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1. 发明授权

US4355192A Process for the production of ethanol and n-propanol from methanol 失效
标题翻译：从甲醇生产乙醇和正丙醇的方法
公开(公告)号：US4355192A
公开(公告)日：1982-10-19
申请号：US328984
申请日：1981-12-09
申请人： Boy Cornils , Carl D. Frohning , Gerhard Diekhaus , Ernst Wiebus , Helmut Bahrmann
发明人： Boy Cornils , Carl D. Frohning , Gerhard Diekhaus , Ernst Wiebus , Helmut Bahrmann
IPC分类号： B01J31/00 , B01J31/30 , C07B61/00 , C07C27/00 , C07C29/32 , C07C31/02 , C07C31/08 , C07C31/10 , C07C67/00 , C07C29/00
CPC分类号： B01J31/185 , B01J27/128 , B01J27/13 , B01J31/24 , B01J31/2404 , B01J31/2409 , C07C29/32 , B01J2231/34 , B01J2231/641 , B01J2531/828 , B01J2531/845 , B01J27/10 , B01J31/30 , Y02P20/52
摘要： In a process for the production of ethanol and n-propanol by conversion of methanol with carbon monoxide and hydrogen in the presence of a catalyst containing cobalt, platinum, at least one halogen or halide, and an organic phosphine or phosphite, the improvement comprising the halogen or halide being chlorine or a chloride, and the phosphine or phosphite being bidentate. In addition, the conversion is carried out at pressures of 200 to 800 bars in the presence of 5 to 25% by weight of water, based on the methanol.
摘要翻译：在含有钴，铂，至少一种卤素或卤化物的催化剂和有机膦或亚磷酸酯存在下，通过甲醇与一氧化碳和氢气的转化来生产乙醇和正丙醇的方法，其改进包括卤素或卤化物是氯或氯化物，并且膦或亚磷酸酯是二齿的。此外，基于甲醇，在5至25重量％的水的存在下，在200至800巴的压力下进行转化。

2. 发明授权

US4424383A Process for producing ethanol and n-propanol from methanol 失效
标题翻译：从甲醇生产乙醇和正丙醇的方法
公开(公告)号：US4424383A
公开(公告)日：1984-01-03
申请号：US320008
申请日：1981-11-10
申请人： Boy Cornils , Carl D. Frohning , Gerhard Diekhaus , Ernst Wiebus , Helmut Bahrmann
发明人： Boy Cornils , Carl D. Frohning , Gerhard Diekhaus , Ernst Wiebus , Helmut Bahrmann
IPC分类号： B01J31/00 , B01J31/24 , B01J31/30 , C07B61/00 , C07C27/00 , C07C29/32 , C07C31/02 , C07C31/08 , C07C31/10 , C07C67/00 , C07C29/00
CPC分类号： B01J31/185 , B01J31/1865 , B01J31/2404 , B01J31/2409 , B01J31/2476 , B01J31/26 , C07C29/32 , C12C11/02 , B01J2231/641 , B01J2531/02 , B01J2531/821 , B01J2531/845
摘要： A method for the production of ethanol or propanol comprising the reaction of methanol with carbon monoxide and hydrogen in the presence of a catalyst. The catalyst contains a cobalt compound, a ruthenium compound, iodine or an iodide, and a bi-dentate organic phosphine or phosphite. The reaction is carried out at 150.degree. to 250.degree. C., 200 to 600 bars, and in the presence of 5 to 25% by weight of water, based on the methanol.
摘要翻译：包括在催化剂存在下包括甲醇与一氧化碳和氢气的反应的乙醇或丙醇的制备方法。催化剂含有钴化合物，钌化合物，碘或碘化物，以及双齿有机膦或亚磷酸酯。该反应在150℃至250℃，200至600巴下进行，并在5至25重量％的水的存在下，基于甲醇进行。

3. 发明授权

US4337363A Process for the preparation of 3-(4-methyl-3-cyclohexen-1-yl) butyraldehyde 失效
标题翻译： 3-（4-甲基-3-环己烯-1-基）丁醛的制备方法
公开(公告)号：US4337363A
公开(公告)日：1982-06-29
申请号：US69659
申请日：1979-08-24
申请人： Helmut Bahrmann , Boy Cornils , Carl D. Frohning , Jurgen Weber
发明人： Helmut Bahrmann , Boy Cornils , Carl D. Frohning , Jurgen Weber
IPC分类号： B01J31/00 , C07B61/00 , C07C45/00 , C07C45/50 , C07C47/225 , C07C67/00
CPC分类号： C07C45/50
摘要： In a process for the preparation of 3-(4-methyl-3-cyclohexen-1-yl) butyraldehyde by hydroformylation of limonene in the presence of a catalyst containing a metal of Group VIII of the Periodic Table, the improvement wherein a rhodium carbonyl complex containing additionally a triphenyl and/or trialkyl phosphine as ligands is used as catalyst and the reaction is conducted at a pressure of 100 to 350 bars and at a temperature of 110.degree. to 160.degree. C., the triphenyl or trialkyl phosphines or mixture thereof being present in an amount of 10 to 50 moles per gram atom of rhodium in the reaction mixture.
摘要翻译：在通过在含有元素周期表第Ⅷ族金属的催化剂的存在下，通过柠檬烯的加氢甲酰化制备3-（4-甲基-3-环己烯-1-基）丁醛的方法，其中铑羰基使用另外含有三苯基和/或三烷基膦作为配体的络合物用作催化剂，反应在100至350巴的压力和110至160℃的温度下进行，三苯基或三烷基膦或其混合物在反应混合物中以每克原子的铑含量为10至50摩尔。

4. 发明授权

US5410072A Mixtures of isomeric pentanoic acids, esters prepared therefrom, and their use as lubricants 失效
标题翻译：异构戊酸的混合物，由其制备的酯及其作为润滑剂的用途
公开(公告)号：US5410072A
公开(公告)日：1995-04-25
申请号：US311557
申请日：1994-09-23
申请人： Helmut Bahrmann , Wolfgang Greb , Georg Dambkes , Peter Heymanns , Heinz Kalbfell , Peter Lappe , Helmut Springer , Eberhard von Mulmann , Jurgen Weber , Ernst Wiebus , Carl D. Frohning , Harald Kappesser
发明人： Helmut Bahrmann , Wolfgang Greb , Georg Dambkes , Peter Heymanns , Heinz Kalbfell , Peter Lappe , Helmut Springer , Eberhard von Mulmann , Jurgen Weber , Ernst Wiebus , Carl D. Frohning , Harald Kappesser
IPC分类号： B01J31/24 , C07B61/00 , C07C45/50 , C07C51/235 , C07C53/126 , C07C53/128 , C07C69/22 , C07C69/33 , C10M105/32 , C10M105/34 , C10M105/38 , C10M171/00 , C10N40/30 , C10N70/00
CPC分类号： C10M171/008 , C07C45/50 , C07C53/126 , C07C53/128 , C10M105/38 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/022 , C10M2211/06 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： Isomeric mixtures of pentanoic acids are prepared by subjecting butene-1/butene-2 mixtures to hydroformylation to form aldehyde mixtures, followed by oxidation of the aldehyde mixtures which have been separated off from the reaction product. The hydroformylation is carried out in a heterogeneous system in the presence of rhodium catalysts which are dissolved in water. The mixture of isomeric 5 carbon monocarboxylic acids produced, when esterified with polyhydric alcohols, yields mixtures of isomeric esters which are useful as lubricants for refrigerant compressors operated with chlorine-free, at least partly fluorinated hydrocarbons as the refrigerant.
摘要翻译：戊烯的异构混合物是通过使丁烯-1 /丁烯-2混合物进行加氢甲酰化形成醛混合物，然后氧化从反应产物中分离的醛混合物来制备的。加氢甲酰化在异相体系中在溶解在水中的铑催化剂存在下进行。当用多元醇酯化时，产生异构体5碳一元羧酸的混合物产生异构酯的混合物，其可用作用于无氯，至少部分氟化的烃作为制冷剂的制冷剂压缩机的润滑剂。

5. 发明授权

US5498587A Hydrogenation catalyst, a process for its preparation, and use thereof 失效
标题翻译：氢化催化剂，其制备方法及其用途
公开(公告)号：US5498587A
公开(公告)日：1996-03-12
申请号：US217151
申请日：1994-03-24
申请人： Gregor Deckers , Gerhard Diekhaus , Bernd Dorsch , Carl D. Frohning , Gerhardt Horn , Horst B. Horrig
发明人： Gregor Deckers , Gerhard Diekhaus , Bernd Dorsch , Carl D. Frohning , Gerhardt Horn , Horst B. Horrig
IPC分类号： B01J21/16 , B01J23/755 , B01J23/78 , B01J32/00 , B01J35/10 , B01J37/18 , C07B61/00 , C07C29/141 , C07C31/10 , C07C31/12 , C09K3/00 , B01J21/10 , B01J23/04
CPC分类号： B01J35/10 , B01J23/755 , B01J23/78 , C07C29/141 , C07C31/10 , C07C31/12 , B01J35/0053 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/108
摘要： A hydrogenation catalyst comprising 25 to 50% by weight of nickel (metallic) 10 to 35% by weight of nickel oxide 4 to 12% by weight of magnesium oxide 1 to 5% by weight of sodium oxide the remainder being a water-insoluble support material,wherein the total of nickel and nickel oxide is 40% to 70% by weight, and the catalyst has a surface area, determined by BET, of 80 to 200 m.sup.2 /g and a total pore volume of 0.35 to 0.6 ml/g. The total pore volume is made up of 30% to 60% by volume from pores having pore radii of .ltoreq.40 .ANG., 4% to 10% by volume from pores having pore radii of >40 to 300 .ANG., and 30% to 60% by volume from pores having pore radii of >300 to 5000 .ANG..A process for preparing the hydrogenation catalyst which comprises preparing, in a precipitation step, a green catalyst from a nickel salt, a magnesium salt, sodium carbonate, and the support material, separating off the mother liquor and partially washing the precipitate, slurrying the green catalyst in alkali solution, separating it from the liquid phase, drying it, and contacting the dried green catalyst with hydrogen until 48% to 86% by weight of the total nickel content is present in metallic form.The hydrogenation catalyst of the invention is particularly suitable for the hydrogenation of propanal, n-butanal, and i-butanal, especially at temperatures between 100.degree. and 160.degree. C.
摘要翻译：一种氢化催化剂，其包含25-50％重量的镍（金属），10-35％（重量）的氧化镍，4至12％（重量）的氧化镁，1至5％（重量）的氧化钠，其余为不溶于水的载体材料，其中镍和氧化镍的总量为40重量％至70重量％，并且催化剂具有由BET测定的表面积为80至200m 2 / g，总孔体积为0.35至0.6ml / g 。总孔体积由孔径为40μm〜40μm的孔径为4〜10体积％的孔径为30〜60体积％，孔径为40〜300埃的孔径为30〜 60％体积的孔径为> 300至5000的孔。一种制备氢化催化剂的方法，包括在沉淀步骤中，从镍盐，镁盐，碳酸钠和载体材料中制备绿色催化剂，分离母液并部分洗涤沉淀物，将绿色碱性溶液中的催化剂，将其与液相分离，干燥，并将干燥的生坯催化剂与氢气接触，直到总镍含量的48重量％至86重量％以金属形式存在。本发明的氢化催化剂特别适用于丙醛，正丁醛和异丁醛的加氢，特别是在100至160℃的温度下。

6. 发明授权

US5600030A Hydrogenation catalyst, a process for its preparation and use thereof 失效
标题翻译：氢化催化剂，其制备方法和用途
公开(公告)号：US5600030A
公开(公告)日：1997-02-04
申请号：US437354
申请日：1995-05-09
申请人： Gregor Deckers , Gerhard Diekhaus , Bernd Dorsch , Carl D. Frohning , Gerhardt Horn , Horst B. Horrig
发明人： Gregor Deckers , Gerhard Diekhaus , Bernd Dorsch , Carl D. Frohning , Gerhardt Horn , Horst B. Horrig
IPC分类号： B01J21/16 , B01J23/755 , B01J23/78 , B01J32/00 , B01J35/10 , B01J37/18 , C07B61/00 , C07C29/141 , C07C31/10 , C07C31/12 , C09K3/00 , C07C27/06
CPC分类号： B01J35/10 , B01J23/755 , B01J23/78 , C07C29/141 , C07C31/10 , C07C31/12 , B01J35/0053 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/108
摘要： A process for hydrogenation of an aldehyde selected from the group consisting of propanal, n-butanal, and i-butanal comprising contacting said aldehyde with hydrogen in the presence of a hydrogenation catalyst comprising in the reduced state25% to 50% by weight of metallic nickel10% to 35% by weight of nickel oxide4% to 12% by weight of magnesium oxide1% to 5% by weight of sodium oxidethe remainder being a water insoluble support material, wherein the total of said nickel and said nickel oxide is 40% to 70% by weight based on said catalyst, said catalyst having a total BET surface area of 80 to 200 m.sup.2 /g and a total pore volume, determined by mercury porosimetry, of 0,35 to 0.6 ml/g,said total volume consisting of 30% to 60% of said volume from pores having pore radii equal to or less than 40 .ANG., 4% to 10% of said volume from pores having pore radii from more than 40 .ANG. to 300 .ANG., and 30% to 60% of said volume from pores having pore radii from more than 300 .ANG. to 5000 .ANG..
摘要翻译：一种氢化选自丙醛，正丁醛和异丁醛的醛的方法，包括在氢化催化剂存在下使所述醛与氢接触，所述氢化催化剂包含25％至50％重量的金属镍10〜35重量％的氧化镍4重量％至12重量％的氧化镁1重量％至5重量％的氧化钠，其余为水不溶性载体材料，其中所述镍和所述氧化镍的总量为基于所述催化剂的40〜70重量％，所述催化剂的总BET表面积为80〜200m 2 / g，通过水银孔率法测定的总孔体积为0.355〜0.6ml / g，所述总体积由孔半径等于或小于40的孔的所述体积的30％至60％组成，所述孔的4％至10％来自具有孔径半径从40多个ANGSTROM至300 ANGSTROM的孔，以及30％至超过300 ANG的孔半径的孔的至少60％ STROM到5000 ANGSTROM。

7. 发明授权

US5550297A Process for the preparation of alcohols or amines 失效
标题翻译：制备醇或胺的方法
公开(公告)号：US5550297A
公开(公告)日：1996-08-27
申请号：US390375
申请日：1995-02-16
申请人： Gerhardt Horn , Carl D. Frohning
发明人： Gerhardt Horn , Carl D. Frohning
IPC分类号： B01J23/80 , B01J23/84 , B01J23/847 , B01J23/85 , B01J23/889 , B01J35/10 , C07B61/00 , C07C29/149 , C07C29/17 , C07C31/125 , C07C209/48 , C07C211/03 , C07C209/14
CPC分类号： B01J37/031 , B01J23/80 , B01J23/84 , B01J35/0053 , C07C209/48 , C07C29/149 , C07C29/177 , B01J35/1014 , B01J35/1019
摘要： A process for catalytic preparation of alcohols or amines by reaction of esters, fatty acids, or nitriles with hydrogen at elevated temperature and pressure. The unreduced catalyst contains, per 100 parts by weight of CuO, 40 to 130 parts by weight of ZnO, 2 to 50 parts by weight of Al.sub.2 O.sub.3, and optionally 0.5 to 8 parts by weight of oxide of Mn, Mo, V, Zr, and/or alkaline earth metal. It has a BET total area of 80 to 175 m.sup.2 /g of catalyst in the unreduced state, and 75% to 95% of the BET total area is formed by pores having a radius r.sub.p .ltoreq.15 nm.
摘要翻译：在高温和高压下通过酯，脂肪酸或腈与氢反应来催化制备醇或胺的方法。未还原的催化剂相对于100重量份的CuO含有40〜130重量份的ZnO，2〜50重量份的Al 2 O 3，以及任选的0.5〜8重量份的Mn，Mo，V，Zr，和/或碱土金属。在未还原状态下，BET总面积为80〜175m2 / g，催化剂的总面积为75％〜95％，由半径rp <15nm的孔形成。

8. 发明授权

US4564642A Process for the manufacture of unsaturated hydrocarbons 失效
标题翻译：不饱和烃的制备方法
公开(公告)号：US4564642A
公开(公告)日：1986-01-14
申请号：US321086
申请日：1981-11-13
申请人： Bernd Bussemeier , Carl D. Frohning , Gerhardt Horn , Werner Kluy
发明人： Bernd Bussemeier , Carl D. Frohning , Gerhardt Horn , Werner Kluy
IPC分类号： C07C1/04 , B01J23/00 , B01J23/74 , B01J23/80 , C07B61/00 , C07C1/00 , C07C1/02 , C07C11/02 , C07C67/00
CPC分类号： B01J23/80 , B01J23/74 , C07C1/02 , C07C2521/06 , C07C2523/12 , C07C2523/745 , C07C2523/75 , C07C2523/78 , C07C2523/80 , C07C2523/83
摘要： A process for the production of unsaturated hydrocarbons by the catalytic hydrogenation of carbon monoxide is disclosed wherein the reaction takes place in the presence of a catalyst containing an oxide of a first metal selected from the transition metals of Group IV and a second metal selected from Group VIII of the periodic table. The reaction takes place at a reaction temperature of between about 250.degree. C. and 350.degree. C. and a reaction pressure of between about 10 and 30 bar.
摘要翻译：公开了一种通过一氧化碳的催化氢化生产不饱和烃的方法，其中反应在含有选自第IV族的过渡金属的第一种金属的氧化物和选自组中的第二种金属的催化剂存在下进行八，周期表。反应在约250℃至350℃的反应温度和约10至30巴之间的反应压力下进行。

9. 发明授权

US5475161A Process for the preparation of alcohols in two stages 失效
标题翻译：两阶段制备醇的方法
公开(公告)号：US5475161A
公开(公告)日：1995-12-12
申请号：US824745
申请日：1992-01-17
申请人： Gerhardt Horn , Carl D. Frohning , Hans Liebern , Wolfgang Zgorzelski
发明人： Gerhardt Horn , Carl D. Frohning , Hans Liebern , Wolfgang Zgorzelski
IPC分类号： B01J23/755 , B01J23/86 , C07B61/00 , C07C29/141 , C07C29/145 , C07C29/17 , C07C31/02 , C07C29/136 , C07C29/14
CPC分类号： C07C29/141 , C07C29/145 , C07C29/172
摘要： A process for the preparation of alcohols by reaction of organic carbonyl compounds with hydrogen in two stages at elevated temperature and, optionally, elevated pressure. In the first stage, hydrogen and the carbonyl compounds are fed as a gas to a copper-containing catalyst and reacted to 80 to 99.5 percent of the theoretical conversion. In the second stage, the reaction product of the first stage is fed to a nickel/alumina/zirconium dioxide catalyst as a liquid, along with hydrogen. The carbonyl compounds used include aldehydes and their derivatives and, in particular, aliphatic unsaturated and saturated aldehydes.
摘要翻译：通过有机羰基化合物与氢在升高的温度和任选的高压下两步反应制备醇的方法。在第一阶段，将氢气和羰基化合物作为气体加入到含铜催化剂中，并反应至理论转化率的80-99.5％。在第二阶段中，将第一阶段的反应产物与氢一起作为液体加入到镍/氧化铝/二氧化锆催化剂中。所用的羰基化合物包括醛及其衍生物，特别是脂族不饱和醛和饱和醛。

10. 发明授权

US5155084A Supported catalysts and a process for their preparation 失效
标题翻译：支持的催化剂及其制备方法
公开(公告)号：US5155084A
公开(公告)日：1992-10-13
申请号：US743193
申请日：1991-08-09
申请人： Gerhardt Horn , Carl D. Frohning
发明人： Gerhardt Horn , Carl D. Frohning
IPC分类号： B01J23/74 , B01J23/755 , B01J23/78 , B01J35/10 , B01J37/03 , C07B61/00 , C07C5/03 , C07C5/10
CPC分类号： B01J23/755 , B01J35/10 , B01J37/03 , B01J23/78 , B01J35/0053 , B01J35/1019 , B01J35/108
摘要： Supported catalysts containing nickel, magnesium oxide and, if desired, further additives, which contain reduced Mg and Ni in a molar ratio of (0.0075 to 0.075):1. The catalyst also have an active nickel metal surface area of 110 to 180 m.sup.2 /g of Ni, and a BET total surface area of 160 to 450 m.sup.2 /g. The invention furthermore relates to a process for the preparation of the catalysts and to their use as catalysts for the hydrogenation of aliphatic and/or aromatic hydrocarbons.
摘要翻译：含有镍，氧化镁和（如果需要的话）其它添加剂的负载催化剂，其中摩尔比为（0.0075-0.075）:1的还原的Mg和Ni。该催化剂还具有110至180m 2 / g Ni的活性镍金属表面积，BET总表面积为160至450m 2 / g。本发明还涉及制备催化剂的方法及其作为用于脂族和/或芳族烃氢化的催化剂的用途。

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