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    • 1. 发明申请
    • NEW POLYISOCYANATE MIXTURES, A PROCESS FOR THEIR PREPARATION AND THEIR USE IN COATING COMPOSITIONS
    • 新型聚异氰酸酯混合物,其制备方法及其在涂料组合物中的用途
    • US20100076152A1
    • 2010-03-25
    • US12625790
    • 2009-11-25
    • Christian WamprechtMartin MelchiorsJörg Schmitz
    • Christian WamprechtMartin MelchiorsJörg Schmitz
    • C08L75/06C08G18/68
    • C08G18/672C08G18/6229C08G18/6254C08G18/8116Y10T428/31551
    • The present invention relates to polyacrylate-modified polyisocyanates which are i) prepared from aromatic, araliphatic, cycloaliphatic and/or aliphatic polyisocyanates having an NCO content of 5% to 25% by weight, an NCO functionality ≧2, a viscosity measured as solvent free resin of 150 to 200,000 mPa·s at 23° C., and ii) contain at least one structural unit of the formula (I) wherein R is hydrogen or a methyl group, R1 is an optionally heteroatom-containing hydrocarbon radical and R2 is a hydrocarbon radical having at least one isocyanate group and optionally urethane, allophanate, biuret, uretdione, isocyanurate and/or iminooxadiazinedione groups and n is a number ≧1. The present invention also relates to a process for preparing these polyisocyanates and to binder compositions containing these polyisocyanates, which may be hydrophilically modified, and a compound having NCO-reactive groups.
    • 本发明涉及聚丙烯酸酯改性的多异氰酸酯,其是i)由NCO含量为5%至25%重量,NCO官能度≥2的芳族,芳脂族,脂环族和/或脂族多异氰酸酯制备的, 树脂在23℃下为150至200,000mPa·s,和ii)包含至少一种式(I)的结构单元,其中R是氢或甲基,R 1是任选含杂原子的烃基,R 2是 具有至少一个异氰酸酯基团和任选的氨基甲酸酯,脲基甲酸酯,缩二脲,脲二酮,异氰脲酸酯和/或亚氨基恶二嗪二酮基团的烃基,n是数≧1。 本发明还涉及一种制备这些多异氰酸酯的方法和含有可以亲水改性的这些多异氰酸酯的粘合剂组合物和具有NCO-反应性基团的化合物。
    • 2. 发明授权
    • Polyisocyanate mixtures, a process for their preparation and their use in coating compositions
    • 多异氰酸酯混合物,其制备方法及其在涂料组合物中的应用
    • US08063144B2
    • 2011-11-22
    • US12625790
    • 2009-11-25
    • Christian WamprechtMartin MelchiorsJörg Schmitz
    • Christian WamprechtMartin MelchiorsJörg Schmitz
    • C08F8/30
    • C08G18/672C08G18/6229C08G18/6254C08G18/8116Y10T428/31551
    • The present invention relates to polyacrylate-modified polyisocyanates which are i) prepared from aromatic, araliphatic, cycloaliphatic and/or aliphatic polyisocyanates having an NCO content of 5% to 25% by weight, an NCO functionality ≧2 and a viscosity measured as solvent free resin of 150 to 200,000 mPa·s at 23° C., and ii) contain at least one structural unit of the formula (I) R is hydrogen or a methyl group, R1 is an optionally heteroatom-containing hydrocarbon radical and R2 is a hydrocarbon radical having at least one isocyanate group and optionally urethane, allophanate, biuret, uretdione, isocyanurate and/or iminooxadiazinedione groups and n is a number ≧1; and to processes for preparing these polyisocyanates and to binder compositions containing these polyisocyanates, which may be hydrophilically modified and a compound having NCO-reactive groups.
    • 本发明涉及聚丙烯酸酯改性的多异氰酸酯,其是i)由NCO含量为5%至25%(重量),NCO官能度≥2的芳族,芳脂族,脂环族和/或脂族多异氰酸酯制备,粘度以无溶剂 树脂在23℃下为150至200,000mPa·s,和ii)含有至少一个式(I)的结构单元,R是氢或甲基,R 1是任选含杂原子的烃基,R 2是 具有至少一个异氰酸酯基团和任选的氨基甲酸酯,脲基甲酸酯,缩二脲,脲二酮,异氰脲酸酯和/或亚氨基恶二嗪二酮基团的烃基,n是数≧1; 以及制备这些多异氰酸酯的方法和含有可以亲水改性的这些多异氰酸酯和具有NCO-反应性基团的化合物的粘合剂组合物。
    • 7. 发明授权
    • Apparatus for feeding a plurality of charging shafts, especially a mixer, with fibre material
    • 用于向纤维材料供给多个充电轴,特别是混合器的装置
    • US07506411B2
    • 2009-03-24
    • US11290580
    • 2005-12-01
    • Konrad TemburgJörg Schmitz
    • Konrad TemburgJörg Schmitz
    • D01G13/00
    • D01G13/00
    • In an apparatus in spinning preparation for feeding a plurality of charging shafts 2 to 6, especially a mixer 1, with fiber material that is transported for example pneumatically in a supply channel 8 and deflected into the charging shafts by means of deflecting devices, each charging shaft is closable at its upper end by means of a rotary gate 11 which, in its open position, closes off the cross-section of the supply channel. In order to increase the efficiency by means that are simple in terms of construction and, above all, to improve the transmission of the drive movement to the movement of the rotary gate 11, the rotary gate co-operates with a drive element 20; 21; 22; 23; 26 which imparts a rotary movement to the rotating axle of the rotary gate.
    • 在用于供给多个充电轴2至6,特别是混合器1的纺丝制备装置中,使用例如在供应通道8中气动输送并通过偏转装置偏转到充电轴中的纤维材料,每次充电 轴通过旋转门11在其上端可关闭,旋转门11在其打开位置处封闭供应通道的横截面。 为了通过简单的结构提高效率,首先,为了改善驱动运动对旋转门11的运动的传递,旋转门与驱动元件20配合; 21; 22; 23; 26,其向旋转门的旋转轴施加旋转运动。
    • 8. 发明授权
    • Preparation of new radiation-curing binders
    • 新型辐射固化胶粘剂的制备
    • US07381785B2
    • 2008-06-03
    • US11080176
    • 2005-03-14
    • Christophe DètrembleurJan WeikardDorota Greszta-FranzWolfgang FischerJörg SchmitzHolger Mundstock
    • Christophe DètrembleurJan WeikardDorota Greszta-FranzWolfgang FischerJörg SchmitzHolger Mundstock
    • C08G18/78C08G18/67C08G18/16C09D175/16
    • C08G18/7837B33Y70/00C08G18/166C08G18/672C09D175/16C08G18/3206
    • Process for preparing binders including reacting A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds containing groups capable of participating in polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and contain isocyanate-reactive groups, followed by C) reaction with one or more hydroxyl-containing compounds other than B), wherein at least one of these compounds has an OH functionality of≧2, D) in the presence of one or more compounds containing phenoxide groups, as catalysts, and E) optionally auxiliaries and additives, where the reaction with compounds of component C) proceeds at least proportionally with the formation of allophanate groups and where and including binders containing allophanate groups and groups capable of participating in a polymerization reaction with ethylenically unsaturated compounds on exposure to actinic radiation, and optionally also contain NCO-reactive groups. The binders are used in coating compositions used to coat substrates.
    • 制备粘合剂的方法包括使A)一种或多种含有脲二酮基团的NCO-官能化合物与B)一种或多种含有能够在曝光于光化辐射下参与与烯属不饱和化合物聚合反应的基团的化合物,并含有异氰酸酯反应性基团, 随后C)与除B)之外的一种或多种含羟基化合物反应,其中这些化合物中的至少一种具有> = 2的OH官能度,D)在一种或多种含有酚盐的化合物的存在下,作为催化剂 和E)任选的助剂和添加剂,其中与组分C)的化合物的反应至少与形成脲基甲酸酯基团成比例地进行,并且其中和包括含有脲基甲酸酯基团和能够与烯属不饱和化合物进行聚合反应的基团的粘合剂 暴露于光化辐射,并且任选地还含有NCO-反应性基团。 粘合剂用于涂覆基材的涂料组合物中。
    • 10. 发明授权
    • Radiation-curing binders and a process for their preparation
    • 辐射固化粘合剂及其制备方法
    • US07666970B2
    • 2010-02-23
    • US11217728
    • 2005-09-01
    • Jan WeikardChristoph GürtlerWolfgang FischerJörg SchmitzHolger Mundstock
    • Jan WeikardChristoph GürtlerWolfgang FischerJörg SchmitzHolger Mundstock
    • C08G18/04C08G18/08C08G18/00C08G18/78
    • C08G18/8175B33Y70/00C09D175/14Y10T428/31551
    • The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ≦130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ≧2, in the presence of D) a catalyst containing one or more ammonium salts or phosphonium salts of aliphatic or cycloaliphatic carboxylic acids, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
    • 本发明涉及一种制备粘合剂的方法,其包含1)脲基甲酸酯基团,2)与烯键式不饱和化合物反应的基团与暴露于光化辐射(辐射固化基团)和3)任选的NCO-反应性基团反应的基团, A)一种或多种含有脲二酮基团的NCO-官能化合物,B)一种或多种含有异氰酸酯反应性基团的化合物和与烯键式不饱和化合物反应而与光化辐射(辐射 - 固化基团),然后C)与除了B)之外的一种或多种饱和的含羟基化合物,在D的存在下,在具有OH官能度≥2的这些化合物中的至少一种的化合物中含有一种或多种铵 脂肪族或脂环族羧酸的盐或鏻盐,与化合物C)的反应至少与脲基甲酸酯基团的形成成比例地发生。 本发明还涉及通过本发明的方法获得的粘合剂。