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1. 发明授权

US08263519B2 Sour service dewaxing catalyst without separate hydrogenation function 有权
标题翻译：酸洗脱蜡催化剂无需单独加氢功能
公开(公告)号：US08263519B2
公开(公告)日：2012-09-11
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
IPC分类号： B01J29/06
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译：提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。

2. 发明申请

US20090176643A1 Sour service dewaxing catalyst without separate hydrogenation function 有权
标题翻译：酸洗脱蜡催化剂无需单独加氢功能
公开(公告)号：US20090176643A1
公开(公告)日：2009-07-09
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/44 , B01J29/06 , B01J29/40 , B01J29/068
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译：提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。

3. 发明授权

US07271118B2 Xylenes isomerization catalyst system and use thereof 有权
标题翻译：二烯异构化催化剂体系及其应用
公开(公告)号：US07271118B2
公开(公告)日：2007-09-18
申请号：US10902322
申请日：2004-07-29
申请人： Brenda A. Raich , Robert A. Crane , Christine N. Elia , Teresa A. Jurgens-Kowal , Gary D. Mohr , David L. Stern
发明人： Brenda A. Raich , Robert A. Crane , Christine N. Elia , Teresa A. Jurgens-Kowal , Gary D. Mohr , David L. Stern
IPC分类号： B01J29/06 , B01J29/068
CPC分类号： C10G45/64 , B01J29/068 , B01J29/22 , B01J29/44 , B01J29/48 , B01J29/74 , B01J29/7415 , B01J29/7469 , B01J29/80 , B01J35/0006 , B01J2229/183 , B01J2229/32 , B01J2229/42 , C10G2300/1096 , C10G2300/4018 , C10G2400/30
摘要： A catalyst system that exhibits a ratio of ethylene saturation to aromatics ring saturation of greater than 3,500. The catalyst system comprises two components and each component comprises a crystalline molecular sieve having a Constraint Index of from about 1 to about 12 and an effective amount of Group VIII metal. The catalyst system finds particular application in ethylbenzene conversion/xylenes isomerization reactions. The catalyst system can be prepared by incorporating the Group VIII metal into the molecular sieves by competitive ion exchange.
摘要翻译：表现出乙烯饱和度与芳烃环饱和度之比大于3,500的催化剂体系。催化剂体系包含两种组分，每种组分包括具有约1至约12约束指数和有效量的第Ⅷ族金属的结晶分子筛。催化剂体系特别适用于乙苯转化/二甲苯异构化反应。可以通过竞争离子交换将VIII族金属掺入分子筛中来制备催化剂体系。

4. 发明授权

US5973193A Ethyl acetate synthesis from ethylene and acetic acid using solid acid catalysts 失效
标题翻译：使用固体酸催化剂从乙烯和乙酸合成乙酸乙酯
公开(公告)号：US5973193A
公开(公告)日：1999-10-26
申请号：US116385
申请日：1998-07-16
申请人： Robert A. Crane , Stephen H. Brown , Lorenzo De Caul
发明人： Robert A. Crane , Stephen H. Brown , Lorenzo De Caul
IPC分类号： C07C67/04
CPC分类号： C07C67/04
摘要： A method of producing ethyl acetate by reacting acetic acid with ethylene in the presence of a solid acidic catalyst comprising a zeolite selected from the group consisting of MCM-22, MCM-49, MCM-56, ZSM-5 and zeolite-Beta.
摘要翻译：在包含选自MCM-22，MCM-49，MCM-56，ZSM-5和沸石-ββ的沸石的固体酸性催化剂存在下，使乙酸与乙烯反应生产乙酸乙酯的方法。

5. 发明授权

US07326818B2 Selectivation of molecular sieve catalysts and use therof in hydrocarbon conversion 有权
标题翻译：选择分子筛催化剂，并在烃转化中使用
公开(公告)号：US07326818B2
公开(公告)日：2008-02-05
申请号：US10641604
申请日：2003-08-15
申请人： Jean W. Beeckman , William G. Borghard , Arthur W. Chester , Robert A. Crane , Owen C. Feeley , John C. Fried , Dominick N. Mazzone , Glenn R. Sweeten
发明人： Jean W. Beeckman , William G. Borghard , Arthur W. Chester , Robert A. Crane , Owen C. Feeley , John C. Fried , Dominick N. Mazzone , Glenn R. Sweeten
IPC分类号： C07C5/00
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/18 , B01J2229/40 , B01J2229/42 , C07C6/123 , C07C2521/08 , C07C2529/40 , Y02P20/52 , Y10S585/906 , C07C15/08
摘要： In a process for preparing a selectivated catalyst composition useful in the disproportionation of toluene, a catalyst comprising an acidic molecular sieve is contacted with a boron compound at a temperature in excess of 500° C.; and the resultant catalyst is then contacted with a medium containing hydrogen ions to at least partially restore the acid activity of the molecular sieve.
摘要翻译：在制备可用于甲苯歧化的选择性催化剂组合物的方法中，包含酸性分子筛的催化剂在硼氢化合物与超过500℃的温度下接触; 然后使得到的催化剂与含有氢离子的介质接触，至少部分地恢复分子筛的酸活性。

6. 发明申请

US20100107734A1 SPECTROPHONE ASSEMBLY FOR IDENTIFYING AND DETECTING MULTIPLE SPECIES 有权
标题翻译：用于识别和检测多种物种的分光器装置
公开(公告)号：US20100107734A1
公开(公告)日：2010-05-06
申请号：US12629692
申请日：2009-12-02
申请人： Robert A. Crane
发明人： Robert A. Crane
IPC分类号： G01N21/17
CPC分类号： G01N29/42 , G01N29/036 , G01N29/222 , G01N29/348 , G01N2291/0215
摘要： A spectrophone assembly comprises a single detector chamber, a plurality of lasers, a gas inlet for supplying a gas sample to the single detector chamber, and at least one microphone. The detector chamber has an internal geometry arranged to be simultaneously acoustically resonant at a plurality of different resonant frequencies. Each laser operates at a different wavelength and is positioned to emit radiation into the single detector chamber, and is operable to emit radiation that is amplitude modulated at a frequency rate corresponding to a particular resonant frequency different from the resonant frequency of each other laser, simultaneously with each other laser. The microphone(s) are positioned in the single detector chamber so that each microphone is located at or near a maximum of a corresponding acoustic resonance defined by the internal geometry of the detector chamber.
摘要翻译：分光投影仪组件包括单个检测器室，多个激光器，用于将气体样品供应到单个检测器室的气体入口和至少一个麦克风。检测器室具有布置成在多个不同谐振频率处同时声学谐振的内部几何形状。每个激光器以不同的波长工作，并且被定位成将辐射发射到单个检测器室中，并且可操作地发射以与每个其它激光器的谐振频率不同的特定谐振频率的频率速率进行幅度调制的辐射与其他激光。麦克风位于单个检测器室中，使得每个麦克风位于由检测器室的内部几何形状限定的对应声共振的最大值处或接近最大值。

7. 发明授权

US07148391B1 Heavy aromatics processing 失效
标题翻译：重芳烃加工
公开(公告)号：US07148391B1
公开(公告)日：2006-12-12
申请号：US10294428
申请日：2002-11-14
申请人： John Scott Buchanan , Ronald J. Cimini , Frank Wenyih Lai , Jose G. Santiesteban , David A. Stachelczyk , David L. Stern , Hye-Kyung C. Timken , William A. Weber , Robert A. Crane
发明人： John Scott Buchanan , Ronald J. Cimini , Frank Wenyih Lai , Jose G. Santiesteban , David A. Stachelczyk , David L. Stern , Hye-Kyung C. Timken , William A. Weber , Robert A. Crane
IPC分类号： C07C5/52
CPC分类号： B01J29/80 , B01J29/40 , B01J29/44 , B01J29/48 , B01J29/70 , B01J29/74 , B01J29/78 , B01J35/002 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C10G45/64 , Y02P20/52
摘要： In a process for converting C9+ aromatic hydrocarbons to lighter aromatic products a feed comprising C9+ aromatic hydrocarbons is contacted under transalkylation reaction conditions with a catalyst composition comprising (i) a first molecular sieve selected from the group consisting of ZSM-12, mordenite and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07; and (ii) a second molecular sieve having a constraint index ranging from 3 to 12. At least the first molecular sieve has a hydrogenation component associated therewith and the first and second molecular sieves are contained in the same catalyst bed. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene.
摘要翻译：在将C 9+芳烃转化成较轻芳香族产物的方法中，包含C 9+芳烃的进料在烷基转移反应条件下与催化剂组合物接触，所述催化剂组合物包含（i）选自ZSM-12，丝光沸石和具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07的d间距最大值的X射线衍射图的多孔结晶无机氧化物材料的第一分子筛 ; 和（ii）约束指数为3至12的第二分子筛。至少第一分子筛具有与之相关的氢化组分，并且第一和第二分子筛包含在相同的催化剂床中。在烷基转移反应条件下将C 9+芳烃转化成含有二甲苯的反应产物。

8. 发明授权

US4824390A Coated electrical connector 失效
标题翻译：涂层电连接器
公开(公告)号：US4824390A
公开(公告)日：1989-04-25
申请号：US153681
申请日：1988-02-08
申请人： Robert A. Crane , John J. Napiorkowski
发明人： Robert A. Crane , John J. Napiorkowski
IPC分类号： H01R9/28 , H01R13/52
CPC分类号： H01R13/5216 , H01R9/28 , Y10S439/936
摘要： An electrical connector, especially for telecommunications, including an electrical insulating block, and an array of cavities disposed in the block. Female contacts are disposed in the cavities and there are corresponding exposed electrical connections attached to the female contacts. An electrically insulating coating of gel-like deformable polymeric silicone material is disposed on the block, in the cavities, and on the female contacts. The coating is deformable and penetratable at ambient temperatures whereby to provide for penetration thereof by mating electrical contacts and enabling an electrical connection between the female and male contacts.
摘要翻译：电连接器，特别是用于电信，包括电绝缘块和设置在块中的空腔阵列。母接头设置在空腔中，并且存在连接到母接头的相应的暴露的电连接。凝胶状可变形聚合物硅酮材料的电绝缘涂层设置在块体上，空腔中和母接头上。该涂层在环境温度下是可变形的和可穿透的，由此通过配合电触头并且能够实现阴阳触头之间的电连接来提供穿透。

9. 发明授权

US4808774A Strain relief device 失效
标题翻译：应变消除装置
公开(公告)号：US4808774A
公开(公告)日：1989-02-28
申请号：US109637
申请日：1987-10-19
申请人： Robert A. Crane
发明人： Robert A. Crane
IPC分类号： H02G3/08 , H02G3/18 , H02G3/22
CPC分类号： H02G3/083
摘要： A strain relief device is disclosed which is adapted to receive wires which extend into an aperture of a service box. The device comprises a structure formed of a cylindrical segment and a conical segment. The cylindrical segment is disposed at the base of the conical segment and each of the segments is hollow. At least one section line, and preferably two, is disposed through the side wall of the structure. The section line extends from the top of the conical segment to the bottom of the cylindrical segment, whereby the segments are split into two sections. An abutment is disposed on the structure which is arranged to urge against the perimeter of the aperture in the service box. The two sections are joined together with a collar which is disposed around the cylindrical segment and co-acts with the abutment to hold the device in the aperture.
摘要翻译：公开了一种应变消除装置，其适于接收延伸到服务箱的孔中的线。该装置包括由圆柱形段和锥形段形成的结构。圆柱形部分设置在锥形部分的基部，每个部分是中空的。至少一个截面线，优选两个，通过该结构的侧壁设置。截面线从圆锥形段的顶部延伸到圆柱形段的底部，由此将段分成两部分。一个支座设置在该结构上，该基座设置成抵靠服务箱中的孔的周边。两个部分连接在一起，所述套环设置在圆柱形部分周围并与邻接件共同作用以将装置保持在孔中。

10. 发明授权

US07439204B2 Process for producing catalysts with reduced hydrogenation activity and use thereof 失效
标题翻译：具有降低的氢化活性的催化剂的制备方法及其用途
公开(公告)号：US07439204B2
公开(公告)日：2008-10-21
申请号：US10800888
申请日：2004-03-15
申请人： Timothy E. McMinn , Ronald J. Cimini , Robert A. Crane , Andrew M. Hiester , Teresa A. Jurgens-Kowal , Gary D. Mohr
发明人： Timothy E. McMinn , Ronald J. Cimini , Robert A. Crane , Andrew M. Hiester , Teresa A. Jurgens-Kowal , Gary D. Mohr
IPC分类号： B01J29/06
CPC分类号： C07C5/2737 , B01J29/064 , B01J29/076 , B01J29/44 , B01J29/48 , B01J37/18 , B01J2229/12 , B01J2229/32 , B01J2229/42 , C07C4/18 , C07C6/126 , C07C2529/48 , Y02P20/52 , C07C15/08
摘要： A process for controlling the hydrogenation activity of a catalyst comprised of a crystalline molecular sieve and at least one hydrogenation metal selected from the group consisting of a Group VIIB metal, a Group VIII metal, and mixtures thereof. The process is carried out by contacting the catalyst with hydrogen under sufficient conditions of temperature and pressure and for sufficient time to reduce the hydrogenolysis activity of the catalyst. The catalyst prepared by the process finds application in the catalytic conversion of organic compounds, such as ethylbenzene dealkylation, xylenes isomerization, and the transalkylation of polyalkylaromatic hydrocarbons.
摘要翻译：用于控制由结晶分子筛和至少一种氢化金属组成的催化剂的加氢活性的方法，该催化剂选自ⅦB族金属，Ⅷ族金属及其混合物。该过程通过在足够的温度和压力条件下使催化剂与氢气接触并进行足够的时间来降低催化剂的氢解活性来进行。通过该方法制备的催化剂可用于有机化合物的催化转化，例如乙苯脱烷基化，二甲苯异构化和聚烷基芳烃的烷基转移。

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