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1. 发明授权

US4075130A Polyoxypropylene polyamine derivatives as defoamers 失效
标题翻译：作为防腐剂的聚氧丙烯聚氨酯衍生物
公开(公告)号：US4075130A
公开(公告)日：1978-02-21
申请号：US718490
申请日：1976-08-30
申请人： Carter G. Naylor , Ernest L. Yeakey
发明人： Carter G. Naylor , Ernest L. Yeakey
IPC分类号： B01D19/04 , C11D1/44 , C11D3/00 , C11D3/30 , C11D1/10 , C11D1/48
CPC分类号： C11D3/30 , B01D19/0413 , C11D1/44 , C11D3/0026
摘要： Novel defoamer and foam inhibitor compositions comprising the reaction product obtained by alkoxylating a polyoxypropylene polyamine having a molecular weight of 190-3000 and selected from the group consisting of a polyoxypropylene diamine of the formula ##STR1## wherein x is an integer of from about 1 to about 40, and a polyoxypropylene triamine of the formula ##STR2## where x, y and z represent integers in the range of about 1 to 15, and the sum of x, y and z is from 3 to about 50, said alkoxylation being carried out with ethylene oxide and a higher alkylene oxide of three carbons or more in a manner such that said defoamer composition has a cloud point of 10-60.degree. C. Said defoamer compositions are particularly useful as a minor portion of a dishwater detergent, and can be used in defoaming and inhibiting foam formation and in diverse types of normally foamable systems, particularly aqueous systems.

2. 发明授权

US4060501A Novolak derivatives as defoamers 失效
标题翻译：酚醛清漆衍生物作为消泡剂
公开(公告)号：US4060501A
公开(公告)日：1977-11-29
申请号：US718640
申请日：1976-08-30
申请人： Carter G. Naylor , Ernest L. Yeakey
发明人： Carter G. Naylor , Ernest L. Yeakey
IPC分类号： B01D19/04 , C11D3/00 , C11D3/37 , C11D1/72 , C11D1/76 , C11D3/20
CPC分类号： C11D3/0026 , B01D19/0404 , C11D3/3703
摘要： Novel defoamer and foam inhibitor compositions comprising the reaction product obtained by alkoxylating a novolak resin having a functionality less than 3, said alkoxylation being carried out with ethylene oxide and a higher alkylene oxide of 3 carbons or more in a manner such that the final defoamer composition has a cloud point of 10.degree.-60.degree. C. Said defoamer compositions are particularly useful as a minor portion of a dishwater detergent, and can be used in defoaming and inhibiting foam formation and in diverse types of normally foamable systems, particularly aqueous systems.
摘要翻译：新型消泡剂和泡沫抑制剂组合物，其包含通过使官能度小于3的酚醛清漆树脂进行烷氧基化而获得的反应产物，所述烷氧基化是用环氧乙烷和3个或更多个碳原子的较高环氧烷进行的，使得最终的消泡剂组合物具有10°-60℃的浊点。所述消泡剂组合物特别可用作洗碗水洗涤剂的少量部分，并且可用于消泡和抑制泡沫形成以及各种类型的通常可发泡的体系，特别是水性体系。

3. 发明授权

US5103062A Modified normally liquid, water-soluble polyoxyalkylene polyamines 失效
标题翻译：改性常规液体，水溶性聚氧化烯多胺
公开(公告)号：US5103062A
公开(公告)日：1992-04-07
申请号：US36955
申请日：1987-04-10
申请人： Michael Cuscurida , Ernest L. Yeakey
发明人： Michael Cuscurida , Ernest L. Yeakey
IPC分类号： C08G65/32 , C07C209/16 , C08G65/28
CPC分类号： C07C209/16
摘要： In accordance with the process of the present invention normally liquid, water-soluble poly(oxyethylene/oxypropylene) polyamine products are prepared using an initiator, which may contain oxyethylene groups. In a series of alkoxylation reaction steps the initiator is reacted with predetermined weight percentages of ethylene oxide and propylene oxide, said process comprising the steps of:a. Charging a predetermined percentage of initiator to an alkoxylation reaction zone,b. Alkoxylating said initiator therein with predetermined percentages of ethylene oxide and propylene oxide to provide an intermediate polyol,c. Propoxylating said intermediate polyol with a predetermined percentage of propylene oxide to provide a normally liquid, water-soluble precursor polyol, andd. Catalytically reductively aminating said precursor polyol in the presence of a reductive amination catalyst in a reaction zone under reductive amination conditions in the presence of ammonia and hydrogen to provide said water-soluble poly(oxyethylene/oxypropylene) polyamine product.
摘要翻译：根据本发明的方法，通常使用可含有氧乙烯基的引发剂来制备通常为水溶性的聚（氧乙烯/氧丙烯）多胺产物。在一系列烷氧基化反应步骤中，引发剂与预定重量百分比的环氧乙烷和环氧丙烷反应，所述方法包括以下步骤：a。将预定百分比的引发剂装入烷氧基化反应区，b。用预定百分比的环氧乙烷和环氧丙烷对所述引发剂进行烷氧基化以提供中间体多元醇，c。用预定百分比的环氧丙烷丙氧基化所述中间体多元醇以提供通常为液体的水溶性前体多元醇，和d。在还原胺化条件下，在氨和氢的存在下，在还原胺化催化剂存在下，在反应区域催化还原胺化所述前体多元醇，以提供所述水溶性聚（氧乙烯/氧丙烯）多胺产物。

4. 发明授权

US4628108A Production of 2-substituted-1,3-dioxolanes from 1,3-dioxolane and formaldehyde 失效
标题翻译：由1,3-二氧戊环和甲醛生产2-取代-1,3-二氧戊环
公开(公告)号：US4628108A
公开(公告)日：1986-12-09
申请号：US683548
申请日：1984-12-19
申请人： John R. Sanderson , Ernest L. Yeakey
发明人： John R. Sanderson , Ernest L. Yeakey
IPC分类号： C07D317/20 , C07D317/22 , C07D317/00
CPC分类号： C07D317/22 , C07D317/20
摘要： It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of an organic peroxide and an ionizable, at least sparingly soluble metal salt, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes. 2-Hydroxyalkyl-1,3-dioxolanes are hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
摘要翻译：根据本发明令人惊奇地发现，当1,3-二氧戊环与有机过氧化物和可电离的至少微溶的金属盐存在下，甲醛反应时，反应优先包括将甲醛加入到 1,3-二氧戊环的2-亚甲基与1,3-二氧戊环的4-亚甲基和5-亚甲基仅有很小的反应，由此形成的反应产物含有大量的2-羟基烷基-1， 3-二氧戊环。相对于乙二醇和相应的二醇醛（CHO-CH2-OH），2-羟基烷基-1,3-二氧戊环水解。二醇醛依次可以被催化氢化以形成额外量的乙二醇。

5. 发明授权

US4539378A Vinyl polymer polyols made using epoxy resin-modified polyols 失效
标题翻译：使用环氧树脂改性多元醇制备的乙烯基聚合物多元醇
公开(公告)号：US4539378A
公开(公告)日：1985-09-03
申请号：US654903
申请日：1984-09-27
申请人： Michael Cuscurida , Ernest L. Yeakey
发明人： Michael Cuscurida , Ernest L. Yeakey
IPC分类号： C08F283/00 , C08F283/06 , C08F283/10 , C08G18/00 , C08G18/63 , C08G65/32 , C08G18/14 , C08G18/67 , C08L71/02
CPC分类号： C08F283/10 , Y10S521/914
摘要： Vinyl polymer polyols made by polymerizing in situ via a free-radical mechanism one or more vinyl monomers in an epoxy resin-modified polyol are described. Preferably, styrene and acrylonitrile are copolymerized in a polyol made by adding epoxy resin to the alkoxylation of a polyol initiator having 3 to 4 hydroxyl groups. The vinyl polymer polyols of this invention give flexible polyurethane foams with greater load-bearing properties.
摘要翻译：描述了通过自由基机理在环氧树脂改性的多元醇中原位聚合制备的一种或多种乙烯基单体制备的乙烯基聚合物多元醇。优选地，苯乙烯和丙烯腈在通过添加环氧树脂制备的多元醇中共聚合到具有3至4个羟基的多元醇引发剂的烷氧基化。本发明的乙烯基聚合物多元醇提供具有更大承载性能的柔性聚氨酯泡沫。

6. 发明授权

US4539339A Polyurethane foams made from vinyl polymer polyols 失效
标题翻译：由乙烯基聚合物多元醇制成的聚氨酯泡沫
公开(公告)号：US4539339A
公开(公告)日：1985-09-03
申请号：US654904
申请日：1984-09-27
申请人： Michael Cuscurida , Ernest L. Yeakey , Bruce W. Peterson
发明人： Michael Cuscurida , Ernest L. Yeakey , Bruce W. Peterson
IPC分类号： C08G18/63 , C08G18/14 , C08G18/48
CPC分类号： C08G18/632 , Y10S521/914
摘要： Polyurethane foams employing vinyl polymer polyols made by polymerizing in situ via a free-radical mechanism one or more vinyl monomers in an epoxy resin-modified polyol are described. Preferably, styrene and acrylonitrile are copolymerized in a polyol made by adding epoxy resin to the alkoxylation of a polyol initiator having 3 to 4 hydroxyl groups. The vinyl polymer polyols of this invention give flexible polyurethane foams with greater load-bearing properties.
摘要翻译：描述了使用通过自由基机理原位聚合制备的乙烯基聚合物多元醇的聚氨酯泡沫，其中环氧树脂改性多元醇中的一种或多种乙烯基单体。优选地，苯乙烯和丙烯腈在通过添加环氧树脂制备的多元醇中共聚合到具有3至4个羟基的多元醇引发剂的烷氧基化。本发明的乙烯基聚合物多元醇提供具有更大承载性能的柔性聚氨酯泡沫。

7. 发明授权

US4049657A Preparation of N-(aminoalkyl)piperazine 失效
标题翻译：制备N-（氨基烷基）哌嗪
公开(公告)号：US4049657A
公开(公告)日：1977-09-20
申请号：US583019
申请日：1975-06-02
申请人： Michael E. Brennan , Philip H. Moss , Ernest L. Yeakey
发明人： Michael E. Brennan , Philip H. Moss , Ernest L. Yeakey
IPC分类号： C07D295/12 , B01J27/00 , C07B61/00 , C07D295/023 , C07D295/13 , C07D241/00
CPC分类号： C07D295/023 , C07D295/13
摘要： An improved process for selectively preparing an N-(aminoalkyl)piperazine compound is disclosed wherein piperazine is contacted with a primary or secondary amino alkanol compound in the presence of a catalytically effective amount of a phosphorus-containing substance at a temperature of from about 250.degree. to about 350.degree. C under a pressure sufficient to maintain the mixture essentially in liquid phase and the N-(aminoalkyl)piperazine is then recovered from the resultant reaction mixture. In a preferred embodiment piperazine is contacted with monoethanolamine to produce N-(2-aminoethyl)-piperazine.
摘要翻译：公开了一种用于选择性制备N-（氨基烷基）哌嗪化合物的改进方法，其中哌嗪在催化有效量的含磷物质存在下，在约250℃的温度下与伯或仲氨基烷醇化合物接触至约350℃，压力足以使混合物基本保持液相，然后从所得反应混合物中回收N-（氨基烷基）哌嗪。在优选的实施方案中，使哌嗪与单乙醇胺接触以产生N-（2-氨基乙基） - 哌嗪。

8. 发明授权

US3959374A Process for the preparation of mixed isomeric methylene-bridged polycyclohexylpolyamines 失效
标题翻译：混合异构亚甲基桥连多环己基多胺的制备方法
公开(公告)号：US3959374A
公开(公告)日：1976-05-25
申请号：US474380
申请日：1974-05-30
申请人： Michael E. Brennan , Ernest L. Yeakey
发明人： Michael E. Brennan , Ernest L. Yeakey
IPC分类号： C07C20060101 , C07C87/40
CPC分类号： C07C209/72
摘要： A process is described for the preparation of mixed isomeric methylene-bridged polycyclohexylpolyamines wherein a mixed isomeric methylene-bridged polyphenyl polyamine mixture having a functionality of from about 2.0 to about 3.3 is pretreated by contacting the mixture and hydrogen with a nickel-containing hydrogenation catalyst at a temperature of from about 25.degree.C. to about 250.degree.C. under a pressure of about 500 to about 15,000 psig. The pretreated isomeric polyamine is then hydrogenated in the presence of ammonia under conventional hydrogenation conditions employing a ruthenium-containing hydrogenation catalyst. The pretreatment step allows the utilization of mixed isomeric methylene-bridged polyphenyl polyamine feed mixtures for the production of isomeric methylene-bridged polycyclohexylpolyamines in high yields without attendant deactivation of the ruthenium hydrogenation catalyst heretofore observed. The process is particularly applicable to continuous operation.
摘要翻译：描述了制备混合异构亚甲基桥连的聚环己基多胺的方法，其中通过使混合物和氢与含镍氢化催化剂接触来预处理官能度为约2.0至约3.3的混合异构亚甲基桥接的聚苯基多胺混合物在约500至约15,000psig的压力下温度为约25℃至约250℃。然后将预处理的异构多胺在氨的存在下在常规氢化条件下使用含钌氢化催化剂进行氢化。预处理步骤允许以高产率利用混合的异构亚甲基桥接的聚苯胺多胺进料混合物来生产异构亚甲基桥连的聚环己基多胺，而无需先前观察到钌氢化催化剂的失活。该过程特别适用于连续操作。

9. 发明授权

US5449838A Isopropyl t-butyl ether (IPTBE) generation from crude acetone 失效
标题翻译：来自粗丙酮的异丙基叔丁基醚（IPTBE）
公开(公告)号：US5449838A
公开(公告)日：1995-09-12
申请号：US175450
申请日：1993-12-30
申请人： John F. Knifton , Ernest L. Yeakey , Pei-Shing E. Dai
发明人： John F. Knifton , Ernest L. Yeakey , Pei-Shing E. Dai
IPC分类号： B01J23/755 , B01J29/70 , B01J29/74 , B01J29/76 , B01J29/78 , B01J31/10 , C07B61/00 , C07C29/145 , C07C41/09 , C07C43/04 , C07C41/00 , C07C43/00
CPC分类号： C07C41/09 , C07C29/145
摘要： Disclosed is a two-step process for the generation of isopropyl t-butyl ether from a crude by-product acetone stream which comprises:a) Hydrogenating said crude acetone over a bulk metal, nickel-rich catalyst to give an isopropanol-rich effluent;b) subjecting said isopropanol-rich intermediate to etherification conditions in the presence of a strong acid catalyst selected from:(1) a cationic resin;(2) a .beta.-zeolite;(3) dealuminized Y-zeolites; and(4) metal-modified .beta.-zeolites.
摘要翻译：公开了从粗副产物丙酮流中产生异丙基叔丁基醚的两步法，该方法包括：a）在大体积金属的富镍催化剂上氢化所述粗丙酮，得到富含异丙醇的流出物; b）在强酸催化剂存在下，使富含异丙醇的中间体经历醚化条件，所述强酸催化剂选自：（1）阳离子树脂; （2）β-沸石; （3）脱铝Y沸石; 和（4）金属改性β-沸石。

10. 发明授权

US4952732A Mannich condensates of a substituted phenol and an alkylamine containing internal alkoxy groups 失效
标题翻译：取代苯酚和含有内部烷氧基的烷基胺的曼尼希缩合物
公开(公告)号：US4952732A
公开(公告)日：1990-08-28
申请号：US621332
申请日：1984-06-15
申请人： George P. Speranza , Robert A. Grigsby, Jr. , Ernest L. Yeakey
发明人： George P. Speranza , Robert A. Grigsby, Jr. , Ernest L. Yeakey
IPC分类号： B01F17/00 , C07C217/50 , C09D7/12 , C23F11/14
CPC分类号： C07C217/50 , B01F17/0042 , B01F17/005 , C09D7/1233 , C23F11/142
摘要： Products useful as surfactants, corrosion inhibitors, water repellent agents, paint adhesion promoters, etc. are prepared by reacting formaldehyde and a phenol with an alkyl amine containing internal propoxy or propoxy/ethoxy groups to thereby provide a corresponding Mannich condensate having a desired utility. The Mannich condensates may also be reacted with an alkylene oxide feed stock containing ethylene oxide or propylene oxide or 1,2-butylene oxide or a mixture thereof under conventional alkoxylation conditions to thereby provide a corresponding alkoxylated Mannich condensate having a utility which may be the same as or different from the utility of the initial Mannich condensate.
摘要翻译：通过使甲醛和苯酚与含有内丙氧基或丙氧基/乙氧基的烷基胺反应制备用作表面活性剂，防腐蚀剂，防水剂，涂料粘合促进剂等的产品，从而提供具有所需效用的相应的曼尼希缩合物。曼尼希缩合物也可以在常规烷氧基化条件下与含有环氧乙烷或环氧丙烷或1,2-环氧丁烷或其混合物的烯化氧原料反应，从而提供相应的烷氧基化曼尼希缩合物，其具有可能相同的效用作为或不同于最初的曼尼希凝析油的效用。

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