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1. 发明申请

US20110160412A1 HYBRID ORGANIC-INORGANIC MATERIALS THAT CONTAIN STABILIZED CARBENE 有权
标题翻译：混合有机无机材料，含有稳定的碳
公开(公告)号：US20110160412A1
公开(公告)日：2011-06-30
申请号：US12812535
申请日：2009-01-23
申请人： Chloe Thieuleux , Christophe Coperet , Laurent Veyre , Robert Corriu , Catherine Reye , Ahmad Mehdi , Jean-Marie Basset , Tarun Maishal , Malika Boualleg , Lyad Karame , Jean-Michel Camus , Johan Alauzun
发明人： Chloe Thieuleux , Christophe Coperet , Laurent Veyre , Robert Corriu , Catherine Reye , Ahmad Mehdi , Jean-Marie Basset , Tarun Maishal , Malika Boualleg , Lyad Karame , Jean-Michel Camus , Johan Alauzun
IPC分类号： C07F1/10 , C07F15/00 , C07C45/68 , C08F4/58
CPC分类号： B01J31/2273 , B01J31/0295 , B01J31/181 , B01J2231/4211 , B01J2531/821 , B01J2531/827 , B01J2540/32
摘要： The present invention relates to materials and particularly “organometallic-organic-inorganic hybrid materials” that can be used as heterogeneous catalysts for selective catalytic reactions. More precisely this invention relates to organic-inorganic hybrid nanostructured materials comprising a regularly distributed stabilized carbene that binds strongly to a metal so as to form a stable organometallic-organic-inorganic hybrid material having high catalytic performances.
摘要翻译：本发明涉及可用作选择性催化反应的非均相催化剂的材料，特别是“有机金属 - 有机 - 无机杂化材料”。更确切地说，本发明涉及有机 - 无机混合纳米结构材料，其包含与金属强烈结合的规则分布稳定的卡宾，以形成具有高催化性能的稳定的有机金属 - 有机 - 无机杂化材料。

2. 发明授权

US08871877B2 Hybrid organic-inorganic materials that contain stabilized carbene 有权
标题翻译：混合有机 - 无机材料，含有稳定的卡宾
公开(公告)号：US08871877B2
公开(公告)日：2014-10-28
申请号：US12812535
申请日：2009-01-23
申请人： Chloe Thieuleux , Christophe Coperet , Laurent Veyre , Robert Corriu , Catherine Reye , Ahmad Mehdi , Jean-Marie Basset , Tarun Maishal , Malika Boualleg , Iyad Karame , Jean-Michel Camus , Johan Alauzun
发明人： Chloe Thieuleux , Christophe Coperet , Laurent Veyre , Robert Corriu , Catherine Reye , Ahmad Mehdi , Jean-Marie Basset , Tarun Maishal , Malika Boualleg , Iyad Karame , Jean-Michel Camus , Johan Alauzun
IPC分类号： C07F1/10 , C07F15/00 , C07C45/68 , C08F4/58
CPC分类号： B01J31/2273 , B01J31/0295 , B01J31/181 , B01J2231/4211 , B01J2531/821 , B01J2531/827 , B01J2540/32
摘要： The present invention relates to materials and particularly “organometallic-organic-inorganic hybrid materials” that can be used as heterogeneous catalysts for selective catalytic reactions. More precisely this invention relates to organic-inorganic hybrid nanostructured materials comprising a regularly distributed stabilized carbene that binds strongly to a metal so as to form a stable organometallic-organic-inorganic hybrid material having high catalytic performances.
摘要翻译：本发明涉及可用作选择性催化反应的非均相催化剂的材料，特别是“有机金属 - 有机 - 无机杂化材料”。更确切地说，本发明涉及有机 - 无机混合纳米结构材料，其包含与金属强烈结合的规则分布稳定的卡宾，以形成具有高催化性能的稳定的有机金属 - 有机 - 无机杂化材料。

3. 发明申请

US20110257006A1 METHOD FOR PREPARING A STRUCTURED POROUS MATERIAL COMPRISING NANOPARTICLES OF METAL 0 IMBEDDED IN THE WALLS THEREOF 审中-公开
标题翻译：制备包含在其中的金属0纳米颗粒的结构化多孔材料的方法
公开(公告)号：US20110257006A1
公开(公告)日：2011-10-20
申请号：US13122420
申请日：2009-09-24
申请人： Chloe Thieuleux , Malika Boualleg , Jean-Pierre Candy , Laurent Veyre , Jean-Marie Basset
发明人： Chloe Thieuleux , Malika Boualleg , Jean-Pierre Candy , Laurent Veyre , Jean-Marie Basset
IPC分类号： B01J35/10 , B01J21/08 , B82Y30/00
CPC分类号： B01J29/0308 , B01J23/42 , B01J23/462 , B01J29/041 , B01J35/0013 , B01J35/006 , B01J35/1023 , B01J35/1028 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/18 , B82Y30/00 , C01B33/02 , C01G23/00 , C01G23/002 , C01P2002/72 , C01P2004/64 , C01P2004/84 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , C07C5/03 , C07C2523/745 , C07C15/073
摘要： The present invention relates to a process for producing a structured porous material comprising a structured inorganic framework made up of metal-oxide based walls in which nanoparticles of metal 0 are incorporated, which comprises the following steps: a) formation of a suspension of hydrophilic nanoparticles of metal 0 stabilized by non-exchangeable ligands that give the nanoparticles their hydrophilic character; b) growth of the inorganic framework from an inorganic precursor around the nanoparticles of metal 0 stabilized by the non-exchangeable hydrophilic ligands, in the presence of a pore-forming agent; and c) elimination of the pore-forming agent and at least partially of the non-exchangeable ligands that give the nanoparticles their hydrophilic character.
摘要翻译：本发明涉及一种生产结构化多孔材料的方法，其包括由金属氧化物基壁形成的结构化无机骨架，其中纳入金属O的纳米颗粒，其包括以下步骤：a）形成亲水性纳米颗粒的悬浮液的非可交换配体稳定的金属0，使纳米颗粒具有亲水性; b）在成孔剂存在下，通过由不可交换的亲水性配体稳定的金属0的纳米颗粒周围的无机前体生长无机骨架; 和c）消除造孔剂和至少部分不可交换的配体，使纳米颗粒具有亲水性。

4. 发明申请

US20080228020A1 Method for Converting Ethylene Into Propylene 失效
标题翻译：将乙烯转化成丙烯的方法
公开(公告)号：US20080228020A1
公开(公告)日：2008-09-18
申请号：US11571602
申请日：2005-06-27
申请人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
发明人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
IPC分类号： C07C2/02
CPC分类号： C07C6/04 , C07C2531/12 , Y02P20/584 , C07C11/06
摘要： The invention relates to a method for converting ethylene into propylene consisting in reacting said ethylene with a supported metal compound comprising an aluminium oxide based support to which a tungsten hydride is grafted. Said reaction is carried out at a temperature ranging from 20 to 600° C., preferably between 50 and 350° C., at an absolute pressure ranging from 0.01 to 8 MPa, preferably between 0.01 and 1 MPa. A catalyst is regeneratable by introducing hydrogen at a temperature of 50-300° C.
摘要翻译：本发明涉及一种将乙烯转化成丙烯的方法，该方法是使所述乙烯与负载型金属化合物反应，该金属化合物包含接枝有氢化钨的氧化铝基载体。所述反应在20〜600℃，优选50〜350℃的温度下进行，绝对压力为0.01〜8MPa，优选为0.01〜1MPa。催化剂可以通过在50-300℃的温度下引入氢气来再生

5. 发明授权

US07635794B2 Method for metathesis of compounds comprising an olefinic double bond, in particular olefins 失效
标题翻译：包含烯属双键，特别是烯烃的化合物的复分解方法
公开(公告)号：US07635794B2
公开(公告)日：2009-12-22
申请号：US11571395
申请日：2005-07-01
申请人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
发明人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
IPC分类号： C07C6/04
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/06
摘要： The invention relates to a method for metathesis of one or several reagents comprising a linear or branched hydrocarbon chain containing a double olefinic bond Csp2═Csp2 consisting in reacting said reagent or reagents with a supported metal compound comprising an aluminum oxide-based support to which a tungsten hydride is grafted. Typically, each said reagent or reagents comprises from 2 to 30 carbon atoms. The reagent can be embodied in the form of olefin. The inventive method can be used, for example for producing propylene from ethylene and butane.
摘要翻译：本发明涉及一种一种或多种试剂的复分解方法，其包含含有双重烯键Csp2-Csp2的直链或支链烃链，所述双链烯烃键Csp2-Csp2使所述试剂或试剂与包含氧化铝基载体的负载金属化合物反应，接枝氢化钨。通常，每个所述试剂或试剂包含2至30个碳原子。试剂可以以烯烃的形式实施。本发明的方法可用于例如从乙烯和丁烷生产丙烯。

6. 发明授权

US06878660B2 Catalyst fixed on a carrier and used for the metathesis of olefins 失效
标题翻译：催化剂固定在载体上并用于烯烃的复分解
公开(公告)号：US06878660B2
公开(公告)日：2005-04-12
申请号：US10363858
申请日：2001-09-14
申请人： Jean-Marie Basset , Mathieu Chabanas , Christophe Coperet
发明人： Jean-Marie Basset , Mathieu Chabanas , Christophe Coperet
IPC分类号： B01J31/26 , B01J31/12 , B01J31/16 , B01J31/22 , C07B61/00 , C07C2/34 , C07C6/04 , C07C11/02 , C07C11/08 , C07C11/107 , C07C13/12 , C07C67/475 , B01J31/00
CPC分类号： B01J31/1625 , B01J31/2265 , B01J2231/543 , B01J2231/74 , C07C6/04 , C07C67/475 , C07C2531/12 , C07C69/593
摘要： The present invention relates to a novel, heterogeneous catalyst which is suitable, in particular, for olefin metathesis. This catalyst is immobilized on an inorganic support and contains at least one active rhenium compound containing at least one carbene group and, if desired, further functional groups. The rhenium compound is bonded to the material used as support by a chemical bond.
摘要翻译：本发明涉及一种新的非均相催化剂，特别适用于烯烃复分解。将该催化剂固定在无机载体上，并含有至少一种含有至少一个卡宾基团的活性铼化合物，如果需要，还含有其它官能团。铼化合物通过化学键与用作载体的材料结合。

7. 发明授权

US06727397B2 Process for manufacturing alkanes with methane 失效
标题翻译：用甲烷制造烷烃的方法
公开(公告)号：US06727397B2
公开(公告)日：2004-04-27
申请号：US10040495
申请日：2002-01-09
申请人： Jean-Marie Basset , Christophe Coperet , Laurent Lefort , Barry Martin Maunders , Olivier Maury , Guillaume Saggio , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Laurent Lefort , Barry Martin Maunders , Olivier Maury , Guillaume Saggio , Jean Thivolle-Cazat
IPC分类号： C07C608
CPC分类号： B01J37/0203 , C07C6/10 , C07C2531/12
摘要： The present invention relates to a process for manufacturing alkanes, comprising, as main stage, a reaction resulting from bringing methane into contact with at least one other starting alkane (A) in the presence of a catalyst based on a metal M capable of catalyzing a metathesis of alkanes. The reaction results in the formation of at least one or two final alkanes (B) having a number of carbon atoms less than or equal to that of the starting alkane (A) and at least equal to 2. Preferably the catalyst comprises a hydride of a metal M grafted to and dispersed over a solid support. The metal M may be chosen from transition metals, lanthanides and actinides. The present invention also relates to the use of a catalyst capable of catalyzing a metathesis of alkanes in 3 reaction resulting from bringing methane into contact with at least one other starting alkane (A).
摘要翻译：本发明涉及一种制备烷烃的方法，该方法主要包括在催化剂存在下使甲烷与至少一种其它起始烷烃（A）接触而产生的反应，所述催化剂基于能够催化一种烷烃的复分解。反应导致至少一种或两种具有小于或等于起始烷烃（A）的碳原子的最终烷烃（B）的形成，并且至少等于2.优选地，催化剂包含金属M接枝并分散在固体支持物上。金属M可以选自过渡金属，镧系元素和锕系元素。本发明还涉及能够在使甲烷与至少一种其它起始烷烃（A）接触的情况下，在3反应中催化烷烃的复分解的催化剂的用途。

8. 发明授权

US07378564B2 Process for manufacturing alkanes by reacting other alkanes with methane 失效
标题翻译：通过使其他烷烃与甲烷反应制备烷烃的方法
公开(公告)号：US07378564B2
公开(公告)日：2008-05-27
申请号：US10502845
申请日：2003-01-22
申请人： Jean-Marie Basset , Christophe Coperet , Richard Pardy , Daravong Soulivong , John Glenn Sunley , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Christophe Coperet , Richard Pardy , Daravong Soulivong , John Glenn Sunley , Jean Thivolle-Cazat
IPC分类号： C07C6/08
CPC分类号： C07C6/10 , B01J21/08 , B01J31/121 , B01J37/0209 , C07C2531/12 , Y10S585/943
摘要： The present invention relates to a process for the manufacture of alkanes comprising a catalytic reaction resulting from contacting methane with at least one other starting alkane (I) in the presence of a metal compound (C) capable of catalysing a reaction for the splitting and/or recombination of a carbon-carbon bond and/or of a carbon-hydrogen bond and/or of a carbon-metal bond, which catalytic reaction results in the formation of at least one final alkane (II) having a number of carbon atoms equal to or greater than (2). In the process, the contacting operation is carried out under a methane partial pressure equal to or greater than 0.1 MPa, preferably in the range from 0.1 to 100 MPa. The metal compound (C) can be chosen from metal compounds supported on and dispersed over a solid support, metal compounds supported on and grafted to a solid support and non-supported metal compounds. Under these conditions, it was found that the yield of the catalytic reaction was improved, and that the catalytic stability and activity of the metal compound (C) over timer were greatly enhanced.
摘要翻译：本发明涉及一种制备烷烃的方法，其包括由甲烷与至少一种其它起始烷烃（I）在能够催化分解和/或反应的反应的金属化合物（C）存在下使甲烷接触而产生的催化反应，或碳 - 碳键和/或碳 - 氢键和/或碳 - 金属键的重组，该催化反应导致至少一个具有多个碳原子的最终烷烃（II）的形成相等至（2）以上。在该过程中，接触操作在等于或大于0.1MPa，优选在0.1至100MPa范围内的甲烷分压下进行。金属化合物（C）可以选自负载在固体载体上并分散在固体载体上的金属化合物，负载在和接枝到固体载体上的金属化合物和非负载的金属化合物。在这些条件下，发现催化反应的产率提高，金属化合物（C）超过定时器的催化稳定性和活性大大提高。

9. 发明授权

US07638672B2 Method for converting ethylene into propylene 失效
标题翻译：乙烯转化成丙烯的方法
公开(公告)号：US07638672B2
公开(公告)日：2009-12-29
申请号：US11571602
申请日：2005-06-27
申请人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
发明人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
IPC分类号： C07C6/04
CPC分类号： C07C6/04 , C07C2531/12 , Y02P20/584 , C07C11/06
摘要： The invention relates to a method for converting ethylene into propylene consisting in reacting said ethylene with a supported metal compound comprising an aluminium oxide based support to which a tungsten hydride is grafted. Said reaction is carried out at a temperature ranging from 20 to 600° C., preferably between 50 and 350° C., at an absolute pressure ranging from 0.01 to 8 MPa, preferably between 0.01 and 1 MPa. A catalyst is regeneratable by introducing hydrogen at a temperature of 50-300° C.
摘要翻译：本发明涉及一种将乙烯转化成丙烯的方法，该方法是使所述乙烯与负载型金属化合物反应，该金属化合物包含接枝有氢化钨的氧化铝基载体。所述反应在20〜600℃，优选50〜350℃的温度下进行，绝对压力为0.01〜8MPa，优选为0.01〜1MPa。催化剂可以通过在50-300℃的温度下引入氢气来再生

10. 发明授权

US07473814B2 Process for converting methane into ethane 失效
标题翻译：将甲烷转化为乙烷的方法
公开(公告)号：US07473814B2
公开(公告)日：2009-01-06
申请号：US10517212
申请日：2003-06-04
申请人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Martin Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Martin Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C2/00
CPC分类号： C07C2/76 , C07C2531/12 , Y10S585/943 , C07C9/06
摘要： The invention relates to a process for producing ethane comprising contacting methane with a metal catalyst selected from metal hydrides, metal organic compounds and mixtures thereof. It also relates to a process for the conversion of methane to carbon-containing products comprising contacting methane with a metal catalyst comprising at least one metal, Me, chosen from the lanthanides, the actinides and the metals from Groups 2 to 12 of the Periodic Table of the Elements, so as to produce ethane in a proportion of at least 65%, especially at least 98% or 99% by weight with respect to carbon-containing products formed in the process. The process can be a single-step process, preferably carried out under conditions involving a non-oxidative catalytic coupling of methane, in particular under operating conditions maintained substantially constant, preferably continuously, during the ethane production, e.g. at a temperature ranging from −30° C. to +80° C., preferably from 20° C. to 500° C., under a total absolute pressure ranging from 10−3 to 100 MPa, preferably from 0.1 to 50 MPa. The metal catalyst may be chosen from metal catalysts supported on and preferably grafted to a solid support. One of the main advantages of the present invention is to produce ethane with a very high selectivity.
摘要翻译：本发明涉及一种生产乙烷的方法，包括使甲烷与选自金属氢化物，金属有机化合物及其混合物的金属催化剂接触。它还涉及将甲烷转化为含碳产物的方法，包括使甲烷与包含至少一种金属的金属催化剂接触，所述金属催化剂选自镧系元素，锕系元素和元素周期表第2至12族中的金属的元素，以便相对于在该方法中形成的含碳产品，以至少65重量％，特别是至少98重量％或99重量％的比例制备乙烷。该方法可以是单步骤方法，优选在涉及甲烷的非氧化催化偶合的条件下进行，特别是在乙烷生产期间，优选连续保持基本上恒定的操作条件下，例如乙烷生产。在-30℃至+ 80℃，优选20℃至500℃的温度下，在绝对压力范围为10-3-100MPa，优选0.1-50MPa的温度下进行。金属催化剂可以选自负载在并优选接枝到固体载体上的金属催化剂。本发明的主要优点之一是以非常高的选择性生产乙烷。

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