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1. 发明授权

US08030240B2 Multiple molecular sieve catalyst for sour service dewaxing 有权
标题翻译：用于酸性脱蜡的多分子筛催化剂
公开(公告)号：US08030240B2
公开(公告)日：2011-10-04
申请号：US12316979
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
IPC分类号： B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/405 , B01J29/44 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/12 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.
摘要翻译：提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。脱蜡催化剂包括至少两种沸石，包括具有低二氧化硅与氧化铝比的沸石。催化剂可以与低表面粘合剂组合，或者配制的催化剂可以具有高比例的沸石表面积与外表面积。

2. 发明申请

US20100075831A1 Multiple molecular sieve catalyst for sour service dewaxing 有权
标题翻译：用于酸性脱蜡的多分子筛催化剂
公开(公告)号：US20100075831A1
公开(公告)日：2010-03-25
申请号：US12316979
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/068 , B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/405 , B01J29/44 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/12 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.
摘要翻译：提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。脱蜡催化剂包括至少两种沸石，包括具有低二氧化硅与氧化铝比的沸石。催化剂可以与低表面粘合剂组合，或者配制的催化剂可以具有高比例的沸石表面积与外表面积。

3. 发明授权

US08263519B2 Sour service dewaxing catalyst without separate hydrogenation function 有权
标题翻译：酸洗脱蜡催化剂无需单独加氢功能
公开(公告)号：US08263519B2
公开(公告)日：2012-09-11
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
IPC分类号： B01J29/06
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译：提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。

4. 发明申请

US20090176643A1 Sour service dewaxing catalyst without separate hydrogenation function 有权
标题翻译：酸洗脱蜡催化剂无需单独加氢功能
公开(公告)号：US20090176643A1
公开(公告)日：2009-07-09
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/44 , B01J29/06 , B01J29/40 , B01J29/068
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译：提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。

5. 发明申请

US20100187156A1 Sour service hydroprocessing for lubricant base oil production 有权
标题翻译：润滑油基础油生产的酸洗加工
公开(公告)号：US20100187156A1
公开(公告)日：2010-07-29
申请号：US12655120
申请日：2009-12-23
申请人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
发明人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
IPC分类号： C10G69/02
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译：提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。

6. 发明授权

US08366908B2 Sour service hydroprocessing for lubricant base oil production 有权
标题翻译：润滑油基础油生产的酸洗加工
公开(公告)号：US08366908B2
公开(公告)日：2013-02-05
申请号：US12655120
申请日：2009-12-23
申请人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
发明人： Krista Marie Prentice , Gary Paul Schleicher , Lei Zhang , Timothy Lee Hilbert , Michel A. Daage , Sylvain Hantzer , Wenyih F. Lai , David Mentzer , William Francis Heaney , Christine Nicole Elia , Shifang Luo , Stephen J. McCarthy , Mohan Kalyanaraman
IPC分类号： C10G73/02 , C10G73/38 , C10G45/58 , C10G45/64
CPC分类号： C10G45/62 , C10G2300/202 , C10G2300/207 , C10G2400/10
摘要： An integrated process for producing lubricant base oils from feedstocks under sour conditions is provided. The ability to process feedstocks under higher sulfur conditions allows for reduced cost processing and increases the flexibility in selecting a suitable feedstock. The sour feed can be delivered to a catalytic dewaxing step without any separation of sulfur and nitrogen contaminants, or a high pressure separation can be used to partially eliminate contaminants.
摘要翻译：提供了一种在酸性条件下从原料生产润滑剂基础油的综合方法。在较高硫条件下处理原料的能力允许降低成本处理并增加选择合适原料的灵活性。可以将酸性进料输送到催化脱蜡步骤，而不会分离硫和氮污染物，或者可以使用高压分离来部分地消除污染物。

7. 发明授权

US06642281B1 Fischer-tropsch process 失效
标题翻译：费 - 托过程
公开(公告)号：US06642281B1
公开(公告)日：2003-11-04
申请号：US09653720
申请日：2000-09-01
申请人： David Chester Long , Michel A. Daage , Russell John Koveal
发明人： David Chester Long , Michel A. Daage , Russell John Koveal
IPC分类号： C07C2700
CPC分类号： C10G2/331 , B01J23/94 , B01J25/04 , C07C1/045 , C07C1/049 , C07C2523/75 , Y02P20/584
摘要： There is provided an improved system and process for the catalytic hydrogenation of carbon monoxide to form a mixture of hydrocarbons utilizing a plurality of reactors in series. Synthesis gas entering the system under pressure is partially converted in at least one initial stage reactor and the effluent therefrom introduced into a final stage reactor. In the at least one initial stage reactor, a portion of the catalyst is continuously or periodically removed with some hydrocarbons and treated to renew, or renew and enhance it, and returned. The treatment comprises reducing the hydrocarbon context of the withdrawn mixture, heating to a temperature above at least one of the metals in the catalyst thereby forming a melt, removing any slag forming on the melt, cooling the melt and reducing the particle size of the resulting solid to a fine powder of renewed catalyst. The renewed catalyst may be treated to further enhance its properties by slurry low temperature oxidation or passivated before being returned to the at least one initial stage reactor. The final stage reactor, which has a catalyst of the same type or differing from that in the at least one initial stage reactor, receives a feed therefrom having a substantially reduced level of impurities, thereby enhancing the efficiency and longevity of the catalyst contained therein. The system can further employ at least one intermediate stage reactor configured so that all stages are operably connected in series and all reactors with a given stage are operably connected in parallel.
摘要翻译：提供了一种用于一氧化碳的催化氢化以形成使用多个串联反应器的烃的混合物的改进的系统和方法。在压力下进入系统的合成气体在至少一个初级反应器中部分转化，并将其流出物引入到最终级反应器中。在至少一个初级反应器中，一部分催化剂用一些碳氢化合物连续地或周期性地除去并被处理以更新，或更新和增强催化剂并返回。处理包括减少抽出的混合物的烃背景，加热到催化剂中的至少一种金属上的温度，从而形成熔体，去除在熔体上形成的任何熔渣，冷却熔体并降低所得到的固体到更新催化剂的细粉末。可以处理更新的催化剂以通过浆料低温氧化进一步增强其性能，或者在被返回到至少一个初级反应器之前被钝化。具有相同类型或不同于至少一个初级反应器中的催化剂的最终级反应器从其中接收具有显着降低的杂质水平的进料，从而提高其中所含催化剂的效率和寿命。该系统可以进一步采用至少一个中间级反应器，其构造成使得所有级可串联地可操作地连接，并且具有给定级的所有反应器可并联地可操作地连接。

8. 发明授权

US06355593B1 Fischer-Tropsch catalyst enhancement 有权
标题翻译：费 - 托催化剂增强
公开(公告)号：US06355593B1
公开(公告)日：2002-03-12
申请号：US09654183
申请日：2000-09-01
申请人： Michel A. Daage , Russell John Koveal , Albert L'Vovich Lapidus , Alla Jurievna Krylova , Shawn Paul Brennan
发明人： Michel A. Daage , Russell John Koveal , Albert L'Vovich Lapidus , Alla Jurievna Krylova , Shawn Paul Brennan
IPC分类号： B01J3100
CPC分类号： C10G2/332 , B01J25/00 , B01J33/00 , B01J37/12
摘要： A process of enhancing both the activity and the methane selectivity of a Dispersed Active Metal (“DAM”) hydrogenation catalyst is disclosed wherein the DAM undergoes low temperature oxidation in a slurry phase to form an oxidized catalyst precursor that is unique in comparison to those formed by conventional high temperature deactivation processes. The oxidized catalyst precursor, which is stable, is subsequently reduced to form an enhanced catalyst by treatment with hydrogen-containing gas at elevated temperature. The process is useful in a wide variety of DAMs formed by art-recognized techniques. The process is equally applicable to the enhanced catalysts formed from the oxidized precursors and their use in hydrogenation reactions.
摘要翻译：公开了一种提高分散活性金属（“DAM”）氢化催化剂的活性和甲烷选择性的方法，其中DAM在淤浆相中经历低温氧化以形成氧化催化剂前体，与所形成的催化剂前体相比是独特的通过常规的高温失活过程。随后通过在高温下用含氢气体处理，将氧化的催化剂前体还原，以形成增强的催化剂。该方法在由艺术公认技术形成的各种DAM中是有用的。该方法同样适用于由氧化前体形成的增强催化剂及其在氢化反应中的应用。

9. 发明授权

US09376756B2 Inhibition of corrosion in boiler systems with etheramines 有权
标题翻译：用醚胺抑制锅炉系统的腐蚀
公开(公告)号：US09376756B2
公开(公告)日：2016-06-28
申请号：US14285686
申请日：2014-05-23
申请人： Michael Siskin , Robert Basil Fedich , Michel A. Daage
发明人： Michael Siskin , Robert Basil Fedich , Michel A. Daage
IPC分类号： C23F11/14 , F22B1/00 , F22B37/02
CPC分类号： C23F11/146 , C23F11/141 , F22B1/00 , F22B37/025
摘要： Aminoethers are used as corrosion inhibitors in boiler systems in which a working fluid comprising water with an aminoether corrosion inhibitor is circulated from a heater to a utilization site at which the working fluid gives up energy and decreases in temperature. A preferred class of aminoethers are the alkoxytriethyleneglycol-tert-alkylamines such as methoxy triethyleneglycol-tert-butylamine.
摘要翻译：氨基醚用作锅炉系统中的腐蚀抑制剂，其中包含水与氨基醚腐蚀抑制剂的工作流体从加热器循环到工作流体释放能量并降低温度的使用场所。优选的氨基醚类是烷氧基三乙二醇 - 叔烷基胺，例如甲氧基三乙二醇 - 叔丁胺。

10. 发明授权

US08425762B2 Aromatic hydrogenation process 有权
公开(公告)号：US08425762B2
公开(公告)日：2013-04-23
申请号：US12316673
申请日：2008-12-16
申请人： Stephen J. McCarthy , Wenyih Frank Lai , Michel A. Daage
发明人： Stephen J. McCarthy , Wenyih Frank Lai , Michel A. Daage
IPC分类号： C10G45/52 , C10G65/08 , B01J21/06
CPC分类号： C10G45/54 , B01J23/42 , B01J23/44 , B01J29/0325 , B01J29/89 , B01J35/002 , B01J2229/20 , B01J2229/42 , C10G45/52
摘要： An MCM-41 catalyst having a crystalline framework containing SiO2 and a Group IV metal oxide, such as TiO2 or ZrO2 is provided. The catalyst is low in acidity and is suitable for use in processes involving aromatic saturation of hydrocarbon feedstocks.

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