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1. 发明授权

US6080516A Fluorescent compositions and their use 失效
标题翻译：荧光成分及其用途
公开(公告)号：US6080516A
公开(公告)日：2000-06-27
申请号：US17870
申请日：1998-02-03
申请人： Brian Gerrard Devlin , Junji Otani , Kazuhiko Kunimoto , Takashi Deno , Abul Iqbal , Sameer Hosam Eldin
发明人： Brian Gerrard Devlin , Junji Otani , Kazuhiko Kunimoto , Takashi Deno , Abul Iqbal , Sameer Hosam Eldin
IPC分类号： H01L51/50 , C07D487/04 , C09B57/12 , C09B67/22 , C09B69/10 , C09K11/06 , H05B33/10 , G03F9/00 , C08K5/00 , G03C5/56
CPC分类号： C09B57/12 , C07D487/04 , C09B67/0033 , C09B69/109 , C09K11/06 , Y10S428/917
摘要： Solid-state fluorescent composition comprising at least one host chromophore selected from the group consisting of a benzo[4,5] imidazo[2,1-a]isoindol-11-ones and an effective amount of at least one guest chromophore, and if desired a polymer C, wherein the emission spectrum of the host chromophore overlaps with the absorption spectrum of the guest chromophore, and wherein (a1) the host chromophore is covalently linked to a polymer backbone A ("host polymer"), and/or (a2) the guest chromophore is covalently linked to a polymer backbone B ("guest polymer").
摘要翻译：固态荧光组合物，其包含至少一种选自苯并[4,5]咪唑并[2,1-a]异吲哚基-11-和有效量的至少一个客体发色团的主发色团，如果需要聚合物C，其中主发色团的发射光谱与客体发色团的吸收光谱重叠，并且其中（a1）主体发色团共价连接到聚合物主链A（“主体聚合物”）和/或（ a2）客体发色团与聚合物主链B（“客体聚合物”）共价连接。

2. 发明授权

US6146809A Fluorescent host-guest-system 失效
标题翻译：荧光主机 - 客机系统
公开(公告)号：US6146809A
公开(公告)日：2000-11-14
申请号：US17868
申请日：1998-02-03
申请人： Brian Gerrard Devlin , Junji Otani , Kazuhiko Kunimoto , Abul Iqbal , Sameer Hosam Eldin
发明人： Brian Gerrard Devlin , Junji Otani , Kazuhiko Kunimoto , Abul Iqbal , Sameer Hosam Eldin
IPC分类号： H01L51/50 , C07D487/04 , C09B57/12 , C09B67/22 , C09B69/10 , C09K11/06 , H05B33/10 , G03C1/73 , C07D235/04 , C08K5/3445 , G03C1/76
CPC分类号： C09B57/12 , C07D487/04 , C09B67/0033 , C09B69/109 , C09K11/06 , Y10S428/917
摘要： Composition comprising a solid organic support material to which either directly or via a bridging group, are covalently linked fluorescent host chromophores and fluorescent guest chromophores, wherein the fluorescence emission spectrum of the host chromophore overlaps with the absorption spectrum of the guest chromophore, wherein the host chromophore is selected from the group consisting of benzo[4,5]imidazo[2,11-a]isoindol-11-ones.
摘要翻译：包含直接或经由桥连基团的固体有机载体的组合物是共价连接的荧光宿主发色团和荧光客体发色团，其中主发色团的荧光发射光谱与客体发色团的吸收光谱重叠，其中主体发色团选自苯并[4,5]咪唑并[2,11-a]异吲哚-11-酮。

3. 发明授权

US06562981B2 Benzo (4,5) imidazo (2,1-a) isoindol-11-ones 失效
标题翻译：苯并（4,5）咪唑并（2,1-a）异吲哚-11-酮
公开(公告)号：US06562981B2
公开(公告)日：2003-05-13
申请号：US10135809
申请日：2002-04-30
申请人： Junji Otani , Kazuhiko Kunimoto , Takashi Deno , Brian Gerrard Devlin , Kunihiko Kodama
发明人： Junji Otani , Kazuhiko Kunimoto , Takashi Deno , Brian Gerrard Devlin , Kunihiko Kodama
IPC分类号： C07D23502
CPC分类号： C09B57/12 , C07D487/04 , C09B67/0033 , C09B69/109 , C09K11/06 , Y10S428/917
摘要： A composition comprising (a) an effective amount of a guest chromophore embedded in a matrix of a host chromophore, or (b) a host chromophore and an effective amount of a guest chromophore both embedded in a polymer matrix, wherein the absorption spectrum of the guest chromophore overlaps with the fluorescence emission spectrum of the host chromophore, and wherein the host chromophore is selected from the group consisting of benzo [4,5]imidazo[2,1-a]isoindol-11-ones.
摘要翻译：一种组合物，其包含（a）有效量的嵌入在主发色团的基质中的客体发色团，或（b）主体发色团和有效量的嵌入在聚合物基质中的客体发色团，其中所述吸收光谱客体发色团与主发色团的荧光发射光谱重叠，其中主发色团选自苯并[4,5]咪唑并[2,1-a]异吲哚-11-酮。

4. 发明授权

US06413655B2 Fluorescent materials and their use 失效
标题翻译：荧光材料及其用途
公开(公告)号：US06413655B2
公开(公告)日：2002-07-02
申请号：US09017872
申请日：1998-02-03
申请人： Junji Otani , Kazuhiko Kunimoto , Takashi Deno , Brian Gerrard Devlin , Kunihiko Kodama
发明人： Junji Otani , Kazuhiko Kunimoto , Takashi Deno , Brian Gerrard Devlin , Kunihiko Kodama
IPC分类号： H05B3314
CPC分类号： C09B57/12 , C07D487/04 , C09B67/0033 , C09B69/109 , C09K11/06 , Y10S428/917
摘要： A composition comprising (a) an effective amount of a guest chromophore embedded in a matrix of a host chromophore, or (b) a host chromophore and an effective amount of a guest chromophore both embedded in a polymer matrix, wherein the absorption spectrum of the guest chromophore overlaps with the fluorescence emission spectrum of the host chromophore, and wherein the host chromophore is selected from the group consisting of benzo [4,5] imidazo [2,1-a] isoindol-11-ones.
摘要翻译：一种组合物，其包含（a）有效量的嵌入在主发色团的基质中的客体发色团，或（b）主体发色团和有效量的嵌入在聚合物基质中的客体发色团，其中所述吸收光谱客体发色团与主发色团的荧光发射光谱重叠，其中主发色团选自苯并[4,5]咪唑并[2,1-a]异吲哚-11-酮。

5. 发明授权

US06274065B1 Process for the preparation of fluorescent compositions, fluorescent compositions and their use 失效
标题翻译：荧光组合物，荧光组合物及其用途的制备方法
公开(公告)号：US06274065B1
公开(公告)日：2001-08-14
申请号：US09017871
申请日：1998-02-03
申请人： Takashi Deno , Kunihiko Kodama , Abul Iqbal , Brian Gerrard Devlin
发明人： Takashi Deno , Kunihiko Kodama , Abul Iqbal , Brian Gerrard Devlin
IPC分类号： C09K1106
CPC分类号： C09B57/12 , C07D487/04 , C09B67/0033 , C09B69/109 , C09K11/06 , Y10S428/917
摘要： Preparation of a solid fluorescent composition comprising (1) mixing a host chromophore and an effective amount of a pigment precursor in a solvent, then generating a pigment as guest chromophore in-situ from the pigment precursor, and, subsequently, isolating the mixture of the host and guest chromophores, thereby forming a solid solution, or (2) mixing a polymer as a matrix or a polymer precursor and a pigment precursor in a solvent, if desired in the presence of a chromophore being a host component, then generating a pigment in-situ from the pigment precursor (being the guest component if a host component is present), and, subsequently, isolating the mixture of polymer and pigment, and—if present—the host component, thereby forming a solid solution, wherein in all cases where there is a host component, the absorption spectrum of the pigment (guest chromophore) overlaps with the fluorescence emission spectrum of the host chromophore.
摘要翻译：固体荧光组合物的制备，其包括（1）将主发色团和有效量的颜料前体混合在溶剂中，然后从颜料前体原位生成作为客体发色团的颜料，随后将主体和客体发色团，从而形成固体溶液，或（2）如果需要，在作为主体组分的发色团存在下，将溶剂中的基质或聚合物前体和颜料前体的聚合物混合，然后产生颜料从颜料前体原位（如果存在主体组分，则是客体组分），然后分离聚合物和颜料的混合物，如果存在的话，分离出主体组分，从而形成固溶体，其中在所有存在主体成分的情况下，颜料（客体发色团）的吸收光谱与主发色团的荧光发射光谱重叠。

6. 发明授权

US6103446A Fluorescent chromophore, covalently linked to an organic support material 失效
标题翻译：与有机载体材料共价连接的荧光发色团
公开(公告)号：US6103446A
公开(公告)日：2000-08-15
申请号：US17869
申请日：1998-02-03
申请人： Brian Gerrard Devlin , Junji Otani , Kazuhiko Kunimoto
发明人： Brian Gerrard Devlin , Junji Otani , Kazuhiko Kunimoto
IPC分类号： H01L51/50 , C07D487/04 , C09B57/12 , C09B67/22 , C09B69/10 , C09K11/06 , H05B33/10 , G03C1/72 , G03C1/73
CPC分类号： C09B57/12 , C07D487/04 , C09B67/0033 , C09B69/109 , C09K11/06 , Y10S428/917
摘要： A composition comprising a solid organic support material to which are either directly, or via a bridging group, covalently linked fluorescent chromophores, characterized in that the chromophores are selected from the group consisting of benzo[4,5]imidazo[2,1-a]isoindol-11-ones.
摘要翻译：一种包含固体有机载体材料的组合物，其直接或经由桥连基团共价连接的荧光发色团，其特征在于所述发色团选自苯并[4,5]咪唑并[2,1-a ]异吲哚-11-酮。

7. 发明授权

US07795359B2 Continuous process for production of polymeric materials 有权
标题翻译：生产聚合物材料的连续工艺
公开(公告)号：US07795359B2
公开(公告)日：2010-09-14
申请号：US11365546
申请日：2006-03-01
申请人： Brian Gerrard Devlin , Troy V. Holland , Dawn Alison Smith , Alexander Azzawi
发明人： Brian Gerrard Devlin , Troy V. Holland , Dawn Alison Smith , Alexander Azzawi
IPC分类号： C08F2/00 , C08G85/00
CPC分类号： B01J19/0093 , B01J2219/00006 , B01J2219/0004 , B01J2219/00835 , B01J2219/00873 , B01J2219/00889 , B01J2219/00932 , B01J2219/00984 , C08F2/01 , C08F2/04 , C08G18/0895 , C08G18/5024 , C08G18/6685
摘要： The invention provides a continuous-flow process for producing a polymeric material. The process of the invention comprises the steps of: introducing at least two solutions, each comprising one or more reactants, into a microreactor to mix the two solutions to form a reacting solution, wherein the one or more reactants are selected from the group consisting of a monomer, an initiator, a coupling agent, a prepolymer, a macromer, and mixtures thereof; feeding continuously the reacting solution into a flow-through polymerization reactor in a coil form, wherein the flow-through polymerization reactor is capable of providing a residence time sufficient for (co)polymerizing the reactants to form a polymer with a desired polydispersity, wherein the flow-through polymerization reactor is immersed in an ultrasonic bath to minimize or substantially eliminate unwanted high-molecular-weight fractions of the polymer.
摘要翻译：本发明提供了用于生产聚合物材料的连续流动方法。本发明的方法包括以下步骤：将至少两种各自包含一种或多种反应物的溶液引入微反应器以混合两种溶液以形成反应溶液，其中一种或多种反应物选自单体，引发剂，偶联剂，预聚物，大分子单体及其混合物; 将反应溶液连续进料到线圈形式的流通聚合反应器中，其中流通聚合反应器能够提供足够的（共）聚合反应物以形成具有所需多分散性的聚合物的停留时间，其中将流通聚合反应器浸入超声波浴中以最小化或基本上消除聚合物的不需要的高分子量级分。

8. 发明授权

US08318059B2 Stabilization of poly(oxyalkylene) containing polymeric materials 有权
标题翻译：含聚（氧化烯）的聚合材料的稳定化
公开(公告)号：US08318059B2
公开(公告)日：2012-11-27
申请号：US12456409
申请日：2009-06-16
申请人： Brian Gerrard Devlin , Arturo Norberto Medina , Karen Belinda Sentell , Stephen Raymond Perreault , Mireille Tena
发明人： Brian Gerrard Devlin , Arturo Norberto Medina , Karen Belinda Sentell , Stephen Raymond Perreault , Mireille Tena
IPC分类号： B29C71/00
CPC分类号： C08L75/14 , A61L27/18 , C08G18/5024 , C08G18/6685 , C08G18/71 , C08G2120/00 , C08K3/32 , C08K5/092 , C08K5/098 , C08K5/175 , C08L71/02 , C08L2203/02 , C08L2666/04
摘要： The present invention provides a method for producing a medical device, preferably an ophthalmic device, more preferably a contact lens, made of a stabilized poly(oxyalkylene)-containing polymeric material. The method of the invention comprises the steps of: curing, in a mold, a composition comprising (a) a prepolymer having at least one poly(oxyalkylene) unit, (b) a biocompatible organic multi-acid or biocompatible salt thereof in an amount sufficient to improve the stability of the poly(oxyalkylene)-containing polymer made from the composition, (c) optionally a photoinitiator or a thermal initiator, and (d) optionally one or more vinylic monomers, to form the medical device being less susceptible to oxidative degradation; and removing the medical device from the mold.
摘要翻译：本发明提供了一种用于制造医疗装置的方法，优选为由具有稳定的聚（氧化烯））聚合物材料制成的眼科装置，更优选隐形眼镜。本发明的方法包括以下步骤：在模具中固化组合物，其包含（a）具有至少一个聚（氧化烯）单元的预聚物，（b）生物相容性有机多酸或其生物相容性盐的量足以提高由组合物制备的聚（氧化烯）聚合物的稳定性，（c）任选的光引发剂或热引发剂，和（d）任选的一种或多种乙烯型单体，以形成不易受氧化降解; 并从模具中取出医疗装置。

9. 发明申请

US20110230588A1 METHOD FOR MAKING CONTACT LENSES 审中-公开
标题翻译：制造接触镜的方法
公开(公告)号：US20110230588A1
公开(公告)日：2011-09-22
申请号：US13114338
申请日：2011-05-24
申请人： Brian Gerrard Devlin , Mireille Tena , Norberto Arturo Medina
发明人： Brian Gerrard Devlin , Mireille Tena , Norberto Arturo Medina
IPC分类号： G02C7/04 , C08L29/04 , C08L75/16 , C08L75/02
CPC分类号： B29D11/0099 , B29C35/0894 , B29C2035/0827 , B29C2035/0833 , B29D11/00057 , B29D11/00125 , B29L2011/0041
摘要： The instant invention pertains to a method and a fluid composition for producing contact lenses with relatively high edge quality and with relatively high precision and fidelity in reproducing a desired lens design. The method of the invention involves: a mold which has a first mold half with a first molding surface and a second mold half with a second molding surface, wherein the first and second mold halves are configured to receive each other such that the cavity is formed between the first and second molding surfaces which define the opposite two surfaces of a contact lens to be produced; a spatial limitation of actinic radiation to define the edge of the contact lens to be produced; and addition of a radical scavenger in a fluid composition comprising a lens-forming material to reduce substantially the crosslinking/polymerizing, caused by diffused, scattered and/or reflected incident actinic radiation, of the fluid composition outside of and around the spatial limitation of actinic radiation.
摘要翻译：本发明涉及一种用于制造具有相对高的边缘质量并且在再现期望的透镜设计时具有相对高的精度和保真度的隐形眼镜的方法和流体组合物。本发明的方法包括：模具，其具有具有第一模制表面的第一模具半部和具有第二模制表面的第二模具半部，其中第一和第二半模构造成彼此接收，使得形成空腔在限定待制造的隐形眼镜的相对的两个表面的第一和第二模制表面之间; 光化辐射的空间限制，以限定要产生的隐形眼镜的边缘; 以及在包含透镜形成材料的流体组合物中添加自由基清除剂，以减少由光化学的空间限制之外和周围的流体组合物的扩散，散射和/或反射入射光化辐射引起的交联/聚合辐射。

10. 发明申请

US20090263278A1 Stabilization of poly(oxyalkylene) containing polymeric materials 有权
标题翻译：含聚（氧化烯）的聚合材料的稳定化
公开(公告)号：US20090263278A1
公开(公告)日：2009-10-22
申请号：US12456409
申请日：2009-06-16
申请人： Brian Gerrard Devlin , Arturo Norberto Medina , Karen Belinda Sentell , Stephen Raymond Perreault , Mireille Tena
发明人： Brian Gerrard Devlin , Arturo Norberto Medina , Karen Belinda Sentell , Stephen Raymond Perreault , Mireille Tena
IPC分类号： A61L2/18
CPC分类号： C08L75/14 , A61L27/18 , C08G18/5024 , C08G18/6685 , C08G18/71 , C08G2120/00 , C08K3/32 , C08K5/092 , C08K5/098 , C08K5/175 , C08L71/02 , C08L2203/02 , C08L2666/04
摘要： The present invention provides a method for producing a medical device, preferably an ophthalmic device, more preferably a contact lens, made of a stabilized poly(oxyalkylene)-containing polymeric material. The method of the invention comprises the steps of: curing, in a mold, a composition comprising (a) a prepolymer having at least one poly(oxyalkylene) unit, (b) a biocompatible organic multi-acid or biocompatible salt thereof in an amount sufficient to improve the stability of the poly(oxyalkylene)-containing polymer made from the composition, (c) optionally a photoinitiator or a thermal initiator, and (d) optionally one or more vinylic monomers, to form the medical device being less susceptible to oxidative degradation; and removing the medical device from the mold.
摘要翻译：本发明提供了一种用于制造医疗装置的方法，优选为由具有稳定的聚（氧化烯））聚合物材料制成的眼科装置，更优选隐形眼镜。本发明的方法包括以下步骤：在模具中固化组合物，其包含（a）具有至少一个聚（氧化烯）单元的预聚物，（b）生物相容性有机多酸或其生物相容性盐的量足以提高由组合物制备的聚（氧化烯）聚合物的稳定性，（c）任选的光引发剂或热引发剂，和（d）任选的一种或多种乙烯型单体，以形成不易受氧化降解; 并从模具中取出医疗装置。

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