleun Lens , Brian Mullen , Vandita Pai-Paranjape
发明人： Katherine Glasgow , Jan-Pleun Lens , Brian Mullen , Vandita Pai-Paranjape
IPC分类号： C08L69/00 , C08G81/00
CPC分类号： C08G77/448 , C08L83/10
摘要： A thermoplastic composition comprises a copolycarbonate comprising 25 to 100 mole percent of a first carbonate unit derived from a dihydroxy aromatic compound having the formula wherein Ra′ and Rb′ are C1-12 alkyl, T is a C5-16 cycloalkylene, a C5-16 cylcloalkylidene, a C1-5 alkylene, a C1-5 alkylidene, a C6-13 arylene, a C7-12 arylalkylene, C7-12 arylalkylidene, a C7-12 alkylarylene, or a C7-12 arylenealkyl, and r and s are each independently 1 to 4, and r and s are 1 to 4; and 0 to 75 mole percent of a second carbonate unit, wherein the first carbonate unit and second carbonate unit are not identical; a polysiloxane-polycarbonate copolymer comprising 0.15 to 30 weight percent of a polysiloxane block comprising siloxane units of the formula wherein E is on average of 4 to 60 units, and 70 to 99.85 weight percent of a third carbonate unit, wherein an article having a thickness of 3.2 mm and molded from the thermoplastic composition has a Dynatup total energy of greater than 50 Joules, as measured at a constant speed of 3.3 to 3.6 m/sec at 23° C. according to ASTM D3763-02. A method of making and articles prepared therefrom are also disclosed.
摘要翻译：热塑性组合物包括共聚碳酸酯，其包含25至100摩尔％的衍生自具有下式的二羟基芳族化合物的第一碳酸酯单元：其中R a'和R b'为C 1-12烷基，T为C 5-6亚环烷基，C 5-16 C 1 -C 5亚烷基，C 1-5亚烷基，C 6-13亚芳基，C 7-12芳基亚烷基，C 7-12芳烷基亚烷基，C 7-12烷基亚芳基或C 7-12亚芳基烷基，r和s分别为独立地1至4，r和s为1至4; 和0至75摩尔％的第二碳酸酯单元，其中所述第一碳酸酯单元和第二碳酸酯单元不相同; 聚硅氧烷 - 聚碳酸酯共聚物，其包含0.15至30重量％的包含下式的硅氧烷单元的聚硅氧烷嵌段，其中E平均为4至60个单元，和70至99.85重量％的第三个碳酸酯单元，其中具有厚度根据ASTM D3763-02，由热塑性组合物模塑的Dynatup总能量大于50焦耳，其在23℃下以3.3至3.6m /秒的恒定速度测量。还公开了一种制备方法和由其制备的制品。

3. 发明申请

US20070100038A1 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
公开(公告)号：US20070100038A1
公开(公告)日：2007-05-03
申请号：US11263325
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： C08K5/41
CPC分类号： C08J3/226 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprises a polycarbonate, and an aromatic sulfonate compound of formula (Y)m—Ar-(Z-S(O)2—X)n wherein each X is independently a substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C1-C20 arylalkyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C7-C40 alkylaryl; Z is —O—, or substituted or unsubstituted —(O—C1-20—)w—O—, wherein w is 1 to 20; Ar is a C6-C62 aromatic group; m is 0-3 and n is 3-6; and each Y is independently C1-C20 alkyl, substituted C1-C20 alkyl, C6-C20 aryl, C1-C8 alkyl-substituted C6-C20 aryl, halogen, nitro, C1-C20 alkoxycarbonyl, C1-C20 alkoxy, or C1-C20 acyl, and further wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, aromatic sulfonate compound, and an effective amount of each of a mold-release agent and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.

4. 发明申请

US20070082989A1 Stabilized thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：稳定的热塑性组合物，制造方法和由其形成的制品
公开(公告)号：US20070082989A1
公开(公告)日：2007-04-12
申请号：US11246651
申请日：2005-10-07
申请人： Katherine Glasgow , Brian Mullen , Matthew Pixton , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Matthew Pixton , Philippe Schottland
IPC分类号： C08K5/00
CPC分类号： C08K5/109 , C08L69/00
摘要： A thermoplastic composition comprises a polycarbonate, an ionizing radiation stabilizing additive, and a poly-substituted aromatic compound of formula: wherein X is an aryl group; Y is a non-hydrogen substituent group, a is 1 to 4, b is 0 to 4, a+b is less than or equal to 4, and c is 0 or 1; and wherein the amounts and identities of the polycarbonate, ionizing radiation stabilizing additive, and poly-substituted aromatic compound are selected such that a molded article having a thickness of 3.18 millimeters and comprising the thermoplastic composition has, after exposure to gamma radiation at 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 50, when compared to the unexposed thermoplastic composition.
摘要翻译：热塑性组合物包含聚碳酸酯，电离辐射稳定添加剂和下式的多取代芳族化合物：其中X是芳基; Y是非氢取代基，a是1至4，b是0至4，a + b小于或等于4，c是0或1; 并且其中选择聚碳酸酯，电离辐射稳定添加剂和多取代芳族化合物的量和身份，使得具有3.18毫米厚度且包含该热塑性组合物的模塑制品在暴露于83kGy的γ辐射之后，以及当根据ASTM D1925-70测量时，与未曝光的热塑性组合物相比，黄度指数（dYI）的增加小于或等于50。

5. 发明授权

US07511092B2 Stabilized thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：稳定的热塑性组合物，制造方法和由其形成的制品
公开(公告)号：US07511092B2
公开(公告)日：2009-03-31
申请号：US11246651
申请日：2005-10-07
申请人： Katherine Glasgow , Brian Mullen , Matthew Robert Pixton , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Matthew Robert Pixton , Philippe Schottland
IPC分类号： C08K5/10
CPC分类号： C08K5/109 , C08L69/00
摘要： A thermoplastic composition comprises a polycarbonate, an ionizing radiation stabilizing additive, and a poly-substituted aromatic compound of formula: wherein X is an aryl group; Y is a non-hydrogen substituent group, a is 1 to 4, b is 0 to 4, a+b is less than or equal to 4, and c is 0 or 1; and wherein the amounts and identities of the polycarbonate, ionizing radiation stabilizing additive, and poly-substituted aromatic compound are selected such that a molded article having a thickness of 3.18 millimeters and comprising the thermoplastic composition has, after exposure to gamma radiation at 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 50, when compared to the unexposed thermoplastic composition.
摘要翻译：热塑性组合物包含聚碳酸酯，电离辐射稳定添加剂和下式的多取代芳族化合物：其中X是芳基; Y是非氢取代基，a是1至4，b是0至4，a + b小于或等于4，c是0或1; 并且其中选择聚碳酸酯，电离辐射稳定添加剂和多取代芳族化合物的量和身份，使得具有3.18毫米厚度且包含该热塑性组合物的模塑制品在暴露于83kGy的γ辐射之后，以及当根据ASTM D1925-70测量时，与未曝光的热塑性组合物相比，黄度指数（dYI）的增加小于或等于50。

6. 发明授权

US07321014B2 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US07321014B2
公开(公告)日：2008-01-22
申请号：US11025249
申请日：2004-12-29
申请人： Katherine Glasgow , Brian Mullen , Paul D. Sybert
发明人： Katherine Glasgow , Brian Mullen , Paul D. Sybert
IPC分类号： C08L69/00 , C08L83/10
CPC分类号： C08L83/10 , C08G63/64 , C08G77/445 , C08G77/448
摘要： A thermoplastic composition is disclosed, comprising the reaction product of: a polyester polycarbonate comprising a polyester unit and a polycarbonate unit; a polysiloxane polycarbonate copolymer having a haze of 30% or less, comprising a polycarbonate unit and a polysiloxane unit; and a transesterification catalyst. The resulting thermoplastic composition has a haze of 30% or less as measured according to ASTM D1003-00 at a thickness of 3.2 millimeters. A method of forming the composition and articles formed from the composition are also disclosed.
摘要翻译：公开了一种热塑性组合物，其包含以下反应产物：包含聚酯单元和聚碳酸酯单元的聚酯聚碳酸酯; 具有30％以下的雾度的聚硅氧烷聚碳酸酯共聚物，其包含聚碳酸酯单元和聚硅氧烷单元; 和酯交换催化剂。所得热塑性组合物的雾度为30％以下，根据ASTM D1003-00测定，厚度为3.2毫米。还公开了形成由组合物形成的组合物和制品的方法。

7. 发明授权

US07812078B2 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：电离辐射稳定的热塑性组合物，制备方法和由其形成的制品
公开(公告)号：US07812078B2
公开(公告)日：2010-10-12
申请号：US11263325
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： C08K5/42
CPC分类号： C08J3/226 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprises a polycarbonate, and an aromatic sulfonate compound of formula (Y)m—Ar—(Z—S(O)2—X)n wherein each X is independently a substituted or unsubstituted C1-C20 alkyl, substituted or unsubstituted C1-C20 arylalkyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C7-C40 alkylaryl; Z is —O—, or substituted or unsubstituted —(O—C1-20—)w—O—, wherein w is 1 to 20; Ar is a C6-C62 aromatic group; m is 0-3 and n is 3-6; and each Y is independently C1-C20 alkyl, substituted C1-C20 alkyl, C6-C20 aryl, C1-C8 alkyl-substituted C6-C20 aryl, halogen, nitro, C1-C20 alkoxycarbonyl, C1-C20 alkoxy, or C1-C20 acyl, and further wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, aromatic sulfonate compound, and an effective amount of each of a mold-release agent and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
摘要翻译：热塑性组合物包含聚碳酸酯和式（Y）m-Ar-（Z-S（O）2-X）n的芳族磺酸盐化合物，其中每个X独立地为取代或未取代的C 1 -C 20烷基，取代或未取代的 C 1 -C 20芳烷基，取代或未取代的C 6 -C 20芳基或取代或未取代的C 7 -C 40烷基芳基; Z是-O-或取代或未取代的 - （O-C 1-20 - ）w -O-，其中w是1至20; Ar为C6-C62芳族基团; m为0-3，n为3-6; 并且每个Y独立地为C 1 -C 20烷基，取代的C 1 -C 20烷基，C 6 -C 20芳基，C 1 -C 8烷基取代的C 6 -C 20芳基，卤素，硝基，C 1 -C 20烷氧基羰基，C 1 -C 20烷氧基或C 1 -C 20 酰基，并且其中由曝露于总γ辐射之后，由聚碳酸酯，芳族磺酸盐化合物和有效量的脱模剂和抗氧化剂组成的厚度为3.2±0.12毫米的模塑制品剂量为83kGy，当根据ASTM D1925-70测量时，与未曝光的模制品相比，黄度指数（dYI）的增加小于或等于45。还公开了制备热塑性组合物的方法及其制备的制品。

8. 发明授权

US07649039B2 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：电离辐射稳定的热塑性组合物，制备方法和由其形成的制品
公开(公告)号：US07649039B2
公开(公告)日：2010-01-19
申请号：US11263372
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： C08K5/42
CPC分类号： C08K5/0008 , C08J3/226 , C08J2369/00 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprising a polycarbonate, and an aromatic sulfonate compound of formula: Ar1—S(O)2—O—L—O—S(O)2—Ar1 wherein each Ar1 is each independently a substituted or unsubstituted C6-20 aryl group, and L is a branched, substituted or unsubstituted divalent aliphatic hydrocarbon, wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
摘要翻译：一种热塑性组合物，其包含聚碳酸酯和下式的芳族磺酸盐化合物：Ar1-S（O）2 -OROS（O）2 -Ar1，其中各Ar1各自独立地为取代或未取代的C6-20芳基，L为支链的，取代的或未取代的二价脂族烃，其中由聚碳酸酯，芳族磺酸盐化合物和有效量的脂肪族二醇，脱模剂和抗氧化剂在暴露于83kGy的总伽马辐射剂量之后，当根据ASTM D1925-70测量时，与未曝光的模塑制品相比，黄色指数（dYI）的增加小于或等于45。还公开了制备热塑性组合物的方法及其制备的制品。

9. 发明申请

US20070100021A1 Ionizing radiation stable thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：电离辐射稳定的热塑性组合物，制备方法和由其形成的制品
公开(公告)号：US20070100021A1
公开(公告)日：2007-05-03
申请号：US11263372
申请日：2005-10-31
申请人： Katherine Glasgow , Brian Mullen , Philippe Schottland
发明人： Katherine Glasgow , Brian Mullen , Philippe Schottland
IPC分类号： G21F1/10
CPC分类号： C08K5/0008 , C08J3/226 , C08J2369/00 , C08J2469/00 , C08K5/42 , C08L69/00
摘要： A thermoplastic composition comprising a polycarbonate, and an aromatic sulfonate compound of formula: Ar1—S(O)2—O-L-O—S(O)2—Ar1 wherein each Ar1 is each independently a substituted or unsubstituted C6-20 aryl group, and L is a branched, substituted or unsubstituted divalent aliphatic hydrocarbon, wherein a molded article having a thickness of 3.2±0.12 millimeters and consisting of the polycarbonate, the aromatic sulfonate compound, and an effective amount of each of an aliphatic diol, a mold release agent, and an antioxidant has, after exposure to a total gamma radiation dose of 83 kGy and when measured according to ASTM D1925-70, an increase in yellowness index (dYI) of less than or equal to 45, when compared to the unexposed molded article. Methods of making the thermoplastic composition, and articles prepared therefrom, are also disclosed.
摘要翻译：一种热塑性组合物，其包含聚碳酸酯和下式的芳香族磺酸酯化合物：＆lt;？in-line-formula description =“In-line formula”end =“lead”？> Ar < ）2-in-line-formula description =“In-line Formulas”end =“ 其中每个Ar 1各自独立地是取代或未取代的C 6-20芳基，L是支链，取代或未取代的二价脂族烃，其中由聚碳酸酯，芳族磺酸盐化合物和有效量的脂肪族二醇，脱模剂和抗氧化剂组成的厚度为3.2±0.12毫米的模制品在暴露于总伽马辐射之后剂量为83kGy，当根据ASTM D1925-70测量时，与未曝光的模制品相比，黄度指数（dYI）的增加小于或等于45。还公开了制备热塑性组合物的方法及其制备的制品。

10. 发明申请

US20060142527A1 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US20060142527A1
公开(公告)日：2006-06-29
申请号：US11025249
申请日：2004-12-29
申请人： Katherine Glasgow , Brian Mullen , Paul Sybert
发明人： Katherine Glasgow , Brian Mullen , Paul Sybert
IPC分类号： C08G77/04 , C08G77/06 , C08L83/04
CPC分类号： C08L83/10 , C08G63/64 , C08G77/445 , C08G77/448
摘要： A thermoplastic composition is disclosed, comprising the reaction product of: a polyester polycarbonate comprising a polyester unit and a polycarbonate unit; a polysiloxane polycarbonate copolymer having a haze of 30% or less, comprising a polycarbonate unit and a polysiloxane unit; and a transesterification catalyst. The resulting thermoplastic composition has a haze of 30% or less as measured according to ASTM D1003-00 at a thickness of 3.2 millimeters. A method of forming the composition and articles formed from the composition are also disclosed.
摘要翻译：公开了一种热塑性组合物，其包含以下反应产物：包含聚酯单元和聚碳酸酯单元的聚酯聚碳酸酯; 具有30％以下的雾度的聚硅氧烷聚碳酸酯共聚物，其包含聚碳酸酯单元和聚硅氧烷单元; 和酯交换催化剂。所得热塑性组合物的雾度为30％以下，根据ASTM D1003-00测定，厚度为3.2毫米。还公开了形成由组合物形成的组合物和制品的方法。

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