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    • 3. 发明授权
    • Method for preparing polyacryl(meth)acrylates
    • 制备聚丙烯酸(甲基)丙烯酸酯的方法
    • US06271324B1
    • 2001-08-07
    • US09297918
    • 1999-05-12
    • Stephan JünglingChristof MehlerHorst WeissSusanne SteigerAxel MüllerHelmut SchlaadBardo Schmitt
    • Stephan JünglingChristof MehlerHorst WeissSusanne SteigerAxel MüllerHelmut SchlaadBardo Schmitt
    • C08F456
    • C08F20/12C08F297/026
    • Homopolymers, copolymers or block copolymers are prepared by anionic polymerization of acrylates and/or methacrylates in the presence of an initiator composition containing A) an organic alkali metal compound, B) an organic aluminum compound and C) an additive which forms a complex with the alkali metal cation and is selected from the group consisting of open-chain ethers having at least two ether oxygen atoms, macrocyclic ethers and cryptands, or from the group consisting of quaternary cations of the general formula I  where A is N, P, As or Sb and Ra, Rb, Rc and Rd, independently of one another, are each unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl, where two neighboring radicals, together with the heteroatom A, may form a 5- or 6-membered heterocyclic structure which may contain one or two further heteroatoms selected from nitrogen, oxygen and sulfur atoms.
    • 均聚物,共聚物或嵌段共聚物通过丙烯酸酯和/或甲基丙烯酸酯在引发剂组合物的存在下的阴离子聚合制备,所述引发剂组合物包含A)有机碱金属化合物,B)有机铝化合物和C)与碱金属形成络合物的添加剂 并且选自具有至少两个醚氧原子的开链醚,大环醚和cryptands,或者由通式I的季铵阳离子组成的组,其中A是N,P,As或Sb和R a, R b,R c和R d彼此独立地为各自为未取代或取代的烷基,环烷基,芳烷基或芳基,其中两个相邻的基团与杂原子A一起可以形成可含有一个的5或6元杂环结构 或另外两个选自氮,氧和硫原子的杂原子。
    • 4. 发明授权
    • Styrene butadiene block copolymer mixtures for shrink-wrap films
    • 用于收缩膜的苯乙烯丁二烯嵌段共聚物混合物
    • US08759445B2
    • 2014-06-24
    • US13000817
    • 2009-06-23
    • Matthias MüllerKonrad KnollChristof MehlerHelmut SteiningerNorbert GüntherbergDaniel WagnerMichael SchusterGeert VerlindenFlorian Greger
    • Matthias MüllerKonrad KnollChristof MehlerHelmut SteiningerNorbert GüntherbergDaniel WagnerMichael SchusterGeert VerlindenFlorian Greger
    • C08L53/02C08F297/04
    • C08L53/02C08F297/04C08L2666/02C08L2666/24
    • A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C., c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, and d) from 0 to 6% by weight of processing aids D, where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.
    • 一种混合物,其包含a)5至95重量%的共聚物A,其包含一种或多种共聚物嵌段(B / S)A,每个共聚物嵌段(B / S)A由65至95重量%的乙烯基芳族单体和35至5重量% 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内,b)95至5重量%的嵌段共聚物B,其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯,并且包含一种或多种共聚物嵌段(B / S)A,各自由65至95重量%的乙烯基芳族单体和35至5重量% 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA,并且包含一种或多种共聚物嵌段(B / S)B,各自由20至60重量%的乙烯基芳族单体组成, 80〜40重量%的二烯,玻璃化转变温度TgB在-70℃〜0℃的范围内,c)0〜45%的重量 除了A和B之外的热塑性聚合物C,以及d)0至6重量%的加工助剂D,其中A至D的总量为100重量%,以及其用于生产收缩膜的用途。
    • 5. 发明申请
    • STYRENE BUTADIENE BLOCK COPOLYMER MIXTURES FOR SHRINK-WRAP FILMS
    • 苯乙烯丁二烯嵌段共聚物混合胶带
    • US20110098401A1
    • 2011-04-28
    • US13000817
    • 2009-06-23
    • Matthias MüllerKonrad KnollChristof MehlerHelmut SteiningerNorbert GüntherbergDaniel WagnerMichael SchusterGeert VerlindenFlorian Greger
    • Matthias MüllerKonrad KnollChristof MehlerHelmut SteiningerNorbert GüntherbergDaniel WagnerMichael SchusterGeert VerlindenFlorian Greger
    • C08L53/02
    • C08L53/02C08F297/04C08L2666/02C08L2666/24
    • A mixture which comprisesa) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.,b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.,c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, andd) from 0 to 6% by weight of processing aids D,where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.
    • 一种混合物,其包含a)5至95重量%的共聚物A,其包含一种或多种共聚物嵌段(B / S)A,每个共聚物嵌段(B / S)A由65至95重量%的乙烯基芳族单体和35至5重量% 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内,b)95至5重量%的嵌段共聚物B,其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯,并且包含一种或多种共聚物嵌段(B / S)A,各自由65至95重量%的乙烯基芳族单体和35至5重量% 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA,并且包含一种或多种共聚物嵌段(B / S)B,各自由20至60重量%的乙烯基芳族单体组成, 80〜40重量%的二烯,玻璃化转变温度TgB在-70℃〜0℃的范围内,c)0〜45%的重量 除了A和B之外的热塑性聚合物C,以及d)0至6重量%的加工助剂D,其中A至D的总量为100重量%,以及其用于生产收缩膜的用途。
    • 9. 发明申请
    • THERMOPLASTIC COMPOSITIONS HAVING IMPROVED FLOWABILITY
    • 具有改善流动性的热塑性组合物
    • US20120220678A1
    • 2012-08-30
    • US13505966
    • 2010-11-02
    • Christof MehlerRolf MinkwitzChristian SchadePiyada CharoensirisomboonNorbert NiessnerKyung Ho Shon
    • Christof MehlerRolf MinkwitzChristian SchadePiyada CharoensirisomboonNorbert NiessnerKyung Ho Shon
    • C08K5/12C08J9/22C08L55/02
    • C08L55/02C08K5/12C08K5/1539C08K2201/014C08L25/12D01F6/56C08L2666/04
    • The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C1-C30-alkyl; or the group —(COOR)n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values is 100% by weight, and also to a process for producing the composition of the invention, to the use of the composition of the invention for producing moldings, foils, foams, or fibers, and to moldings, foils, foams, or fibers comprising the composition of the invention.
    • 本发明涉及包含(i)组分(I)的组合物,至少一种包含组分A和B的模塑组合物,其中A)是作为组分A的接枝共聚物,B)是作为组分B的热塑性共聚物; 和(ii)至少一种式(I)的环己烷多羧酸衍生物; 作为其中R 1为C 1 -C 10 - 烷基或C 3 -C 8 - 环烷基的组分(II),m为0,1,2或3,n为2,3或4,并且R为氢或C 1 -C 30 - 烷基; 或(COOR)基团形成下式的酸酐,其中组分(I)占组分A的11至19.9重量%和组分B的80.1至89重量%是本发明必需的,其中 每个重量百分比值基于组分A和B的全部,并且这些值的总和为100重量%,并且还涉及制备本发明组合物的方法,使用组合物 用于生产模制品,箔,泡沫或纤维的本发明以及包含本发明组合物的模制品,箔,泡沫或纤维。