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    • 2. 发明授权
    • High toughness, high strength sintered silicon nitride
    • 高韧性,高强度烧结氮化硅
    • US5312788A
    • 1994-05-17
    • US76940
    • 1993-06-16
    • Chien-Wei LiJean Yamanis
    • Chien-Wei LiJean Yamanis
    • C04B35/584C04B35/593C04B35/80C04B41/80C04B35/58
    • C04B41/80C04B35/5935C04B35/806
    • A silicon nitride sintered body has a composition consisting essentially of 85 to 94% by weight .beta. silicon nitride, 6 to 15% by weight grain boundary phase consisting essentially of (i) at least two rare earth elements, wherein yttrium is considered a rare earth, and, optionally, strontium which, calculated as SrO, is 0-2 percent by weight of the total body, and (ii) at least two of Si, N, O and C, and an additive consisting essentially of a metal-carbon compound present in the amount of about 0.2 to 3.5% by volume. The additive is substantially homogeneously dispersed within the sintered body. The sintered body has a density at least 95% of theoretical and the ceramic has high strength and high toughness and is especially suited for industrial applications such as components for gas turbine and automotive engines. The sintered body has a microstructure wherein (i) the .beta. silicon nitride grains are acicular and have an average grain width ranging from 0.5 to 1.5 .mu.m, (ii) at least 25% of the grains have width greater than 0.7 .mu.m, and at least 10% of the grains have width greater than 1 .mu.m, and (iii) no more than 5% of grains have width greater than 3.5 .mu.m and apparent aspect ratio greater than 5, with the proviso that the average aspect ratio is at least 1.8.
    • 氮化硅烧结体具有基本上由85至94重量%的β氮化硅,6至15重量%的晶界相组成的组成,其基本上由(i)至少两个稀土元素组成,其中钇被认为是稀土 ,和任选的以SrO计为0-2重量%的锶,和(ii)Si,N,O和C中的至少两个,以及基本上由金属 - 碳组成的添加剂 化合物的存在量为约0.2-3.5%(体积)。 添加剂基本均匀地分散在烧结体内。 烧结体的密度至少为理论值的95%,陶瓷具有高强度和高韧性,特别适用于燃气轮机和汽车发动机的部件等工业应用。 所述烧结体具有以下微结构:(i)所述β型氮化硅晶粒为针状,平均晶粒宽度为0.5〜1.5μm,(ii)所述晶粒的至少25%的宽度大于0.7μm, 至少10%的晶粒具有大于1μm的宽度,和(iii)不超过5%的晶粒宽度大于3.5μm,并且视在长宽比大于5,条件是平均纵横比为 至少1.8。
    • 7. 发明申请
    • COMPOSITE SEAL FOR FUEL CELLS, PROCESS OF MANUFACTURE, AND FUEL CELL STACK USING SAME
    • 燃料电池的复合密封,制造工艺和使用其的燃料电池堆叠
    • US20130101915A1
    • 2013-04-25
    • US13806152
    • 2010-06-25
    • Jean YamanisSunil G. WarrierSarah Arsenault-PreeceJustin R. Hawkes
    • Jean YamanisSunil G. WarrierSarah Arsenault-PreeceJustin R. Hawkes
    • H01M8/02
    • H01M8/028H01M8/0282H01M8/0286H01M8/2425H01M8/2432H01M8/2457H01M8/249Y02P70/56
    • A seal is provided for use in a solid oxide fuel cell, wherein the seal is formed of alternating adjacent layers of a fiber tow material and a foil material. A solid oxide fuel cell stack is also disclosed and is formed of repeating cell units, each cell unit having a plurality of fuel cell stack components defining opposed component surfaces, and the seal as described above positioned between the opposed component surfaces. A process is also provided for manufacturing a composite seal for a solid oxide fuel cell, and the process including the steps of: (a) feeding a quantity of spooled fiber tow material through an inert bonding agent to form a coated fiber tow material; (b) winding the coated fiber tow material about a mandrel to form a wound layer of fiber tow material; (c) feeding a quantity of spooled foil material about the wound layer of fiber tow material to form a wound layer of foil material; and (d) repeating steps (a) through (c) until forming a composite seal having desired thickness and width.
    • 提供用于固体氧化物燃料电池的密封件,其中密封件由交替的纤维丝束材料和箔材料的相邻层形成。 还公开了固体氧化物燃料电池堆,并且由重复的电池单元形成,每个电池单元具有限定相对的元件表面的多个燃料电池堆组件,以及定位在相对的组件表面之间的如上所述的密封件。 还提供了一种用于制造用于固体氧化物燃料电池的复合密封件的方法,该方法包括以下步骤:(a)通过惰性粘合剂将一定数量的缠绕纤维丝束材料供给以形成涂覆的纤维束材料; (b)围绕心轴卷绕涂覆的纤维丝束材料以形成纤维束材料的卷绕层; (c)在纤维丝束材料的缠绕层周围供给一定数量的缠绕箔材料以形成箔材料的卷绕层; 和(d)重复步骤(a)至(c),直到形成具有所需厚度和宽度的复合密封件。