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1. 发明授权

US5578684A Preparation of polyvinylpyridine N-oxides 失效
标题翻译：聚乙烯吡啶N-氧化物的制备
公开(公告)号：US5578684A
公开(公告)日：1996-11-26
申请号：US507237
申请日：1995-08-24
申请人： Christian Schade , Dieter Boeckh , Juergen Detering
发明人： Christian Schade , Dieter Boeckh , Juergen Detering
IPC分类号： C08F8/06 , C08F26/08 , C08F8/42
CPC分类号： C08F8/06
摘要： Polyvinylpyridine N-oxides are prepared by oxidizing polyvinyl-pyridines with aqueous solutions of hydrogen peroxide in the presence of acids and oxides or acids of elements of Groups 5b, 6b, 7b and 8 of the Periodic Table or of salts of these acids as catalyst, it also being possible for the oxidation to take place in the absence of the catalysts when from 40 to 80% strength aqueous solutions of at least dibasic carboxylic acids or of polymers of monoethylenically unsaturated carboxylic acids are used as solvent.
摘要翻译： PCT No.PCT / EP94 / 00490 Sec。 371日期1995年8月24日 102（e）日期1995年8月24日PCT 1995年2月21日提交PCT公布。出版物WO94 / 20549 日期1994年9月15日聚乙烯基吡啶N-氧化物是通过在酸和氧化物的存在下用水过氧化氢水溶液氧化聚乙烯吡啶而制备的，其中元素周期表第5b，6b，7b和8族的元素，或这些酸作为催化剂，当使用40-80％强度的至少二元羧酸的水溶液或单烯属不饱和羧酸的聚合物作为溶剂时，也可以在不存在催化剂的情况下进行氧化。

2. 发明授权

US08022134B2 Modified polyaminoamides 有权
标题翻译：改性聚氨基酰胺
公开(公告)号：US08022134B2
公开(公告)日：2011-09-20
申请号：US10592370
申请日：2005-03-18
申请人： Cordula Mock-Knoblauch , Juergen Detering , Dieter Boeckh , Parmod Kakumanu Reddy , Xinbei None Song
发明人： Cordula Mock-Knoblauch , Juergen Detering , Dieter Boeckh , Parmod Kakumanu Reddy , Xinbei None Song
IPC分类号： C08G73/02 , C11D3/37
CPC分类号： C08G73/0293 , B01F17/0042 , C08G69/26 , C08G69/48 , C08G73/0286 , C11D3/0036 , C11D3/3719
摘要： The present invention relates to novel modified polyaminoamides which are useful as dispersing agents for particulate inorganic solids, especially for inorganic pigments such as clay minerals. The new polyamides are also useful as graying inhibiting additives and detergency boosting additives in washing composition for laundry. In the modified polyaminoamide according to the invention at least a part of the amino nitrogens of the polymer carry both a hydrocarbon radical R which is selected from C1-C6-alkyl, C6-C16-aryl-C1-C4-alkyl and a group AIk-O-A, wherein A is hydrogen or an acidic group selected from B1—PO(OH)2, B1—S(O)2OH and B2—COOH which may be present in the acidic or anionic form, wherein B1 is a single bond or C1-C6-alkanediyl, and B2 is C1-C6-alkanediyl and Alk is C2-C6-alkane-1,2-diyl, and a moiety of the formula (I) —(CH2—CR1R2—O—)pA ,wherein A is as defined above R1 is independently selected from hydrogen, C1-C12-alkyl, C2-C8-alkenyl, C6-C16-aryl or C6-C16-aryl-C1-C4-alkyl, R2 is independently selected from hydrogen or methyl and p is an integer provided that p has a number average of at least 10.
摘要翻译：本发明涉及可用作颗粒状无机固体分散剂的新型改性聚氨基酰胺，特别是无机颜料如粘土矿物。新型聚酰胺也可用作用于洗涤用洗涤剂组合物中的抑灰添加剂和助洗剂。在根据本发明的改性聚氨基酰胺中，聚合物的至少一部分氨基氮携带选自C 1 -C 6烷基，C 6 -C 16 - 芳基-C 1 -C 4 - 烷基和基团AI k的烃基R -OA，其中A是氢或选自B1-PO（OH）2，B1-S（O）2OH和B2-COOH的酸性基团，其可以以酸性或阴离子形式存在，其中B1是单键或 C1-C6链烷二基，B2是C1-C6烷二基，Alk是C2-C6-烷烃-1,2-二基，和式（I） - （CH2-CR1R2-O-）pA的部分，其中 A如上所定义，R 1独立地选自氢，C 1 -C 12 - 烷基，C 2 -C 8 - 烯基，C 6 -C 16 - 芳基或C 6 -C 16 - 芳基-C 1 -C 4烷基，R 2独立地选自氢或甲基并且p是整数，条件是p的数均数至少为10。

3. 发明授权

US5639832A Preparation of products of the reaction of polyaspartimide and amino acids and the use thereof 失效
标题翻译：聚天冬氨酰亚胺和氨基酸反应产物的制备及其应用
公开(公告)号：US5639832A
公开(公告)日：1997-06-17
申请号：US507291
申请日：1995-09-06
申请人： Matthias Kroner , Gunnar Schornick , Dieter Boeckh , Richard Baur , Birgit Potthoff-Karl , Volker Schwendemann , Christian Schade , Alexander Kud
发明人： Matthias Kroner , Gunnar Schornick , Dieter Boeckh , Richard Baur , Birgit Potthoff-Karl , Volker Schwendemann , Christian Schade , Alexander Kud
IPC分类号： B01F17/52 , C08G69/08 , C08G69/10 , C08G73/00 , C08G73/10 , C11D3/37 , C08F283/00 , C08G63/91
CPC分类号： C08G69/08 , C08G69/10 , C08G73/1092 , C11D3/3719
摘要： Process for the preparation of products of the reaction of polyaspartimides and amino acids by reaction of amino acids with polyaspartimides in aqueous medium at pH values at which at least 5% of the amino groups in the amino acids are in non-protonated form in equilibrium with the protonated form, and use of the reaction products obtainable in this way and of products of the reaction of polyaspartimides with alkanolamines or aminated C.sub.1 -C.sub.30 -fatty alcohol alkoxylates which contain as copolymerized units up to 50 mol % of ethylene oxide and/or propylene oxide per mol of fatty alcohol, as additive to detergents and cleaners, as scale inhibitor and as dispersant.
摘要翻译： PCT No.PCT / EP94 / 00511 Sec。 371日期：1995年9月6日 102（e）1995年9月6日PCT PCT 1994年2月23日PCT公布。 WO94 / 20563 PCT出版物日期1994年9月15日通过氨基酸与聚天冬酰胺在水性介质中的反应制备聚天冬酰胺和氨基酸的反应产物的过程，其pH值为至少5％氨基酸中的氨基是非 - 质子化形式与质子化形式平衡，以及可以以这种方式获得的反应产物和聚天冬酰胺与链烷醇胺或胺化C1-C30-脂肪醇烷氧基化物反应的产物的使用，其含有高达50mol％乙烯的共聚单元氧化物和/或环氧丙烷/摩尔脂肪醇，作为除垢剂和清洁剂的添加剂，作为阻垢剂和分散剂。

4. 发明授权

US6025317A Powdery porous polymers containing N-vinylimidazol units, process for their preparation and their use 失效
标题翻译：含有N-乙烯基咪唑单元的粉状多孔聚合物，其制备方法及其用途
公开(公告)号：US6025317A
公开(公告)日：2000-02-15
申请号：US29075
申请日：1998-03-03
申请人： Stefan Stein , Dieter Boeckh , Christian Schade , Gerhard Rossler
发明人： Stefan Stein , Dieter Boeckh , Christian Schade , Gerhard Rossler
IPC分类号： C08F2/10 , C08F26/02 , C08F26/06 , C11D3/00 , C11D3/37 , C08F126/06 , B01J39/20
CPC分类号： C11D3/3776 , C08F26/02 , C08F26/06 , C11D3/0021
摘要： Porous polymers which are in powder form and contain N-vinylimidazole units and which are obtainable by free-radical precipitation polymerization ofa) 5-100% by weight of at least one N-vinylimidazole of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl, N-vinylaxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers,b) 0-95% by weight of other copolymerizable monoethylenically unsaturated monomers andc) 0-50% by weight of at least one monomer with at least two non-conjugated ethylenic double bonds in aqueous solution which contains 0.5-30% by weight of at least one electrolyte and, based on the monomers employed, 0.5-80% by weight of at least one surfactant, a process of the preparation thereof, and the use of the porous polymers.
摘要翻译： PCT No.PCT / EP96 / 03795 371日期1998年3月3日 102（e）1998年3月3日PCT PCT 1996年8月29日PCT公布。公开号WO97 / 09359 日期1997年3月13日为粉末形式并含有N-乙烯基咪唑单元的多孔聚合物，其可通过自由基沉淀聚合获得，a）5-100重量％的至少一种下式的N-乙烯基咪唑其中R1， R2和R3相同或不同，为H，C1-C4-烷基，N-乙烯基唑烷酮，N-乙烯基三唑，4-乙烯基吡啶N-氧化物或所述单体的混合物，b）0-95％重量的其它可共聚单烯键不饱和单体和c）0-50重量％的至少一种在水溶液中具有至少两个非共轭烯键双键的单体，其含有0.5-30重量％的至少一种电解质，并且基于所用的单体为0.5 -80重量％的至少一种表面活性剂，其制备方法和多孔聚合物的用途。

5. 发明授权

US5962613A Water soluble crosslinked copolymers, their preparation and their use 失效
标题翻译：水溶性交联共聚物，其制备及其用途
公开(公告)号：US5962613A
公开(公告)日：1999-10-05
申请号：US952114
申请日：1997-11-24
申请人： Christian Schade , Jurgen Detering , Stefan Stein , Dieter Boeckh , Hans-Ulrich Jager
发明人： Christian Schade , Jurgen Detering , Stefan Stein , Dieter Boeckh , Hans-Ulrich Jager
IPC分类号： C08F2/38 , C08F26/00 , C08F226/06 , C08L39/00 , C11D3/37 , C08F220/54
CPC分类号： C08F226/06 , C11D3/3776
摘要： Water-soluble copolymers which are obtainable by free-radical solution polymerization ofa) 10-99.5% by weight of at least one vinylimidazole of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl, monomers of the formula ##STR2## where R.sup.4 and R.sup.5 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl or together form a ring of 3 to 5 methylene groups,N-vinyloxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers,b) 0-89.5% by weight of other copolymerizable monoethylenically unsaturated monomers andc) 0.5-30% by weight of at least one monomer which acts as crosslinker and has at least two non-conjugated ethylenic double bondsin water and/or polar organic solvents in the presence of polymerization regulators, using from 0.1 to 5 parts by weight of polymerization regulator per 1 part by weight of crosslinker, a process for preparing the copolymers by free-radical solution polymerization of the monomers in the presence of polymerization regulators and the use of the copolymers as additive to detergents.
摘要翻译： PCT No.PCT / EP96 / 02179 371日期：1997年11月24日 102（e）1997年11月24日PCT PCT 1996年5月21日PCT公布。第WO96 / 37525号公报日期1996年11月28日可通过自由基溶液聚合获得的水溶性共聚物a）10-99.5重量％的至少一种下式的其中R 1，R 2和R 3相同或不同的乙烯基咪唑是H，C1 C 1-4烷基，其中R 4和R 5相同或不同并且是H，C 1 -C 4 - 烷基或一起形成3至5个亚甲基的环，N-乙烯基恶唑烷酮，N-乙烯基三唑，4-乙烯基吡啶N - 所述单体的混合物，b）0-89.5重量％的其它可共聚单烯属不饱和单体和c）0.5-30重量％的至少一种充当交联剂并且具有至少两个非共轭烯属双键的单体在聚合调节剂存在下，在水和/或极性有机溶剂中键合，每1重量份交联剂使用0.1至5重量份的聚合调节剂，通过单体的自由基溶液聚合制备共聚物的方法在po的存在裂解调节剂以及共聚物作为洗涤剂添加剂的用途。

6. 发明授权

US08759275B2 High-efficiency perfume capsules 有权
标题翻译：高效香水胶囊
公开(公告)号：US08759275B2
公开(公告)日：2014-06-24
申请号：US12939757
申请日：2010-11-04
申请人： Johan Smets , Pascale Claire Annick Vansteenwinckel , Yonas Gizaw , Frank Hulskotter , Dieter Boeckh , Hans-Joachim Haehnle
发明人： Johan Smets , Pascale Claire Annick Vansteenwinckel , Yonas Gizaw , Frank Hulskotter , Dieter Boeckh , Hans-Joachim Haehnle
IPC分类号： C11D17/00 , C11D17/06 , C11D3/50 , C11D3/60 , C11D11/00 , A61K8/11 , D06L1/16 , B08B7/00 , A61K8/81 , A01N25/28 , A61K8/73 , C09B67/02 , B01J13/22 , A23L1/22 , A23L1/00 , A61Q19/00
CPC分类号： C11D17/0039 , A01N25/28 , A23L27/72 , A23P10/30 , A61K8/11 , A61K8/585 , A61K8/731 , A61K8/8147 , A61K8/8152 , A61K2800/412 , A61Q5/02 , A61Q19/00 , B01J13/06 , B01J13/22 , C09B67/0097 , C11B9/00 , C11B9/0023 , C11D1/12 , C11D1/29 , C11D3/001 , C11D3/2044 , C11D3/225 , C11D3/3703 , C11D3/3723 , C11D3/373 , C11D3/505 , C11D11/0017 , C11D17/06
摘要： The present application relates to high efficiency particles and compositions, such as consumer products, comprising such high efficiency particles as well as processes for making and using such high efficiency particles and compositions comprising such high efficiency particles. Such high efficiency particles and compositions provide enhanced benefit agent delivery to a situs that is treated with such high efficiency particles and compositions.
摘要翻译：本申请涉及包含这种高效颗粒的高效颗粒和组合物，例如消费品，以及用于制备和使用这种高效颗粒的方法和包含这种高效颗粒的组合物。这种高效颗粒和组合物提供增强的有益剂递送到用这种高效颗粒和组合物处理的部位。

7. 发明授权

US08669221B2 Cleaning compositions with alkoxylated polyalkylenimines 有权
标题翻译：具有烷氧基化聚亚烷基亚胺的清洁组合物
公开(公告)号：US08669221B2
公开(公告)日：2014-03-11
申请号：US11918752
申请日：2006-04-12
申请人： Dieter Boeckh , Christian Bittner , Andrea Margret Misske , Arturo Luis Casado Dominguez
发明人： Dieter Boeckh , Christian Bittner , Andrea Margret Misske , Arturo Luis Casado Dominguez
IPC分类号： C11D3/30 , B08B3/04
CPC分类号： C11D3/3723 , C08G73/0206
摘要： Cleaning compositions comprising amphiphilic water-soluble alkoxylated polyalkylenimines having an inner polyethylene oxide block and an outer polypropylene oxide block.
摘要翻译：包含具有内部聚环氧乙烷嵌段和外部聚环氧丙烷嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺的清洗组合物。

8. 发明申请

US20130059927A1 Emulsions of Polyisobutenes, Substance and Process 审中-公开
公开(公告)号：US20130059927A1
公开(公告)日：2013-03-07
申请号：US13697485
申请日：2011-05-11
申请人： Dieter Boeckh , Klaus Mühlbach , Markus Brym , Sopia Ebert , Ivette Garcia Castro , Jack Tinsley , Rainer Dobrawa , Valentin Cepus , Rajan K. Panandiker , Julie Menkhaus , Frank Huelskoetter
发明人： Dieter Boeckh , Klaus Mühlbach , Markus Brym , Sopia Ebert , Ivette Garcia Castro , Jack Tinsley , Rainer Dobrawa , Valentin Cepus , Rajan K. Panandiker , Julie Menkhaus , Frank Huelskoetter
IPC分类号： C08L23/20 , A61K8/06 , C09D123/20 , A61K47/32 , C09J123/20
CPC分类号： C08K5/05 , C08L23/0846 , C08L23/22 , C08L2666/06
摘要： The present invention is directed to stable emulsions comprising polyolefins, in particular polyisobutene, the process to obtain said emulsions and the use of said emulsions.

9. 发明授权

US08143209B2 Cleaning compositions with amphiphilic graft polymers based on polyalkylene oxides and vinyl esters 有权
标题翻译：基于聚环氧烷和乙烯基酯的两亲接枝聚合物的清洗组合物
公开(公告)号：US08143209B2
公开(公告)日：2012-03-27
申请号：US12226185
申请日：2007-05-29
申请人： Dieter Boeckh , Lidcay Herrera Taboada , Asimina Kavarnou-Seiler , Gerd Konrad , Birgit Reinhard , Arturo Luis Casado-Dominguuez , Frank Hulskotter , James Lee Danziger
发明人： Dieter Boeckh , Lidcay Herrera Taboada , Asimina Kavarnou-Seiler , Gerd Konrad , Birgit Reinhard , Arturo Luis Casado-Dominguuez , Frank Hulskotter , James Lee Danziger
IPC分类号： C11D3/37 , C11D1/00
CPC分类号： C08F283/06 , C11D3/3788
摘要： Laundry detergent and cleaning compositions comprising amphiphilic graft polymers based on water-soluble polyalkylene oxides (A) as a graft base and side chains formed by polymerization of a vinyl ester component (B), said polymers having an average of ≦1 graft site per 50 alkylene oxide units and mean molar masses Mw of from 3000 to 100,000.
摘要翻译：洗衣洗涤剂和洗涤剂组合物，其包含基于水溶性聚环氧烷（A）作为接枝基质的两亲性接枝聚合物和通过乙烯基酯组分（B）的聚合形成的侧链，所述聚合物具有平均为nlE; 1个接枝位点/ 50个氧化烯单元，平均摩尔质量Mw为3000至100,000。

10. 发明申请

US20100286342A1 PROCESS FOR THE ALKOXYLATION OF AMINO GROUP CONTAINING POLYMERS 有权
标题翻译：含氨基聚合物的烷氧基化方法
公开(公告)号：US20100286342A1
公开(公告)日：2010-11-11
申请号：US12743754
申请日：2008-11-17
申请人： Dieter Boeckh , Stefan Frenzel , Christian Bittner , Andrea Misske , Ulrich Annen , Wilfried Sager , Sophia Ebert , Andreas Eichhorn
发明人： Dieter Boeckh , Stefan Frenzel , Christian Bittner , Andrea Misske , Ulrich Annen , Wilfried Sager , Sophia Ebert , Andreas Eichhorn
IPC分类号： C08F8/00
CPC分类号： C08G65/2618 , C08G65/2633 , C08G65/2648 , C08L71/02 , C08L77/00 , C08L79/00 , C08L2666/20
摘要： The present invention relates to a process for the alkoxylation of a first polymer comprising at least one monomer unit having NH groups and optionally NH2 groups, wherein the first polymer has a molecular weight Mw of at least 500 g/mol, comprising the steps of (a) reacting the first polymer with alkylene oxide in a reaction mixture comprising a solvent until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, is from 0.75 to 1.25; (b) adding a second polymer of formula (I), wherein R is a linear or branched alkyl group having from 1 to 20 carbon atoms, each R′ is independently a linear or branched alkyl group having from 1 to 20 carbon atoms or hydrogen, each n is independently from 1 to 5 and m is from 5 to 40, to the reaction mixture of step (a); (c) at least partially removing the solvent from the reaction mixture of step (b); and (d) further reacting the reaction mixture of step (c) with alkylene oxide at a given temperature until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, of the first polymer is from 2 to 40. The present invention also relates to a polymer composition obtainable from that process and the use of such a polymer composition.
摘要翻译：本发明涉及第一聚合物的烷氧基化方法，其包括至少一个具有NH基团和任选的NH 2基团的单体单元，其中第一聚合物的分子量Mw至少为500g / mol，包括步骤（ a）在包含溶剂的反应混合物中使第一聚合物与烯化氧反应，直到每个NH基团和每个任选的NH 2基团的平均烷氧基化程度计算为两个NH基团为0.75至1.25; （b）添加式（I）的第二聚合物，其中R是具有1至20个碳原子的直链或支链烷基，每个R'独立地是具有1至20个碳原子的直链或支链烷基或氢相对于步骤（a）的反应混合物，每个n独立地为1至5，m为5至40。（c）至少部分地从步骤（b）的反应混合物中除去溶剂; 和（d）在给定温度下使步骤（c）的反应混合物与烯化氧进一步反应，直到第一聚合物的两个NH基团计算的每个NH基团和每个任选的NH 2基团的平均烷氧基化程度为2 本发明还涉及可从该方法获得的聚合物组合物和这种聚合物组合物的用途。

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