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1. 发明申请

US20120125233A1 ORGANICALLY MODIFIED SILICA AND USE THEREOF 有权
标题翻译：有机改性二氧化硅及其用途
公开(公告)号：US20120125233A1
公开(公告)日：2012-05-24
申请号：US13360238
申请日：2012-01-27
申请人： Brian T. Holland , Ji Cui , Timothy S. Keizer
发明人： Brian T. Holland , Ji Cui , Timothy S. Keizer
IPC分类号： C09D7/12 , B32B5/16 , B82Y99/00
CPC分类号： C07F7/1804 , C07B2200/11 , Y10T428/2982
摘要： Disclosed and claimed is a novel protective coating for metal surfaces. The protective coating includes one part by weight of the organosilane-modified silica nanoparticles made by the disclosed process and further includes from 0.3 to 3 parts by weight of the reaction product of (1) a compound comprising a polyamine in which a plurality of amine groups are bonded to at least one radical selected from the group consisting of hydrocarbon and hydrocarbon ether groups that separate nitrogen atoms of said amine groups by at least four intermediate atoms in a chain, and (2) a silane which carries a plurality of silicon-bonded hydrolyzable groups and a silicon-bonded organic group that is covalently reactive to and which bonds with said amine group, said silane also comprising hydrolyzable groups, to provide a reaction product molecule which comprises an average of 2.5 to 3.5 silane groups per molecule.
摘要翻译：公开并要求保护的是用于金属表面的新型保护涂层。保护涂层包括由所公开的方法制备的一份重量的有机硅烷改性二氧化硅纳米颗粒，并且还包括0.3至3重量份的（1）包含多胺的化合物的反应产物，其中多个胺基与至少一种选自烃和烃醚基团的基团键合，所述烃基和烃醚基团将所述胺基团的氮原子分成链中至少四个中间原子，和（2）硅烷，其携带多个硅键合可水解基团和与所述胺基共价反应并与其结合的硅键合的有机基团，所述硅烷还包含可水解基团，以提供包含平均每分子2.5至3.5个硅烷基团的反应产物分子。

2. 发明申请

US20070282122A1 Organically modifid silica and use thereof 有权
标题翻译：有机二氧化硅及其用途
公开(公告)号：US20070282122A1
公开(公告)日：2007-12-06
申请号：US11443515
申请日：2006-05-30
申请人： Brian T. Holland , Ji Cui , Timothy S. Keizer
发明人： Brian T. Holland , Ji Cui , Timothy S. Keizer
IPC分类号： C07F7/00
CPC分类号： C07F7/1804 , C07B2200/11 , Y10T428/2982
摘要： Organosilane-modified nanoparticles of silica, having a particle size of no more than 1 micron, in which the organosilane resides throughout the entire volume of the nanoparticles and not just at the surfaces of the nanoparticle. The nanoparticles may be in a colloidal solution. They may be prepared by hydrolyzing an alkali silicate under acidic conditions to obtain a silicic acid dispersion, followed by adding an organosilane having hydroxyl and/or hydrolyzable groups to the dispersion under acid conditions; and then raising the pH of the dispersion to at least eight to form the nanoparticles. They may be used in an effective paint primer/protective coating formulation.
摘要翻译：有机硅烷改性的二氧化硅纳米颗粒，其粒径不超过1微米，其中有机硅烷位于纳米颗粒的整个体积内，而不仅仅在纳米颗粒的表面。纳米颗粒可以是胶体溶液。它们可以通过在酸性条件下水解碱金属硅酸盐来获得硅酸分散体，然后在酸性条件下向分散体中加入具有羟基和/或可水解基团的有机硅烷来制备; 然后将分散体的pH提高至至少8以形成纳米颗粒。它们可以用于有效的漆底漆/保护涂层制剂中。

3. 发明授权

US08372999B2 Organically modified silica and use thereof 有权
标题翻译：有机改性二氧化硅及其用途
公开(公告)号：US08372999B2
公开(公告)日：2013-02-12
申请号：US13360238
申请日：2012-01-27
申请人： Brian T. Holland , Ji Cui , Timothy S. Keizer
发明人： Brian T. Holland , Ji Cui , Timothy S. Keizer
IPC分类号： C07F7/10
CPC分类号： C07F7/1804 , C07B2200/11 , Y10T428/2982
摘要： Disclosed and claimed is a novel protective coating for metal surfaces. The protective coating includes one part by weight of the organosilane-modified silica nanoparticles made by the disclosed process and further includes from 0.3 to 3 parts by weight of the reaction product of (1) a compound comprising a polyamine in which a plurality of amine groups are bonded to at least one radical selected from the group consisting of hydrocarbon and hydrocarbon ether groups that separate nitrogen atoms of said amine groups by at least four intermediate atoms in a chain, and (2) a silane which carries a plurality of silicon-bonded hydrolyzable groups and a silicon-bonded organic group that is covalently reactive to and which bonds with said amine group, said silane also comprising hydrolyzable groups, to provide a reaction product molecule which comprises an average of 2.5 to 3.5 silane groups per molecule.
摘要翻译：公开并要求保护的是用于金属表面的新型保护涂层。保护涂层包括由所公开的方法制备的一份重量的有机硅烷改性二氧化硅纳米颗粒，并且还包括0.3至3重量份的（1）包含多胺的化合物的反应产物，其中多个胺基与至少一种选自烃和烃醚基团的基团键合，所述烃基和烃醚基团将所述胺基团的氮原子分成链中至少四个中间原子，和（2）硅烷，其携带多个硅键合可水解基团和与所述胺基共价反应并与其结合的硅键合的有机基团，所述硅烷还包含可水解基团，以提供包含平均每分子2.5至3.5个硅烷基团的反应产物分子。

4. 发明授权

US08106229B2 Organically modifid silica and use thereof 有权
标题翻译：有机二氧化硅及其用途
公开(公告)号：US08106229B2
公开(公告)日：2012-01-31
申请号：US11443515
申请日：2006-05-30
申请人： Brian T. Holland , Ji Cui , Timothy S. Keizer
发明人： Brian T. Holland , Ji Cui , Timothy S. Keizer
IPC分类号： C07F7/10
CPC分类号： C07F7/1804 , C07B2200/11 , Y10T428/2982
摘要： Organosilane-modified nanoparticles of silica, having a particle size of no more than 1 micron, in which the organosilane resides throughout the entire volume of the nanoparticles and not just at the surfaces of the nanoparticle. The nanoparticles may be in a colloidal solution. They may be prepared by hydrolyzing an alkali silicate under acidic conditions to obtain a silicic acid dispersion, followed by adding an organosilane having hydroxyl and/or hydrolyzable groups to the dispersion under acid conditions; and then raising the pH of the dispersion to at least eight to form the nanoparticles. They may be used in an effective paint primer/protective coating formulation.
摘要翻译：有机硅烷改性的二氧化硅纳米颗粒，其粒径不超过1微米，其中有机硅烷位于纳米颗粒的整个体积内，而不仅仅在纳米颗粒的表面。纳米颗粒可以是胶体溶液。它们可以通过在酸性条件下水解碱金属硅酸盐来获得硅酸分散体，然后在酸性条件下向分散体中加入具有羟基和/或可水解基团的有机硅烷来制备; 然后将分散体的pH提高至至少8以形成纳米颗粒。它们可以用于有效的漆底漆/保护涂层制剂中。

5. 发明申请

US20180221833A1 SYSTEMS AND METHODS TO NITROGEN-INFUSE AND DISPENSE BEVERAGES 审中-公开
公开(公告)号：US20180221833A1
公开(公告)日：2018-08-09
申请号：US15941869
申请日：2018-03-30
申请人： Robert D. Hyde , James G. Neighbors , Brian T. Holland , Jackie Fendley , Robert F. Hoskin
发明人： Robert D. Hyde , James G. Neighbors , Brian T. Holland , Jackie Fendley , Robert F. Hoskin
IPC分类号： B01F5/04 , A47J31/46 , A47J31/40 , A23L2/54 , B01F3/04 , B01F15/00 , B67D1/00
摘要： In a method for infusing a gas from a gas source into a liquid beverage, liquid beverage is driven from a beverage container into a liquid inlet port of a venturi mixing device. Nitrogen is infused into the liquid beverage by driving nitrogen through a gas inlet port of the venturi mixing device, thereby delivering nitrogen-infused liquid beverage to a discharge port of the venturi mixing device. The nitrogen-infused liquid beverage is poured from the discharge port through a faucet.

6. 发明授权

US07097031B2 Lubricious liners and methods for their use 有权
标题翻译：润滑衬垫及其使用方法
公开(公告)号：US07097031B2
公开(公告)日：2006-08-29
申请号：US10711428
申请日：2004-09-17
申请人： Brian T. Holland , Gregory T. Robitaille , Jim J. Hilarides
发明人： Brian T. Holland , Gregory T. Robitaille , Jim J. Hilarides
IPC分类号： B65G15/60
CPC分类号： B65G17/40 , B65G45/02 , B65G2201/0244 , B65G2201/0252
摘要： Conveyor systems and methods for transporting articles, such as containers, using the conveyor systems are provided. The conveyor systems include a lubricious liner adhesively attached to a surface of a conveyor or an article for transport on the conveyor, such that the liner is disposed between the article and the surface. The lubricious liners facilitate the transport of the articles by the conveyor systems.
摘要翻译：提供了使用输送机系统输送物品（例如容器）的输送系统和方法。输送机系统包括粘附在输送机表面上的润滑衬套或用于在输送机上运输的制品，使得衬垫设置在制品和表面之间。润滑衬垫有助于输送机系统运输物品。

7. 发明授权

US08003707B2 Metal-rich siliceous compositions and methods of producing same 有权
标题翻译：富含金属的硅质组合物及其制备方法
公开(公告)号：US08003707B2
公开(公告)日：2011-08-23
申请号：US12628472
申请日：2009-12-01
申请人： Brian T. Holland
发明人： Brian T. Holland
IPC分类号： B01F3/12
CPC分类号： B01J20/103 , B01J20/16 , B01J20/3236 , B01J23/44 , B01J23/66 , B01J23/70 , B01J27/13 , B01J29/049 , B01J35/0013 , B01J37/031 , B01J37/04 , B82Y30/00 , C01B33/141 , C01B33/151 , C01G55/00 , C01P2002/72 , C01P2004/64 , C01P2006/12 , C01P2006/14
摘要： A modified sol-gel method to create metal-rich siliceous material, such as colloidal silica or aluminosilicate particles is disclosed. Initially, the metal salt of choice is added to a silicic acid solution or a silicic acid solution containing aluminum salt. The aluminum is added to vary the metal-support interaction as it forms Al—O—Si linkages within the silica matrix. Besides aluminum, other metals can be added that form M—O—Si (M=Ti, B, etc.) linkages, which do not become reduced when treated with a reducing agent. Once the metal, silicic acid and/or aluminum salt is generated, it is subjected to colloidal growth by addition to a basic heel. Upon colloidal synthesis, the metal salt containing colloidal particle is left as is to maximize colloidal stability or is reduced with hydrazine to produce the zero valence metal-containing colloidal particle. Keeping a particle colloidal before use may be an effective method of forming a catalyst material as it can be easily spray-dried or mixed with other materials for extruded catalyst particles.
摘要翻译：公开了一种改进的溶胶 - 凝胶法制备富含硅的硅质材料，例如胶体二氧化硅或硅铝酸盐颗粒。首先，将所选择的金属盐加入到含有铝盐的硅酸溶液或硅酸溶液中。添加铝以改变金属 - 载体相互作用，因为它在二氧化硅基体内形成Al-O-Si键。除了铝之外，可以加入形成M-O-Si（M = Ti，B等）键的其它金属，当用还原剂处理时，其不会降低。一旦生成了金属，硅酸和/或铝盐，则通过加入到基础鞋跟中进行胶体生长。在胶体合成时，含有胶体颗粒的金属盐保持原样以最大化胶体稳定性，或者用肼还原以产生含零价金属的胶体颗粒。在使用前保持颗粒胶体可能是形成催化剂材料的有效方法，因为它可以容易地喷雾干燥或与挤出的催化剂颗粒的其它材料混合。

8. 发明申请

US20080108497A1 METAL-RICH SILICEOUS COMPOSITIONS AND METHODS OF PRODUCING SAME 审中-公开
标题翻译：金属矿物质组合物及其生产方法
公开(公告)号：US20080108497A1
公开(公告)日：2008-05-08
申请号：US11557548
申请日：2006-11-08
申请人： Brian T. Holland
发明人： Brian T. Holland
IPC分类号： C09K13/04 , B01J20/10 , C04B35/14 , B24D3/34
CPC分类号： B01J20/103 , B01J20/16 , B01J20/3236 , B01J23/44 , B01J23/66 , B01J23/70 , B01J27/13 , B01J29/049 , B01J35/0013 , B01J37/031 , B01J37/04 , B82Y30/00 , C01B33/141 , C01B33/151 , C01G55/00 , C01P2002/72 , C01P2004/64 , C01P2006/12 , C01P2006/14
摘要： A modified sol-gel method to create metal-rich siliceous material, such as colloidal silica or aluminosilicate particles is disclosed. Initially, the metal salt of choice is added to a silicic acid solution or a silicic acid solution containing aluminum salt. The aluminum is added to vary the metal-support interaction as it forms Al—O—Si linkages within the silica matrix. Besides aluminum, other metals can be added that form M-O—Si (M=Ti, B, etc.) linkages, which do not become reduced when treated with a reducing agent. Once the metal, silicic acid and/or aluminum salt is generated, it is subjected to colloidal growth by addition to a basic heel. Upon colloidal synthesis, the metal salt containing colloidal particle is left as is to maximize colloidal stability or is reduced with hydrazine to produce the zero valence metal-containing colloidal particle. Keeping a particle colloidal before use may be an effective method of forming a catalyst material as it can be easily spray-dried or mixed with other materials for extruded catalyst particles.
摘要翻译：公开了一种改进的溶胶 - 凝胶法制备富含硅的硅质材料，例如胶体二氧化硅或硅铝酸盐颗粒。首先，将所选择的金属盐加入到含有铝盐的硅酸溶液或硅酸溶液中。添加铝以改变金属 - 载体相互作用，因为它在二氧化硅基体内形成Al-O-Si键。除了铝之外，可以加入形成M-O-Si（M = Ti，B等）键的其它金属，当用还原剂处理时，其不会降低。一旦生成了金属，硅酸和/或铝盐，则通过加入到基础鞋跟中进行胶体生长。在胶体合成时，含有胶体颗粒的金属盐保持原样以使胶体稳定性最大化，或者用肼还原以产生含零价金属的胶体颗粒。在使用前保持颗粒胶体可能是形成催化剂材料的有效方法，因为它可以容易地喷雾干燥或与挤出的催化剂颗粒的其它材料混合。

9. 发明申请

US20100166692A1 METHOD FOR TREATING DAMAGED HAIR IN CONJUNCTION WITH THE RELAXING PROCESS 审中-公开
标题翻译：用于处理与松弛过程相关的损伤头发的方法
公开(公告)号：US20100166692A1
公开(公告)日：2010-07-01
申请号：US12346310
申请日：2008-12-30
申请人： Yin Z. Hessefort , Brian T. Holland , Jeffery M. Atkins , Sascha Weiz , Xiaojin Harry Li , Virginie Kompalitch
发明人： Yin Z. Hessefort , Brian T. Holland , Jeffery M. Atkins , Sascha Weiz , Xiaojin Harry Li , Virginie Kompalitch
IPC分类号： A61K8/81 , A61Q5/04
CPC分类号： A61K8/8147 , A61K8/8158 , A61K2800/5424 , A61Q5/04 , A61Q5/12
摘要： A method of treating one or more damaged hair shafts, each hair shaft including a cuticle layer and a cortex enclosed in the cuticle layer is disclosed. The method comprises: selecting one or more polymers that can penetrate the hair shafts with a pore size of about 5 angstroms to about 5000 angstroms; and treating the hair shafts by applying an effective amount of a composition containing said anionic polymers to said hair shafts.
摘要翻译：公开了一种处理一个或多个受损发根的方法，每个毛轴包括角质层和包围在角质层中的皮层。该方法包括：选择一种或多种可以以大约5埃至大约5000埃的孔径穿透毛干的聚合物; 以及通过将有效量的含有所述阴离子聚合物的组合物施用到所述毛干来处理毛干。

10. 发明申请

US20100074974A1 METAL-RICH SILICEOUS COMPOSITIONS AND METHODS OF PRODUCING SAME 有权
标题翻译：金属矿物质组合物及其生产方法
公开(公告)号：US20100074974A1
公开(公告)日：2010-03-25
申请号：US12628472
申请日：2009-12-01
申请人： Brian T. Holland
发明人： Brian T. Holland
IPC分类号： A61K8/25 , B01J23/56 , B01J23/44 , B01J21/08 , C09K13/00 , C09D1/00 , C07K1/14 , H01L21/461 , C12H1/048 , C09K8/74 , A61K8/00 , A61K8/04 , D21H21/00
CPC分类号： B01J20/103 , B01J20/16 , B01J20/3236 , B01J23/44 , B01J23/66 , B01J23/70 , B01J27/13 , B01J29/049 , B01J35/0013 , B01J37/031 , B01J37/04 , B82Y30/00 , C01B33/141 , C01B33/151 , C01G55/00 , C01P2002/72 , C01P2004/64 , C01P2006/12 , C01P2006/14
摘要： A modified sol-gel method to create metal-rich siliceous material, such as colloidal silica or aluminosilicate particles is disclosed. Initially, the metal salt of choice is added to a silicic acid solution or a silicic acid solution containing aluminum salt. The aluminum is added to vary the metal-support interaction as it forms Al—O—Si linkages within the silica matrix. Besides aluminum, other metals can be added that form M—O—Si (M=Ti, B, etc.) linkages, which do not become reduced when treated with a reducing agent. Once the metal, silicic acid and/or aluminum salt is generated, it is subjected to colloidal growth by addition to a basic heel. Upon colloidal synthesis, the metal salt containing colloidal particle is left as is to maximize colloidal stability or is reduced with hydrazine to produce the zero valence metal-containing colloidal particle. Keeping a particle colloidal before use may be an effective method of forming a catalyst material as it can be easily spray-dried or mixed with other materials for extruded catalyst particles.
摘要翻译：公开了一种改进的溶胶 - 凝胶法制备富含硅的硅质材料，例如胶体二氧化硅或硅铝酸盐颗粒。首先，将所选择的金属盐加入到含有铝盐的硅酸溶液或硅酸溶液中。添加铝以改变金属 - 载体相互作用，因为它在二氧化硅基体内形成Al-O-Si键。除了铝之外，可以加入形成M-O-Si（M = Ti，B等）键的其它金属，当用还原剂处理时，其不会降低。一旦生成了金属，硅酸和/或铝盐，则通过加入到基础鞋跟中进行胶体生长。在胶体合成时，含有胶体颗粒的金属盐保持原样以使胶体稳定性最大化，或者用肼还原以产生含零价金属的胶体颗粒。在使用前保持颗粒胶体可能是形成催化剂材料的有效方法，因为它可以容易地喷雾干燥或与挤出的催化剂颗粒的其它材料混合。

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