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1. 发明授权

US5386007A Siloxane copolymers containing alkenyl groups, their preparation and their use 失效
标题翻译：含有烯基的硅氧烷共聚物，其制备及其应用
公开(公告)号：US5386007A
公开(公告)日：1995-01-31
申请号：US179408
申请日：1994-01-10
申请人： Christian Herzig , Michael Geck , Alfred Rengstl , Friedrich Hockemeyer , Helmut Oswaldbauer
发明人： Christian Herzig , Michael Geck , Alfred Rengstl , Friedrich Hockemeyer , Helmut Oswaldbauer
IPC分类号： C08L83/05 , C08G77/20 , C08G77/22 , C08G77/50 , C08L83/02 , C08L83/04 , C08L83/07 , C08L83/14 , C09D183/07 , C09D183/14 , D21H19/32 , C08G77/06
CPC分类号： D21H19/32 , C08G77/50 , C08L83/14 , C09D183/14
摘要： The present invention relates to siloxane copolymers containing alkenyl groups and a process for their preparation. The siloxane copolymers of the present invention can be used in cross-linkable compositions for the production of coatings which repel tacky substances, an example of which would include coatings for release papers or films.
摘要翻译：本发明涉及含烯基的硅氧烷共聚物及其制备方法。本发明的硅氧烷共聚物可用于生产排斥粘性物质的涂料的可交联组合物，其实例包括用于剥离纸或薄膜的涂料。

2. 发明授权

US5401821A Process for the preparation of an organopolysiloxane resin 失效
标题翻译：制备有机聚硅氧烷树脂的方法
公开(公告)号：US5401821A
公开(公告)日：1995-03-28
申请号：US165788
申请日：1993-12-13
申请人： Michael Geck , Christian Herzig , Bernward Deubzer , Helmut Oswaldbauer
发明人： Michael Geck , Christian Herzig , Bernward Deubzer , Helmut Oswaldbauer
IPC分类号： B01D19/04 , C08G77/06 , C08G77/32 , C08G77/36 , C09D7/12 , D21H19/32 , G03G9/087 , C08G77/08
CPC分类号： B01D19/0409 , C08G77/06 , C09D7/125 , D21H19/32 , G03G9/08773
摘要： Process for the preparation of an organopolysiloxane resin, which comprisesin a first stage reacting at least one silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)in which a has a value of 0, 1, 2 or 3, R and R.sup.1 are monovalent organic radicals which may be the same or different and/or a partial hydrolyzate thereof, with the proviso that at least one silane of formula (I), where a is 0 or 1 and/or a partial hydrolyzate thereof is employed, and optionally an organo(poly)siloxane with water in the presence of a poly-protic acid and optionally other substances, subsequently partly neutralizing the acid by addition of a base and then distilling off at least some of the compound R.sup.1 OH formed,in a second stage reacting the homogeneous reaction mass resulting from the first stage in the presence of a base and a water-insoluble organic solvent and distilling off the water and the compound R.sup.1 OH,in a third stage, bringing the homogeneous reaction mass resulting from the second stage to a pH of between 6 and 8 by buffering with a poly-protic acid and/or salts thereof, distilling off the water and any compound R.sup.1 OH still present and filtering off the salt which has precipitated, andoptionally, in a fourth stage separating the homogeneous reaction mass resulting from the third stage from the water-insoluble organic solvent.
摘要翻译：一种制备有机聚硅氧烷树脂的方法，该方法包括在第一阶段使至少一种式RaSi（OR1）4-a（I）的硅烷反应其中a值为0,1,2或3，R和 R 1是可以相同或不同的一价有机基团和/或其部分水解产物，条件是使用至少一种式（I）的硅烷，其中a为0或1，和/或其部分水解产物，和任选的有机（聚）硅氧烷与水在多质子酸和任选的其它物质的存在下，随后通过加入碱部分中和酸，然后在第二次蒸馏出至少一些所形成的化合物R 1 OH 在碱的存在和水不溶性有机溶剂的存在下使由第一阶段产生的均相反应物质反应，并在第三阶段中蒸馏除去水和化合物R1OH，使由第二阶段产生的均匀反应物质 pH在6 a之间通过用聚 - 质子酸和/或其盐缓冲，蒸出水和仍存在的任何化合物R1OH，并过滤沉淀的盐，并且任选地在第四阶段中分离由第三阶段来自水不溶性有机溶剂。

3. 发明授权

US5866666A Siloxane copolymers containing vinyloxy groups, their preparation and their use 失效
标题翻译：含有乙烯基氧基的硅氧烷共聚物，其制备及其应用
公开(公告)号：US5866666A
公开(公告)日：1999-02-02
申请号：US778796
申请日：1997-01-03
申请人： Christian Herzig , Alfred Rengstl
发明人： Christian Herzig , Alfred Rengstl
IPC分类号： C08G77/38 , C08G77/50 , C08G77/04
CPC分类号： C08G77/50 , C08G77/38
摘要： The present invention relates to siloxane copolymers containing vinyloxy groups and a method of preparing the siloxane copolymers. The copolymers of the present invention are useful for the production of coatings which can be crosslinked by light and radiation-curable printing inks.
摘要翻译：本发明涉及含有乙烯基氧基的硅氧烷共聚物和制备硅氧烷共聚物的方法。本发明的共聚物可用于生产可通过光和可辐射固化印刷油墨交联的涂料。

4. 发明授权

US5719248A Siloxane copolymers containing vinyloxy groups, their preparation and their use 失效
标题翻译：含有乙烯基氧基的硅氧烷共聚物，其制备及其应用
公开(公告)号：US5719248A
公开(公告)日：1998-02-17
申请号：US325232
申请日：1994-10-21
申请人： Christian Herzig , Alfred Rengstl
发明人： Christian Herzig , Alfred Rengstl
IPC分类号： C08F290/00 , C08F299/08 , C08G77/06 , C08G77/14 , C08G77/38 , C08G77/50 , C08L83/04 , C08L83/07 , C09D183/04 , C09D183/07 , C08G77/08
CPC分类号： C08G77/50 , C08G77/38
摘要： The invention relates to organopolysiloxane copolymers having at least one Si-bonded vinyloxy-functional group and their preparation. The compositions of the present compound crosslink particularly rapidly under light.
摘要翻译： PCT No.PCT / EP93 / 01115 Sec。 371日期：1994年10月21日 102（e）日期1994年10月21日PCT提交1993年5月6日PCT公布。公开号WO93 / 22369 日期：1993年11月11日本发明涉及具有至少一个Si键合的乙烯氧基官能团的有机聚硅氧烷共聚物及其制备方法。本发明化合物的组合物在光照下特别快速地交联。

5. 发明授权

US5134203A Crosslinkable compositions and their use in the production of coatings which repel sticky substances 失效
标题翻译：可交联组合物及其在生产涂覆物质的涂料中的用途
公开(公告)号：US5134203A
公开(公告)日：1992-07-28
申请号：US691912
申请日：1991-04-26
申请人： Friedrich Hockemeyer , Christian Herzig
发明人： Friedrich Hockemeyer , Christian Herzig
IPC分类号： C08L83/05 , C08L83/06 , C08L83/07 , C08L83/08 , C09D183/04 , C09D183/06 , C09D183/07 , C09D183/08 , C09J7/02 , C09J183/00 , C09J183/07 , D21H19/32 , D21H27/00 , D21H27/06
CPC分类号： D21H27/001 , C08L83/06 , C08L83/08 , C09D183/06 , C09D183/08 , D21H19/32 , D21H27/06
摘要： Crosslinkable compositions containing(1) An organopolysiloxane having alkenyloxy functional groups and containing Si-bonded radicals Y of the formula--(CH.sub.2).sub.2 --R.sup.1 --(A--R.sup.2).sub.z --O--R.sup.3 --CH.dbd.CH.sub.2, in whichA represents --O--, --S--or ##STR1## group, R.sup.1 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical of a cycloalkylene radical having from 5 to 7 carbon atoms per radical,R.sup.2 represents a straight-chain or branched alkylene radical having from 2 to 4 carbon atoms per radical, which can be substituted by a hydroxyl group, methoxy group, ethoxy group or trimethylsiloxy group,R.sup.3 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical, and z is 0, 1 or 2,(2) an organopolysiloxane containing Si-bonded hydrogen atoms, and(3) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.
摘要翻译：含有（1）具有烯氧基官能团并含有式 - （CH 2）2 -R 1 - （A-R 2）z O-R 3 -CH = CH 2的Si键合基团Y的有机聚硅氧烷的交联组合物，其中A表示-O- ，-S-或基团，R 1表示每个基团具有5至7个碳原子的环亚烷基基团具有1至7个碳原子的直链或支链亚烷基，R 2表示直链或每个基团具有2至4个碳原子的支链亚烷基，其可被羟基，甲氧基，乙氧基或三甲基甲硅烷氧基取代，R 3表示每个基团具有1至7个碳原子的直链或支链亚烷基，z为0,1或2，（2）含有Si键合的氢原子的有机聚硅氧烷，（3）促进将Si键合的氢加成脂肪族双键的催化剂。

6. 发明授权

US06274692B1 Cross-linkable compounds, optionally containing MQ silicon resins 有权
标题翻译：可交联的化合物，任选地含有MQ硅树脂
公开(公告)号：US06274692B1
公开(公告)日：2001-08-14
申请号：US09381414
申请日：1999-09-30
申请人： Christian Herzig , Oliver Zoellner , Friedrich Hockemeyer , Robert Banfic
发明人： Christian Herzig , Oliver Zoellner , Friedrich Hockemeyer , Robert Banfic
IPC分类号： C08G7720
CPC分类号： C09D183/04 , C08G77/20 , C09D183/14 , C08L83/00
摘要： The invention relates to new, cross-linkable compounds containing (A1) linear organopolysiloxanes with aliphatically unsaturated hydrocarbon radicals, said organopolysiloxanes being of general formula (I) R1aR3-aSiO(R2SiO)c[R2Si—Y—SiR2O(R2SiO)c]dSiR3-bR1b, wherein R can be the same or different, and represents a monovalent, optionally halogenated hydrocarbon radical which is free of terminal aliphatic carbon—carbon multiple bonds, R1 represents a monovalent aliphatically unsaturated hydrocarbon radical, Y represents a bivalent organic radical which is free of terminal aliphatic carbon—carbon multiple bonds, a is 0 or 1, b is 0 or 1, and the sum of a+b per molecule is 1 or 2, c is a whole number to the value of 1 to 1000, d is 0 or a whole number to the value of 1 to 10, and optionally, (A2) MQ silicone resins which are soluble in (A1), on the condition that if MQ silicone resins (A2) are not used, the sum of a+b in the formula (I) is 1.3 to 1.9 on average and that if MQ silicone resins (A2) are used, the sum of a+b in formula (I) is 1.0 to 1.9 on average; (B) organo-silicon compounds with Si-bonded hydrogen atoms; (C) catalysts which promote the formation of an aliphatic multiple bond by Si-bonded hydrogen; and optionally, (D) agents which slow down the formation of an aliphatic multiple bond by Si-bonded hydrogen at room temperature.
摘要翻译：本发明涉及含有（A1）具有脂肪族不饱和烃基的线性有机聚硅氧烷的新的可交联化合物，所述有机聚硅氧烷具有通式（I）R1aR3-aSiO（R2SiO）c [R2Si-Y-SiR2O（R2SiO）c] dSiR3 -bR1b，其中R可以相同或不同，并且表示没有末端脂族碳 - 碳多重键的单价任选卤代烃基，R1表示一价脂族不饱和烃基，Y表示二价有机基团，其为没有末端脂肪族碳 - 碳多重键，a为0或1，b为0或1，每分子a + b的和为1或2，c为1至1000的整数，d （A1）中可溶的（A2）MQ有机硅树脂，如果不使用MQ有机硅树脂（A2），则为0或0〜1的整数，式（I）中的+ b平均为1.3〜1.9，如果MQ有机硅树脂（A2），式（I）中a + b的和平均为1.0〜1.9; （B）具有硅键合氢原子的有机硅化合物; （C）促进通过Si键合氢形成脂族多重键的催化剂; 和任选的（D）在室温下通过Si键合的氢减慢形成脂族多重键的试剂。

7. 发明授权

US08598108B2 Fabric care compositions comprising organosiloxane polymers 有权
公开(公告)号：US08598108B2
公开(公告)日：2013-12-03
申请号：US13569373
申请日：2012-08-08
申请人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
发明人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C11D3/2072 , C11D3/373 , C11D3/3738 , C11D3/50 , C11D11/0017
摘要： The present composition relates to fabric care compositions comprising an organosiloxane polymer. Methods of using such compositions including contacting a fabric with the composition and rinsing the fabric are also disclosed.

8. 发明授权

US08263543B2 Fabric care compositions comprising organosiloxane polymers 有权
标题翻译：包含有机硅氧烷聚合物的织物护理组合物
公开(公告)号：US08263543B2
公开(公告)日：2012-09-11
申请号：US12752860
申请日：2010-04-01
申请人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
发明人： Rajan Keshav Panandiker , Kerry Andrew Vetter , Bernard William Kluesener , Iskender Yilgor , Christian Herzig , Richard Becker , Rafael Trujillo Rosaldo , Leslie Dawn Waits , Janine A. Flood , Keith Homer Baker , Jennifer Beth Ponder , Mark Gregory Solinsky , Matthew Scott Wagner , Pradipta Sarkar , Emily Suzanne Klinker , Julie Ann O'Neil
IPC分类号： C11D3/37
CPC分类号： C11D3/3742 , C11D3/2072 , C11D3/373 , C11D3/3738 , C11D3/50 , C11D11/0017
摘要： The present composition relates to fabric care compositions comprising an organosiloxane polymer. Methods of using such compositions including contacting a fabric with the composition and rinsing the fabric are also disclosed.
摘要翻译：本发明组合物涉及包含有机硅氧烷聚合物的织物护理组合物。还公开了使用这种组合物的方法，包括使织物与组合物接触并漂洗织物。

9. 发明授权

US08084552B2 Method for producing silicone polyethers 有权
标题翻译：硅氧烷聚醚的制备方法
公开(公告)号：US08084552B2
公开(公告)日：2011-12-27
申请号：US12921044
申请日：2009-03-03
申请人： Christian Herzig
发明人： Christian Herzig
IPC分类号： C08F283/06 , C08F283/12 , C08G77/46
CPC分类号： C08G77/46 , C08G77/12
摘要： Silicone polyethers are prepared in a two stage process by reacting an unsaturated polyether with a first Si—H functional organopolysiloxane and then with a second organopolysiloxane, in which the weight ratio of silicon bonded hydrogen in the first and second organopolysiloxanes is at least 0.9. The reaction is more rapid than a single step process and produces a product with less unreacted Si—H content.
摘要翻译：通过使不饱和聚醚与第一Si-H官能的有机聚硅氧烷，然后与第二有机聚硅氧烷反应制备硅氧烷聚醚，其中第一和第二有机聚硅氧烷中硅键合氢的重量比至少为0.9。反应比单步法更快，并产生具有较少未反应的Si-H含量的产物。

10. 发明授权

US07645360B2 Defoamer formulations 有权
标题翻译：消泡剂配方
公开(公告)号：US07645360B2
公开(公告)日：2010-01-12
申请号：US11915941
申请日：2006-05-24
申请人： Willibald Burger , Christian Herzig , Josef Wimmer
发明人： Willibald Burger , Christian Herzig , Josef Wimmer
IPC分类号： D21H21/00
CPC分类号： C08G18/61 , B01D19/0409 , C08G77/458
摘要： Defoamer compositions of high effectiveness containing at least one siloxane-based antifoam and polysiloxane copolymers obtained by coupling a polysiloxane bearing active-hydrogen-containing hydrophilic polymer moieties by means of a di- or polyisocyanate.
摘要翻译：通过用二异氰酸酯或多异氰酸酯偶联含有含活性氢的亲水性聚合物部分的聚硅氧烷获得的含有至少一种基于硅氧烷的消泡剂和聚硅氧烷共聚物的高效消泡剂组合物。

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