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1. 发明授权

US06290763B1 AZO dyes and compositions comprising such dyes 失效
标题翻译： AZO染料和包含这种染料的组合物
公开(公告)号：US06290763B1
公开(公告)日：2001-09-18
申请号：US09269061
申请日：1999-03-18
申请人： Christine Millard , Peter Gregory , Roy Bradbury
发明人： Christine Millard , Peter Gregory , Roy Bradbury
IPC分类号： C09D1102
CPC分类号： C09D11/328 , C09B43/16
摘要： Azo dyes of Formula (1) have utility as dyes for ink-jet printing, where Formula (1) represents: which comprises any suitable form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: n represents from 1 to 5 inclusive; R1, R1B, R4 and R4B each independently comprises at least one of the following substituents, optionally substituted: H, C1-8alkyl; C1-8,alkoxy; —NHCOH, C1-8alkylcarbonylamino; and —NHCONR5R6 where R5 and R6 each independently comprises at least one of the following substituents: H, C1-8alkyl and aryl; and R2 and R3 each independently comprises at least one of the following substituents, optionally substituted: H; C1-8alkoxy; -NHC1-8alkyleneOH, —SC1-8-alkyleneSO3H; -NHC1-8alkyleneN(C1-8alkyl)2; where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link, where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link; a moiety of Formula (2) where m and p is each independently from 0 to 5 inclusive, provided that (m+p) is from 1 to 5 inclusive; and R1A, R2A, R4A and R4C each independently comprises at least one of those optionally substituted substituents as defined herein for R1, R2, R4 and R4B respectively; and any other suitable labile or non-labile substituent not mentioned above; where the optional substituents herein comprise: C1-4alkyl (optionally substituted with at least one halo)., C1-4alkoxy (optionally substituted with at least one halo), carboxy, sulpho, hydroxy, amino, mercapto, cyano, nitro and halo.
摘要翻译：式（1）的偶氮染料可用作喷墨印刷用染料，其中式（1）表示：其包含任何合适形式的化合物：例如盐; 立体异构体，两性离子，多晶型物，复合物，同位素形式，它们在同一物种及其混合物中的组合; 其中：n表示1〜5; R1，R1B，R4和R4B各自独立地包含至少一个以下取代基，任选被取代：H，C 1-8烷基; C 1-8，烷氧基; -NHCOH，C 1-8烷基羰基氨基; 和-NHCONR 5 R 6，其中R 5和R 6各自独立地包含以下取代基中的至少一个：H，C 1-8烷基和芳基; 且R 2和R 3各自独立地包含至少一个以下取代基，任选地被取代：H; C 1-8烷氧基 -NHC1-8亚烷基OH，-SC1-8-亚烷基SO3H; -NHC1-8亚烷基N（C1-8烷基）2;其中X包括以下之一：-NHC1-8亚烷基; -NH 2 SO 2 NHC 1-8亚烷基; 和直链，其中X包含以下之一：-NHC1-8亚烷基; -NH 2 SO 2 NHC 1-8亚烷基; 和直链;式（2）的部分，其中m和p各自独立地为0至5，其中（m + p）为1至5（包括端值）; R1A，R2A，R4A和R4C各自独立地包含至少一种如本文定义的对于R 1，R 2，R 4和R 4B定义的那些取代的取代基; 以及上文未提及的其他合适的不稳定或非不稳定取代基; 其中本文的任选取代基包括：C 1-4烷基（任选被至少一个卤素取代），C 1-4烷氧基（任选被至少一个卤素取代），羧基，磺基，羟基，氨基，巯基，氰基，硝基和卤素。

2. 发明授权

US5189154A Anionic phthalocyanine compounds 失效
标题翻译：阴离子型酞菁化合物
公开(公告)号：US5189154A
公开(公告)日：1993-02-23
申请号：US720296
申请日：1991-06-28
申请人： Peter Gregory , Ronald W. Kenyon , Christine Millard
发明人： Peter Gregory , Ronald W. Kenyon , Christine Millard
IPC分类号： C07C47/04 , C07D487/22 , C09B47/26 , C09B62/036 , C09D11/00 , C09D11/02
CPC分类号： C09D11/328 , C09B47/26 , C09B62/036
摘要： Anionic phthalocyanine compounds which, in the free acid form, have the Formula (1):Pc(SO.sub.3 H).sub.t (SO.sub.2 --NR.sup.1 --L--NR.sup.2 --X--NR.sup.3 --G).sub.q (1)The compounds are useful as the colored component of inks, particularly those used in ink jet printing.

3. 发明授权

US07481522B2 Compositions and inks containing disazo dyes 失效
标题翻译：含有双偶氮染料的组合物和油墨
公开(公告)号：US07481522B2
公开(公告)日：2009-01-27
申请号：US10516496
申请日：2003-06-05
申请人： Alan Dickinson , Neil James Thompson , Paul Wight , Peter Gregory , Philip John Double , Roy Bradbury
发明人： Alan Dickinson , Neil James Thompson , Paul Wight , Peter Gregory , Philip John Double , Roy Bradbury
IPC分类号： G01D11/00
CPC分类号： C09D11/30
摘要： A process for printing an image on a substrate including applying thereto a composition including a liquid medium and a compound of Formula (1) A-N═N-L-N═N-A wherein: each A independently is optionally substituted aryl or heteroaryl; and L is an optionally substituted, optionally metallised 1,8-dihydroxynaphthylene group; provided that: (i) at most one of the groups represented by A has a hydroxy substituent ortho to the —N═N— groups shown in Formula (1); and (ii) Formula (1) is not: Also claimed are compositions for printing, compounds and processes for making the compounds.
摘要翻译：一种在基材上印刷图像的方法，包括向其施涂包含液体介质和式（1）A-N-N-L-N-N-A的化合物的组合物，其中：每个A独立地为任选取代的芳基或杂芳基; 并且L是任选取代的任选金属化的1,8-二羟基萘基; 条件是：（i）由A表示的至多一个基团具有与式（1）所示的-N-N-基邻位的羟基取代基; 和（ii）式（1）不是：还要求的是用于印刷的组合物，化合物和制备该化合物的方法。

4. 发明授权

US4859651A Thermal transfer printing 失效
标题翻译：热转印
公开(公告)号：US4859651A
公开(公告)日：1989-08-22
申请号：US227990
申请日：1988-08-03
申请人： Peter Gregory , Roy Bradbury , Barry H. Meyrick
发明人： Peter Gregory , Roy Bradbury , Barry H. Meyrick
IPC分类号： B41M5/385 , B41M5/26 , B41M5/388 , B41M5/39
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer printing sheet, suitable for use in a thermal transfer printing process, comprising a substrate having a coating comprising a water-insoluble dye of the formula: ##STR1## wherein R represents the residue of an active methylene compound;X represents hydrogen, halogen or an optionally substituted alkyl, aryl or heteroaryl radical;Y represents cyano, nitro, alkanoyl, aroyl, alkylsulphonyl, arylsulphonyl or a group of the formula --COOR.sup.1 or --CONR.sup.2 R.sup.3 wherein R.sup.1 represents a hydrocarbyl radical and each of R.sup.2 and R.sup.3, independently, represents hydrogen or a hydrocarbyl radical; andE represents the residue of a coupling component.

5. 发明授权

US07056376B2 Printing process using specified AZO compounds 有权
标题翻译：使用指定的AZO化合物进行印刷
公开(公告)号：US07056376B2
公开(公告)日：2006-06-06
申请号：US10411327
申请日：2003-04-11
申请人： Ajay Haridas Popat , Alan Dickinson , Maria Soteri Hadjisoteriou , Neil James Thompson , Paul Wight , Peter Gregory , Roy Bradbury , Philip John Double , Thomas Paul
发明人： Ajay Haridas Popat , Alan Dickinson , Maria Soteri Hadjisoteriou , Neil James Thompson , Paul Wight , Peter Gregory , Roy Bradbury , Philip John Double , Thomas Paul
IPC分类号： C09D11/00 , C09B35/378
CPC分类号： D06P5/30 , C09B33/22 , C09B35/40 , C09B35/52 , C09B35/58 , C09B35/60 , C09B35/64 , C09B45/24 , C09D11/328 , C09D11/40 , D06P1/18
摘要： A process for printing an image on a substrate comprising applying thereto a composition comprising a liquid medium and a compound of Formula (1): T-Q-N═N-L-T Formula (1) wherein: each T independently is an azo group; Q is an optionally substituted, optionally metallised 1,8-dihydroxynaphthyl group; and L is a divalent organic linker group. Also claimed are compositions and dyes.
摘要翻译：一种用于在基材上印刷图像的方法，包括向其施加包含液体介质和式（1）化合物的组合物：<？在线公式描述=“在线式”末端=“lead”→> TQNNLT 式（1）<？in-line-formula description =“In-line formula”end =“tail”？>其中：每个T独立地是偶氮基团; Q是任选取代的，任选金属化的1,8-二羟基萘基; L是二价有机连接基团。还要求的是组合物和染料。

6. 发明授权

US5882391A Bisazo inkjet dyes 失效
标题翻译：双偶氮喷墨染料
公开(公告)号：US5882391A
公开(公告)日：1999-03-16
申请号：US948037
申请日：1997-10-09
申请人： Peter Gregory , Prahalad Manibhai Mistry , Roy Bradbury , Paul Wight
发明人： Peter Gregory , Prahalad Manibhai Mistry , Roy Bradbury , Paul Wight
IPC分类号： C09B31/08 , C09D11/00 , D06P5/30 , C09D11/02
CPC分类号： C09D11/328 , C09B31/08 , D06P5/30 , Y10T428/24802
摘要： A bisazo dye of Formula (1) and salts thereof: ##STR1## in which R is H or ##STR2## R.sub.1 and R.sub.2 each independently is H, optionally substituted C.sub.1-4 -alkyl or optionally substituted aryl;R.sub.3 and R.sub.5 together with the carbon atoms to which they are attached form a 5- or 6-membered carbocyclic ring which is optionally substituted by SO.sub.3 H;R.sub.4 is H;R.sub.6 is COOH;n is 1, 2 or 3; andp is 1, 2, 3 or 4.The dyes are useful for ink jet printing.
摘要翻译：式（1）的双偶氮染料及其盐：其中R为H或R 1和R 2各自独立地为H，任选取代的C 1-4 - 烷基或任选取代的芳基的式（1） R3和R5与它们所连接的碳原子一起形成任选被SO 3 H取代的5-或6-元碳环; R4是H; R6是COOH; n为1,2或3; 并且p是1,2,3或4.这些染料可用于喷墨印刷。

7. 发明授权

US4968657A Thermal transfer printing 失效
标题翻译：热转印
公开(公告)号：US4968657A
公开(公告)日：1990-11-06
申请号：US342018
申请日：1989-04-24
申请人： Peter Gregory , Roy Bradbury
发明人： Peter Gregory , Roy Bradbury
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/388 , B41M5/39 , C07D213/84 , C09B29/42 , C09B57/00
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer printing sheet, suitable for use in a thermal transfer printing process, comprising a substrate having a coating comprising a dye of the formula: ##STR1## wherein X represents nitro or --COOR.sup.1 in which R.sup.1 is an optionally substituted hydrocarbyl radical;Y represents an optionally substituted C.sub.1-10 -alkyl or alkoxy radical;Z represents an alkyl radical, andR represents an alkyl radical which may be interrupted by one or two --O-- or --COO-- links.

8. 发明授权

US4892859A Thermal transfer printing 失效
公开(公告)号：US4892859A
公开(公告)日：1990-01-09
申请号：US225213
申请日：1988-07-28
申请人： Peter Gregory , Roy Bradbury
发明人： Peter Gregory , Roy Bradbury
IPC分类号： B41M5/385 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , C09B29/36
CPC分类号： B41M5/388 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer printing sheet suitable for use in a thermal transfer printing process, comprising a substrate having a coating comprising a dye of the formula: ##STR1## wherein: R represents an optionally substituted alkyl, aryl or aralkyl radical;n is one or 2;X represents hydrogen, halogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C.sub.1-4 -alkoxy, C.sub.1-4 -alkylthio, beta-cyanoethyl, C.sub.1-4 -alklcarbonylamino or C.sub.1-4 -alkylsulphonylamino;Y represents hydrogen or methoxy, andeach of R.sup.1 and R.sup.2 independently, represents allyl, C.sub.1-2 -alkyl or C.sub.1-4 -alkyl substituted by a group selected from cyano, C.sub.1-4 -alkoxycarbonyl, C.sub.1-4 -alkylcarbonyloxy, R.sup.3 CONH--, R.sup.3 NHCO-- and R.sup.3 NHCOO-- which R.sup.3 represents C.sub.1-4 -alkyl or optionally substituted aryl.

9. 发明授权

US4808568A Thermal transfer printing 失效
标题翻译：热转印
公开(公告)号：US4808568A
公开(公告)日：1989-02-28
申请号：US46187
申请日：1987-05-05
申请人： Peter Gregory , Roy Bradbury
发明人： Peter Gregory , Roy Bradbury
IPC分类号： B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , G09F9/302 , H03K17/296 , B41M5/035
CPC分类号： B41M5/385 , G09F9/302 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer printing sheet, suitable for use in a thermal transfer printing process, especially for the conversion of a digital image into a visible print, comprising a substrate having a coating comprising a dye of the formula: ##STR1## whereinRing A is unsubstituted or carries, in the 2- or 4-position with respect to the azo link, at least one group selected from --CX.sub.3, X.sup.1, CN, NO.sub.2, --OCO.Y, --CO.Y, --CO.H, --OSO.sub.2.Y and --SO.sub.2.Y, provided that A is substituted when Z is CH.sub.3 and R is C.sub.2-4 -alkyl;X & X.sup.1 are each independently halogen;Y is selected from R.sup.1, --OR.sup.1, SR.sup.1 and --NR.sup.1 R.sup.2 ;R.sup.1 is selected from C.sub.1-12 -alkyl, C.sub.1-12 -alkyl interrupted by one or two groups selected from --O--, --CO--, O.CO-- and --CO.O--, C.sub.3-7 -cycloalkyl, mono- or bi-cyclic aryl and C.sub.1-3 -alkylene attached to an adjacent carbon atom on Ring A;R.sup.2 is selected from H, C.sub.1-12 -alkyl, C.sub.3-7 -cycloalkyl and mono- or bi-cyclic aryl;Z is C.sub.1-12 -alkyl or phenyl; andR is selected from C.sub.2-12 -alkyl unbranched in the alpha-position, C.sub.2-12 -alkyl unbranched in alpha-position and interrupted by one or two groups selected from --O--, --CO--, O.CO-- and --CO.O--, phenyl, C.sub.1-4 -alkylphenyl, biphenyl and biphenyl interrupted by a group selected from --O--, --CO--, O.CO-- and --CO.O--, each of which is free from hydrogen atoms capable of intermolecular hydrogen bonding.
摘要翻译：一种适用于热转印印刷工艺的热转印片材，特别是用于将数字图像转化成可见印刷物的热转印片材，其包含具有包含下式染料的涂层的基材：其中环A为未取代的或在相对于偶氮键的2-或4-位上携带至少一个选自-CX 3，X 1，CN，NO 2，-OCO.Y，-CO.Y，-CO.H，-OSO 2的基团 Y和-SO 2 Y，条件是当Z为CH 3且A为C 2-4烷基时，A为取代基; X＆X1各自独立地为卤素; Y选自R1，-OR1，SR1和-NR1R2; R 1选自C 1-12 - 烷基，被一个或两个选自-O - ， - CO-，OCO-和-COO基团间隔的C 1-12 - 烷基，C 3-7 - 环烷基，或环环A上的相邻碳原子上的双环芳基和C1-3亚烷基; R 2选自H，C 1-12 - 烷基，C 3-7 - 环烷基和单环或双环芳基; Z是C 1-12 - 烷基或苯基; 并且R选自在α-位上未分支的C 2-12 - 烷基，在α-位上未分支并被一个或两个选自-O - ， - CO-，O.CO-和 - CO，O-，苯基，C 1-4 - 烷基苯基，联苯基和联苯被选自-O - ， - CO-，OCO-和-CO.O-的基团中断，各自不含氢原子的分子间氢键。

10. 发明授权

US4725284A Thermal transfer printing with z-alkyl-phenoxy anthraquinone dye mixture 失效
标题翻译：用Z-烷基 - 苯氧基蒽醌染料混合物进行热转印
公开(公告)号：US4725284A
公开(公告)日：1988-02-16
申请号：US886644
申请日：1986-07-18
申请人： William Black , Roy Bradbury , Peter Gregory , Roy Porter , Geoffrey R. Rothwell
发明人： William Black , Roy Bradbury , Peter Gregory , Roy Porter , Geoffrey R. Rothwell
IPC分类号： B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , C09B67/22
CPC分类号： B41M5/3852 , C09B67/0038 , Y10S428/913 , Y10S8/922 , Y10S8/928
摘要： The invention relates to:(A) A thermal transfer printing sheet comprising a substrate having a coating comprising either,(i) a dye of the formula: ##STR1## wherein R.sup.1 is C.sub.5-12 -alkyl;R.sup.2 is H or C.sub.1-12 -alkyl; and Rings A & B are optionally substituted in the free positions by non-ionic groups; or(ii) a mixture of at least two dyes of the formula: ##STR2## wherein R.sup.3 is H or C.sub.1-12 -alkyl;R.sup.4 is H or C.sub.1-4 -alkyl; and Rings A & B are optionally substituted in the free positions by non-ionic groups; provided that in at least one component R.sup.3 is C.sub.5-12 -alkyl and in at least one other component R.sup.3 is H or C.sub.1-4 -alkyl;(B) A thermal transfer printing process using the transfer sheets; and(C) The mixture of dyes defined in (A)(ii).
摘要翻译：本发明涉及：（A）一种热转印片，其包含具有涂层的基底，该涂层包含：（i）下式的染料：其中R1为C5-12-烷基; R2是H或C1-12 - 烷基; 环A和B任选在非离子基团的任意位置被取代; 或（ii）至少两种下式的染料的混合物：其中R 3是H或C 1-12 - 烷基; R4是H或C1-4烷基; 环A和B任选在非离子基团的任意位置被取代; 条件是在至少一个组分R 3为C 5- 12 - 烷基且至少一个其它组分R 3为H或C 1-4 - 烷基; （B）使用转印纸的热转印印刷工艺; 和（C）（A）（ii）中定义的染料混合物。

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