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1. 发明授权

US06605191B1 Method for reprocessing reaction mixtures containing diaryl carbonate 失效
标题翻译：后处理含有碳酸二芳基酯的反应混合物的方法
公开(公告)号：US06605191B1
公开(公告)日：2003-08-12
申请号：US09868298
申请日：2001-06-15
申请人： Carsten Hesse , Ursula Jansen , Johann Rechner , Claus-Peter Reisinger , Rob Eek , Kaspar Hallenberger , Martin Friedrich
发明人： Carsten Hesse , Ursula Jansen , Johann Rechner , Claus-Peter Reisinger , Rob Eek , Kaspar Hallenberger , Martin Friedrich
IPC分类号： B01D122
CPC分类号： C07C68/08 , C07C69/96
摘要： A process for the work up of a reaction mixture obtained from the preparation of diaryl carbonate by direct carbonylation of aromatic hydroxy compounds is disclosed. The process entails obtaining a reaction mixture that contains diaryl carbonate, aromatic hydroxy compound, water, base and quaternary salt, separating the mixture in a distillation apparatus having only one theoretical separation stage into a liquid phase and a gas phase and recycling the liquid phase without further work up to the reaction step of the direct carbonylation.
摘要翻译：公开了通过芳族羟基化合物的直接羰基化制备碳酸二芳基酯获得的反应混合物的处理方法。该方法需要获得含有碳酸二芳基酯，芳族羟基化合物，水，碱和季盐的反应混合物，在仅具有一个理论分离阶段的蒸馏装置中将混合物分离成液相和气相并循环液相而没有进一步处理直接羰基化的反应步骤。

2. 发明授权

US06437166B1 Method for reprocessing reaction mixtures containing diaryl carbonate 失效
标题翻译：后处理含有碳酸二芳基酯的反应混合物的方法
公开(公告)号：US06437166B1
公开(公告)日：2002-08-20
申请号：US09868412
申请日：2001-06-14
申请人： Carsten Hesse , Ursula Jansen , Johann Rechner , Claus-Peter Reisinger , Rob Eek , Kaspar Hallenberger , Martin Friedrich
发明人： Carsten Hesse , Ursula Jansen , Johann Rechner , Claus-Peter Reisinger , Rob Eek , Kaspar Hallenberger , Martin Friedrich
IPC分类号： C07C6996
CPC分类号： C07C68/08 , C07C69/96
摘要： A process for the work up of reaction mixtures containing diaryl carbonate, aromatic hydroxy compound, water, base and quaternary salt, which are obtained in the preparation of diaryl carbonates by direct carbonylation of aromatic hydroxy compounds, is described. In the process of the present invention an adduct of diaryl carbonate and aromatic hydroxy compound is crystallized from the reaction mixture. A distillate comprising aromatic hydroxy compound is removed from the liquid phase either prior to or after crystallization of the adduct of diaryl carbonate and aromatic hydroxy compound. The liquid phase remaining after the crystallization and distillation steps may be recycled, without further work up, back to the direct carbonylation process step by which the diaryl carbonate is initially prepared.
摘要翻译：描述了通过芳族羟基化合物的直接羰基化制备碳酸二芳酯中获得的包含碳酸二芳基酯，芳族羟基化合物，水，碱和季盐的反应混合物的处理方法。在本发明的方法中，碳酸二芳酯和芳族羟基化合物的加合物从反应混合物中结晶。在碳酸二芳基酯和芳族羟基化合物的加合物结晶之前或之后，从液相中除去包含芳族羟基化合物的馏出物。在结晶和蒸馏步骤后残留的液相可以循环使用，而不需要进一步的后处理，回到最初制备碳酸二芳基酯的直接羰基化工艺步骤。

3. 发明授权

US06469191B1 Method for producing diaryl carbonates 失效
标题翻译：碳酸二芳基酯的制备方法
公开(公告)号：US06469191B1
公开(公告)日：2002-10-22
申请号：US09868558
申请日：2001-06-19
申请人： Claus-Peter Reisinger , Ursula Jansen , Johann Rechner , Rob Eek
发明人： Claus-Peter Reisinger , Ursula Jansen , Johann Rechner , Rob Eek
IPC分类号： C07C6996
CPC分类号： C07C68/005 , C07C69/96
摘要： A process for the production of an aromatic carbonate is disclosed. Accordingly, an aromatic hydroxy compound is reacted with carbon monoxide and oxygen in the presence of a platinum group metal catalyst, a co-catalyst, a base, and optionally a quaternary salt as well as an inert organic solvent. The reaction is carried out under conditions whereby the inert organic solvent forms an azeotrope with the water arising during the reaction. The azeotrope is then removed from the reaction mixture.
摘要翻译：公开了一种生产芳族碳酸酯的方法。因此，在铂族金属催化剂，助催化剂，碱，任选的季盐以及惰性有机溶剂的存在下，芳族羟基化合物与一氧化碳和氧反应。该反应在惰性有机溶剂与反应期间产生的水形成共沸物的条件下进行。然后从反应混合物中除去共沸物。

4. 发明授权

US06177538B1 Method for producing tetrabutyl ammonium phenolate diphenol adduct 失效
标题翻译：生产四丁基苯酚酚二酚加合物的方法
公开(公告)号：US06177538B1
公开(公告)日：2001-01-23
申请号：US09446999
申请日：1999-12-30
申请人： Carsten Hesse , Ursula Jansen , Johann Rechner
发明人： Carsten Hesse , Ursula Jansen , Johann Rechner
IPC分类号： C08G6538
CPC分类号： B01J31/0239 , C07C37/055 , C07C37/64 , C07C37/72 , C07C37/82 , C07C209/68 , Y02P20/52 , C07C211/63 , C07C39/04 , C07C39/235
摘要： The invention relates to a method for producing and purifying tetrabutyl ammonium phenolate diphenol adduct by reacting an alkali phenolate with tetrabutyl ammonium salts in an aqueous phase and subsequently precipitating the adduct by adding phenol.
摘要翻译：本发明涉及通过在水相中使碱性酚盐与四丁基铵盐反应并随后通过加入苯酚使加合物沉淀来生产和提纯四丁基苯酚酚二酚加合物的方法。

5. 发明授权

US07056855B1 Liquid tetrabutyl ammonium phenolate formulation 失效
标题翻译：液体四丁基铵苯酚盐配方
公开(公告)号：US07056855B1
公开(公告)日：2006-06-06
申请号：US09868489
申请日：1999-12-09
申请人： Carsten Hesse , Ursula Jansen , Johann Rechner
发明人： Carsten Hesse , Ursula Jansen , Johann Rechner
IPC分类号： B01J31/00
CPC分类号： B01J31/0279 , C07C37/00 , Y02P20/52 , C07C39/04
摘要： A process for preparing a formulation containing tetrabutylammonium phenolate and phenol is disclosed. The process entails combining a solution of tetrabutylammonium bromide in phenol with a solution of sodium phenolate to form a mixture, excess phenol is removed by distillation, and sodium bromide is filtered off. The formulation, that contains tetrabutylammonium phenolate and phenol in a weight ratio of 40:60 to 70:30, has a solidification point of less than 25° C. and finds use as a catalyst constituent.
摘要翻译：公开了一种制备含有四丁基苯酚铵和苯酚的制剂的方法。该方法需要将苯酚中的四丁基溴化铵溶液与苯酚钠溶液混合以形成混合物，通过蒸馏除去过量的苯酚，并滤出溴化钠。含有重量比为40:60〜70:30的苯酚四丁铵和苯酚的配方具有小于25℃的固化点，可用作催化剂成分。

6. 发明授权

US09040732B2 Process for preparing diaryl carbonates from dialkyl carbonates 有权
标题翻译：由碳酸二烷基酯制备碳酸二芳基酯的方法
公开(公告)号：US09040732B2
公开(公告)日：2015-05-26
申请号：US12483669
申请日：2009-06-12
申请人： Andre Düx , Guenter Olf , Kaspar Hallenberger , Georg Ronge , Ricarda Leiberich , Johan Vanden Eynde , Wim Wuytack , Pieter Ooms , Johann Rechner
发明人： Andre Düx , Guenter Olf , Kaspar Hallenberger , Georg Ronge , Ricarda Leiberich , Johan Vanden Eynde , Wim Wuytack , Pieter Ooms , Johann Rechner
IPC分类号： C07C69/96 , C07C68/06
CPC分类号： C07C68/06 , Y02P20/124 , C07C69/96
摘要： The invention provides a process for preparing diaryl carbonates from dialkyl carbonates and aromatic hydroxyl compounds using at least two reaction columns, a process section for recovering the dialkyl carbonate used in the reaction and for removing the alcohol of reaction, one or more process steps for removing the by-products obtained in the process which have a boiling point between that of the dialkyl carbonate and that of the alkyl aryl carbonate formed during the preparation of the diaryl carbonate, and a process step for further purification of the diaryl carbonate obtained from the reaction columns.
摘要翻译：本发明提供了一种使用至少两个反应塔从碳酸二烷基酯和芳族羟基化合物制备碳酸二芳基酯的方法，用于回收反应中使用的二烷基碳酸酯和用于除去反应醇的工艺部分，一个或多个除去工艺步骤在碳酸二烷基酯碳酸二烷基酯和碳酸二芳基酯的碳酸烷基芳基酯的沸点相同的过程中获得的副产物，以及从反应中得到的进一步纯化碳酸二芳基酯的工艺步骤列。

7. 发明申请

US20110206568A1 PROCESS FOR THE PREPARATION OF DIARYL CARBONATES OR ARYLALKYL CARBONATES FROM DIALKYL CARBONATES 审中-公开
标题翻译：从碳酸二甲酯制备二元碳酸酯或碳酸亚乙酯的方法
公开(公告)号：US20110206568A1
公开(公告)日：2011-08-25
申请号：US13102255
申请日：2011-05-06
申请人： Andre Düx , Pieter Ooms , Johann Rechner , Kaspar Hallenberger , Georg Ronge , Johan Vanden Eynde
发明人： Andre Düx , Pieter Ooms , Johann Rechner , Kaspar Hallenberger , Georg Ronge , Johan Vanden Eynde
IPC分类号： B01J8/06
CPC分类号： C07C68/06 , B01D3/009 , Y02P20/127 , C07C69/96
摘要： The invention provides a process for the preparation of diaryl carbonates and/or alkylaryl carbonates from dialkyl carbonates and aromatic hydroxy compounds using one or more intermediate condensers for improving heat integration.
摘要翻译：本发明提供了一种使用一种或多种中间冷凝器制备碳酸二芳基酯和/或碳酸二烷基酯从碳酸二烷基酯和芳族羟基化合物制备方法，用于改善热量积分。

8. 发明申请

US20100010252A1 PROCESS FOR PREPARING DIARYL CARBONATES FROM DIALKYL CARBONATES 有权
标题翻译：从碳酸二乙酯制备二元碳酸盐的方法
公开(公告)号：US20100010252A1
公开(公告)日：2010-01-14
申请号：US12483669
申请日：2009-06-12
申请人： Andre Düx , Guenter Olf , Kaspar Hallenberger , Georg Ronge , Ricarda Leiberich , Johan Vanden Eynde , Wim Wuytack , Pieter Ooms , Johann Rechner
发明人： Andre Düx , Guenter Olf , Kaspar Hallenberger , Georg Ronge , Ricarda Leiberich , Johan Vanden Eynde , Wim Wuytack , Pieter Ooms , Johann Rechner
IPC分类号： C07C69/96
CPC分类号： C07C68/06 , Y02P20/124 , C07C69/96
摘要： The invention provides a process for preparing diaryl carbonates from dialkyl carbonates and aromatic hydroxyl compounds using at least two reaction columns, a process section for recovering the dialkyl carbonate used in the reaction and for removing the alcohol of reaction, one or more process steps for removing the by-products obtained in the process which have a boiling point between that of the dialkyl carbonate and that of the alkyl aryl carbonate formed during the preparation of the diaryl carbonate, and a process step for further purification of the diaryl carbonate obtained from the reaction columns.
摘要翻译：本发明提供了一种使用至少两个反应塔从碳酸二烷基酯和芳族羟基化合物制备碳酸二芳基酯的方法，用于回收反应中使用的二烷基碳酸酯和用于除去反应醇的工艺部分，一个或多个除去工艺步骤在碳酸二烷基酯碳酸二烷基酯和碳酸二芳基酯的碳酸烷基芳基酯的沸点相同的过程中获得的副产物，以及从反应中得到的进一步纯化碳酸二芳基酯的工艺步骤列。

9. 发明授权

US08952189B2 Process for preparing diaryl carbonates or alkyl aryl carbonates from dialkyl carbonates 有权
标题翻译：由碳酸二烷基酯制备碳酸二芳基酯或碳酸烷基酯的方法
公开(公告)号：US08952189B2
公开(公告)日：2015-02-10
申请号：US12755873
申请日：2010-04-07
申请人： Andre Düx , Helmut Mothes , Kaspar Hallenberger , Georg Ronge , Rafael Warsitz , Pieter Ooms , Johann Rechner
发明人： Andre Düx , Helmut Mothes , Kaspar Hallenberger , Georg Ronge , Rafael Warsitz , Pieter Ooms , Johann Rechner
IPC分类号： C07C68/06 , C07C69/96
CPC分类号： C07C68/06 , Y02P20/127 , C07C69/96
摘要： The invention relates to a process for preparing diaryl carbonates and/or alkyl aryl carbonates from dialkyl carbonates and aromatic hydroxy compounds using a reactive dividing wall column.
摘要翻译：本发明涉及使用反应性分隔壁塔从碳酸二烷基酯和芳族羟基化合物制备碳酸二芳基酯和/或烷基芳基碳酸酯的方法。

10. 发明授权

US08039659B2 Processes for preparing diaryl and/or alkylaryl carbonates from dialkyl carbonates 有权
标题翻译：由碳酸二烷基酯制备二芳基和/或烷基芳基碳酸酯的方法
公开(公告)号：US08039659B2
公开(公告)日：2011-10-18
申请号：US12210279
申请日：2008-09-15
申请人： Andre Düx , Pieter Ooms , Johann Rechner , Matthias Böhm , Kaspar Hallenberger , Georg Ronge , Johan Vanden Eynde
发明人： Andre Düx , Pieter Ooms , Johann Rechner , Matthias Böhm , Kaspar Hallenberger , Georg Ronge , Johan Vanden Eynde
IPC分类号： C07C69/96
CPC分类号： C07C68/06 , C07C69/96
摘要： Processes comprising: reacting a dialkyl carbonate and an aromatic hydroxy compound in the presence of a transesterification catalyst in a first reaction column, the first reaction column comprising a top section, a bottom section, a rectifying section in an upper portion of the column and a reaction zone below the rectifying section; feeding a bottom product from the first reaction column to a further reaction column; the bottom product comprising a diaryl carbonate, an alkylaryl carbonate, or both, and residual unreacted dialkyl carbonate and aromatic hydroxy compound; the further reaction column comprising a top section, a rectifying section in an upper portion of the column and a reaction zone below the rectifying section; and reacting the residual unreacted dialkyl carbonate and aromatic hydroxy compound in the further reaction column; feeding a process stream to a distillation column, the process stream comprising a mixture of unreacted dialkyl carbonate and one or more reaction-product alcohols drawn from the first reaction column, the further reaction column, or both, such that the unreacted dialkyl carbonate is separated from the one or more reaction-product alcohols; and recycling the separated, unreacted dialkyl carbonate to the first reaction column; wherein the further reaction column comprises one or more condensers, and heat of condensation from the one or more condensers is fed back into the process.
摘要翻译：方法包括：在第一反应塔中的酯交换催化剂存在下使碳酸二烷基酯和芳族羟基化合物反应，所述第一反应塔包括塔的上部的顶部，底部，精馏段和整流段下方的反应区; 将底部产物从第一反应塔进料至另一反应塔; 底部产物包含碳酸二芳基酯，碳酸二烷基酯或二者，和残留的未反应的碳酸二烷基酯和芳族羟基化合物; 所述另外的反应塔包括顶部，所述塔的上部的精馏部和所述精馏部下方的反应区; 并使残留的未反应的碳酸二烷基碳酸酯和芳族羟基化合物在另外的反应塔中反应; 将工艺流输送到蒸馏塔，所述工艺流包含未反应的碳酸二烷基酯和从第一反应塔，进一步的反应塔或两者中抽出的一种或多种反应产物醇的混合物，使得未反应的碳酸二烷基酯被分离由一种或多种反应产物醇; 并将分离的未反应的碳酸二烷基酯再循环到第一反应塔中; 其中所述另外的反应塔包括一个或多个冷凝器，并且将来自所述一个或多个冷凝器的冷凝热反馈到所述方法中。

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