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1. 发明授权

US4772624A 1,4-bis-substituted-2,6,7-trioxabicyclo(2.2.2)-octanes having ethynyl substituted phenyl group 失效
标题翻译：具有乙炔基取代的苯基的1,4-双 - 取代-2,6,7-三氧杂双环（2.2.2） - 辛烷
公开(公告)号：US4772624A
公开(公告)日：1988-09-20
申请号：US779167
申请日：1985-09-23
申请人： Christopher J. Palmer , John E. Casida
发明人： Christopher J. Palmer , John E. Casida
IPC分类号： A01N43/90 , A01N55/00 , C07D493/08 , C07D497/08 , C07F7/08 , A01N43/32 , C07D323/04
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07D497/08 , C07F7/0812 , C09K2019/3425
摘要： A compound of the formula ##STR1## wherein R is C.sub.3 -C.sub.10 normal- or branched- alkyl or cycloalkyl, C.sub.3 -C.sub.10 normal- or branched- alkyl or cycloalkyl having one or more halogen, cyano, C.sub.1 -C.sub.2 partially or completely halogenated alkyl, or C.sub.1 -C.sub.3 alkoxy or partially or completely halogenated alkoxy substituents, C.sub.3 -C.sub.10 cycloalkyl having C.sub.1 -C.sub.2 alkyl substituents, phenyl, or phenyl having one or more halogen, cyano, nitro, ethynl, C.sub.1 -C.sub.2 alkyl or partially or completely halogenated alkyl, or C.sub.1 -C.sub.3 alkoxy or partially or completely halogenated alkoxy substituents; wherein at least one of R.sub.2 -R.sub.6 is ethynyl; and wherein the remainder of R.sub.2 -R.sub.6 are independently either hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, partially or completely halogenated C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.3 alkoxy, partially or completely halogenated C.sub.1 -C.sub.3 alkoxy, ethynyl, nitro, cyano, or azido. Such a compound is useful in killing pests, particularly insects.
摘要翻译：其中R是具有一个或多个卤素，氰基，C 1 -C 2部分或完全卤代烷基的C 3 -C 10正或支链烷基或环烷基，C 3 -C 10正链或支链烷基或环烷基的化合物，或C 1 -C 3烷氧基或部分或完全卤化的烷氧基取代基，具有C 1 -C 2烷基取代基的C 3 -C 10环烷基，苯基或具有一个或多个卤素，氰基，硝基，乙炔基，C 1 -C 2烷基或部分或完全卤化的苯基烷基或C 1 -C 3烷氧基或部分或完全卤化的烷氧基取代基; 其中R 2 -R 6中的至少一个是乙炔基; 部分或完全卤化的C 1 -C 2烷基，C 1 -C 3烷氧基，部分或完全卤化的C 1 -C 3烷氧基，乙炔基，硝基，氰基或叠氮这种化合物可用于杀死害虫，特别是昆虫。

2. 发明授权

US4876274A New class of pesticides comprising 1,4-bis-substituted-2,6,7-trioxabicyclo(2.2.2)octanes 失效
标题翻译：含有1,4-双取代-2,6,7-三氧杂双环（2.2.2）辛烷的新一类农药
公开(公告)号：US4876274A
公开(公告)日：1989-10-24
申请号：US902083
申请日：1986-08-27
申请人： Christopher J. Palmer , John E. Casida
发明人： Christopher J. Palmer , John E. Casida
IPC分类号： A01N43/90 , C07D493/08
CPC分类号： C07D493/08 , A01N43/90
摘要： A pesticidal composition comprising a compound having the formula R--C(CH.sub.2 O).sub.3 C--X wherein R and X are each organic substituents and wherein the compound has an LD.sub.50, in micrograms of compound per gram of body weight of a selected pest, of less than about 400 and/or an LD.sub.50 in the presence of synergist of less than about 20 is disclosed along with its use in killing pests. Pesticidal activity has been found against a broad range of types of insects. The pesticidal activity of the composition is strongly enhanced by the use of a selected synergist.
摘要翻译：一种农药组合物，其包含具有式RC（CH 2 O）3 C-X的化合物，其中R和X各自是有机取代基，并且其中所述化合物具有LD50，以每克体重的所选有害生物的微克化合物的小于约在小于约20的增效剂存在下，400和/或LD 50以及其在杀虫中的应用被公开。针对广泛类型的昆虫已经发现杀虫活性。组合物的杀虫活性通过使用所选择的增效剂强烈增强。

3. 发明授权

US5204333A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US5204333A
公开(公告)日：1993-04-20
申请号：US839685
申请日：1992-02-24
申请人： John P. Larkin , John B. Weston , Ian H. Smith , Christopher J. Palmer , John E. Casida
发明人： John P. Larkin , John B. Weston , Ian H. Smith , Christopher J. Palmer , John E. Casida
IPC分类号： A01N43/90 , A01N55/00 , C07D493/08 , C07D495/08 , C07D497/08
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07D495/08 , C07D497/08
摘要： The present invention provides compounds of the formula (I): ##STR1## wherein R is a phenyl group, substituted fluorine atoms formulations containing them and their use in controlling pest infestation.
摘要翻译：本发明提供式（I）化合物：其中R是苯基，含有它们的取代氟原子制剂及其在防治害虫侵袭中的用途。

4. 发明授权

US5057508A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US5057508A
公开(公告)日：1991-10-15
申请号：US481616
申请日：1990-02-20
申请人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
发明人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
IPC分类号： A01N43/90 , A01N55/00 , C07D493/08 , C07D497/08 , C07F7/08
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07D497/08 , C07F7/0812
摘要： Bicyclo-[2,2,1]-heptanes, bicyclo-[2,2,2]-octanes and bicyclo[2,2,3]-nonanes having 2 or 3 ring hetero atoms selected from O, S and N, substituted at the 1-position by a 4-alkynylphenyl group and at the 4-position and optionally at the 3 and/or 5-position are valuable pesticides, particularly insecticides and acaracides. The compounds may be prepared by reacting an alkyne with the corresponding 4-iodophenyl substituted compound or by debromination of the corresponding 4-dibromomethylphenyl substituted compound.
摘要翻译：具有2或3个选自O，S和N的环杂原子的双环 - [2,2,1] - 庚烷，双环 - [2,2,2] - 辛烷和双环[2,2,3] - 壬烷取代在4-位炔基苯基在1-位，在4-位和任选地在3和/或5位上是有价值的农药，特别是杀虫剂和吖啶。化合物可以通过使炔与相应的4-碘苯基取代的化合物反应或通过相应的4-二溴甲基苯基取代的化合物的脱溴来制备。

5. 发明授权

US5061726A Alkynylphenyl-substituted 1,3-oxathione compounds with pesticidal activity 失效
标题翻译：具有杀虫活性的炔基苯基取代的1,3-氧硫基化合物
公开(公告)号：US5061726A
公开(公告)日：1991-10-29
申请号：US514011
申请日：1990-04-26
申请人： Christopher J. Palmer , John E. Casida , John P. Larkin
发明人： Christopher J. Palmer , John E. Casida , John P. Larkin
IPC分类号： A01N43/32 , C07D327/06
CPC分类号： C07D327/06 , A01N43/32
摘要： Pesticidally-active alkynylphenyl-substituted 1,3-oxathianes and related substituted compounds of the formula: ##STR1## and their use in controlling pests such as arthropods and helminths are described.
摘要翻译：描述了农药活性炔基苯基取代的1,3-氧硫杂环己烷和下式的相关取代的化合物及其在控制害虫如节肢动物和蠕虫中的用途。

6. 发明授权

US4965257A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US4965257A
公开(公告)日：1990-10-23
申请号：US384067
申请日：1989-07-24
申请人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
发明人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
IPC分类号： A01N43/90 , A01N55/00 , C07D493/08 , C07D497/08 , C07F7/08
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07D497/08 , C07F7/0812
摘要： Bicyclo-[2,2,1]-heptanes, bicyclo-[2,2,2]-octanes and bicyclo-[2,2,3]-nonanes, having 2 or 3 ring hetero atoms selected from O, S and N, substituted at the 1-position by a 4-alkynylphenyl group and at the 4-position and optionally at the 3 and/or 5-position are valuable pesticides, particularly insecticides and acaracides. The compounds may be prepared by reacting an alkyne with the corresponding 4-iodophenyl substituted compounds or by debromination of the corresponding 4-dibromomethylphenyl substituted compound.
摘要翻译：具有2或3个选自O，S和N的环杂原子的双环 - [2,2,1]庚烷，双环 - [2,2,2] - 辛烷和双环 - [2,2,3] - 壬烷在4-位被4-炔基苯基取代，在4位和任选在3位和/或5位被取代是有价值的农药，特别是杀虫剂和吖啶。化合物可以通过使炔与相应的4-碘苯基取代的化合物反应或通过相应的4-二溴甲基苯基取代的化合物的脱溴来制备。

7. 发明授权

US4942173A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US4942173A
公开(公告)日：1990-07-17
申请号：US315247
申请日：1989-02-24
申请人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
发明人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
IPC分类号： A01N43/90 , A01N55/00 , C07C43/13 , C07D493/08 , C07F7/08
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07C43/13 , C07F7/0812
摘要： The present invention relates to a compound of the formula (I): ##STR1## wherein R is C.sub.2-10 alkyl, alkenyl or alkynyl, each optionally substituted by or methyl substituted by cyano, C.sub.3-4 cycloalkyl, halo, C.sub.1-4 alkoxy or a group S(O)m R.sup.4 where R.sup.4 is C.sub.1-4 alkyl and m is 0, 1 or 2, or Ris C.sub.3-10 cycloalkyl, C.sub.4-10 cycloalkenyl or phenyl, each optionally substituted by C.sub.1-4 alkoxy, C.sub.1-3 alkyl, C.sub.2-4 alkynyl, halo, cyano or a group S(O)m R.sup.4 as defined hereinbefore; R.sup.1 is halo, C.sub.1-3 alkyl, C.sub.2-3 alkenyl or alkynyl each optionally substituted by halo, cyano, C.sub.1-4 alkoxy, alkyl carbalkoxy containing up to 6 carbon atoms, a group S(O)m R.sup.4 as defined hereinbefore or alkynyl substituted by tri-C.sub.1-4 alkylsilyl, or R.sup.1 is cyano, spiro-cyclopropyl, gem dimethyl, gem dicyano, gem diethynyl, oxo or methylene optionally substituted by cyano of C.sub.1-3 alkyl optionally substituted by fluorine, or R.sup.1 and R and the carbon atoms to which they are attached form a C.sub.5-7 carbocyclic ring optionally substituted by halo, C.sub.1-3 alkyl or alkoxy or C.sub.2-3 alkenyl, R.sup.2 is phenyl substituted by an C.sub.2-3 alkynyl group or by a tri-C.sub.1-4 alkylsilylalkynyl group and R.sup.3 is hydrogen, C.sub.1-3 alkyl, C.sub.2-3 alkenyl or alkynyl each optionally substituted by cyano, C.sub.1-4 alkylthio, C.sub.1-4 alkoxy or halo, or R.sup.3 is cyano or halo, its use in medicine, pharmaceutical compositions containing it and its preparation.
摘要翻译：本发明涉及式（I）的化合物：其中R为C 2-10烷基，烯基或炔基，各自任选被被氰基取代的甲基，C 3-4的环烷基，卤素，C 1 -4-烷氧基或基团S（O）m R 4，其中R 4是C 1-4烷基，m是0,1或2，或者R 3为C 3-10环烷基，C 4-10环烯基或苯基，各自任选被C 1-4烷氧基，C 1-3烷基，C 2-4炔基，卤素，氰基或如上所定义的基团S（O）m R 4; R 1为卤素，C 1-3烷基，任选被卤素，氰基，C 1-4烷氧基，含有至多6个碳原子的烷基烷氧基取代的C 2-3烯基或炔基，如上所定义的基团S（O）m R 4或炔基被三-C 1-4烷基甲硅烷基取代，或R 1是氰基，螺环丙基，二甲基，双环戊二烯，偕二乙炔基，氧代或亚甲基，任选被氰基任选被氟取代的C 1-3烷基取代，或R 1和R，它们连接的碳原子形成任选被卤素，C 1-3烷基或烷氧基或C 2-3烯基取代的C 5-7碳环，R 2是被C 2-3炔基取代的苯基或被三-C 1-4 烷基甲硅烷基炔基和R3是氢，C1-3烷基，C2-3烯基或炔基，各自任选被氰基，C1-4烷硫基，C1-4烷氧基或卤素取代，或R3是氰基或卤素，其用于医药，药物组合物包含它及其准备。

8. 发明授权

US5371075A Trithiabicyclo[2,2,2]octanes 失效
标题翻译：三硫杂双环[2,2,2]辛烷
公开(公告)号：US5371075A
公开(公告)日：1994-12-06
申请号：US921056
申请日：1992-07-29
申请人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
发明人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
IPC分类号： A01N43/90 , A01N55/00 , C07D493/08 , C07D497/08 , C07F7/08 , A61K31/655
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07D497/08 , C07F7/0812
摘要： Bicyclo-[2,2,1]-heptanes, bicyclo-[2,2,2,]-octanes and bicyclo-[2,2,3]-nonanes having 2 or 3 ring hetero atoms selected from O, S and N, substituted at the 1-position by a 4-alkynylphenyl group and at the 4-position and optionally at the 3 and/or 5-position are valuable pesticides, particularly insecticides and acaracides. The compounds may be prepared by reacting an alkyne with the corresponding 4-iodophenyl substituted compound or by debromination of the corresponding 4-dibromomethylphenyl substituted compound.
摘要翻译：具有2或3个选自O，S和N的环杂原子的双环 - [2,2,1] - 庚烷，双环 - [2,2,2] - 辛烷和双环 - [2,2,3] - 壬烷在4-位被4-炔基苯基取代，在4位和任选在3位和/或5位被取代是有价值的农药，特别是杀虫剂和吖啶。化合物可以通过使炔与相应的4-碘苯基取代的化合物反应或通过相应的4-二溴甲基苯基取代的化合物的脱溴来制备。

9. 发明授权

US5157029A Pesticidal compounds 失效
标题翻译：杀虫化合物
公开(公告)号：US5157029A
公开(公告)日：1992-10-20
申请号：US739842
申请日：1991-08-02
申请人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
发明人： John E. Casida , Christopher J. Palmer , John P. Larkin , Ian H. Smith
IPC分类号： A01N43/90 , A01N55/00 , C07D493/08 , C07D497/08 , C07F7/08
CPC分类号： C07D493/08 , A01N43/90 , A01N55/00 , C07D497/08 , C07F7/0812
摘要： Bicyclo-[2,2,1]-heptanes, bicyclo-[2,2,2]-octanes and bicyclo-[2,2,3]-nonanes having 2 or 3 ring hetero atoms selected from O, S and N, substituted at the 1-position by a 4-alkynylphenyl group and at the 4-position and optionally at the 3 and/or 5-position are valuable pesticides, particularly insecticides and acaracides. The compounds may be prepared by reacting an alkyne with the corresponding 4-iodophenyl substituted compound or by debromination of the corresponding 4-dibromomethylphenyl substituted compound.
摘要翻译：具有2或3个选自O，S和N的环杂原子的双环 - [2,2,1] - 庚烷，双环 - [2,2,2] - 辛烷和双环 - [2,2,3] 在4-位被4-炔基苯基取代，4-位和任选在3和/或5位是有价值的杀虫剂，特别是杀虫剂和杀螨剂。化合物可以通过使炔与相应的4-碘苯基取代的化合物反应或通过相应的4-二溴甲基苯基取代的化合物的脱溴来制备。

10. 发明授权

US5033537A Heat exchanger with flow passages which deform in operation towards equalization 失效
标题翻译：具有流动通道的换热器，其在操作中变形以均衡
公开(公告)号：US5033537A
公开(公告)日：1991-07-23
申请号：US421276
申请日：1989-10-13
申请人： Howard S. Atkin , Christopher J. Palmer
发明人： Howard S. Atkin , Christopher J. Palmer
IPC分类号： F24F12/00 , F28D9/00 , F28F21/06
CPC分类号： F28D9/0087 , F24F12/001 , F28D9/0037 , F28F21/065 , Y02B30/563 , Y10S165/905 , Y10S165/906
摘要： There is disclosed an air conditioning unit for location in the wall of a room and which comprises a heat exchanger, an external supply fan operable to blow air into the room through the heat exchanger and an extract fan operable to draw air out of the room through the heat exchanger, in which the heat exchanger comprises a stack of thin flexible plates which are spaced apart from each other so as to define between opposed faces of adjacent plates extract air flow paths and supply air flow paths through the heat exchanger, with the spacing apart of the faces defining the extract air flow paths being greater than the spacing apart of the faces defining the supply air flow paths whereby the depth of the extract air flow paths initially is greater than the depth of the supply air flow paths, but during operation any tendency for the flexible plates to deform under differential pressure action results in the depths of the extract air flow paths and supply air flow paths being substantially equalized, which provides more efficient heat transfer between the air flow paths.

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